Gas Separations using Nanoporous Atomically Thin Membranes: Recent Theoretical, Simulation, and Experimental Advances

Yuan, Zhe; He, Guangwei; Li, Sylvia Xin; Misra, Rahul Prasanna; Strano, Michael S.; Blankschtein, Daniel

doi:10.1002/adma.202201472

Title: Gas Separations using Nanoporous Atomically Thin Membranes: Recent Theoretical, Simulation, and Experimental Advances

Journal Article · 18 June 2022 · Advanced Materials

DOI: https://doi.org/10.1002/adma.202201472 · OSTI ID:1872993

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Department of Chemical Engineering Massachusetts Institute of Technology Cambridge MA 02139 USA

Abstract Porous graphene and other atomically thin 2D materials are regarded as highly promising membrane materials for high‐performance gas separations due to their atomic thickness, large‐scale synthesizability, excellent mechanical strength, and chemical stability. When these atomically thin materials contain a high areal density of gas‐sieving nanoscale pores, they can exhibit both high gas permeances and high selectivities, which is beneficial for reducing the cost of gas‐separation processes. Here, recent modeling and experimental advances in nanoporous atomically thin membranes for gas separations is discussed. The major challenges involved, including controlling pore size distributions, scaling up the membrane area, and matching theory with experimental results, are also highlighted. Finally, important future directions are proposed for real gas‐separation applications of nanoporous atomically thin membranes.

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Research Organization:: Massachusetts Institute of Technology (MIT), Cambridge, MA (United States)

Sponsoring Organization:: Army Research Office (ARO); National Science Foundation (NSF); Swiss National Science Foundation; US Army Research Laboratory (ARL); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019112

OSTI ID:: 1872993

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 32 Vol. 34; ISSN 0935-9648

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (186)

