Ferromagnetic Cr4PtGa17: A Half-Heusler-Type Compound with a Breathing Pyrochlore Lattice

Gui, Xin; Feng, Erxi; Cao, Huibo; Cava, Robert J.

doi:10.1021/jacs.1c06667

Title: Ferromagnetic Cr₄PtGa₁₇: A Half-Heusler-Type Compound with a Breathing Pyrochlore Lattice

Journal Article · 26 August 2021 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.1c06667 · OSTI ID:1883976

^[1]; Feng, Erxi ^[2];

^[2]; Cava, Robert J. ^[1]

Princeton Univ., NJ (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Here, we describe the crystal structure and elementary magnetic properties of a previously unreported ternary intermetallic compound, Cr₄PtGa₁₇, which crystallizes in a rhombohedral unit cell in the noncentrosymmetric space group R3m. The crystal structure is closely related to those of XYZ half-Heusler compounds, where X, Y, and Z are reported to be single elements only, occupying three different face-centered-cubic sublattices. The new material, Cr₄PtGa₁₇, can be most straightforwardly illustrated by writing the formula as (PtGa₂)(Cr₄Ga₁₄)Ga (X = PtGa₂, Y = Cr₄Ga₁₄, Z = Ga); that is, the X and Y sites are occupied by clusters instead of single elements. The magnetic Cr occupies a breathing pyrochlore lattice. Ferromagnetic ordering is found below T_C ~ 61 K, by both neutron diffraction and magnetometer studies, with a small, saturated moment of ~0.25 μ_B/Cr observed at 2 K, making Cr₄PtGa₁₇ the first ferromagnetically ordered material with a breathing pyrochlore lattice. A magnetoresistance of ~140% was observed at 2 K. DFT calculations suggest that the material has a nearly half-metallic electronic structure. The new material, Cr₄PtGa₁₇, the first realization of both a half-Heusler-type structure and a breathing pyrochlore lattice, might pave a new way to achieve novel types of half-Heusler compounds.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1883976

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 35 Vol. 143; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (78)

