Single-Atom Metal Oxide Sites as Traps for Charge Separation in the Zirconium-Based Metal–Organic Framework NDC–NU-1000

Kramar, Boris V.; Phelan, Brian T.; Sprague-Klein, Emily A.; Diroll, Benjamin T.; Lee, Sungsik; Otake, Ken-ichi; Palmer, Rebecca; Mara, Michael W.; Farha, Omar K.; Hupp, Joseph T.; Chen, Lin X.

doi:10.1021/acs.energyfuels.1c02623

Title: Single-Atom Metal Oxide Sites as Traps for Charge Separation in the Zirconium-Based Metal–Organic Framework NDC–NU-1000

Journal Article · 20 September 2021 · Energy and Fuels

DOI: https://doi.org/10.1021/acs.energyfuels.1c02623 · OSTI ID:1878492

Kramar, Boris V. ^[1];

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^[1]; Palmer, Rebecca ^[1];

^[3];

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Northwestern Univ., Evanston, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Northwestern Univ., Evanston, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States)

Solvothermal deposition in metal–organic frameworks (MOFs) can be utilized to mount single-metal-atom catalytic species at chemically reactive sites on hexa-Zr(IV)-oxy(oxo,hydroxo,aqua) nodes in nanoscale crystallites of the MOF NDC-NU-1000 in a self-limiting fashion. Upon photoexcitation of the 1,3,6,8-tetrakis(p-benzoato)pyrene chromophores of the parent framework, charge transfer may occur between the chromophores and the installed heterometal sites. Extended X-ray absorption fine structure studies revealed the single-atom nature of the installed species. A combination of steady-state and ultrafast optical spectroscopy was utilized to uncover evidence of a charge-separated (CS) state arising in the metalated samples. The relevant dynamics were characterized with transient photoluminescence and femtosecond transient absorption spectroscopy. Here, we find that a titanium-oxy single atom site gives rise to the longest-lived CS species compared to cobalt and nickel in a similar arrangement. This study provides guidance in designing MOF-based catalytic systems for photocatalysis and solar-fuel production.

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Research Organization:: Argonne National Laboratory (ANL); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: US Department of the Navy, Office of Naval Research (ONR); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357; FG02-87ER13808

OSTI ID:: 1878492

Journal Information:: Energy and Fuels, Journal Name: Energy and Fuels Journal Issue: 23 Vol. 35; ISSN 0887-0624

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (89)

