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Title: Unraveling hydridic-to-protonic dihydrogen bond predominance in monohydrated dodecaborate clusters

Journal Article · · Chemical Science
DOI: https://doi.org/10.1039/D2SC03986A · OSTI ID:1881356
 [1];  [2]; ORCiD logo [3];  [1]; ORCiD logo [1];  [4];  [1]; ORCiD logo [5]; ORCiD logo [3];  [5]
  1. State Key Laboratory of Precision Spectroscopy, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China
  2. Physical Sciences Division, Pacific Northwest National Laboratory, 902 Battelle Boulevard, P. O. Box 999, MS K8-88, Richland, Washington 99352, USA, Department of Chemistry, Anhui University, Hefei, Anhui, 230601, China
  3. Physical Sciences Division, Pacific Northwest National Laboratory, 902 Battelle Boulevard, P. O. Box 999, MS K8-88, Richland, Washington 99352, USA
  4. College of Chemistry & Molecular Sciences, Wuhan University, Wuhan, Hubei 430072, China
  5. State Key Laboratory of Precision Spectroscopy, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, China, Collaborative Innovation Center of Extreme Optics, Shanxi University, Taiyuan, Shanxi 030006, China
+ Show Author Affiliations

A joint gas-phase ion spectroscopic and multiscale theoretical study reveals unequivocally the predominance of the hydridic-to-protonic dihydrogen bond over the prototypical strong hydrogen bond in monohydrated dodecaborate clusters.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
National Natural Science Foundation of China (NSFC); Project 111; Shanghai Rising-Star Program; USDOE
Grant/Contract Number:
AC05-76RL01830
OSTI ID:
1881356
Report Number(s):
PNNL-SA-176151
Journal Information:
Chemical Science, Journal Name: Chemical Science Journal Issue: 34 Vol. 13; ISSN 2041-6520; ISSN CSHCBM
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

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