Alkali Metal Ions Dictate the Structure and Reactivity of an Iron(II) Imido Complex

Gao, Yafei; Pink, Maren; Smith, Jeremy M.

doi:10.1021/jacs.1c11429

Title: Alkali Metal Ions Dictate the Structure and Reactivity of an Iron(II) Imido Complex

Journal Article · 24 January 2022 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.1c11429 · OSTI ID:1903365

^[1]; Pink, Maren ^[2];

^[2]

Indiana Univ., Bloomington, IN (United States); Indiana University
Indiana Univ., Bloomington, IN (United States)

The presence of redox innocent metal ions has been proposed to modulate the reactivity of metal ligand multiple bonds; however, insight from structure/function relationships is limited. Here, alkali metal reduction of the Fe(III) imido complex [Ph₂B(^tBuIm)₂Fe=NDipp] (1) provides the series of structurally characterized Fe(II) imido complexes [Ph₂B(^tBuIm)₂Fe=NDippLi(THF)₂] (2), [Ph₂B(^tBuIm)₂Fe=NDippNa(THF)₃] (3), and [Ph₂B(^tBuIm)₂Fe=NDippK]₂ (4), in which the alkali metal cations coordinate the imido ligand. Structural investigations demonstrate that the alkali metal ions modestly lengthen the Fe=N bond distance from that in the charge separated complex [Ph₂B(^tBuIm)₂Fe=NDipp][K(18-C-6)THF₂] (5), with the longest bond observed for the smallest alkali metal ion. In contrast to 5, the imido ligands in 2–4 can be protonated and alkylated to afford Fe(II) amido complexes. Combined experimental and computational studies reveal that the alkali metal polarizes the Fe=N bond, and the basicity of imido ligand increases according to 5 < 4 ≈ 3 < 2. The basicity of the imido ligands influences the relative rates of reaction with 1,4-cyclohexadiene, specifically by gating access to complex 5, which is the species that is active for HAT. All complexes 2–4 react with benzophenone form metastable Fe(II) intermediates that subsequently eliminate the metathesis product Ph₂C=NDipp, with relative rates dependent on the alkali metal ion. By contrast, the same reaction with 5 does not lead to the formation of Ph₂C=NDipp. Furthermore, these results demonstrate that the coordination of alkali metal ions dictate both the structure and reactivity of the imido ligand and moreover can direct the reactivity of reaction intermediates.

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Research Organization:: Indiana Univ., Bloomington, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019466

OSTI ID:: 1903365

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 4 Vol. 144; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (65)

