Metal–Organic Frameworks with Low‐Valent Metal Nodes

Sikma, R. Eric; Balto, Krista P.; Figueroa, Joshua S.; Cohen, Seth M.

doi:10.1002/ange.202206353

Title: Metal–Organic Frameworks with Low‐Valent Metal Nodes

Journal Article · 19 July 2022 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.202206353 · OSTI ID:1880723

Sikma, R. Eric ^[1];

^[1];

^[1]

Department of Chemistry and Biochemistry University of California, San Diego La Jolla CA 92093 USA

Abstract Metal–organic frameworks (MOFs) are crystalline, 2‐ and 3‐dimensional coordination polymers formed by bonding interactions between metals and multitopic organic ligands. These are typically formed using hard Lewis basic organic ligands with high oxidation state metal ions. The use of low‐valent metals as structural elements in MOFs is far less common, despite the widespread use of such metals for catalysis, luminescence, and other applications. This Minireview focuses on recent advances in the field of low‐valent MOFs and offers a perspective on the future development of these materials.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02-08ER46519; SC0018243

OSTI ID:: 1880723

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 33 Vol. 134; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (104)

A Nanoporous Metal-Organic Framework Based on Bulky Phosphane Ligands Xu, Xingling; Nieuwenhuyzen, Mark; James, Stuart L. Angewandte Chemie, Vol. 114, Issue 5 https://doi.org/10.1002/1521-3757(20020301)114:5<790::AID-ANGE790>3.0.CO;2-7	journal	March 2002
N-Heterocyclische Carbene: ein neues Konzept in der metallorganischen Katalyse N-Heterocyclische Carbene, 31. Mitteilung. – 30. Mitteilung: Lit. [80] Herrmann, Wolfgang A. Angewandte Chemie, Vol. 114, Issue 8 https://doi.org/10.1002/1521-3757(20020415)114:8<1342::AID-ANGE1342>3.0.CO;2-A	journal	April 2002
A Nanoporous Metal–Organic Framework Based on Bulky Phosphane Ligands We thank the McClay Trust and the EPSRC for funding, and are grateful to the referees for their suggestions. Xu, Xingling; Nieuwenhuyzen, Mark; James, Stuart L. Angewandte Chemie International Edition, Vol. 41, Issue 5 https://doi.org/10.1002/1521-3773(20020301)41:5<764::AID-ANIE764>3.0.CO;2-N	journal	March 2002
N-Heterocyclic Carbenes: A New Concept in Organometallic Catalysis Herrmann, Wolfgang A. Angewandte Chemie International Edition, Vol. 41, Issue 8 https://doi.org/10.1002/1521-3773(20020415)41:8<1290::AID-ANIE1290>3.0.CO;2-Y	journal	April 2002
Introduction to Reticular Chemistry Yaghi, Omar M.; Kalmutzki, Markus J.; Diercks, Christian S. Wiley‐VCH Verlag GmbH & Co. https://doi.org/10.1002/9783527821099	journal	January 2019
Funktionale poröse Koordinationspolymere Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro Angewandte Chemie, Vol. 116, Issue 18 https://doi.org/10.1002/ange.200300610	journal	April 2004
Supramolecular Tetrahedra of Phosphines and Coinage Metals Lim, Sang Ho; Su, Yongxuan; Cohen, Seth M. Angewandte Chemie, Vol. 124, Issue 21 https://doi.org/10.1002/ange.201200730	journal	April 2012
Scorpionate-Type Coordination in MFU-4 l Metal-Organic Frameworks: Small-Molecule Binding and Activation upon the Thermally Activated Formation of Open Metal Sites Denysenko, Dmytro; Grzywa, Maciej; Jelic, Jelena Angewandte Chemie, Vol. 126, Issue 23 https://doi.org/10.1002/ange.201310004	journal	May 2014
