DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Developing ductile and isotropic Ti alloy with tailored composition for laser powder bed fusion

Journal Article · · Additive Manufacturing
 [1];  [1];  [2];  [3];  [3];  [1];  [1];  [1];  [1];  [4]
  1. Shanghai Jiao Tong University (China)
  2. Argonne National Laboratory (ANL), Argonne, IL (United States)
  3. Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
  4. Norwegian University of Science and Technology, Trondheim (Norway)

Laser powder bed fusion (LPBF) is an advanced technology to create metallic components with complex geometry. Ti-6Al-4V (Ti64) is one of the most frequently used materials for LPBF. The intrinsic high cooling rates and ultra-high directional thermal gradient of melt, however, lead to a hierarchical structure composed of fine martensitic alpha' within columnar prior-beta grains in LPBF Ti64. This microstructure results in poor ductility and strong mechanical anisotropy in as-built Ti64 components, which largely limit their applications. Here, we report that the above shortcomings can be overcome by tailoring the alloy composition. Specifically, by reducing the aluminum content from 6 wt% to 4 wt%, the resultant LPBF Ti-4Al-4V (Ti44) alloy exhibits substantially improved ductility and mechanical isotropy. These improvements are attributed to grain refinement during solidification and the activation of multiple slip modes and twinning in the as-built material during deformation. This work offers a simple strategy to design new titanium alloys for LPBF with significantly improved ductility and isotropy.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1896788
Journal Information:
Additive Manufacturing, Journal Name: Additive Manufacturing Vol. 52; ISSN 2214-8604
Publisher:
ElsevierCopyright Statement
Country of Publication:
United States
Language:
English

References (48)

Interface‐Mediated Twinning‐Induced Plasticity in a Fine Hexagonal Microstructure Generated by Additive Manufacturing journal October 2021
A Statistical Theory of Solid Solution Hardening journal January 1970
Deformation behavior of HCP Ti-Al alloy single crystals journal March 2002
Grain refinement of magnesium alloys journal July 2005
As-Fabricated and Heat-Treated Microstructures of the Ti-6Al-4V Alloy Processed by Selective Laser Melting journal May 2011
Microstructures and Grain Refinement of Additive-Manufactured Ti-xW Alloys journal May 2017
Understanding the High Strength and Good Ductility in LPSO-Containing Mg Alloy Using Synchrotron X-ray Diffraction journal August 2018
The Influence of Iron in Minimizing the Microstructural Anisotropy of Ti-6Al-4V Produced by Laser Powder-Bed Fusion journal March 2020
Grain Refinement of Alloys in Fusion-Based Additive Manufacturing Processes journal June 2020
Microstructures and Mechanical Properties of Ti6Al4V Parts Fabricated by Selective Laser Melting and Electron Beam Melting journal August 2013
Defect, Microstructure, and Mechanical Property of Ti-6Al-4V Alloy Fabricated by High-Power Selective Laser Melting journal September 2017
MAUD Rietveld Refinement Software for Neutron Diffraction Texture Studies of Single- and Dual-Phase Materials journal August 2021
Dislocations, grain size and planar faults in nanostructured copper determined by high resolution X-ray diffraction and a new procedure of peak profile analysis journal June 1998
Thermodynamic aspects of grain growth restriction in multicomponent alloy solidification journal September 2011
Investigation of deformation and microstructural evolution in Grade 91 ferritic–martensitic steel by in situ high-energy X-rays journal January 2014
Additive manufacturing of strong and ductile Ti–6Al–4V by selective laser melting via in situ martensite decomposition journal February 2015
In situ tailoring microstructure in additively manufactured Ti-6Al-4V for superior mechanical performance journal February 2017
Micro-and meso-structures and their influence on mechanical properties of selectively laser melted Ti-6Al-4V journal August 2018
Study of slip activity in a Mg-Y alloy by in situ high energy X-ray diffraction microscopy and elastic viscoplastic self-consistent modeling journal August 2018
Globularization using heat treatment in additively manufactured Ti-6Al-4V for high strength and toughness journal January 2019
Microstructural optimization through heat treatment for enhancing the fracture toughness and fatigue crack growth resistance of selective laser melted Ti 6Al 4V alloy journal May 2019
Effect of heat treatment on the tensile behavior of selective laser melted Ti-6Al-4V by in situ X-ray characterization journal May 2020
Optimisation of process parameters to address fundamental challenges during selective laser melting of Ti-6Al-4V: A review journal May 2018
Heat treatment of Ti6Al4V produced by Selective Laser Melting: Microstructure and mechanical properties journal November 2012
Experimental realisation of build orientation effects on the mechanical properties of truly as-built Ti-6Al-4V SLM parts journal April 2021
Strain localization in Ti-6Al-4V Widmanstätten microstructures produced by additive manufacturing journal December 2016
Formation and control of martensite in Ti-6Al-4V alloy produced by selective laser melting journal October 2016
A microstructure sensitive model for deformation of Ti-6Al-4V describing Cast-and-Wrought and Additive Manufacturing morphologies journal December 2018
Effects of boron addition on microstructures and mechanical properties of Ti-6Al-4V manufactured by direct laser deposition journal December 2019
A physically-based structure-property model for additively manufactured Ti-6Al-4V journal July 2021
Microstructure and tensile properties of selectively laser-melted and of HIPed laser-melted Ti–6Al–4V journal August 2013
Effect of the build orientation on the mechanical properties and fracture modes of SLM Ti–6Al–4V journal October 2014
Spatially dependent properties in a laser additive manufactured Ti–6Al–4V component journal January 2016
Quantitative relationship between anisotropic strain to failure and grain morphology in additively manufactured Ti-6Al-4V journal October 2017
Controlling martensitic decomposition during selective laser melting to achieve best ductility in high strength Ti-6Al-4V journal January 2019
Microstructure and tensile properties of additive manufactured Ti-6Al-4V with refined prior-β grain structure obtained by rapid heat treatment journal May 2021
Controllable mechanical anisotropy of selective laser melted Ti6Al4V: A new perspective into the effect of grain orientations and primary grain structure journal October 2021
Texture analysis with the new HIPPO TOF diffractometer
  • Wenk, H. -R.; Lutterotti, L.; Vogel, S.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 515, Issue 3 https://doi.org/10.1016/j.nima.2003.05.001
journal December 2003
Additive manufacturing of metallic components – Process, structure and properties journal March 2018
Achieving superior ductility for laser solid formed extra low interstitial Ti-6Al-4V titanium alloy through equiaxial alpha microstructure journal March 2018
Elimination of oxygen sensitivity in α-titanium by substitutional alloying with Al journal October 2021
Additive manufacturing of ultrafine-grained high-strength titanium alloys journal December 2019
Non-Destructive Characterization of Engineering Materials Using High-Energy X-rays at the Advanced Photon Source journal May 2017
GSAS-II : the genesis of a modern open-source all purpose crystallography software package journal March 2013
Direct imaging of short-range order and its impact on deformation in Ti-6Al journal December 2019
Microstructural Control of Additively Manufactured Metallic Materials journal July 2016
Metal Additive Manufacturing: A Review of Mechanical Properties journal July 2016
Certification of Standard Reference Material 660B journal June 2011