Metal–Organic Framework Thin Films as Platforms for Atomic Layer Deposition of Cobalt Ions To Enable Electrocatalytic Water Oxidation Kung, Chung-Wei; Mondloch, Joseph E.; Wang, Timothy C. ACS Applied Materials & Interfaces, Vol. 7, Issue 51 https://doi.org/10.1021/acsami.5b06901	journal	December 2015
The formation of the Co 3 O 4 cobalt oxide within CoO substrate Żyła, Małgorzata; Smoła, Grzegorz; Knapik, Arkadiusz Corrosion Science, Vol. 112 https://doi.org/10.1016/j.corsci.2016.08.016	journal	November 2016
Heterometal incorporation in NH ₂ -MIL-125(Ti) and its participation in the photoinduced charge-separated excited state Hanna, Lauren; Long, Conor L.; Zhang, Xiaoyi Chemical Communications, Vol. 56, Issue 78 https://doi.org/10.1039/D0CC05339B	journal	January 2020
Metal–Organic Frameworks in Heterogeneous Catalysis: Recent Progress, New Trends, and Future Perspectives Bavykina, Anastasiya; Kolobov, Nikita; Khan, Il Son Chemical Reviews, Vol. 120, Issue 16 https://doi.org/10.1021/acs.chemrev.9b00685	journal	March 2020
Rational Design of Catalytic Centers in Crystalline Frameworks Tu, Wenguang; Xu, You; Yin, Shengming Advanced Materials, Vol. 30, Issue 33 https://doi.org/10.1002/adma.201707582	journal	June 2018
Nickel–Carbon–Zirconium Material Derived from Nickel-Oxide Clusters Installed in a Metal–Organic Framework Scaffold by Atomic Layer Deposition Palmer, Rebecca H.; Kung, Chung-Wei; Liu, Jian Langmuir, Vol. 34, Issue 47 https://doi.org/10.1021/acs.langmuir.8b02166	journal	November 2018
Dynamic Stokes shift in green fluorescent protein variants Abbyad, P.; Childs, W.; Shi, X. Proceedings of the National Academy of Sciences, Vol. 104, Issue 51 https://doi.org/10.1073/pnas.0706185104	journal	December 2007
Dielectric constants of formamide and dimethylformamide via computer simulation Essex, Jonathan W.; Jorgensen, William L. The Journal of Physical Chemistry, Vol. 99, Issue 51 https://doi.org/10.1021/j100051a021	journal	December 1995
Light-Harvesting in Porous Crystalline Compositions: Where We Stand toward Robust Metal–Organic Frameworks Yu, Jierui; Li, Xinlin; Deria, Pravas ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 2 https://doi.org/10.1021/acssuschemeng.8b05673	journal	December 2018
Fabrication of Transparent-Conducting-Oxide-Coated Inverse Opals as Mesostructured Architectures for Electrocatalysis Applications: A Case Study with NiO Williams, Vennesa O.; DeMarco, Erica J.; Katz, Michael J. ACS Applied Materials & Interfaces, Vol. 6, Issue 15 https://doi.org/10.1021/am501910n	journal	July 2014
Ground-State versus Excited-State Interchromophoric Interaction: Topology Dependent Excimer Contribution in Metal–Organic Framework Photophysics Deria, Pravas; Yu, Jierui; Smith, Tanner Journal of the American Chemical Society, Vol. 139, Issue 16 https://doi.org/10.1021/jacs.7b02188	journal	April 2017
Scalable synthesis and post-modification of a mesoporous metal-organic framework called NU-1000 Wang, Timothy C.; Vermeulen, Nicolaas A.; Kim, In Soo Nature Protocols, Vol. 11, Issue 1 https://doi.org/10.1038/nprot.2016.001	journal	December 2015
Wavelength-Dependent Energy and Charge Transfer in MOF: A Step toward Artificial Porous Light-Harvesting System Li, Xinlin; Yu, Jierui; Gosztola, David J. Journal of the American Chemical Society, Vol. 141, Issue 42 https://doi.org/10.1021/jacs.9b08078	journal	September 2019
Encapsulation of Single Iron Sites in a Metal–Porphyrin Framework for High-Performance Photocatalytic CO ₂ Reduction Wang, Sha-Sha; Huang, Hai-Hua; Liu, Meng Inorganic Chemistry, Vol. 59, Issue 9 https://doi.org/10.1021/acs.inorgchem.0c00407	journal	April 2020
Atomically Dispersed Metal Sites in MOF-Based Materials for Electrocatalytic and Photocatalytic Energy Conversion Liang, Zibin; Qu, Chong; Xia, Dingguo Angewandte Chemie International Edition, Vol. 57, Issue 31 https://doi.org/10.1002/anie.201800269	journal	June 2018