Beneficial Contribution of Alloy Disorder to Electron and Phonon Transport in Half-Heusler Thermoelectric Materials Xie, Hanhui; Wang, Heng; Pei, Yanzhong Advanced Functional Materials, Vol. 23, Issue 41 https://doi.org/10.1002/adfm.201300663	journal	April 2013
High Efficiency Half-Heusler Thermoelectric Materials for Energy Harvesting Zhu, Tiejun; Fu, Chenguang; Xie, Hanhui Advanced Energy Materials, Vol. 5, Issue 19 https://doi.org/10.1002/aenm.201500588	journal	July 2015
Martensitic and Magnetic Transformation Behaviors in Heusler-Type NiMnIn and NiCoMnIn Metamagnetic Shape Memory Alloys Ito, W.; Imano, Y.; Kainuma, R. Metallurgical and Materials Transactions A, Vol. 38, Issue 4 https://doi.org/10.1007/s11661-007-9094-9	journal	April 2007
Magnetoresistive memory technology Daughton, J. M. Thin Solid Films, Vol. 216, Issue 1 https://doi.org/10.1016/0040-6090(92)90888-I	journal	August 1992
Oxide pyrochlores — A review Subramanian, M. A.; Aravamudan, G.; Subba Rao, G. V. Progress in Solid State Chemistry, Vol. 15, Issue 2 https://doi.org/10.1016/0079-6786(83)90001-8	journal	January 1983
Superconductivity in ternary Heusler intermetallic compounds Wernick, J. H.; Hull, G. W.; Geballe, T. H. Materials Letters, Vol. 2, Issue 2 https://doi.org/10.1016/0167-577X(83)90043-5	journal	October 1983
Magnetism in the Huesler alloys: Co2TiSn and Co2TiAl Mohn, P.; Blaha, P.; Schwarz, K. Journal of Magnetism and Magnetic Materials, Vol. 140-144 https://doi.org/10.1016/0304-8853(94)00941-4	journal	February 1995
Recent advances in magnetic structure determination by neutron powder diffraction Rodríguez-Carvajal, Juan Physica B: Condensed Matter, Vol. 192, Issue 1-2 https://doi.org/10.1016/0921-4526(93)90108-I	journal	October 1993
Structural, half-metallic and elastic properties of the half-Heusler compounds NiMnM (M = Sb, As and Si) and IrMnAs from first-principles calculations Wu, Yufeng; Wu, Bo; Wei, Zhenyi Intermetallics, Vol. 53 https://doi.org/10.1016/j.intermet.2014.04.012	journal	October 2014
Recent progress of half-Heusler for moderate temperature thermoelectric applications Chen, Shuo; Ren, Zhifeng Materials Today, Vol. 16, Issue 10 https://doi.org/10.1016/j.mattod.2013.09.015	journal	October 2013
Simple rules for the understanding of Heusler compounds Graf, Tanja; Felser, Claudia; Parkin, Stuart S. P. Progress in Solid State Chemistry, Vol. 39, Issue 1 https://doi.org/10.1016/j.progsolidstchem.2011.02.001	journal	May 2011
Effects of Disorder on the Electronic Structure and Thermoelectric Properties of an Inverse Full-Heusler Mn ₂ CoAl Alloy Li, Hezhang; Hayashi, Kei; Nagashima, Yoshimi Chemistry of Materials, Vol. 33, Issue 7 https://doi.org/10.1021/acs.chemmater.0c04902	journal	March 2021
Thermoelectric Properties of n-type ZrNiPb-Based Half-Heuslers Mao, Jun; Zhou, Jiawei; Zhu, Hangtian Chemistry of Materials, Vol. 29, Issue 2 https://doi.org/10.1021/acs.chemmater.6b04898	journal	January 2017
Designing High-Efficiency Nanostructured Two-Phase Heusler Thermoelectrics Kocevski, Vancho; Wolverton, Chris Chemistry of Materials, Vol. 29, Issue 21 https://doi.org/10.1021/acs.chemmater.7b03379	journal	October 2017
Chemistry of Quantum Spin Liquids Chamorro, Juan R.; McQueen, Tyrel M.; Tran, Thao T. Chemical Reviews, Vol. 121, Issue 5 https://doi.org/10.1021/acs.chemrev.0c00641	journal	November 2020
Exploitable Magnetic Anisotropy of the Two-Dimensional Magnet CrI ₃ Kim, Jeongwoo; Kim, Kyoung-Whan; Kim, Bumseop Nano Letters, Vol. 20, Issue 2 https://doi.org/10.1021/acs.nanolett.9b03815	journal	December 2019