Multifunktionale, Defekt-manipulierte Metall-organische Gerüste mit Rutheniumzentren: Sorption und katalytische Eigenschaften Kozachuk, Olesia; Luz, Ignacio; Llabrés i. Xamena, Francesc X. Angewandte Chemie, Vol. 126, Issue 27 https://doi.org/10.1002/ange.201311128	journal	May 2014
Postsynthetic Improvement of the Physical Properties in a Metal-Organic Framework through a Single Crystal to Single Crystal Transmetallation Grancha, Thais; Ferrando-Soria, Jesús; Zhou, Hong-Cai Angewandte Chemie, Vol. 127, Issue 22 https://doi.org/10.1002/ange.201501691	journal	April 2015
A Metal-Organic Framework with Cooperative Phosphines That Permit Post-Synthetic Installation of Open Metal Sites Dunning, Samuel G.; Nandra, Gianne; Conn, Adam D. Angewandte Chemie, Vol. 130, Issue 30 https://doi.org/10.1002/ange.201802402	journal	June 2018
Metal–Organic Frameworks with Zero and Low‐Valent Metal Nodes Connected by Tetratopic Phosphine Ligands Sikma, R. Eric; Cohen, Seth M. Angewandte Chemie, Vol. 134, Issue 11 https://doi.org/10.1002/ange.202115454	journal	January 2022
Functional Porous Coordination Polymers Kitagawa, Susumu; Kitaura, Ryo; Noro, Shin-ichiro Angewandte Chemie International Edition, Vol. 43, Issue 18, p. 2334-2375 https://doi.org/10.1002/anie.200300610	journal	April 2004
Supramolecular Tetrahedra of Phosphines and Coinage Metals Lim, Sang Ho; Su, Yongxuan; Cohen, Seth M. Angewandte Chemie International Edition, Vol. 51, Issue 21 https://doi.org/10.1002/anie.201200730	journal	April 2012
Scorpionate-Type Coordination in MFU-4 l Metal-Organic Frameworks: Small-Molecule Binding and Activation upon the Thermally Activated Formation of Open Metal Sites Denysenko, Dmytro; Grzywa, Maciej; Jelic, Jelena Angewandte Chemie International Edition, Vol. 53, Issue 23 https://doi.org/10.1002/anie.201310004	journal	May 2014
Multifunctional, Defect-Engineered Metal-Organic Frameworks with Ruthenium Centers: Sorption and Catalytic Properties Kozachuk, Olesia; Luz, Ignacio; Llabrés i. Xamena, Francesc X. Angewandte Chemie International Edition, Vol. 53, Issue 27 https://doi.org/10.1002/anie.201311128	journal	May 2014
Postsynthetic Improvement of the Physical Properties in a Metal-Organic Framework through a Single Crystal to Single Crystal Transmetallation Grancha, Thais; Ferrando-Soria, Jesús; Zhou, Hong-Cai Angewandte Chemie International Edition, Vol. 54, Issue 22 https://doi.org/10.1002/anie.201501691	journal	April 2015
A Metal-Organic Framework with Cooperative Phosphines That Permit Post-Synthetic Installation of Open Metal Sites Dunning, Samuel G.; Nandra, Gianne; Conn, Adam D. Angewandte Chemie International Edition, Vol. 57, Issue 30 https://doi.org/10.1002/anie.201802402	journal	June 2018
Metal–Organic Frameworks with Zero and Low‐Valent Metal Nodes Connected by Tetratopic Phosphine Ligands Sikma, R. Eric; Cohen, Seth M. Angewandte Chemie International Edition, Vol. 61, Issue 11 https://doi.org/10.1002/anie.202115454	journal	January 2022
Elucidating Gating Effects for Hydrogen Sorption in MFU-4-Type Triazolate-Based Metal-Organic Frameworks Featuring Different Pore Sizes Denysenko, Dmytro; Grzywa, Maciej; Tonigold, Markus Chemistry - A European Journal, Vol. 17, Issue 6 https://doi.org/10.1002/chem.201001872	journal	January 2011
Main-Chain Organometallic Microporous Polymers Based on Triptycene: Synthesis and Catalytic Application in the Suzuki-Miyaura Coupling Reaction Zhang, Chun; Wang, Jing-Jing; Liu, Ying Chemistry - A European Journal, Vol. 19, Issue 16 https://doi.org/10.1002/chem.201203975	journal	March 2013
