Experimental Determination of the Relationship Between Organic Aerosol Viscosity and Ice Nucleation at Upper Free Tropospheric Conditions

Kasparoglu, Sabin; Perkins, Russell; Ziemann, Paul J.; DeMott, Paul J.; Kreidenweis, Sonia M.; Finewax, Zachary; Deming, Benjamin L.; DeVault, Marla P.; Petters, Markus D.

doi:10.1029/2021JD036296

Title: Experimental Determination of the Relationship Between Organic Aerosol Viscosity and Ice Nucleation at Upper Free Tropospheric Conditions

Journal Article · 12 August 2022 · Journal of Geophysical Research: Atmospheres

DOI: https://doi.org/10.1029/2021JD036296 · OSTI ID:1881060

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Department of Marine, Earth, and Atmospheric Sciences NC State University Raleigh NC USA
Department of Atmospheric Science Colorado State University Fort Collins CO USA
University of Colorado Boulder Boulder CO USA
University of Colorado Boulder Boulder CO USA, Now at NOAA Chemical Sciences Laboratory Boulder CO USA

Abstract This work presents measurements of the ice nucleating ability of secondary organic material recorded between −40 and −70°C and relative humidity with respect to ice (RH _ice ) between 150% and 220%. For a subset of systems, temperature and humidity dependence of particle viscosity as well as dry glass transition temperature were characterized using the dual tandem differential mobility analyzer method. Eleven unique monoterpene, sesquiterpene and aromatic precursors were used to generate secondary organic material (SOM) using either an oxidation flow reactor (OFR) or an environmental chamber (EC). For the SOM for which viscosity was measured, the particle glass transition temperatures varied between 6 and 23°C ( n = 8). Measurements were performed to verify that increased relative humidity did not plasticize the particles below −10°C at residence times similar to those in the ice nucleation instrument. No heterogeneous ice nucleation was observed at the ∼0.5% onset threshold for any of the materials generated. The ice nucleation occurs by the freezing of SOM solution droplets consistent with homogeneous freezing indicating that they form an aqueous solution, or the SOM particles required water saturation to freeze, indicating that they were hydrophobic. Experiments exploring the influence of functional groups and mass loading did not reveal any obvious influence of particle chemistry or generation conditions on the results. Close structural matches between known organic ice nucleating particles as precursor or formed products did not yield materials that promoted freezing. These experiments suggest that heterogeneous ice formation of glassy secondary organic materials is likely uncommon under upper free tropospheric conditions.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0018265

OSTI ID:: 1881060

Journal Information:: Journal of Geophysical Research: Atmospheres, Journal Name: Journal of Geophysical Research: Atmospheres Journal Issue: 16 Vol. 127; ISSN 2169-897X

Publisher:: American Geophysical Union (AGU)Copyright Statement

Country of Publication:: United States

Language:: English

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Ice nucleation by surrogates for atmospheric mineral dust and mineral dust/sulfate particles at cirrus temperatures Archuleta, C. M.; DeMott, P. J.; Kreidenweis, S. M. Atmospheric Chemistry and Physics, Vol. 5, Issue 10 https://doi.org/10.5194/acp-5-2617-2005	journal	January 2005
A single parameter representation of hygroscopic growth and cloud condensation nucleus activity Petters, M. D.; Kreidenweis, S. M. Atmospheric Chemistry and Physics, Vol. 7, Issue 8 https://doi.org/10.5194/acp-7-1961-2007	journal	January 2007
The formation, properties and impact of secondary organic aerosol: current and emerging issues Hallquist, M.; Wenger, J. C.; Baltensperger, U. Atmospheric Chemistry and Physics, Vol. 9, Issue 14 https://doi.org/10.5194/acp-9-5155-2009	journal	January 2009
Influence of particle size on the ice nucleating ability of mineral dusts Welti, A.; Lüönd, F.; Stetzer, O. Atmospheric Chemistry and Physics, Vol. 9, Issue 18 https://doi.org/10.5194/acp-9-6705-2009	journal	January 2009
Characterization of a thermodenuder-particle beam mass spectrometer system for the study of organic aerosol volatility and composition Faulhaber, A. E.; Thomas, B. M.; Jimenez, J. L. Atmospheric Measurement Techniques, Vol. 2, Issue 1 https://doi.org/10.5194/amt-2-15-2009	journal	January 2009
The Model of Emissions of Gases and Aerosols from Nature version 2.1 (MEGAN2.1): an extended and updated framework for modeling biogenic emissions Guenther, A. B.; Jiang, X.; Heald, C. L. Geoscientific Model Development, Vol. 5, Issue 6 https://doi.org/10.5194/gmd-5-1471-2012	journal	January 2012
Dataset for "Experimental determination of the relationship between organic aerosol viscosity and ice nucleation at upper free tropospheric conditions" Kasparoglu, Sabin; Perkins, Russell; Ziemann, Paul J. Zenodo https://doi.org/10.5281/ZENODO.6547307	dataset	January 2022

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