Zirkonkarbid ermöglicht verkokungsresistente Methan‐Trockenreformierung auf Nickel‐Zirkon‐Katalysatoren

Haug, Leander; Thurner, Christoph; Bekheet, Maged F.; Bischoff, Benjamin; Gurlo, Aleksander; Kunz, Martin; Sartory, Bernhard; Penner, Simon; Klötzer, Bernhard

doi:10.1002/ange.202213249

Title: Zirkonkarbid ermöglicht verkokungsresistente Methan‐Trockenreformierung auf Nickel‐Zirkon‐Katalysatoren

Journal Article · 14 November 2022 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.202213249 · OSTI ID:1902504

^[1]; Thurner, Christoph ^[1];

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Institut für Physikalische Chemie Universität Innsbruck Innrain 52 c 6020 Innsbruck Österreich
Fachgebiet Keramische Werkstoffe Institut für Werkstoffwissenschaften und -technologien Technische Universität Berlin, Straße des 17. Juni 135 10623 Berlin Deutschland
Advanced Light Source Lawrence Berkeley National Laboratory Berkeley CA 94720 USA
Materials Center Leoben Forschung GmbH Roseggerstrasse 12 8700 Leoben Österreich

Abstract Graphitische Ablagerungen lösen sich in Ni ⁰ ‐Nanopartikeln auf, um rezyklierte CH ₄ ‐Adsorptionsstellen und oberflächennahe/gelöste C‐Atome bereitzustellen, die zur Ni ⁰ /ZrO ₂ ‐Grenzfläche wandern und eine lokale Zr _x C _y ‐Bildung induzieren. Die daraus resultierenden sauerstoffarmen karbidischen Phasengrenzflächen unterstützen die Kinetik der CO ₂ ‐Aktivierung zu CO(g). Dieser Grenzflächen‐Karbid‐Mechanismus ermöglicht einen verstärkten Übertritt von Kohlenstoff auf den ZrO ₂ ‐Träger und stellt einen alternativen Weg der Katalysatorregeneration im Vergleich zum umgekehrten Sauerstoffübertritt auf Ni/CeZr _x O _y ‐Katalysatoren dar. Er ist daher eher auf Trägern mit begrenzter Sauerstoffspeicher‐ bzw. Austausch‐Kinetik, aber signifikanter karbothermischer Reduzierbarkeit, wahrscheinlich.

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Sponsoring Organization:: USDOE

OSTI ID:: 1902504

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 50 Vol. 134; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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