Main-Chain Organometallic Microporous Polymers Bearing Triphenylene-Tris(N-Heterocyclic Carbene)-Gold Species: Catalytic Properties Gonell, Sergio; Poyatos, Macarena; Peris, Eduardo Chemistry - A European Journal, Vol. 20, Issue 19 https://doi.org/10.1002/chem.201400371	journal	March 2014
Synthetic and Structural Studies on High-Nuclearity Silver Ethynide Cluster Systems Xie, Yun-Peng; Mak, Thomas C. W. Journal of Cluster Science, Vol. 25, Issue 1 https://doi.org/10.1007/s10876-013-0651-7	journal	October 2013
The stabilisation of low valent states of the transition metals Chatt, Joseph Journal of Inorganic and Nuclear Chemistry, Vol. 8 https://doi.org/10.1016/0022-1902(58)80223-7	journal	January 1958
Heterogeneous catalytic hydrogenation of alkenes and alkynes in the presence of coordination polymers of palladium(0;II) and platinum(0;II) Jaffe, Irene; Segal, Marcos; Efraty, Avi Journal of Organometallic Chemistry, Vol. 294, Issue 2 https://doi.org/10.1016/0022-328X(85)87477-5	journal	October 1985
New palladium(O) and platinum(O) 4,4'-diisocyanobiphenyl matrices for heterogeneous catalytic hydrogenation of alkenes and alkynes Feinstein-Jaffe, Irene; Efraty, Avi Journal of Molecular Catalysis, Vol. 35, Issue 3 https://doi.org/10.1016/0304-5102(86)87076-6	journal	June 1986
Zerovalent transition metal complexes of organic isocyanides Yamamoto, Yasuhiro Coordination Chemistry Reviews, Vol. 32, Issue 3 https://doi.org/10.1016/S0010-8545(00)80375-6	journal	August 1980
Excited state properties of transition metal phosphine complexes Vogler, Arnd; Kunkely, Horst Coordination Chemistry Reviews, Vol. 230, Issue 1-2 https://doi.org/10.1016/S0010-8545(01)00438-6	journal	August 2002
Homogeneous catalysis with transition metal complexes containing sulfur ligands Bayón, J. Carles; Claver, Carmen; Masdeu-Bultó, Anna M. Coordination Chemistry Reviews, Vol. 193-195 https://doi.org/10.1016/S0010-8545(99)00169-1	journal	October 1999
Ordered copper aryldiisocyanide polymers from soluble Cu(I) precursors Feinstein-Jaffe, Irene; Biran, Inbal; Mahalu, Diana Inorganica Chimica Acta, Vol. 154, Issue 2 https://doi.org/10.1016/S0020-1693(00)90127-0	journal	December 1988
Metal–organic frameworks containing N-heterocyclic carbenes and their precursors Ezugwu, Chizoba I.; Kabir, Nawsad Alam; Yusubov, Mekhman Coordination Chemistry Reviews, Vol. 307 https://doi.org/10.1016/j.ccr.2015.06.012	journal	January 2016
Pore engineering of metal-organic frameworks with coordinating functionalities Jeoung, Sungeun; Kim, Seongwoo; Kim, Min Coordination Chemistry Reviews, Vol. 420 https://doi.org/10.1016/j.ccr.2020.213377	journal	October 2020
Two- and three-dimensional silver acetylide frameworks with high-nuclearity silver cluster building blocks assembled using a bifunctional (4-ethynylphenyl)diphenyl phosphine ligand Zhang, Shaokang; Zhang, Zongyao; Cao, Rui Inorganica Chimica Acta, Vol. 461 https://doi.org/10.1016/j.ica.2017.01.030	journal	May 2017
MOFs as catalysts: Activity, reusability and shape-selectivity of a Pd-containing MOF Llabrés i Xamena, Françesc X.; Abad, Alberto; Corma, Avelino Journal of Catalysis, Vol. 250, Issue 2, p. 294-298 https://doi.org/10.1016/j.jcat.2007.06.004	journal	September 2007
Electron donor-acceptor properties of substituted pyridine ligands on fac-tricarbonylrhenium(I) systems Farrell, Joshua R.; Kerins, Gerard J.; Niederhoffer, Kira L. Journal of Organometallic Chemistry, Vol. 813 https://doi.org/10.1016/j.jorganchem.2016.03.030	journal	July 2016