Coordination-Number Dependence of Reactivity in an Imidoiron(III) Complex Eckert, Nathan A.; Vaddadi, Sridhar; Stoian, Sebastian Angewandte Chemie International Edition, Vol. 45, Issue 41 https://doi.org/10.1002/anie.200601927	journal	October 2006
Evidence for the Existence of a Terminal Imidoscandium Compound: Intermolecular CH Activation and Complexation Reactions with the Transient ScNAr Species Scott, Jennifer; Basuli, Falguni; Fout, Alison R. Angewandte Chemie International Edition, Vol. 47, Issue 44 https://doi.org/10.1002/anie.200803325	journal	October 2008
Terminal Iron Dinitrogen and Iron Imide Complexes Supported by a Tris(phosphino)borane Ligand Moret, Marc-Etienne; Peters, Jonas C. Angewandte Chemie International Edition, Vol. 50, Issue 9 https://doi.org/10.1002/anie.201006918	journal	January 2011
Isolation and Characterization of Stable Iron(I) Sulfide Complexes Rodriguez, Meghan M.; Stubbert, Bryan D.; Scarborough, Christopher C. Angewandte Chemie International Edition, Vol. 51, Issue 33 https://doi.org/10.1002/anie.201202211	journal	July 2012
(Aminocarbene)(Divinyltetramethyldisiloxane)Iron(0) Compounds: A Class of Low-Coordinate Iron(0) Reagents Zhang, Hezhong; Ouyang, Zhenwu; Liu, Yuesheng Angewandte Chemie International Edition, Vol. 53, Issue 32 https://doi.org/10.1002/anie.201404677	journal	June 2014
A Terminal Imido Complex of an Iron–Sulfur Cluster Sridharan, Arun; Brown, Alexandra C.; Suess, Daniel L. M. Angewandte Chemie International Edition, Vol. 60, Issue 23 https://doi.org/10.1002/anie.202102603	journal	April 2021
Lewis Acid Coupled Electron Transfer of Metal-Oxygen Intermediates Fukuzumi, Shunichi; Ohkubo, Kei; Lee, Yong-Min Chemistry - A European Journal, Vol. 21, Issue 49 https://doi.org/10.1002/chem.201502693	journal	September 2015
Reactions of a Niobium Nitride Complex Prepared from Dinitrogen: Synthesis of Imide and Ureate Complexes and Ammonia Formation Akagi, Fumio; Suzuki, Shoui; Ishida, Yutaka European Journal of Inorganic Chemistry, Vol. 2013, Issue 22-23 https://doi.org/10.1002/ejic.201300172	journal	May 2013
An Open-Shell Spin Singlet Copper-Nitrene Intermediate Binding Redox-innocent Metal Ions: Influence of the Lewis Acidity of the Metal Ions on Spectroscopic and Reactivity Properties: An Open-Shell Spin Singlet Copper-Nitrene Intermediate Monte-Pérez, Inés; Kundu, Subrata; Ray, Kallol Zeitschrift für anorganische und allgemeine Chemie, Vol. 641, Issue 1 https://doi.org/10.1002/zaac.201400389	journal	November 2014
The calcium and chloride requirements of the O2 evolving complex Yocum, C. Coordination Chemistry Reviews, Vol. 252, Issue 3-4 https://doi.org/10.1016/j.ccr.2007.08.010	journal	February 2008
Metal ion-coupled and decoupled electron transfer Fukuzumi, Shunichi; Ohkubo, Kei Coordination Chemistry Reviews, Vol. 254, Issue 3-4 https://doi.org/10.1016/j.ccr.2009.10.020	journal	February 2010
The impact of alkali and alkaline earth metals on green ammonia synthesis Wang, Qianru; Guo, Jianping; Chen, Ping Chem, Vol. 7, Issue 12 https://doi.org/10.1016/j.chempr.2021.08.021	journal	December 2021
C–H activation by a terminal imidoiron(III) complex to form a cyclopentadienyliron(II) product Cowley, Ryan E.; Holland, Patrick L. Inorganica Chimica Acta, Vol. 369, Issue 1 https://doi.org/10.1016/j.ica.2010.11.031	journal	April 2011
Calcium in the oxygen-evolving complex: Structural and mechanistic role determined by X-ray spectroscopy Yachandra, Vittal K.; Yano, Junko Journal of Photochemistry and Photobiology B: Biology, Vol. 104, Issue 1-2 https://doi.org/10.1016/j.jphotobiol.2011.02.019	journal	July 2011
Synthesis, structure, and C–H bond activation reaction of an iron(IV) terminal imido complex bearing trifluoromethyl groups Liu, Qing; Long, Linhong; Ma, Pengchen Cell Reports Physical Science, Vol. 2, Issue 6 https://doi.org/10.1016/j.xcrp.2021.100454	journal	June 2021
C–H Bond Cleavage by Bioinspired Nonheme Metal Complexes Lee, Justin L.; Ross, Dolores L.; Barman, Suman K. Inorganic Chemistry, Vol. 60, Issue 18 https://doi.org/10.1021/acs.inorgchem.1c01754	journal	September 2021