Half-Metallic Ferromagnetism in Synthetic Co ₉ Se ₈ Nanosheets with Atomic Thickness Zhang, Xiaodong; Zhang, Jiajia; Zhao, Jinyang Journal of the American Chemical Society, Vol. 134, Issue 29 https://doi.org/10.1021/ja3046603	journal	July 2012
Half-Metallicity in MnPSe ₃ Exfoliated Nanosheet with Carrier Doping Li, Xingxing; Wu, Xiaojun; Yang, Jinlong Journal of the American Chemical Society, Vol. 136, Issue 31 https://doi.org/10.1021/ja505097m	journal	July 2014
Half-Metallic Ferromagnetism and Large Negative Magnetoresistance in the New Lacunar Spinel GaTi ₃ VS ₈ Dorolti, Eugen; Cario, Laurent; Corraze, Benoît Journal of the American Chemical Society, Vol. 132, Issue 16 https://doi.org/10.1021/ja908128b	journal	April 2010
Zero-point entropy in ‘spin ice’ Ramirez, A. P.; Hayashi, A.; Cava, R. J. Nature, Vol. 399, Issue 6734 https://doi.org/10.1038/20619	journal	May 1999
Time-reversal symmetry breaking and spontaneous Hall effect without magnetic dipole order Machida, Yo; Nakatsuji, Satoru; Onoda, Shigeki Nature, Vol. 463, Issue 7278 https://doi.org/10.1038/nature08680	journal	December 2009
Large, non-saturating magnetoresistance in WTe2 Ali, Mazhar N.; Xiong, Jun; Flynn, Steven Nature, Vol. 514, Issue 7521 https://doi.org/10.1038/nature13763	journal	September 2014
Discovery of intrinsic ferromagnetism in two-dimensional van der Waals crystals Gong, Cheng; Li, Lin; Li, Zhenglu Nature, Vol. 546, Issue 7657 https://doi.org/10.1038/nature22060	journal	April 2017
Layer-dependent ferromagnetism in a van der Waals crystal down to the monolayer limit Huang, Bevin; Clark, Genevieve; Navarro-Moratalla, Efrén Nature, Vol. 546, Issue 7657 https://doi.org/10.1038/nature22391	journal	June 2017
Observation of unusual topological surface states in half-Heusler compounds LnPtBi (Ln=Lu, Y) Liu, Z. K.; Yang, L. X.; Wu, S. -C. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12924	journal	September 2016
Quantum fluctuations in spin-ice-like Pr2Zr2O7 Kimura, K.; Nakatsuji, S.; Wen, J-J. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2914	journal	June 2013
Realizing high figure of merit in heavy-band p-type half-Heusler thermoelectric materials Fu, Chenguang; Bai, Shengqiang; Liu, Yintu Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms9144	journal	September 2015
Tunable multifunctional topological insulators in ternary Heusler compounds Chadov, Stanislav; Qi, Xiaoliang; Kübler, Jürgen Nature Materials, Vol. 9, Issue 7 https://doi.org/10.1038/nmat2770	journal	May 2010
Half-Heusler ternary compounds as new multifunctional experimental platforms for topological quantum phenomena Lin, Hsin; Wray, L. Andrew; Xia, Yuqi Nature Materials, Vol. 9, Issue 7 https://doi.org/10.1038/nmat2771	journal	May 2010
Heusler, Weyl and Berry Manna, Kaustuv; Sun, Yan; Muechler, Lukas Nature Reviews Materials, Vol. 3, Issue 8 https://doi.org/10.1038/s41578-018-0036-5	journal	July 2018
Thickness-dependent magnetic order in CrI3 single crystals Liu, Yu; Wu, Lijun; Tong, Xiao Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-50000-x	journal	September 2019
Formation of breathing pyrochlore lattices: structural, thermodynamic and crystal chemical aspects Talanov, Mikhail V.; Talanov, Valeriy M. CrystEngComm, Vol. 22, Issue 7 https://doi.org/10.1039/C9CE01635J	journal	January 2020
Half Metallic Magnets Pickett, Warren E.; Moodera, Jagadeesh S. Physics Today, Vol. 54, Issue 5 https://doi.org/10.1063/1.1381101	journal	May 2001
Martensitic transformation and shape memory effect in ferromagnetic Heusler alloy Ni2FeGa Liu, Z. H.; Zhang, M.; Cui, Y. T. Applied Physics Letters, Vol. 82, Issue 3 https://doi.org/10.1063/1.1534612	journal	January 2003