Spectroelectrochemical studies of nickel(I) complexes: one-electron reduction of nickel(II) complexes of dithiocarbamate and phosphine ligands [Ni(R2NCS2)x(Ph2PCH2CH2PPh2)2-x]2-x (x = 0, 1, 2) Bowmaker, Graham A.; Boyd, Peter D. W.; Campbell, Graeme K. Inorganic Chemistry, Vol. 21, Issue 3 https://doi.org/10.1021/ic00133a054	journal	March 1982
Exceptionally Long-Lived Charge Separated State in Zeolitic Imidazolate Framework: Implication for Photocatalytic Applications Pattengale, Brian; Yang, Sizhuo; Ludwig, John Journal of the American Chemical Society, Vol. 138, Issue 26 https://doi.org/10.1021/jacs.6b04615	journal	June 2016
Recent Advances of Cobalt-Based Electrocatalysts for Oxygen Electrode Reactions and Hydrogen Evolution Reaction Zhong, Haihong; Campos-Roldán, Carlos; Zhao, Yuan Catalysts, Vol. 8, Issue 11 https://doi.org/10.3390/catal8110559	journal	November 2018
Revisiting the structural homogeneity of NU-1000, a Zr-based metal–organic framework Islamoglu, Timur; Otake, Ken-ichi; Li, Peng CrystEngComm, Vol. 20, Issue 39 https://doi.org/10.1039/C8CE00455B	journal	January 2018
Efficient Visible-Light-Driven Carbon Dioxide Reduction by a Single-Atom Implanted Metal-Organic Framework Zhang, Huabin; Wei, Jing; Dong, Juncai Angewandte Chemie International Edition, Vol. 55, Issue 46 https://doi.org/10.1002/anie.201608597	journal	October 2016
Identification Schemes for Metal–Organic Frameworks To Enable Rapid Search and Cheminformatics Analysis Bucior, Benjamin J.; Rosen, Andrew S.; Haranczyk, Maciej Crystal Growth & Design, Vol. 19, Issue 11 https://doi.org/10.1021/acs.cgd.9b01050	journal	September 2019
Excited-State Electronic Properties in Zr-Based Metal–Organic Frameworks as a Function of a Topological Network Yu, Jierui; Park, JaeHong; Van Wyk, Andrea Journal of the American Chemical Society, Vol. 140, Issue 33 https://doi.org/10.1021/jacs.8b04980	journal	July 2018
Surface Restructuring of Nanoparticles: An Efficient Route for Ligand−Metal Oxide Crosstalk Rajh, T.; Chen, L. X.; Lukas, K. The Journal of Physical Chemistry B, Vol. 106, Issue 41 https://doi.org/10.1021/jp021235v	journal	October 2002
Single-Atom-Based Vanadium Oxide Catalysts Supported on Metal–Organic Frameworks: Selective Alcohol Oxidation and Structure–Activity Relationship Otake, Ken-ichi; Cui, Yuexing; Buru, Cassandra T. Journal of the American Chemical Society, Vol. 140, Issue 28 https://doi.org/10.1021/jacs.8b05107	journal	June 2018
Titration of Zr₃(μ-OH) Hydroxy Groups at the Cornerstones of Bulk MOF UiO-67, [Zr₆O₄(OH)₄(biphenyldicarboxylate)₆], and Their Reaction with [AuMe(PMe₃)] Larabi, Cherif; Quadrelli, Elsje Alessandra European Journal of Inorganic Chemistry, Vol. 2012, Issue 18, p. 3014-3022 https://doi.org/10.1002/ejic.201200033	journal	May 2012
Zirconium-Porphyrin-Based Metal-Organic Framework Hollow Nanotubes for Immobilization of Noble-Metal Single Atoms He, Ting; Chen, Shuangming; Ni, Bing Angewandte Chemie International Edition, Vol. 57, Issue 13 https://doi.org/10.1002/anie.201800817	journal	February 2018
p-Type semiconducting nickel oxide as an efficiency-enhancing anode interfacial layer in polymer bulk-heterojunction solar cells Irwin, M. D.; Buchholz, D. B.; Hains, A. W. Proceedings of the National Academy of Sciences, Vol. 105, Issue 8, p. 2783-2787 https://doi.org/10.1073/pnas.0711990105	journal	February 2008
Highly active nickel oxide water oxidation catalysts deposited from molecular complexes Singh, Archana; Chang, Shery L. Y.; Hocking, Rosalie K. Energy Environ. Sci., Vol. 6, Issue 2 https://doi.org/10.1039/C2EE23862D	journal	January 2013
