Understanding fragility and engineering activation stability in two-dimensional covalent organic frameworks

Journal Article · 24 August 2022 · Chemical Science

DOI: https://doi.org/10.1039/D2SC03489A · OSTI ID:1880384

Zhu, Dongyang  ^[1]; Zhang, Jun-Jie  ^[2]; Wu, Xiaowei  ^[3]; Yan, Qianqian ^[2]; Liu, Fangxin ^[1]; Zhu, Yifan  ^[2]; Gao, Xiaodong ^[4]; Rahman, Muhammad M.  ^[2]; Yakobson, Boris I. ^[5]; Ajayan, Pulickel M. ^[2]; Verduzco, Rafael  ^[6]

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1. Department of Chemical and Biomolecular Engineering, Rice University, 6100 Main Street, MS-362, Houston, Texas 77005, USA
2. Department of Materials Science and NanoEngineering, Rice University, 6100 Main Street, MS-325, Houston, Texas 77005, USA
3. CAS Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter (FJIRSM), Chinese Academy of Sciences, Fuzhou 350002, China, Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials, Xiamen Institute of Rare Earth Materials (XMIREM), Haixi Institutes, Chinese Academy of Sciences, Xiamen 361021, China
4. Department of Earth, Environmental, and Planetary Sciences, Rice University, 6100 Main Street, MS-126, Houston, Texas 77005, USA
5. Department of Materials Science and NanoEngineering, Rice University, 6100 Main Street, MS-325, Houston, Texas 77005, USA, Department of Chemistry, Rice University, MS-60, 6100 Main Street, Houston, Texas 77005, USA
6. Department of Chemical and Biomolecular Engineering, Rice University, 6100 Main Street, MS-362, Houston, Texas 77005, USA, Department of Materials Science and NanoEngineering, Rice University, 6100 Main Street, MS-325, Houston, Texas 77005, USA

We establish relationships between COF pore size, the type of pore substituent, pore architecture, and structural robustness and demonstrate that activation stability can be systematically tuned using a multivariate synthesis approach.

• Research Organization: Rice University, Houston, TX (United States)
• Sponsoring Organization: US Army Research laboratory (ARL); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES); Welch Foundation for Chemical Research
• Grant/Contract Number: SC0012547
• OSTI ID: 1880384
• Journal Information: Chemical Science, Journal Name: Chemical Science Journal Issue: 33 Vol. 13; ISSN 2041-6520; ISSN CSHCBM
• Publisher: Royal Society of Chemistry (RSC)Copyright Statement
• Country of Publication: United Kingdom
• Language: English

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY