Solid Electrolytes in the Spotlight

Doeff, Marca M.; Clément, Raphaële J.; Canepa, Pieremanuele

doi:10.1021/acs.chemmater.1c03770

Title: Solid Electrolytes in the Spotlight

Journal Article · 25 January 2022 · Chemistry of Materials

DOI: https://doi.org/10.1021/acs.chemmater.1c03770 · OSTI ID:1896469

^[1];

^[2];

^[3]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Santa Barbara, CA (United States)
National Univ. of Singapore (Singapore)

This virtual issue is targeted to students and researchers, and highlights 32 research articles published over the past 5 years (from July 2016 to July 2021) in Chemistry of Materials (CM). Here, the compilation of papers summarizes the latest advances in the field of solid-state electrolytes for lithium (Li)-, sodium (Na)-, and multivalent-ion (not among the 32 articles discussed) all-solid-state batteries (ASSBs), with a focus on inorganic materials and excluding hybrid systems, e.g., polymer/ceramic composites or systems including liquid media. A total of 125 articles reporting exciting experimental and/or theoretical findings on solid electrolytes were considered for this issue. During 2017–2019, there were about 25–30 papers published per year on this topic, but 2020 and 2021 saw a significant increase, with 26 publications in the first half of 2021 alone. Submissions came from many countries around the world, as shown in Figure 1. While most papers were led by research groups located in the United States, Germany and Japan follow closely, and Austria, the United Kingdom, Canada, and China are also well represented.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1896469

Journal Information:: Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 2 Vol. 34; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (32)

