Review–From LiMn2O4 to Partially-Disordered Li2MnNiO4: The Evolution of Lithiated-Spinel Cathodes for Li-Ion Batteries

Thackeray, Michael M.; Lee, Eungje; Shi, Boyu; Croy, Jason R.

doi:10.1149/1945-7111/ac50dd

Title: Review–From LiMn₂O₄ to Partially-Disordered Li₂MnNiO₄: The Evolution of Lithiated-Spinel Cathodes for Li-Ion Batteries

Journal Article · 10 February 2022 · Journal of the Electrochemical Society

DOI: https://doi.org/10.1149/1945-7111/ac50dd · OSTI ID:1886334

^[1]; Lee, Eungje ^[1]; Shi, Boyu ^[1];

^[1]

Argonne National Lab. (ANL), Lemont, IL (United States)

This personal narrative relates to the discovery in 1981 of stoichiometric LiM₂O₄ spinel electrodes (where M = metal cation) for lithium-ion batteries by the Goodenough group at Oxford University, UK, and the subsequent identification and evolution of stable lithiated-spinel Li₂M₂O₄ (or LiMO₂) cathodes at the Council for Scientific and Industrial Research in South Africa and Argonne National Laboratory (USA). In this work, the competition that occurs between the formation of lithiated-spinel and layered (LiMO₂) structures at 400 °C, and recent efforts to design high-capacity, Mn-rich composite cathodes with partial disorder, are discussed. The paper is written in honor of John Goodenough's 100th birthday.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1886334

Journal Information:: Journal of the Electrochemical Society, Journal Name: Journal of the Electrochemical Society Journal Issue: 2 Vol. 169; ISSN 0013-4651

Publisher:: IOP PublishingCopyright Statement

Country of Publication:: United States

Language:: English

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