Building thiol and metal-thiolate functions into coordination nets: Clues from a simple molecule He, Jun; Yang, Chen; Xu, Zhengtao Journal of Solid State Chemistry, Vol. 182, Issue 7 https://doi.org/10.1016/j.jssc.2009.04.024	journal	July 2009
Silver(I) macrocycles and coordination polymers containing pyridyl carboxylate and phosphine ligands Kole, Goutam Kumar; Chin, Chia Keat; Tan, Geok Kheng Polyhedron, Vol. 52 https://doi.org/10.1016/j.poly.2012.04.003	journal	March 2013
Site Isolation in Metal–Organic Frameworks Enables Novel Transition Metal Catalysis Drake, Tasha; Ji, Pengfei; Lin, Wenbin Accounts of Chemical Research, Vol. 51, Issue 9 https://doi.org/10.1021/acs.accounts.8b00297	journal	August 2018
Metal–Organic Frameworks: Examples, Counterexamples, and an Actionable Definition Seth, Saona; Matzger, Adam J. Crystal Growth & Design, Vol. 17, Issue 8 https://doi.org/10.1021/acs.cgd.7b00808	journal	June 2017
Elucidating the Structure of the Metal–Organic Framework Ru-HKUST-1 Lorzing, Gregory R.; Balto, Krista P.; Antonio, Alexandra M. Chemistry of Materials, Vol. 32, Issue 18 https://doi.org/10.1021/acs.chemmater.0c01944	journal	August 2020
Computational Ligand Descriptors for Catalyst Design Durand, Derek J.; Fey, Natalie Chemical Reviews, Vol. 119, Issue 11 https://doi.org/10.1021/acs.chemrev.8b00588	journal	October 2018
Aqueous Stability and Ligand Substitution of a Layered Cu(I)/Isocyanide-Based Organometallic Network Material with a Well-Defined Channel Structure Arroyave, Alejandra; Gembicky, Milan; Rheingold, Arnold L. Inorganic Chemistry, Vol. 59, Issue 17 https://doi.org/10.1021/acs.inorgchem.0c01630	journal	August 2020
Crystalline Hydrogen-Bonding Networks and Mixed-Metal Framework Materials Enabled by an Electronically Differentiated Heteroditopic Isocyanide/Carboxylate Linker Group Balto, Krista P.; Gembicky, Milan; Rheingold, Arnold L. Inorganic Chemistry, Vol. 60, Issue 16 https://doi.org/10.1021/acs.inorgchem.1c01804	journal	August 2021
Single-Crystal-to-Single-Crystal Metalation of a Metal–Organic Framework: A Route toward Structurally Well-Defined Catalysts Gonzalez, Miguel I.; Bloch, Eric D.; Mason, Jarad A. Inorganic Chemistry, Vol. 54, Issue 6 https://doi.org/10.1021/acs.inorgchem.5b00096	journal	February 2015
In Situ Construction of Three Anion-Dependent Cu(I) Coordination Networks as Promising Heterogeneous Catalysts for Azide–Alkyne “Click” Reactions Xu, Zhenghu; Han, Lu−Lu; Zhuang, Gui−Lin Inorganic Chemistry, Vol. 54, Issue 10 https://doi.org/10.1021/acs.inorgchem.5b00110	journal	April 2015
Cu(I) Coordination Polymers as the Green Heterogeneous Catalysts for Direct C–H Bonds Activation of Arylalkanes to Ketones in Water with Spatial Confinement Effect Wang, Xiaolu; Liu, Mengjia; Wang, Yuqing Inorganic Chemistry, Vol. 56, Issue 21 https://doi.org/10.1021/acs.inorgchem.7b02106	journal	October 2017
Structural Diversity of Copper(I) Cluster-Based Coordination Polymers with Pyrazine-2-thiol Ligand Liang, Xiao-Qian; Gupta, Rakesh Kumar; Li, Yun-Wu Inorganic Chemistry, Vol. 59, Issue 5 https://doi.org/10.1021/acs.inorgchem.9b02919	journal	February 2020
Fundamental Insights into the Reactivity and Utilization of Open Metal Sites in Cu(I)-MFU-4 l Li, Lin; Yang, Yahui; Mohamed, Mona H. Organometallics, Vol. 38, Issue 18 https://doi.org/10.1021/acs.organomet.9b00351	journal	August 2019
