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Title: Multicomponent Reactions Among Alkyl Isocyanides, sp Reactants, and sp2 Carbon Cages

Journal Article · · Synlett
 [1];  [2];  [3];  [2]
  1. Rutgers, The State Univ. of New Jersey, Piscataway, NJ (United States); Rutgers University
  2. Rutgers, The State Univ. of New Jersey, Piscataway, NJ (United States)
  3. Univ. Rovira i Virgili, Tarragona (Spain)
+ Show Author Affiliations

We explored the reactivity and substrate scope of the reactions among an alkyl isocyanide, an sp-hybridized reactant (i.e. alkyne or allene), and a carbon cage, as a new approach to functionalize fullerenes and metallofullerenes. Furthermore, this account summarizes the key findings in our recent published work, and some original data for the reaction involving an isocyanide, allenes, and metallofullerene Lu3N@C80.

Research Organization:
Rutgers Univ., Piscataway, NJ (United States)
Sponsoring Organization:
USDOE
Grant/Contract Number:
SC0020260
OSTI ID:
1879640
Journal Information:
Synlett, Journal Name: Synlett Journal Issue: 10 Vol. 33; ISSN 0936-5214
Publisher:
ThiemeCopyright Statement
Country of Publication:
United States
Language:
English

References (14)

General Rule for the Stabilization of Fullerene Cages Encapsulating Trimetallic Nitride Templates journal November 2005
Trimetallic Nitride Endohedral Fullerenes: Experimental and Theoretical Evidence for the M 3 N 6+ @C 2 n 6− model journal February 2009
Unexpected Formation of Metallofulleroids from Multicomponent Reactions, with Crystallographic and Computational Studies of the Cluster Motion journal October 2021
Synthesis and Electrochemical Studies of Bingel-Hirsch Derivatives of M3N@Ih-C80 (M=Sc, Lu) journal March 2010
Biomedical Applications of Metal-Encapsulated Fullerene Nanoparticles journal December 2016
Fullerenes as Nanocontainers That Stabilize Unique Actinide Species Inside: Structures, Formation, and Reactivity journal March 2019
Isocyanide-Induced Annulation Leading to Cyclopento-, Methano-, and Cyclopentano-[60]Fullerene Derivatives journal November 2021
Endohedral Metallofullerenes Based on Spherical I h -C 80 Cage: Molecular Structures and Paramagnetic Properties journal December 2013
Azide Addition to an Endohedral Metallofullerene: Formation of Azafulleroids of Sc 3 N@ I h -C 80 journal July 2012
Structures of Gd 3 N@C 80 Prato Bis-Adducts: Crystal Structure, Thermal Isomerization, and Computational Study journal June 2019
A New Method for the Functionalization of [60] Fullerene:  An Unusual 1,3-Dipolar Cycloaddition Pathway Leading to a C 60 Housane Derivative journal November 2005
A multicomponent molecular approach to artificial photosynthesis – the role of fullerenes and endohedral metallofullerenes journal January 2016
W(CO) 3 (Ph 2 PC 2 H 4 PPh 2 )(η 2 -Sc 3 N@I h -C 80 /Sc 3 N@D 5h -C 80 ): regioselective synthesis and crystallographic characterization of air-stable mononuclear complexes of endohedral fullerenes journal January 2016
Gadolinium based endohedral metallofullerene Gd 2 @C 79 N as a relaxation boosting agent for dissolution DNP at high fields journal January 2018

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Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
cluster motion
endohedral
fullerenes
isocyanide
multi-component reaction