Metamagnetic shape memory effect in a Heusler-type Ni43Co7Mn39Sn11 polycrystalline alloy Kainuma, R.; Imano, Y.; Ito, W. Applied Physics Letters, Vol. 88, Issue 19 https://doi.org/10.1063/1.2203211	journal	May 2006
Magnetic Critical Scattering Collins, Malcolm F.; Shapiro, Stephen M. Physics Today, Vol. 43, Issue 10 https://doi.org/10.1063/1.2810726	journal	October 1990
Designing shape-memory Heusler alloys from first-principles Siewert, M.; Gruner, M. E.; Dannenberg, A. Applied Physics Letters, Vol. 99, Issue 19 https://doi.org/10.1063/1.3655905	journal	November 2011
Basics and prospective of magnetic Heusler compounds Felser, Claudia; Wollmann, Lukas; Chadov, Stanislav APL Materials, Vol. 3, Issue 4 https://doi.org/10.1063/1.4917387	journal	April 2015
Realization of multifunctional shape-memory ferromagnets in all- d -metal Heusler phases Wei, Z. Y.; Liu, E. K.; Chen, J. H. Applied Physics Letters, Vol. 107, Issue 2 https://doi.org/10.1063/1.4927058	journal	July 2015
Large low-field positive magnetoresistance in nonmagnetic half-Heusler ScPtBi single crystal Hou, Zhipeng; Wang, Yue; Liu, Enke Applied Physics Letters, Vol. 107, Issue 20 https://doi.org/10.1063/1.4936179	journal	November 2015
Half-Heusler compounds: novel materials for energy and spintronic applications Casper, F.; Graf, T.; Chadov, S. Semiconductor Science and Technology, Vol. 27, Issue 6 https://doi.org/10.1088/0268-1242/27/6/063001	journal	April 2012
First-principles study of exchange interactions and Curie temperatures of half-metallic ferrimagnetic full Heusler alloys Mn ₂ V Z (Z = Al, Ge) Şaşioglu, E.; Sandratskii, L. M.; Bruno, P. Journal of Physics: Condensed Matter, Vol. 17, Issue 6 https://doi.org/10.1088/0953-8984/17/6/017	journal	January 2005
Spin-polarization and electronic properties of half-metallic Heusler alloys calculated from first principles Galanakis, I.; Mavropoulos, Ph Journal of Physics: Condensed Matter, Vol. 19, Issue 31 https://doi.org/10.1088/0953-8984/19/31/315213	journal	July 2007
Crystallographic, magnetic and electronic structures of a new layered ferromagnetic compound Cr ₂ Ge ₂ Te ₆ Carteaux, V.; Brunet, D.; Ouvrard, G. Journal of Physics: Condensed Matter, Vol. 7, Issue 1 https://doi.org/10.1088/0953-8984/7/1/008	journal	January 1995
Behavior of the breathing pyrochlore lattice Ba ₃ Yb ₂ Zn ₅ O ₁₁ in applied magnetic field Rau, J. G.; Wu, L. S.; May, A. F. Journal of Physics: Condensed Matter, Vol. 30, Issue 45 https://doi.org/10.1088/1361-648X/aae45a	journal	October 2018
Ferromagnetism of Cr Be 12 Wolcott, N. M.; Falge, R. L. Physical Review, Vol. 171, Issue 2 https://doi.org/10.1103/PhysRev.171.591	journal	July 1968
Negative magnetoresistance of pregraphitic carbons Bright, A. A. Physical Review B, Vol. 20, Issue 12 https://doi.org/10.1103/PhysRevB.20.5142	journal	December 1979
Full-potential self-consistent linearized-augmented-plane-wave method for calculating the electronic structure of molecules and surfaces: O 2 molecule Wimmer, E.; Krakauer, H.; Weinert, M. Physical Review B, Vol. 24, Issue 2 https://doi.org/10.1103/PhysRevB.24.864	journal	July 1981
Accurate and simple analytic representation of the electron-gas correlation energy Perdew, John P.; Wang, Yue Physical Review B, Vol. 45, Issue 23, p. 13244-13249 https://doi.org/10.1103/PhysRevB.45.13244	journal	June 1992
Theory of polarization of crystalline solids King-Smith, R. D.; Vanderbilt, David Physical Review B, Vol. 47, Issue 3 https://doi.org/10.1103/PhysRevB.47.1651	journal	January 1993