Linear and T-Shaped Iron(I) Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis and Structure Characterization Ouyang, Zhenwu; Du, Jingzhen; Wang, Lei Inorganic Chemistry, Vol. 54, Issue 17 https://doi.org/10.1021/acs.inorgchem.5b01522	journal	August 2015
A Two-Coordinate Iron(II) Imido Complex with NHC Ligation: Synthesis, Characterization, and Its Diversified Reactivity of Nitrene Transfer and C–H Bond Activation Cheng, Jun; Liu, Jian; Leng, Xuebing Inorganic Chemistry, Vol. 58, Issue 11 https://doi.org/10.1021/acs.inorgchem.9b01147	journal	May 2019
Electronic and Structural Comparisons between Iron(II/III) and Ruthenium(II/III) Imide Analogs Aldrich, Kelly E.; Fales, B. Scott; Singh, Amrendra K. Inorganic Chemistry, Vol. 58, Issue 17 https://doi.org/10.1021/acs.inorgchem.9b01672	journal	August 2019
Effect of Lewis Acids on the Structure and Reactivity of a Mononuclear Hydroxomanganese(III) Complex Rice, Derek B.; Grotemeyer, Elizabeth N.; Donovan, Anna M. Inorganic Chemistry, Vol. 59, Issue 5 https://doi.org/10.1021/acs.inorgchem.9b02980	journal	February 2020
Three-Coordinate Iron(II) Dialkenyl Compound with NHC Ligation: Synthesis, Structure, and Reactivity Liu, Yuesheng; Wang, Lei; Deng, Liang Organometallics, Vol. 34, Issue 17 https://doi.org/10.1021/acs.organomet.5b00632	journal	August 2015
A Bidentate Carbene Ligand Stabilizes a Low-Coordinate Iron(0) Carbonyl Complex Hickey, Anne K.; Lee, Wei-Tsung; Chen, Chun-Hsing Organometallics, Vol. 35, Issue 17 https://doi.org/10.1021/acs.organomet.6b00599	journal	August 2016
Water-Splitting Chemistry of Photosystem II McEvoy, James P.; Brudvig, Gary W. Chemical Reviews, Vol. 106, Issue 11 https://doi.org/10.1021/cr0204294	journal	November 2006
Thermochemistry of Proton-Coupled Electron Transfer Reagents and its Implications Warren, Jeffrey J.; Tronic, Tristan A.; Mayer, James M. Chemical Reviews, Vol. 110, Issue 12 https://doi.org/10.1021/cr100085k	journal	December 2010
Scandium Ion-Enhanced Oxidative Dimerization and N -Demethylation of N , N -Dimethylanilines by a Non-Heme Iron(IV)-Oxo Complex Park, Jiyun; Morimoto, Yuma; Lee, Yong-Min Inorganic Chemistry, Vol. 50, Issue 22 https://doi.org/10.1021/ic201545a	journal	November 2011
Ligand Effects on Hydrogen Atom Transfer from Hydrocarbons to Three-Coordinate Iron Imides Cowley, Ryan E.; Holland, Patrick L. Inorganic Chemistry, Vol. 51, Issue 15 https://doi.org/10.1021/ic300870y	journal	July 2012
Monomeric Bis(anilido)iron(II) Complexes with N -Heterocyclic Carbene Ligation: Synthesis, Characterization, and Redox Reactivity toward Aryl Halides Wang, Xiaojie; Mo, Zhenbo; Xiao, Jie Inorganic Chemistry, Vol. 52, Issue 1 https://doi.org/10.1021/ic301894e	journal	December 2012
Synthetic Cluster Models of Biological and Heterogeneous Manganese Catalysts for O ₂ Evolution Tsui, Emily Y.; Kanady, Jacob S.; Agapie, Theodor Inorganic Chemistry, Vol. 52, Issue 24 https://doi.org/10.1021/ic402236f	journal	December 2013
Anomalous One-Electron Processes in the Chemistry of Uranium Nitrogen Multiple Bonds Mullane, Kimberly C.; Lewis, Andrew J.; Yin, Haolin Inorganic Chemistry, Vol. 53, Issue 17 https://doi.org/10.1021/ic501149u	journal	August 2014
Planar Three-Coordinate High-Spin Fe ^II Complexes with Large Orbital Angular Momentum: Mössbauer, Electron Paramagnetic Resonance, and Electronic Structure Studies Andres, Hanspeter; Bominaar, Emile L.; Smith, Jeremy M. Journal of the American Chemical Society, Vol. 124, Issue 12 https://doi.org/10.1021/ja012327l	journal	March 2002
A Low-Spin d ⁵ Iron Imide: Nitrene Capture by Low-Coordinate Iron(I) Provides the 4-Coordinate Fe(III) Complex [PhB(CH ₂ PPh ₂ ) ₃ ]Fe⋮N- p -tolyl Brown, Steven D.; Betley, Theodore A.; Peters, Jonas C. Journal of the American Chemical Society, Vol. 125, Issue 2 https://doi.org/10.1021/ja028448i	journal	January 2003
Ground-State Singlet L ₃ Fe-(μ-N)-FeL ₃ and L ₃ Fe(NR) Complexes Featuring Pseudotetrahedral Fe(II) Centers Brown, Steven D.; Peters, Jonas C. Journal of the American Chemical Society, Vol. 127, Issue 6 https://doi.org/10.1021/ja0453073	journal	February 2005