Functionalized Ruthenium–Phosphine Metal–Organic Framework for Continuous Vapor-Phase Dehydrogenation of Formic Acid Beloqui Redondo, Amaia; Morel, Flavien L.; Ranocchiari, Marco ACS Catalysis, Vol. 5, Issue 12 https://doi.org/10.1021/acscatal.5b01987	journal	November 2015
Standard Practices of Reticular Chemistry Gropp, Cornelius; Canossa, Stefano; Wuttke, Stefan ACS Central Science, Vol. 6, Issue 8 https://doi.org/10.1021/acscentsci.0c00592	journal	July 2020
Postsynthetic Modification: An Enabling Technology for the Advancement of Metal–Organic Frameworks Kalaj, Mark; Cohen, Seth M. ACS Central Science, Vol. 6, Issue 7 https://doi.org/10.1021/acscentsci.0c00690	journal	July 2020
Computational Perspective on Pd-Catalyzed C–C Cross-Coupling Reaction Mechanisms García-Melchor, Max; Braga, Ataualpa A. C.; Lledós, Agustí Accounts of Chemical Research, Vol. 46, Issue 11 https://doi.org/10.1021/ar400080r	journal	July 2013
Three-Dimensional Phosphine Metal–Organic Frameworks Assembled from Cu(I) and Pyridyl Diphosphine Tan, Xin; Li, Lei; Zhang, Jianyong Chemistry of Materials, Vol. 24, Issue 3 https://doi.org/10.1021/cm202608f	journal	December 2011
Chiral Sulfur Ligands for Asymmetric Catalysis Mellah, Mohamed; Voituriez, Arnaud; Schulz, Emmanuelle Chemical Reviews, Vol. 107, Issue 11 https://doi.org/10.1021/cr068440h	journal	October 2007
Photochemistry of metal carbonyls Wrighton, Mark Chemical Reviews, Vol. 74, Issue 4 https://doi.org/10.1021/cr60290a001	journal	August 1974
Stable Carbenes Bourissou, Didier; Guerret, Olivier; Gabbaï, François P. Chemical Reviews, Vol. 100, Issue 1 https://doi.org/10.1021/cr940472u	journal	January 2000
H ₂ , N ₂ , CO, and CO ₂ Sorption Properties of a Series of Robust Sodalite-Type Microporous Coordination Polymers Navarro, Jorge A. R.; Barea, Elisa; Salas, Juan M. Inorganic Chemistry, Vol. 45, Issue 6 https://doi.org/10.1021/ic060049r	journal	March 2006
Self-Assembled Supramolecular Clusters Based on Phosphines and Coinage Metals: Tetrahedra, Helicates, and Mesocates Lim, Sang Ho; Cohen, Seth M. Inorganic Chemistry, Vol. 52, Issue 14 https://doi.org/10.1021/ic302840x	journal	June 2013
Comparative Measure of the Electronic Influence of Highly Substituted Aryl Isocyanides Carpenter, Alex E.; Mokhtarzadeh, Charles C.; Ripatti, Donald S. Inorganic Chemistry, Vol. 54, Issue 6 https://doi.org/10.1021/ic5030845	journal	February 2015
Solution Behavior and Structural Properties of Cu(I) Complexes Featuring m -Terphenyl Isocyanides Fox, Brian J.; Sun, Queena Y.; DiPasquale, Antonio G. Inorganic Chemistry, Vol. 47, Issue 19 https://doi.org/10.1021/ic8010986	journal	October 2008
Metal-acetylide bonding in (.eta.5-C5H5)Fe(CO)2C.tplbond.CR compounds. Measures of metal-d.pi.-acetylide-.pi. interactions from photoelectron spectroscopy Lichtenberger, Dennis L.; Renshaw, Sharon K.; Bullock, R. Morris Journal of the American Chemical Society, Vol. 115, Issue 8 https://doi.org/10.1021/ja00061a028	journal	April 1993
Hydrothermal Synthesis of a Metal-Organic Framework Containing Large Rectangular Channels Yaghi, O. M.; Li, Hailian Journal of the American Chemical Society, Vol. 117, Issue 41, p. 10401-10402 https://doi.org/10.1021/ja00146a033	journal	October 1995
Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3D-linked molecular rods. A reappraisal of the zinc cyanide and cadmium cyanide structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4][CuIZnII(CN)4] and CuI[4,4',4'',4'''-tetracyanotetraphenylmethane]BF4.xC6H5NO2 Hoskins, B. F.; Robson, Richard Journal of the American Chemical Society, Vol. 112, Issue 4 https://doi.org/10.1021/ja00160a038	journal	February 1990