Thermally Driven Interfacial Degradation between Li ₇ La ₃ Zr ₂ O ₁₂ Electrolyte and LiNi _0.6 Mn _0.2 Co _0.2 O ₂ Cathode Kim, Younggyu; Kim, Dongha; Bliem, Roland Chemistry of Materials, Vol. 32, Issue 22 https://doi.org/10.1021/acs.chemmater.0c02261	journal	November 2020
Unraveling the Origin of Moisture Stability of Halide Solid-State Electrolytes by In Situ and Operando Synchrotron X-ray Analytical Techniques Li, Weihan; Liang, Jianwen; Li, Minsi Chemistry of Materials, Vol. 32, Issue 16 https://doi.org/10.1021/acs.chemmater.0c02419	journal	July 2020
Dynamics of Hydroxyl Anions Promotes Lithium Ion Conduction in Antiperovskite Li ₂ OHCl Wang, Fei; Evans, Hayden A.; Kim, Kwangnam Chemistry of Materials, Vol. 32, Issue 19 https://doi.org/10.1021/acs.chemmater.0c02602	journal	September 2020
Phase Behavior in Rhombohedral NaSiCON Electrolytes and Electrodes Deng, Zeyu; Sai Gautam, Gopalakrishnan; Kolli, Sanjeev Krishna Chemistry of Materials, Vol. 32, Issue 18 https://doi.org/10.1021/acs.chemmater.0c02695	journal	August 2020
Investigating the Calcination and Sintering of Li ₇ La ₃ Zr ₂ O ₁₂ (LLZO) Solid Electrolytes Using Operando Synchrotron X-ray Characterization and Mesoscale Modeling Barai, Pallab; Fister, Timothy; Liang, Yujia Chemistry of Materials, Vol. 33, Issue 12 https://doi.org/10.1021/acs.chemmater.0c04393	journal	June 2021
Maintaining a Flat Li Surface during the Li Stripping Process via Interface Design Yang, Chi-Ta; Qi, Yue Chemistry of Materials, Vol. 33, Issue 8 https://doi.org/10.1021/acs.chemmater.0c04814	journal	April 2021
Material Design Strategy for Halide Solid Electrolytes Li ₃ MX ₆ (X = Cl, Br, and I) for All-Solid-State High-Voltage Li-Ion Batteries Kim, Kwangnam; Park, Dongsu; Jung, Hun-Gi Chemistry of Materials, Vol. 33, Issue 10 https://doi.org/10.1021/acs.chemmater.1c00555	journal	May 2021
Insights into the Rich Polymorphism of the Na ⁺ Ion Conductor Na ₃ PS ₄ from the Perspective of Variable-Temperature Diffraction and Spectroscopy Famprikis, Theodosios; Bouyanfif, Houssny; Canepa, Pieremanuele Chemistry of Materials, Vol. 33, Issue 14 https://doi.org/10.1021/acs.chemmater.1c01113	journal	July 2021
Exploring Aliovalent Substitutions in the Lithium Halide Superionic Conductor Li _{3– x} In _{1– x} Zr _x Cl ₆ (0 ≤ x ≤ 0.5) Helm, Bianca; Schlem, Roman; Wankmiller, Björn Chemistry of Materials, Vol. 33, Issue 12 https://doi.org/10.1021/acs.chemmater.1c01348	journal	June 2021
Metastability in Li–La–Ti–O Perovskite Materials and Its Impact on Ionic Conductivity Jonderian, Antranik; Ting, Michelle; McCalla, Eric Chemistry of Materials, Vol. 33, Issue 12 https://doi.org/10.1021/acs.chemmater.1c01490	journal	June 2021
Scandium-Substituted Na ₃ Zr ₂ (SiO ₄ ) ₂ (PO ₄ ) Prepared by a Solution-Assisted Solid-State Reaction Method as Sodium-Ion Conductors Ma, Qianli; Guin, Marie; Naqash, Sahir Chemistry of Materials, Vol. 28, Issue 13 https://doi.org/10.1021/acs.chemmater.6b02059	journal	June 2016
Structural Insights and 3D Diffusion Pathways within the Lithium Superionic Conductor Li ₁₀ GeP ₂ S ₁₂ Weber, Dominik A.; Senyshyn, Anatoliy; Weldert, Kai S. Chemistry of Materials, Vol. 28, Issue 16 https://doi.org/10.1021/acs.chemmater.6b02424	journal	August 2016
Diffusion Mechanism of Li Argyrodite Solid Electrolytes for Li-Ion Batteries and Prediction of Optimized Halogen Doping: The Effect of Li Vacancies, Halogens, and Halogen Disorder de Klerk, Niek J. J.; Rosłoń, Irek; Wagemaker, Marnix Chemistry of Materials, Vol. 28, Issue 21 https://doi.org/10.1021/acs.chemmater.6b03630	journal	October 2016
Electrochemical Nature of the Cathode Interface for a Solid-State Lithium-Ion Battery: Interface between LiCoO ₂ and Garnet-Li ₇ La ₃ Zr ₂ O ₁₂ Park, Kyusung; Yu, Byeong-Chul; Jung, Ji-Won Chemistry of Materials, Vol. 28, Issue 21 https://doi.org/10.1021/acs.chemmater.6b03870	journal	October 2016
Interface Stability of Argyrodite Li ₆ PS ₅ Cl toward LiCoO ₂ , LiNi _1/3 Co _1/3 Mn _1/3 O ₂ , and LiMn ₂ O ₄ in Bulk All-Solid-State Batteries Auvergniot, Jérémie; Cassel, Alice; Ledeuil, Jean-Bernard Chemistry of Materials, Vol. 29, Issue 9 https://doi.org/10.1021/acs.chemmater.6b04990	journal	April 2017
Evolution at the Solid Electrolyte/Gold Electrode Interface during Lithium Deposition and Stripping Sang, Lingzi; Haasch, Richard T.; Gewirth, Andrew A. Chemistry of Materials, Vol. 29, Issue 7 https://doi.org/10.1021/acs.chemmater.7b00034	journal	March 2017
Structural and Electronic-State Changes of a Sulfide Solid Electrolyte during the Li Deinsertion–Insertion Processes Hakari, Takashi; Deguchi, Minako; Mitsuhara, Kei Chemistry of Materials, Vol. 29, Issue 11 https://doi.org/10.1021/acs.chemmater.7b00551	journal	May 2017