Thermodynamics of Hydrogen Atom Transfer to a High-Valent Iron Imido Complex Nieto, Ismael; Ding, Feizhi; Bontchev, Ranko P. Journal of the American Chemical Society, Vol. 130, Issue 9 https://doi.org/10.1021/ja0776834	journal	March 2008
Phosphinidene Complexes of Scandium: Powerful PAr Group-Transfer Vehicles to Organic and Inorganic Substrates Wicker, Benjamin F.; Scott, Jennifer; Andino, José G. Journal of the American Chemical Society, Vol. 132, Issue 11 https://doi.org/10.1021/ja100214e	journal	March 2010
Metal Ion-Coupled Electron Transfer of a Nonheme Oxoiron(IV) Complex: Remarkable Enhancement of Electron-Transfer Rates by Sc ³⁺ Morimoto, Yuma; Kotani, Hiroaki; Park, Jiyun Journal of the American Chemical Society, Vol. 133, Issue 3 https://doi.org/10.1021/ja109056x	journal	January 2011
Catalytic C−H Bond Amination from High-Spin Iron Imido Complexes King, Evan R.; Hennessy, Elisabeth T.; Betley, Theodore A. Journal of the American Chemical Society, Vol. 133, Issue 13 https://doi.org/10.1021/ja110066j	journal	April 2011
Selectivity and Mechanism of Hydrogen Atom Transfer by an Isolable Imidoiron(III) Complex Cowley, Ryan E.; Eckert, Nathan A.; Vaddadi, Sridhar Journal of the American Chemical Society, Vol. 133, Issue 25 https://doi.org/10.1021/ja2005303	journal	June 2011
Metal Ion Effect on the Switch of Mechanism from Direct Oxygen Transfer to Metal Ion-Coupled Electron Transfer in the Sulfoxidation of Thioanisoles by a Non-Heme Iron(IV)−Oxo Complex Park, Jiyun; Morimoto, Yuma; Lee, Yong-Min Journal of the American Chemical Society, Vol. 133, Issue 14 https://doi.org/10.1021/ja200901n	journal	April 2011
Lewis Acid Trapping of an Elusive Copper–Tosylnitrene Intermediate Using Scandium Triflate Kundu, Subrata; Miceli, Enrico; Farquhar, Erik Journal of the American Chemical Society, Vol. 134, Issue 36 https://doi.org/10.1021/ja306674h	journal	August 2012
Alkali Metal Control over N–N Cleavage in Iron Complexes Grubel, Katarzyna; Brennessel, William W.; Mercado, Brandon Q. Journal of the American Chemical Society, Vol. 136, Issue 48 https://doi.org/10.1021/ja507442b	journal	November 2014
Effects of Noncovalent Interactions on High-Spin Fe(IV)–Oxido Complexes Oswald, Victoria F.; Lee, Justin L.; Biswas, Saborni Journal of the American Chemical Society, Vol. 142, Issue 27 https://doi.org/10.1021/jacs.0c03085	journal	June 2020
Two-State Reactivity in Iron-Catalyzed Alkene Isomerization Confers σ-Base Resistance Lutz, Sean A.; Hickey, Anne K.; Gao, Yafei Journal of the American Chemical Society, Vol. 142, Issue 36 https://doi.org/10.1021/jacs.0c07300	journal	August 2020
Catalytic Carbodiimide Guanylation by a Nucleophilic, High Spin Iron(II) Imido Complex Gao, Yafei; Carta, Veronica; Pink, Maren Journal of the American Chemical Society, Vol. 143, Issue 14 https://doi.org/10.1021/jacs.1c02068	journal	April 2021
Spectroscopic Identification of an Fe ^III Center, not Fe ^IV , in the Crystalline Sc–O–Fe Adduct Derived from [Fe ^IV (O)(TMC)] ²⁺ Prakash, Jai; Rohde, Gregory T.; Meier, Katlyn K. Journal of the American Chemical Society, Vol. 137, Issue 10 https://doi.org/10.1021/jacs.5b00535	journal	March 2015
Three-Coordinate Iron(IV) Bisimido Complexes with Aminocarbene Ligation: Synthesis, Structure, and Reactivity Wang, Lei; Hu, Lianrui; Zhang, Hezhong Journal of the American Chemical Society, Vol. 137, Issue 44 https://doi.org/10.1021/jacs.5b09579	journal	October 2015
Characterization of Iron-Imido Species Relevant for N -Group Transfer Chemistry Iovan, Diana A.; Betley, Theodore A. Journal of the American Chemical Society, Vol. 138, Issue 6 https://doi.org/10.1021/jacs.5b12582	journal	February 2016
An Alkali Metal-Capped Cerium(IV) Imido Complex Solola, Lukman A.; Zabula, Alexander V.; Dorfner, Walter L. Journal of the American Chemical Society, Vol. 138, Issue 22 https://doi.org/10.1021/jacs.6b03293	journal	May 2016
Cerium(IV) Imido Complexes: Structural, Computational, and Reactivity Studies Solola, Lukman A.; Zabula, Alexander V.; Dorfner, Walter L. Journal of the American Chemical Society, Vol. 139, Issue 6 https://doi.org/10.1021/jacs.6b12369	journal	February 2017