A Titanium Metal–Organic Framework with Visible‐Light‐Responsive Photocatalytic Activity Cadiau, Amandine; Kolobov, Nikita; Srinivasan, Sivaranjani Angewandte Chemie International Edition, Vol. 59, Issue 32 https://doi.org/10.1002/anie.202000158	journal	May 2020
Electronic origins of photocatalytic activity in d0 metal organic frameworks Nasalevich, Maxim A.; Hendon, Christopher H.; Santaclara, Jara G. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep23676	journal	March 2016
The Synthesis Science of Targeted Vapor-Phase Metal–Organic Framework Postmodification Kim, In Soo; Ahn, Sol; Vermeulen, Nicolaas A. Journal of the American Chemical Society, Vol. 142, Issue 1 https://doi.org/10.1021/jacs.9b10034	journal	December 2019
Introduction to Electron Transfer: Theoretical Foundations and Pedagogical Examples Piechota, Eric J.; Meyer, Gerald J. Journal of Chemical Education, Vol. 96, Issue 11 https://doi.org/10.1021/acs.jchemed.9b00489	journal	October 2019
Node-Accessible Zirconium MOFs Lu, Zhiyong; Liu, Jian; Zhang, Xuan Journal of the American Chemical Society, Vol. 142, Issue 50 https://doi.org/10.1021/jacs.0c09782	journal	December 2020
Standard Electrode Potentials and Temperature Coefficients in Water at 298.15 K Bratsch, Steven G. Journal of Physical and Chemical Reference Data, Vol. 18, Issue 1 https://doi.org/10.1063/1.555839	journal	January 1989
Zr ₆ O ₈ Node-Catalyzed Butene Hydrogenation and Isomerization in the Metal–Organic Framework NU-1000 Hicks, Kenton E.; Rosen, Andrew S.; Syed, Zoha H. ACS Catalysis, Vol. 10, Issue 24 https://doi.org/10.1021/acscatal.0c03579	journal	December 2020
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953	journal	October 2008
XAFS Studies of Surface Structures of TiO ₂ Nanoparticles and Photocatalytic Reduction of Metal Ions Chen, Lin X.; Rajh, Tijana; Wang, Zhiyu The Journal of Physical Chemistry B, Vol. 101, Issue 50 https://doi.org/10.1021/jp971930g	journal	December 1997
Role of a Modulator in the Synthesis of Phase-Pure NU-1000 Webber, Thomas E.; Liu, Wei-Guang; Desai, Sai Puneet ACS Applied Materials & Interfaces, Vol. 9, Issue 45 https://doi.org/10.1021/acsami.7b11348	journal	November 2017
Understanding Intrinsic Light Absorption Properties of UiO-66 Frameworks: A Combined Theoretical and Experimental Study Hendrickx, Kevin; Vanpoucke, Danny E. P.; Leus, Karen Inorganic Chemistry, Vol. 54, Issue 22 https://doi.org/10.1021/acs.inorgchem.5b01593	journal	November 2015
Heterogeneous Single-Atom Photocatalysts: Fundamentals and Applications Gao, Chao; Low, Jingxiang; Long, Ran Chemical Reviews, Vol. 120, Issue 21 https://doi.org/10.1021/acs.chemrev.9b00840	journal	March 2020
Pyrene-based metal organic frameworks: from synthesis to applications Kinik, F. Pelin; Ortega-Guerrero, Andres; Ongari, Daniele Chemical Society Reviews, Vol. 50, Issue 5 https://doi.org/10.1039/D0CS00424C	journal	January 2021
Site-Directed Synthesis of Cobalt Oxide Clusters in a Metal–Organic Framework Peters, Aaron W.; Otake, Kenichi; Platero-Prats, Ana E. ACS Applied Materials & Interfaces, Vol. 10, Issue 17 https://doi.org/10.1021/acsami.8b02825	journal	March 2018
Interfacial Electron Transfer into Functionalized Crystalline Polyoxotitanate Nanoclusters Snoeberger, Robert C.; Young, Karin J.; Tang, Jiji Journal of the American Chemical Society, Vol. 134, Issue 21 https://doi.org/10.1021/ja301238t	journal	May 2012
One-electron-reduced nickel(II)-macrocyclic ligand complexes. Four-coordinate nickel(I) species and nickel(II)-ligand radical species which form paramagnetic, five-coordinate nickel(I) adducts Gagne, Robert R.; Ingle, D. Michael Inorganic Chemistry, Vol. 20, Issue 2 https://doi.org/10.1021/ic50216a020	journal	February 1981
A nickel(III) complex with a NiO6 coordination sphere Bhattacharya, Samaresh; Mukherjee, Rabindranath; Chakravorty, Animesh Inorganic Chemistry, Vol. 25, Issue 19 https://doi.org/10.1021/ic00239a026	journal	September 1986
