Solvation, Rational Design, and Interfaces: Development of Divalent Electrolytes

Leon, Noel J.; He, Mingfu; Liao, Chen

doi:10.3389/fenrg.2021.802398

Title: Solvation, Rational Design, and Interfaces: Development of Divalent Electrolytes

Journal Article · 05 January 2022 · Frontiers in Energy Research

DOI: https://doi.org/10.3389/fenrg.2021.802398 · OSTI ID:1874947

Leon, Noel J. ^[1]; He, Mingfu ^[1]; Liao, Chen ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR)

Rechargeable multivalent ion batteries are promising tools to complement current lithium-ion batteries for a future of diverse energy storage needs. Divalent Mg and Ca are attractive candidates for their high crustal abundance, high volumetric anode capacity, and infrequent dendrite formation during electrochemical cycling. Electrolyte research is central to these efforts and continually improves coulombic efficiencies towards the ideal 100%. This mini-review discusses recent work towards fundamental understandings that push these chemistries towards practical use. Piecing together compatible cathode and electrolytes for a complete practical multivalent ion battery lacks a cohesive method for further development and refinement. Understanding liquid solvation, utilizing rational design, and probing interfacial interactions are focal points that govern electrolyte performance. The combination of these areas will be critical for meaningful development.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Joint Center for Energy Storage Research (JCESR)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1874947

Journal Information:: Frontiers in Energy Research, Journal Name: Frontiers in Energy Research Vol. 9; ISSN 2296-598X

Publisher:: Frontiers Research FoundationCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Solvation, Rational Design, and Interfaces: Development of Divalent Electrolytes

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