Half-metallic ferrimagnetism in Mn 2 VAl Weht, Ruben; Pickett, Warren E. Physical Review B, Vol. 60, Issue 18 https://doi.org/10.1103/PhysRevB.60.13006	journal	November 1999
Band-structure calculations of the half-metallic ferromagnetism and structural stability of full- and half-Heusler phases Block, T.; Carey, M. J.; Gurney, B. A. Physical Review B, Vol. 70, Issue 20 https://doi.org/10.1103/PhysRevB.70.205114	journal	November 2004
Ni-based superconductor: Heusler compound ZrNi 2 Ga Winterlik, Jürgen; Fecher, Gerhard H.; Felser, Claudia Physical Review B, Vol. 78, Issue 18 https://doi.org/10.1103/PhysRevB.78.184506	journal	November 2008
Superconductivity in palladium-based Heusler compounds Winterlik, Jürgen; Fecher, Gerhard H.; Thomas, Anja Physical Review B, Vol. 79, Issue 6 https://doi.org/10.1103/PhysRevB.79.064508	journal	February 2009
Magnetic properties of the half-metallic Heusler alloys Co 2 VAl and Co 2 VGa under pressure Kanomata, T.; Chieda, Y.; Endo, K. Physical Review B, Vol. 82, Issue 14 https://doi.org/10.1103/PhysRevB.82.144415	journal	October 2010
Superconductivity in the Heusler family of intermetallics Klimczuk, T.; Wang, C. H.; Gofryk, K. Physical Review B, Vol. 85, Issue 17 https://doi.org/10.1103/PhysRevB.85.174505	journal	May 2012
Experimental realization of a quantum breathing pyrochlore antiferromagnet Kimura, K.; Nakatsuji, S.; Kimura, T. Physical Review B, Vol. 90, Issue 6 https://doi.org/10.1103/PhysRevB.90.060414	journal	August 2014
Magnetic structure of the antiferromagnetic half-Heusler compound NdBiPt Müller, R. A.; Desilets-Benoit, A.; Gauthier, N. Physical Review B, Vol. 92, Issue 18 https://doi.org/10.1103/PhysRevB.92.184432	journal	November 2015
Quantum spin ice on the breathing pyrochlore lattice Savary, Lucile; Wang, Xiaoqun; Kee, Hae-Young Physical Review B, Vol. 94, Issue 7 https://doi.org/10.1103/PhysRevB.94.075146	journal	August 2016
Negative thermal expansion and magnetoelastic coupling in the breathing pyrochlore lattice material LiGaCr 4 S 8 Pokharel, G.; May, A. F.; Parker, D. S. Physical Review B, Vol. 97, Issue 13 https://doi.org/10.1103/PhysRevB.97.134117	journal	April 2018
Half-Heusler Compounds as a New Class of Three-Dimensional Topological Insulators Xiao, Di; Yao, Yugui; Feng, Wanxiang Physical Review Letters, Vol. 105, Issue 9 https://doi.org/10.1103/PhysRevLett.105.096404	journal	August 2010
Breathing Pyrochlore Lattice Realized in A -Site Ordered Spinel Oxides LiGaCr 4 O 8 and LiInCr 4 O 8 Okamoto, Yoshihiko; Nilsen, Gøran J.; Attfield, J. Paul Physical Review Letters, Vol. 110, Issue 9 https://doi.org/10.1103/PhysRevLett.110.097203	journal	February 2013
Cluster Frustration in the Breathing Pyrochlore Magnet LiGaCr 4 S 8 Pokharel, Ganesh; Arachchige, Hasitha Suriya; Williams, Travis J. Physical Review Letters, Vol. 125, Issue 16 https://doi.org/10.1103/PhysRevLett.125.167201	journal	October 2020
New Class of Materials: Half-Metallic Ferromagnets de Groot, R. A.; Mueller, F. M.; Engen, P. G. van Physical Review Letters, Vol. 50, Issue 25 https://doi.org/10.1103/PhysRevLett.50.2024	journal	June 1983
Geometrical Frustration in the Ferromagnetic Pyrochlore Ho 2 Ti 2 O 7 Harris, M. J.; Bramwell, S. T.; McMorrow, D. F. Physical Review Letters, Vol. 79, Issue 13 https://doi.org/10.1103/PhysRevLett.79.2554	journal	September 1997
Local Spin Resonance and Spin-Peierls-like Phase Transition in a Geometrically Frustrated Antiferromagnet Lee, S. -H.; Broholm, C.; Kim, T. H. Physical Review Letters, Vol. 84, Issue 16 https://doi.org/10.1103/PhysRevLett.84.3718	journal	April 2000