Metal–Organic Frameworks as a Good Platform for the Fabrication of Single-Atom Catalysts Huang, Haigen; Shen, Kui; Chen, Fengfeng ACS Catalysis, Vol. 10, Issue 12 https://doi.org/10.1021/acscatal.0c01459	journal	May 2020
Isomer of linker for NU-1000 yields a new she -type, catalytic, and hierarchically porous, Zr-based metal–organic framework Lu, Zhiyong; Wang, Rui; Liao, Yijun Chemical Communications, Vol. 57, Issue 29 https://doi.org/10.1039/D0CC07974J	journal	January 2021
Single crystal structure and photocatalytic behavior of grafted uranyl on the Zr-node of a pyrene-based metal–organic framework Knapp, Julia G.; Zhang, Xuan; Elkin, Tatyana CrystEngComm, Vol. 22, Issue 11 https://doi.org/10.1039/C9CE02034A	journal	January 2020
Redox-Mediator-Assisted Electrocatalytic Hydrogen Evolution from Water by a Molybdenum Sulfide-Functionalized Metal–Organic Framework Noh, Hyunho; Kung, Chung-Wei; Otake, Ken-ichi ACS Catalysis, Vol. 8, Issue 10 https://doi.org/10.1021/acscatal.8b02921	journal	September 2018
Does one-electron transfer to nickel(II) porphyrins involve the metal or the porphyrin ligand? Lexa, Doris; Momenteau, Michel; Mispelter, Joel Inorganic Chemistry, Vol. 28, Issue 1 https://doi.org/10.1021/ic00300a009	journal	January 1989
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297 https://doi.org/10.1021/ja4050828	journal	May 2013
Metal-organic framework encapsulated single-atom Pt catalysts for efficient photocatalytic hydrogen evolution Li, Jian; Huang, Hongliang; Liu, Peng Journal of Catalysis, Vol. 375 https://doi.org/10.1016/j.jcat.2019.06.024	journal	July 2019
Single-Site Heterogeneous Catalysts Thomas, John Meurig; Raja, Robert; Lewis, Dewi W. Angewandte Chemie International Edition, Vol. 44, Issue 40, p. 6456-6482 https://doi.org/10.1002/anie.200462473	journal	October 2005
Light-Harvesting “Antenna” Behavior in NU-1000 Goswami, Subhadip; Yu, Jierui; Patwardhan, Sameer ACS Energy Letters, Vol. 6, Issue 3 https://doi.org/10.1021/acsenergylett.0c02514	journal	February 2021
Symmetry breaking charge transfer as a means to study electron transfer with no driving force Kellogg, Michael; Akil, Ali; Muthiah Ravinson, Daniel Sylvinson Faraday Discussions, Vol. 216 https://doi.org/10.1039/C8FD00201K	journal	January 2019
Charge-Transfer within Zr-Based Metal–Organic Framework: The Role of Polar Node Van Wyk, Andrea; Smith, Tanner; Park, Jaehong Journal of the American Chemical Society, Vol. 140, Issue 8 https://doi.org/10.1021/jacs.7b13211	journal	February 2018
Theoretical Investigation of Charge Transfer in Metal Organic Frameworks for Electrochemical Device Applications Patwardhan, Sameer; Schatz, George C. The Journal of Physical Chemistry C, Vol. 119, Issue 43 https://doi.org/10.1021/acs.jpcc.5b06065	journal	October 2015
Surface analysis and the adsorption of Co(II) on goethite Schenck, C. V.; Dillard, J. G.; Murray, J. W. Journal of Colloid and Interface Science, Vol. 95, Issue 2 https://doi.org/10.1016/0021-9797(83)90199-6	journal	October 1983
Metal-Organic Frameworks as Platforms for Catalytic Applications Jiao, Long; Wang, Yang; Jiang, Hai-Long Advanced Materials, Vol. 30, Issue 37 https://doi.org/10.1002/adma.201703663	journal	November 2017
Anisotropic Redox Conductivity within a Metal–Organic Framework Material Goswami, Subhadip; Hod, Idan; Duan, Jiaxin Dawn Journal of the American Chemical Society, Vol. 141, Issue 44 https://doi.org/10.1021/jacs.9b07658	journal	October 2019
Optimal methodology for explicit solvation prediction of band edges of transition metal oxide photocatalysts Park, Kyoung-Won; Kolpak, Alexie M. Communications Chemistry, Vol. 2, Issue 1 https://doi.org/10.1038/s42004-019-0179-3	journal	July 2019