Infinite polymeric frameworks consisting of three dimensionally linked rod-like segments Hoskins, Bernard F.; Robson, Richard Journal of the American Chemical Society, Vol. 111, Issue 15 https://doi.org/10.1021/ja00197a079	journal	July 1989
Strongly Luminescent Three-Coordinate Gold(I) Polymers: 1D Chain-Link Fence and 2D Chickenwire Structures Brandys, Marie-Claude; Puddephatt, Richard J. Journal of the American Chemical Society, Vol. 123, Issue 20 https://doi.org/10.1021/ja010128w	journal	April 2001
Polymeric Complexes of Silver(I) with Diphosphine Ligands: Self-Assembly of a Puckered Sheet Network Structure Brandys, Marie-Claude; Puddephatt, Richard J. Journal of the American Chemical Society, Vol. 124, Issue 15 https://doi.org/10.1021/ja0113293	journal	March 2002
Reversible Anion Exchange and Catalytic Properties of Two Cationic Metal−Organic Frameworks Based on Cu(I) and Ag(I) Fei, Honghan; Rogow, David L.; Oliver, Scott R. J. Journal of the American Chemical Society, Vol. 132, Issue 20 https://doi.org/10.1021/ja102134c	journal	May 2010
A Practice of Reticular Chemistry: Construction of a Robust Mesoporous Palladium Metal–Organic Framework via Metal Metathesis He, Tao; Kong, Xiang-Jing; Zhou, Jian Journal of the American Chemical Society, Vol. 143, Issue 26 https://doi.org/10.1021/jacs.1c04077	journal	June 2021
Low-Valent Metal Ions as MOF Pillars: A New Route Toward Stable and Multifunctional MOFs Sikma, R. Eric; Katyal, Naman; Lee, Su-Kyung Journal of the American Chemical Society, Vol. 143, Issue 34 https://doi.org/10.1021/jacs.1c05564	journal	August 2021
Robust, Chiral, and Porous BINAP-Based Metal–Organic Frameworks for Highly Enantioselective Cyclization Reactions Sawano, Takahiro; Thacker, Nathan C.; Lin, Zekai Journal of the American Chemical Society, Vol. 137, Issue 38 https://doi.org/10.1021/jacs.5b09225	journal	September 2015
Improved Catalytic Activity and Stability of a Palladium Pincer Complex by Incorporation into a Metal–Organic Framework Burgess, Samantha A.; Kassie, Abebu; Baranowski, Sarah A. Journal of the American Chemical Society, Vol. 138, Issue 6 https://doi.org/10.1021/jacs.5b12366	journal	February 2016
Robust, Transformable, and Crystalline Single-Node Organometallic Networks Constructed from Ditopic m -Terphenyl Isocyanides Agnew, Douglas W.; Gembicky, Milan; Moore, Curtis E. Journal of the American Chemical Society, Vol. 138, Issue 46 https://doi.org/10.1021/jacs.6b10460	journal	November 2016
Crystalline Coordination Networks of Zero-Valent Metal Centers: Formation of a 3-Dimensional Ni(0) Framework with m -Terphenyl Diisocyanides Agnew, Douglas W.; DiMucci, Ida M.; Arroyave, Alejandra Journal of the American Chemical Society, Vol. 139, Issue 48 https://doi.org/10.1021/jacs.7b09569	journal	November 2017
Organoarsine Metal–Organic Framework with cis -Diarsine Pockets for the Installation of Uniquely Confined Metal Complexes Sikma, R. Eric; Kunal, Pranaw; Dunning, Samuel G. Journal of the American Chemical Society, Vol. 140, Issue 31 https://doi.org/10.1021/jacs.8b05644	journal	July 2018
Highly Conducting Neutral Coordination Polymer with Infinite Two-Dimensional Silver–Sulfur Networks Huang, Xing; Li, Haisheng; Tu, Zeyi Journal of the American Chemical Society, Vol. 140, Issue 45 https://doi.org/10.1021/jacs.8b07921	journal	September 2018
