On the Interfacial Behavior of Catenated Poly(l-lactide) at the Air–Water Interface

Rong, Li-Han; Cheng, Xiang; Ge, Jin; Wang, Hanyu; Cao, Peng-Fei; Caldona, Eugene B.; Advincula, Rigoberto C.

doi:10.1021/acs.langmuir.2c00454

Title: On the Interfacial Behavior of Catenated Poly(l-lactide) at the Air–Water Interface

Journal Article · 02 August 2022 · Langmuir

DOI: https://doi.org/10.1021/acs.langmuir.2c00454 · OSTI ID:1887655

Rong, Li-Han ^[1]; Cheng, Xiang ^[1]; Ge, Jin ^[1];

^[2];

^[3];

^[4];

^[5]

Case Western Reserve Univ., Cleveland, OH (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences
Beijing University of Chemical Technology (China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences; Univ. of Tennessee, Knoxville, TN (United States)
Case Western Reserve Univ., Cleveland, OH (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences; Univ. of Tennessee, Knoxville, TN (United States)

Interfacial properties of polymeric materials are significantly influenced by their architectural structures and spatial features, while such a study of topologically interesting macromolecules is rarely reported. Here, we reported, for the first time, the interfacial behavior of catenated poly(l-lactide) (C-PLA) at the air–water interface and compared it with its linear analogue (L-PLA). The isotherms of surface pressure–area per repeating unit showed significant interfacial behavioral differences between the two polymers with different topologies. Isobaric creep experiments and compression–expansion cycles also showed that C-PLA demonstrated higher stability at the air–water interface. Interestingly, when the films at different surface pressures were transferred via the Langmuir–Blodgett method, successive atomic force microscopy imaging displayed distinct nanomorphologies, in which the surface of C-PLA exhibited nanofibrous structures, while that of the L-PLA revealed a smoother topology with less fiber-like structures.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1887655

Journal Information:: Langmuir, Journal Name: Langmuir Journal Issue: 32 Vol. 38; ISSN 0743-7463

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: On the Interfacial Behavior of Catenated Poly(l-lactide) at the Air–Water Interface

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