A Mononuclear Nonheme Iron(V)-Imido Complex Hong, Seungwoo; Sutherlin, Kyle D.; Vardhaman, Anil Kumar Journal of the American Chemical Society, Vol. 139, Issue 26 https://doi.org/10.1021/jacs.7b04695	journal	June 2017
High-Spin Iron Imido Complexes Competent for C–H Bond Amination Wilding, Matthew J. T.; Iovan, Diana A.; Betley, Theodore A. Journal of the American Chemical Society, Vol. 139, Issue 34 https://doi.org/10.1021/jacs.7b06682	journal	August 2017
Direct Comparison of C–H Bond Amination Efficacy through Manipulation of Nitrogen-Valence Centered Redox: Imido versus Iminyl Wilding, Matthew J. T.; Iovan, Diana A.; Wrobel, Alexandra T. Journal of the American Chemical Society, Vol. 139, Issue 41 https://doi.org/10.1021/jacs.7b08714	journal	October 2017
A Mononuclear Non-heme Manganese(III)–Aqua Complex as a New Active Oxidant in Hydrogen Atom Transfer Reactions Sankaralingam, Muniyandi; Lee, Yong-Min; Karmalkar, Deepika G. Journal of the American Chemical Society, Vol. 140, Issue 40 https://doi.org/10.1021/jacs.8b07772	journal	September 2018
A Dimeric Hydride-Bridged Complex with Geometrically Distinct Iron Centers Giving Rise to an S = 3 Ground State Hickey, Anne K.; Greer, Samuel M.; Valdez-Moreira, Juan A. Journal of the American Chemical Society, Vol. 141, Issue 30 https://doi.org/10.1021/jacs.9b04389	journal	July 2019
Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters Tsui, Emily Y.; Tran, Rosalie; Yano, Junko Nature Chemistry, Vol. 5, Issue 4 https://doi.org/10.1038/nchem.1578	journal	March 2013
Elucidating bonding preferences in tetrakis(imido)uranate(VI) dianions Anderson, Nickolas H.; Xie, Jing; Ray, Debmalya Nature Chemistry, Vol. 9, Issue 9 https://doi.org/10.1038/nchem.2767	journal	April 2017
Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer Fukuzumi, Shunichi; Morimoto, Yuma; Kotani, Hiroaki Nature Chemistry, Vol. 2, Issue 9 https://doi.org/10.1038/nchem.731	journal	July 2010
The first group 4 metal bis(imido) and tris(imido) complexes Schwarz, Andrew D.; Nielson, Alastair J.; Kaltsoyannis, Nikolas Chem. Sci., Vol. 3, Issue 3 https://doi.org/10.1039/C1SC00786F	journal	January 2012
Facile hydrogen atom transfer to iron( iii ) imido radical complexes supported by a dianionic pentadentate ligand Spasyuk, Denis M.; Carpenter, Stephanie H.; Kefalidis, Christos E. Chemical Science, Vol. 7, Issue 9 https://doi.org/10.1039/C6SC01433J	journal	January 2016
Exploring the reactivity of tungsten bis(imido) dimethyl complexes with methyl aluminium reagents: implications for ethylene dimerization Wright, William R. H.; Batsanov, Andrei S.; Howard, Judith A. K. Dalton Transactions, Vol. 39, Issue 30 https://doi.org/10.1039/c0dt00110d	journal	January 2010
Application of molybdenum bis(imido) complexes in ethylene dimerisation catalysis Wright, William R. H.; Batsanov, Andrei S.; Messinis, Antonis M. Dalton Transactions, Vol. 41, Issue 18 https://doi.org/10.1039/c2dt12061e	journal	January 2012
A change in the oxidation state of iron: scandium is not innocent Swart, Marcel Chemical Communications, Vol. 49, Issue 59 https://doi.org/10.1039/c3cc42200c	journal	January 2013
Reduction potentials of heterometallic manganese-oxido cubane complexes modulated by redox-inactive metals Tsui, E. Y.; Agapie, T. Proceedings of the National Academy of Sciences, Vol. 110, Issue 25 https://doi.org/10.1073/pnas.1302677110	journal	June 2013
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
A Synthetic Model of the Mn3Ca Subsite of the Oxygen-Evolving Complex in Photosystem II Kanady, J. S.; Tsui, E. Y.; Day, M. W. Science, Vol. 333, Issue 6043 https://doi.org/10.1126/science.1206036	journal	August 2011
Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination Hennessy, E. T.; Betley, T. A. Science, Vol. 340, Issue 6132 https://doi.org/10.1126/science.1233701	journal	May 2013

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Title: Alkali Metal Ions Dictate the Structure and Reactivity of an Iron(II) Imido Complex

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