Metal–Organic Frameworks as Catalysts for Organic Synthesis: A Critical Perspective Pascanu, Vlad; González Miera, Greco; Inge, A. Ken Journal of the American Chemical Society, Vol. 141, Issue 18 https://doi.org/10.1021/jacs.9b00733	journal	April 2019
Designing Open Metal Sites in Metal–Organic Frameworks for Paraffin/Olefin Separations Mohamed, Mona H.; Yang, Yahui; Li, Lin Journal of the American Chemical Society, Vol. 141, Issue 33 https://doi.org/10.1021/jacs.9b06582	journal	August 2019
Bonding of η ¹ -Acetylide Ligands to Electron-Rich Ruthenium Centers: Can Electron-Withdrawing Ligands Induce Significant Metal-to-Ligand Back-Bonding? McGrady, John E.; Lovell, Timothy; Stranger, Robert Organometallics, Vol. 16, Issue 18 https://doi.org/10.1021/om970212d	journal	September 1997
Spontaneous assembly of a hinged coordination network Gardner, Geoffrey B.; Venkataraman, D.; Moore, Jeffrey S. Nature, Vol. 374, Issue 6525 https://doi.org/10.1038/374792a0	journal	April 1995
Unique structural features in silver( I ) dithioether complexes: the single-crystal structures of [Ag _n (PhSCH ₂ CH ₂ CH ₂ SPh) _2n ](BF ₄ ) _n ·0.5nH ₂ O and [Ag _n (MeSCH ₂ CH ₂ CH ₂ SMe) _n ](BF ₄ ) _n Black, Jane R.; Champness, Neil R.; Levason, William J. Chem. Soc., Chem. Commun., Issue 12 https://doi.org/10.1039/C39950001277	journal	January 1995
Metal–organic frameworks as solid catalysts for the synthesis of nitrogen-containing heterocycles Dhakshinamoorthy, Amarajothi; Garcia, Hermenegildo Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C3CS60442J	journal	January 2014
Beyond post-synthesis modification: evolution of metal–organic frameworks via building block replacement Deria, Pravas; Mondloch, Joseph E.; Karagiaridi, Olga Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00067F	journal	January 2014
Post-synthetic metalation of metal–organic frameworks Evans, Jack D.; Sumby, Christopher J.; Doonan, Christian J. Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00076E	journal	January 2014
Applications of metal–organic frameworks in heterogeneous supramolecular catalysis Liu, Jiewei; Chen, Lianfen; Cui, Hao Chemical Society Reviews, Vol. 43, Issue 16, p. 6011-6061 https://doi.org/10.1039/C4CS00094C	journal	January 2014
Tetraphenylethylene-based phosphine: tuneable emission and carbon dioxide fixation Zhang, Jianyong; Yang, Qiuli; Zhu, Yixuan Dalton Trans., Vol. 43, Issue 42 https://doi.org/10.1039/C4DT01808G	journal	January 2014
Pyridine versus acetonitrile coordination in rhodium–N-heterocyclic carbene square-planar complexes Palacios, Laura; Di Giuseppe, Andrea; Castarlenas, Ricardo Dalton Transactions, Vol. 44, Issue 12 https://doi.org/10.1039/C5DT00182J	journal	January 2015
Templating metastable Pd ₂ carboxylate aggregates Wang, Chen-Hao; Gao, Wen-Yang; Ma, Qing Chemical Science, Vol. 10, Issue 6 https://doi.org/10.1039/C8SC04940H	journal	January 2019
A palladium–carbon-connected organometallic framework and its catalytic application Dong, Ying; Jv, Jing-Jing; Wu, Xiao-Wei Chemical Communications, Vol. 55, Issue 96 https://doi.org/10.1039/C9CC07829K	journal	January 2019
Mixed precious-group metal–organic frameworks: a case study of the HKUST-1 analogue [Ru _x Rh _3−x (BTC) ₂ ] Heinz, Werner R.; Kratky, Tim; Drees, Markus Dalton Transactions, Vol. 48, Issue 32 https://doi.org/10.1039/C9DT01198F	journal	January 2019
Improving MOF stability: approaches and applications Ding, Meili; Cai, Xuechao; Jiang, Hai-Long Chemical Science, Vol. 10, Issue 44 https://doi.org/10.1039/C9SC03916C	journal	January 2019