Grain Boundary Contributions to Li-Ion Transport in the Solid Electrolyte Li ₇ La ₃ Zr ₂ O ₁₂ (LLZO) Yu, Seungho; Siegel, Donald J. Chemistry of Materials, Vol. 29, Issue 22 https://doi.org/10.1021/acs.chemmater.7b02805	journal	November 2017
Fast Li-Ion Dynamics in Stoichiometric Li ₂ S–Ga ₂ Se ₃ –GeSe ₂ Glasses Marple, Maxwell A. T.; Aitken, Bruce G.; Kim, Sangtae Chemistry of Materials, Vol. 29, Issue 20 https://doi.org/10.1021/acs.chemmater.7b02858	journal	October 2017
Surface Chemistry Mechanism of Ultra-Low Interfacial Resistance in the Solid-State Electrolyte Li ₇ La ₃ Zr ₂ O ₁₂ Sharafi, Asma; Kazyak, Eric; Davis, Andrew L. Chemistry of Materials, Vol. 29, Issue 18 https://doi.org/10.1021/acs.chemmater.7b03002	journal	September 2017
Synthesis and Electrochemical Properties of I 4̅-Type Li _{1+2 x} Zn _{1– x} PS ₄ Solid Electrolyte Suzuki, Naoki; Richards, William D.; Wang, Yan Chemistry of Materials, Vol. 30, Issue 7 https://doi.org/10.1021/acs.chemmater.7b03833	journal	March 2018
Probing Solid–Solid Interfacial Reactions in All-Solid-State Sodium-Ion Batteries with First-Principles Calculations Tang, Hanmei; Deng, Zhi; Lin, Zhuonan Chemistry of Materials, Vol. 30, Issue 1 https://doi.org/10.1021/acs.chemmater.7b04096	journal	December 2017
Crystal Structures, Local Atomic Environments, and Ion Diffusion Mechanisms of Scandium-Substituted Sodium Superionic Conductor (NASICON) Solid Electrolytes Deng, Yue; Eames, Christopher; Nguyen, Long H. B. Chemistry of Materials, Vol. 30, Issue 8 https://doi.org/10.1021/acs.chemmater.7b05237	journal	March 2018
Garnet Electrolytes for Solid State Batteries: Visualization of Moisture-Induced Chemical Degradation and Revealing Its Impact on the Li-Ion Dynamics Brugge, Rowena H.; Hekselman, A. K. Ola; Cavallaro, Andrea Chemistry of Materials, Vol. 30, Issue 11 https://doi.org/10.1021/acs.chemmater.8b00486	journal	May 2018
Superion Conductor Na _11.1 Sn _2.1 P _0.9 Se ₁₂ : Lowering the Activation Barrier of Na ⁺ Conduction in Quaternary 1–4–5–6 Electrolytes Duchardt, Marc; Neuberger, Sven; Ruschewitz, Uwe Chemistry of Materials, Vol. 30, Issue 12 https://doi.org/10.1021/acs.chemmater.8b01656	journal	May 2018
Correlating Ion Mobility and Single Crystal Structure in Sodium-Ion Chalcogenide-Based Solid State Fast Ion Conductors: Na ₁₁ Sn ₂ PnS ₁₂ (Pn = Sb, P) Ramos, Erika P.; Zhang, Zhizhen; Assoud, Abdeljalil Chemistry of Materials, Vol. 30, Issue 21 https://doi.org/10.1021/acs.chemmater.8b02077	journal	August 2018
Untangling the Structure and Dynamics of Lithium-Rich Anti-Perovskites Envisaged as Solid Electrolytes for Batteries Hanghofer, Isabel; Redhammer, Günther J.; Rohde, Sebastian Chemistry of Materials, Vol. 30, Issue 22 https://doi.org/10.1021/acs.chemmater.8b02568	journal	October 2018
Machine Learning-Assisted Discovery of Solid Li-Ion Conducting Materials Sendek, Austin D.; Cubuk, Ekin D.; Antoniuk, Evan R. Chemistry of Materials, Vol. 31, Issue 2 https://doi.org/10.1021/acs.chemmater.8b03272	journal	November 2018
Lesson Learned from NMR: Characterization and Ionic Conductivity of LGPS-like Li ₇ SiPS ₈ Harm, Sascha; Hatz, Anna-Katharina; Moudrakovski, Igor Chemistry of Materials, Vol. 31, Issue 4 https://doi.org/10.1021/acs.chemmater.8b04051	journal	January 2019
⁷ Li NMR Chemical Shift Imaging To Detect Microstructural Growth of Lithium in All-Solid-State Batteries Marbella, Lauren E.; Zekoll, Stefanie; Kasemchainan, Jitti Chemistry of Materials, Vol. 31, Issue 8 https://doi.org/10.1021/acs.chemmater.8b04875	journal	April 2019
Visualization of the Interfacial Decomposition of Composite Cathodes in Argyrodite-Based All-Solid-State Batteries Using Time-of-Flight Secondary-Ion Mass Spectrometry Walther, Felix; Koerver, Raimund; Fuchs, Till Chemistry of Materials, Vol. 31, Issue 10 https://doi.org/10.1021/acs.chemmater.9b00770	journal	April 2019
Toward Standardization of Electrochemical Impedance Spectroscopy Studies of Li-Ion Conductive Ceramics Krasnikova, Irina V.; Pogosova, Mariam A.; Sanin, Alexey O. Chemistry of Materials, Vol. 32, Issue 6 https://doi.org/10.1021/acs.chemmater.9b04899	journal	February 2020

Similar Records

Fatigue and fracture mechanics: 27. volume

Conference · 1997 · OSTI ID:544215

Piascik, R S; Newman, Jr, J C; Dowling, N E

A successful start for mLife

Journal Article · 2023 · mLife (Online) · OSTI ID:2370360

Huang, Li; Zhou, Jizhong

Summary of national and international radioactive waste management programs

Technical Report · 1979 · OSTI ID:6222068

Harmon, K M

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Solid Electrolytes in the Spotlight

Citation Formats

References (32)

Similar Records

Related Subjects