Statics and Dynamics of Incommensurate Spin Order in a Geometrically Frustrated Antiferromagnet CdCr 2 O 4 Chung, J. -H.; Matsuda, M.; Lee, S. -H. Physical Review Letters, Vol. 95, Issue 24 https://doi.org/10.1103/PhysRevLett.95.247204	journal	December 2005
Quantum Excitations in Quantum Spin Ice Ross, Kate A.; Savary, Lucile; Gaulin, Bruce D. Physical Review X, Vol. 1, Issue 2 https://doi.org/10.1103/PhysRevX.1.021002	journal	October 2011
Magnetic pyrochlore oxides Gardner, Jason S.; Gingras, Michel J. P.; Greedan, John E. Reviews of Modern Physics, Vol. 82, Issue 1 https://doi.org/10.1103/RevModPhys.82.53	journal	January 2010
An empirical method for correcting diffractometer data for absorption effects Walker, N.; Stuart, D. Acta Crystallographica Section A Foundations of Crystallography, Vol. 39, Issue 1 https://doi.org/10.1107/S0108767383000252	journal	January 1983
Crystal structure refinement with SHELXL Sheldrick, George M. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053229614024218	journal	January 2015
Topological R PdBi half-Heusler semimetals: A new family of noncentrosymmetric magnetic superconductors Nakajima, Yasuyuki; Hu, Rongwei; Kirshenbaum, Kevin Science Advances, Vol. 1, Issue 5 https://doi.org/10.1126/sciadv.1500242	journal	June 2015
Negative Magneto-Resistance in Pyrolytic Carbons Yazawa, Kazuhiko Journal of the Physical Society of Japan, Vol. 26, Issue 6 https://doi.org/10.1143/JPSJ.26.1407	journal	June 1969
Heusler 4.0: Tunable Materials Wollmann, Lukas; Nayak, Ajaya K.; Parkin, Stuart S. P. Annual Review of Materials Research, Vol. 47, Issue 1 https://doi.org/10.1146/annurev-matsci-070616-123928	journal	July 2017
Superconductivity and magnetic order in the noncentrosymmetric half-Heusler compound ErPdBi Pan, Y.; Nikitin, A. M.; Bay, T. V. EPL (Europhysics Letters), Vol. 104, Issue 2 https://doi.org/10.1209/0295-5075/104/27001	journal	October 2013
DEMAND, a Dimensional Extreme Magnetic Neutron Diffractometer at the High Flux Isotope Reactor Cao, Huibo; Chakoumakos, Bryan; Andrews, Katie Crystals, Vol. 9, Issue 1 https://doi.org/10.3390/cryst9010005	journal	December 2018
Magnetic and Structural Properties of A-Site Ordered Chromium Spinel Sulfides: Alternating Antiferromagnetic and Ferromagnetic Interactions in the Breathing Pyrochlore Lattice Okamoto, Yoshihiko; Mori, Masaki; Katayama, Naoyuki Journal of the Physical Society of Japan, Vol. 87, Issue 3 https://doi.org/10.7566/JPSJ.87.034709	journal	March 2018
Magnetic anisotropy of the single-crystalline ferromagnetic insulator Cr ₂ Ge ₂ Te ₆ Zhang, Xiao; Zhao, Yuelei; Song, Qi Japanese Journal of Applied Physics, Vol. 55, Issue 3 https://doi.org/10.7567/JJAP.55.033001	journal	February 2016

Similar Records

On the brass- and silver-colored forms of PTGA{sub 2}

Conference · 1996 · OSTI ID:414108

Morosin, B; Swenson, D

Synthesis, structure, and magnetism of Tb{sub 4}PdGa{sub 12} and Tb{sub 4}PtGa{sub 12}

Journal Article · 2005 · Journal of Solid State Chemistry · OSTI ID:20721665

Williams, Willa M; Moldovan, M; Young, D P; +1 more

Experimental and theoretical study of the electronic structure of PtGa{sub 2}

Journal Article · 2001 · Physical Review B · OSTI ID:40205477

Hsu, Li-Shing; Guo, G Y; Denlinger, J D; +1 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Crystal structure
Lattices
Magnetic properties
Materials
Physiology

Title: Ferromagnetic Cr4PtGa17: A Half-Heusler-Type Compound with a Breathing Pyrochlore Lattice

Citation Formats

References (78)

Linked Research (1)

Similar Records

Related Subjects

Title: Ferromagnetic Cr₄PtGa₁₇: A Half-Heusler-Type Compound with a Breathing Pyrochlore Lattice