On the Standard Potential of the Titanium(III)-Titanium(II) Couple Olver, John W.; Ross, James W. Journal of the American Chemical Society, Vol. 85, Issue 17 https://doi.org/10.1021/ja00900a006	journal	September 1963
Single Pt Atoms Confined into a Metal-Organic Framework for Efficient Photocatalysis Fang, Xinzuo; Shang, Qichao; Wang, Yu Advanced Materials, Vol. 30, Issue 7 https://doi.org/10.1002/adma.201705112	journal	January 2018
One-electron Ni(ii)/(i) redox couple: potential role in hydrogen activation and production Tereniak, Stephen J.; Marlier, Elodie E.; Lu, Connie C. Dalton Transactions, Vol. 41, Issue 26 https://doi.org/10.1039/c2dt30176h	journal	January 2012
Pushing the Limits on Metal–Organic Frameworks as a Catalyst Support: NU-1000 Supported Tungsten Catalysts for o -Xylene Isomerization and Disproportionation Ahn, Sol; Nauert, Scott L.; Buru, Cassandra T. Journal of the American Chemical Society, Vol. 140, Issue 27 https://doi.org/10.1021/jacs.8b04059	journal	June 2018
NiO nanostructures: synthesis, characterization and photocatalyst application in dye wastewater treatment Motahari, Fereshteh; Mozdianfard, Mohammad Reza; Soofivand, Faezeh RSC Advances, Vol. 4, Issue 53 https://doi.org/10.1039/c4ra02697g	journal	January 2014
Synthesis of nanocrystals of Zr-based metal–organic frameworks with csq-net: significant enhancement in the degradation of a nerve agent simulant Li, Peng; Klet, Rachel C.; Moon, Su-Young Chem. Commun., Vol. 51, Issue 54 https://doi.org/10.1039/C5CC03398E	journal	January 2015
Modulating Coordination Environment of Single-Atom Catalysts and Their Proximity to Photosensitive Units for Boosting MOF Photocatalysis Ma, Xing; Liu, Hang; Yang, Weijie Journal of the American Chemical Society, Vol. 143, Issue 31 https://doi.org/10.1021/jacs.1c05032	journal	July 2021
Energetics of the Nanocrystalline Titanium Dioxide/Aqueous Solution Interface: Approximate Conduction Band Edge Variations between H ₀ = −10 and H _- = +26 Lyon, L. Andrew; Hupp, Joseph T. The Journal of Physical Chemistry B, Vol. 103, Issue 22 https://doi.org/10.1021/jp9908404	journal	June 1999
Laurdan solvatochromism: solvent dielectric relaxation and intramolecular excited-state reaction Viard, M.; Gallay, J.; Vincent, M. Biophysical Journal, Vol. 73, Issue 4 https://doi.org/10.1016/S0006-3495(97)78253-5	journal	October 1997
Metal-organic framework membranes with single-atomic centers for photocatalytic CO2 and O2 reduction Hao, Yu-Chen; Chen, Li-Wei; Li, Jiani Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-22991-7	journal	May 2021
Tuning the Surface Chemistry of Metal Organic Framework Nodes: Proton Topology of the Metal-Oxide-Like Zr ₆ Nodes of UiO-66 and NU-1000 Yang, Dong; Bernales, Varinia; Islamoglu, Timur Journal of the American Chemical Society, Vol. 138, Issue 46 https://doi.org/10.1021/jacs.6b08273	journal	November 2016
The role of redox hopping in metal–organic framework electrocatalysis Lin, Shaoyang; Usov, Pavel M.; Morris, Amanda J. Chemical Communications, Vol. 54, Issue 51 https://doi.org/10.1039/C8CC01664J	journal	January 2018
Metal–Organic Framework Thin Films Composed of Free-Standing Acicular Nanorods Exhibiting Reversible Electrochromism Kung, Chung-Wei; Wang, Timothy Chiaan; Mondloch, Joseph E. Chemistry of Materials, Vol. 25, Issue 24 https://doi.org/10.1021/cm403726v	journal	December 2013
Understanding TiO ₂ Photocatalysis: Mechanisms and Materials Schneider, Jenny; Matsuoka, Masaya; Takeuchi, Masato Chemical Reviews, Vol. 114, Issue 19 https://doi.org/10.1021/cr5001892	journal	May 2014
Unexpected “Spontaneous” Evolution of Catalytic, MOF-Supported Single Cu(II) Cations to Catalytic, MOF-Supported Cu(0) Nanoparticles Yang, Ying; Zhang, Xuan; Kanchanakungwankul, Siriluk Journal of the American Chemical Society, Vol. 142, Issue 50 https://doi.org/10.1021/jacs.0c10367	journal	December 2020