Isonitriles as supporting and non-innocent ligands in metal catalysis Knorn, Matthias; Lutsker, Eugen; Reiser, Oliver Chemical Society Reviews, Vol. 49, Issue 21 https://doi.org/10.1039/D0CS00223B	journal	January 2020
The chemistry of phosphines in constrained, well-defined microenvironments Orton, Georgia R. F.; Pilgrim, Ben S.; Champness, Neil R. Chemical Society Reviews, Vol. 50, Issue 7 https://doi.org/10.1039/D0CS01556C	journal	January 2021
Synthesis of a palladium based MOF via an effective post-synthetic modification approach and its catalytic activity towards Heck type coupling reactions Parshamoni, Srinivasulu; Nasani, Rajendar; Paul, Abhik Inorganic Chemistry Frontiers, Vol. 8, Issue 3 https://doi.org/10.1039/D0QI01052A	journal	January 2021
Isolating reactive metal-based species in Metal–Organic Frameworks – viable strategies and opportunities Young, Rosemary J.; Huxley, Michael T.; Pardo, Emilio Chemical Science, Vol. 11, Issue 16 https://doi.org/10.1039/D0SC00485E	journal	January 2020
Modulated self-assembly of metal–organic frameworks Forgan, Ross S. Chemical Science, Vol. 11, Issue 18 https://doi.org/10.1039/D0SC01356K	journal	January 2020
Zero-valent metals in metal–organic frameworks: fac -M(CO) ₃ (pyrazine) _3/2 Voigt, Laura; Wugt Larsen, René; Kubus, Mariusz Chemical Communications, Vol. 57, Issue 32 https://doi.org/10.1039/D1CC00864A	journal	January 2021
Precious metal polymers: platinum or gold atoms in the backbone Puddephatt, R. J. Chemical Communications, Issue 10 https://doi.org/10.1039/a800244d	journal	January 1998
A robust, porous, cationic silver(i) 3,5-diphenyl-1,2,4-triazolate framework with a uninodal 49.66 netElectronic supplementary information (ESI) available: experimental details, XPRD patterns, TGA curves and IR spectra. See http://www.rsc.org/suppdata/cc/b4/b404269g/ Yang, Guang; Raptis, Raphael G. Chemical Communications, Issue 18 https://doi.org/10.1039/b404269g	journal	January 2004
Main-chain organometallic polymers: synthetic strategies, applications, and perspectives Williams, Kyle A.; Boydston, Andrew J.; Bielawski, Christopher W. Chemical Society Reviews, Vol. 36, Issue 5 https://doi.org/10.1039/b601574n	journal	January 2007
Macrocycles, catenanes, oligomers and polymers in gold chemistry Puddephatt, R. J. Chemical Society Reviews, Vol. 37, Issue 9 https://doi.org/10.1039/b708622a	journal	January 2008
Solvothermal growth of a ruthenium metal–organic framework featuring HKUST-1 structure type as thin films on oxide surfaces Kozachuk, Olesia; Yusenko, Kirill; Noei, Heshmat Chemical Communications, Vol. 47, Issue 30 https://doi.org/10.1039/c1cc11107h	journal	January 2011
A coordination polymer of (Ph3P)AuCl prepared by post-synthetic modification and its application in 1-hexene/n-hexane separation Nuñez, Ana J.; Shear, Lindsey N.; Dahal, Naween Chemical Communications, Vol. 47, Issue 43 https://doi.org/10.1039/c1cc14682c	journal	January 2011
A Chemically Functionalizable Nanoporous Material [Cu₃(TMA)₂(H₂O)₃]_n Chui, Stephen S.-Y.; Lo, Samuel M.-F.; Charmant, Jonathan P. H. Science, Vol. 283, Issue 5405, p. 1148-1150 https://doi.org/10.1126/science.283.5405.1148	journal	February 1999
Terminology of metal–organic frameworks and coordination polymers (IUPAC Recommendations 2013) Batten, Stuart R.; Champness, Neil R.; Chen, Xiao-Ming Pure and Applied Chemistry, Vol. 85, Issue 8 https://doi.org/10.1351/PAC-REC-12-11-20	journal	July 2013

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