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Title: Integrated photoelectrochemical energy storage cells prepared by benchtop ion soft landing

Journal Article · · ChemComm
DOI: https://doi.org/10.1039/D2CC02595G · OSTI ID:1878425

Soft landing eliminates counter cations from Keggin polyoxometalate-based photocathodes, resulting in a ∼370% increase in maximum power output from a novel device that simultaneously harvests and stores solar energy.

Research Organization:
Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
National Institutes of Health (NIH); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; USDOE Office of Science (SC), Biological and Environmental Research (BER)
Grant/Contract Number:
AC05-76RL01830; SC0010729
OSTI ID:
1878425
Report Number(s):
PNNL-SA-151277
Journal Information:
ChemComm, Journal Name: ChemComm Journal Issue: 65 Vol. 58; ISSN CHCOFS; ISSN 1359-7345
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (31)

From Isolated Ions to Multilayer Functional Materials Using Ion Soft Landing journal November 2018
DRILL Interface Makes Ion Soft Landing Broadly Accessible for Energy Science and Applications journal June 2018
A Solar Rechargeable Flow Battery Based on Photoregeneration of Two Soluble Redox Couples journal April 2013
Soft- and reactive landing of ions onto surfaces: Concepts and applications: CONCEPTS AND APPLICATIONS journal April 2015
All-vanadium redox photoelectrochemical cell: An approach to store solar energy journal August 2014
Visualisation of the local electrochemical activity of thermal sprayed anti-corrosion coatings using scanning electrochemical microscopy journal August 2009
Synthesis, structure, and characterization of two polyoxometalate–photosensitizer hybrid materials journal December 2010
Tungsten-doped vanadium dioxide thin films as smart windows with self-cleaning and energy-saving functions journal February 2017
Photoluminescent multilayer film based on polyoxometalate and tris(2,2-bipyridine)ruthenium journal October 2004
Unbiased solar energy storage: Photoelectrochemical redox flow battery journal April 2016
Solar energy storage in the rechargeable batteries journal October 2017
Advances in solar photovoltaics: Technology review and patent trends journal November 2019
Energy efficient hydrogel based smart windows with low cost transparent conducting electrodes journal April 2017
Next-Generation Multifunctional Electrochromic Devices journal July 2016
Portable Photoelectrochemical Device Integrated with Self-Powered Electrochromic Tablet for Visual Analysis journal February 2018
In Situ Infrared Spectroelectrochemistry for Understanding Structural Transformations of Precisely Defined Ions at Electrochemical Interfaces journal August 2018
Controlling the Activity and Stability of Electrochemical Interfaces Using Atom-by-Atom Metal Substitution of Redox Species journal December 2018
Introduction:  PolyoxometalatesMulticomponent Molecular Vehicles To Probe Fundamental Issues and Practical Problems journal February 1998
Photo- and Electrochromism of Polyoxometalates and Related Materials journal February 1998
Reactivity of Anhydrous Keggin-Type Heteropolyacids with Alkylsilanes: Synthesis and Characterization journal September 2010
Aqueous Lithium–Iodine Solar Flow Battery for the Simultaneous Conversion and Storage of Solar Energy journal June 2015
Solution Viscosity Effects on the Heterogeneous Electron Transfer Kinetics of Ferrocenemethanol in Dimethyl Sulfoxide−Water Mixtures journal January 2002
Construction of Self-Assembled Ultrathin Polyoxometalate/1,10-Decanediamine Photochromic Films journal April 2004
Vibrational Spectroscopy of a Keggin Polyoxometalate on Metal Electrode Surfaces journal January 2004
Photoredox Chemistry in Oxide Clusters. Photochromic and Redox Properties of Polyoxometalates in Connection with Analog Solid State Colloidal Systems journal January 1996
Nanoporous Thermochromic VO 2 (M) Thin Films: Controlled Porosity, Largely Enhanced Luminous Transmittance and Solar Modulating Ability journal February 2014
Photoelectrochemical energy conversion and storage using polycrystalline chalcogenide electrodes journal June 1976
Rational design of efficient electrode–electrolyte interfaces for solid-state energy storage using ion soft landing journal April 2016
Integrated photoelectrochemical energy storage: solar hydrogen generation and supercapacitor journal December 2012
On the diffusion of ferrocenemethanol in room-temperature ionic liquids: an electrochemical study journal January 2011
In situ solid-state electrochemistry of mass-selected ions at well-defined electrode–electrolyte interfaces journal November 2016