Ion transfer across the water\|trifluorotoluene interface Olaya, Astrid J.; Ge, Peiyu; Girault, Hubert H. Electrochemistry Communications, Vol. 19 https://doi.org/10.1016/j.elecom.2012.03.010	journal	June 2012
Ammonia Capture within Zirconium Metal–Organic Frameworks: Reversible and Irreversible Uptake Liu, Jian; Lu, Zhiyong; Chen, Zhijie ACS Applied Materials & Interfaces, Vol. 13, Issue 17 https://doi.org/10.1021/acsami.1c02370	journal	April 2021
Cobalt oxide as photocatalyst for water splitting: Temperature-dependent phase structures Moridon, Siti Nurul Falaein; Salehmin, Mohd Ikhmal; Mohamed, Mohamad Azuwa International Journal of Hydrogen Energy, Vol. 44, Issue 47 https://doi.org/10.1016/j.ijhydene.2019.08.075	journal	October 2019
Hydrogenation catalysts Beeck, O. Discussions of the Faraday Society, Vol. 8 https://doi.org/10.1039/df9500800118	journal	January 1950
Ultrasmall Dispersible Crystalline Nickel Oxide Nanoparticles as High-Performance Catalysts for Electrochemical Water Splitting Fominykh, Ksenia; Feckl, Johann M.; Sicklinger, Johannes Advanced Functional Materials, Vol. 24, Issue 21 https://doi.org/10.1002/adfm.201303600	journal	March 2014
Toward Inexpensive Photocatalytic Hydrogen Evolution: A Nickel Sulfide Catalyst Supported on a High-Stability Metal–Organic Framework Peters, Aaron W.; Li, Zhanyong; Farha, Omar K. ACS Applied Materials & Interfaces, Vol. 8, Issue 32 https://doi.org/10.1021/acsami.6b04729	journal	August 2016
Single‐Site, Single‐Metal‐Atom, Heterogeneous Electrocatalyst: Metal–Organic‐Framework Supported Molybdenum Sulfide for Redox Mediator‐Assisted Hydrogen Evolution Reaction Noh, Hyunho; Yang, Ying; Zhang, Xuan ChemElectroChem, Vol. 7, Issue 2 https://doi.org/10.1002/celc.201901650	journal	January 2020
Long-Lived Photoinduced Charge Separation in a Trinuclear Iron-μ ₃ -oxo-based Metal–Organic Framework Hanna, Lauren; Kucheryavy, Pavel; Liu, Cunming The Journal of Physical Chemistry C, Vol. 121, Issue 25 https://doi.org/10.1021/acs.jpcc.7b03936	journal	June 2017
Structure and Dynamics of Zr ₆ O ₈ Metal–Organic Framework Node Surfaces Probed with Ethanol Dehydration as a Catalytic Test Reaction Yang, Dong; Ortuño, Manuel A.; Bernales, Varinia Journal of the American Chemical Society, Vol. 140, Issue 10 https://doi.org/10.1021/jacs.7b13330	journal	February 2018
Postsynthetic Tuning of Metal–Organic Frameworks for Targeted Applications Islamoglu, Timur; Goswami, Subhadip; Li, Zhanyong Accounts of Chemical Research, Vol. 50, Issue 4 https://doi.org/10.1021/acs.accounts.6b00577	journal	February 2017
Design of a highly sensitive and selective C2H5OH sensor using p-type Co3O4 nanofibers Yoon, Ji-Wook; Choi, Joong-Ki; Lee, Jong-Heun Sensors and Actuators B: Chemical, Vol. 161, Issue 1 https://doi.org/10.1016/j.snb.2011.11.002	journal	January 2012
Size Control of the MOF NU-1000 through Manipulation of the Modulator/Linker Competition Webber, Thomas E.; Desai, Sai Puneet; Combs, Rebecca L. Crystal Growth & Design, Vol. 20, Issue 5 https://doi.org/10.1021/acs.cgd.9b01590	journal	April 2020
X-ray photoelectron studies on some oxides and hydroxides of cobalt, nickel, and copper McIntyre, N. S.; Cook, M. G. Analytical Chemistry, Vol. 47, Issue 13 https://doi.org/10.1021/ac60363a034	journal	November 1975

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
charge separation
metal-organic frameworks
single site metal oxides
charge transfer
kinetics
metals
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Title: Single-Atom Metal Oxide Sites as Traps for Charge Separation in the Zirconium-Based Metal–Organic Framework NDC–NU-1000

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