Membrane Technology and Applications Baker, Richard W. ohn Wiley & Sons, Ltd https://doi.org/10.1002/0470020393	book	January 2004
Facile Synthesis of Nanostructured Carbon through Self-Assembly between Block Copolymers and Carbohydrates Rodriguez, A. T.; Li, X.; Wang, J. Advanced Functional Materials, Vol. 17, Issue 15 https://doi.org/10.1002/adfm.200600952	journal	October 2007
Wetting-Assisted Crack- and Wrinkle-Free Transfer of Wafer-Scale Graphene onto Arbitrary Substrates over a Wide Range of Surface Energies Kim, Hyun Ho; Lee, Seong Kyu; Lee, Seung Goo Advanced Functional Materials, Vol. 26, Issue 13 https://doi.org/10.1002/adfm.201504551	journal	January 2016
Synergistic CO ₂ ‐Sieving from Polymer with Intrinsic Microporosity Masking Nanoporous Single‐Layer Graphene He, Guangwei; Huang, Shiqi; Villalobos, Luis Francisco Advanced Functional Materials, Vol. 30, Issue 39 https://doi.org/10.1002/adfm.202003979	journal	August 2020
A Rational Strategy for Graphene Transfer on Substrates with Rough Features Hong, Jin-Yong; Shin, Yong Cheol; Zubair, Ahmad Advanced Materials, Vol. 28, Issue 12 https://doi.org/10.1002/adma.201505527	journal	January 2016
Carbon Nanomembranes Turchanin, Andrey; Gölzhäuser, Armin Advanced Materials, Vol. 28, Issue 29 https://doi.org/10.1002/adma.201506058	journal	June 2016
Nanoporous Atomically Thin Graphene Membranes for Desalting and Dialysis Applications Kidambi, Piran R.; Jang, Doojoon; Idrobo, Juan-Carlos Advanced Materials, Vol. 29, Issue 33 https://doi.org/10.1002/adma.201700277	journal	June 2017
In Situ Repair of 2D Chalcogenides under Electron Beam Irradiation Shen, Yuting; Xu, Tao; Tan, Xiaodong Advanced Materials, Vol. 30, Issue 14 https://doi.org/10.1002/adma.201705954	journal	February 2018
Gas‐Permeable, Multifunctional On‐Skin Electronics Based on Laser‐Induced Porous Graphene and Sugar‐Templated Elastomer Sponges Sun, Bohan; McCay, Richard N.; Goswami, Shivam Advanced Materials, Vol. 30, Issue 50 https://doi.org/10.1002/adma.201804327	journal	August 2018
Facile Fabrication of Large-Area Atomically Thin Membranes by Direct Synthesis of Graphene with Nanoscale Porosity Kidambi, Piran R.; Nguyen, Giang D.; Zhang, Sui Advanced Materials, Vol. 30, Issue 49 https://doi.org/10.1002/adma.201804977	journal	October 2018
Direct Chemical Vapor Deposition Synthesis of Porous Single‐Layer Graphene Membranes with High Gas Permeances and Selectivities Yuan, Zhe; He, Guangwei; Faucher, Samuel Advanced Materials, Vol. 33, Issue 44 https://doi.org/10.1002/adma.202104308	journal	September 2021
High-Flux Carbon Molecular Sieve Membranes for Gas Separation Richter, Hannes; Voss, Hartwig; Kaltenborn, Nadine Angewandte Chemie International Edition, Vol. 56, Issue 27 https://doi.org/10.1002/anie.201701851	journal	June 2017
Porous Graphene as an Atmospheric Nanofilter Blankenburg, Stephan; Bieri, Marco; Fasel, Roman Small, Vol. 6, Issue 20 https://doi.org/10.1002/smll.201001126	journal	September 2010
Gas Separation Membranes: Polymeric and Inorganic Ismail, Ahmad Fauzi; Khulbe, Kailash Chandra; Matsuura, Takeshi https://doi.org/10.1007/978-3-319-01095-3	book	January 2015
Boundary conditions for stokes flows near a porous membrane Tio, Kek-Kiong; Sadhal, Satwindar Singh Applied Scientific Research, Vol. 52, Issue 1 https://doi.org/10.1007/BF00849164	journal	January 1994
Molecular dynamics simulations of trihalomethanes removal from water using boron nitride nanosheets Azamat, Jafar; Khataee, Alireza; Joo, Sang Woo Journal of Molecular Modeling, Vol. 22, Issue 4 https://doi.org/10.1007/s00894-016-2939-7	journal	March 2016
Carbon molecular sieve gas separation membranes-I. Preparation and characterization based on polyimide precursors Jones, Cheryl W.; Koros, William J. Carbon, Vol. 32, Issue 8 https://doi.org/10.1016/0008-6223(94)90135-X	journal	January 1994
The mean free path in air Jennings, S. G. Journal of Aerosol Science, Vol. 19, Issue 2 https://doi.org/10.1016/0021-8502(88)90219-4	journal	April 1988
Nonphysical sampling distributions in Monte Carlo free-energy estimation: Umbrella sampling Torrie, G. M.; Valleau, J. P. Journal of Computational Physics, Vol. 23, Issue 2 https://doi.org/10.1016/0021-9991(77)90121-8	journal	February 1977
Correlation of separation factor versus permeability for polymeric membranes Robeson, Lloyd M. Journal of Membrane Science, Vol. 62, Issue 2 https://doi.org/10.1016/0376-7388(91)80060-J	journal	October 1991
The solution-diffusion model: a review Wijmans, J. G.; Baker, R. W. Journal of Membrane Science, Vol. 107, Issue 1-2 https://doi.org/10.1016/0376-7388(95)00102-I	journal	November 1995
Promising monolayer membranes for CO2/N2/CH4 separation: Graphdiynes modified respectively with hydrogen, fluorine, and oxygen atoms Zhao, Lianming; Sang, Pengpeng; Guo, Sheng Applied Surface Science, Vol. 405 https://doi.org/10.1016/j.apsusc.2017.02.054	journal	May 2017
Theoretical investigation of gas separation in functionalized nanoporous graphene membranes Wang, Yong; Yang, Qingyuan; Zhong, Chongli Applied Surface Science, Vol. 407 https://doi.org/10.1016/j.apsusc.2017.02.253	journal	June 2017
Mechanistic insights into porous graphene membranes for helium separation and hydrogen purification Wei, Shuxian; Zhou, Sainan; Wu, Zhonghua Applied Surface Science, Vol. 441 https://doi.org/10.1016/j.apsusc.2018.02.111	journal	May 2018
Strain-controlled carbon nitride: A continuously tunable membrane for gas separation Wang, Maohuai; Wang, Zhaojie; Zhou, Sainan Applied Surface Science, Vol. 506 https://doi.org/10.1016/j.apsusc.2019.144675	journal	March 2020
Uncertainty in the separation properties of functionalized porous graphenes Li, Yuanzhen; Zhang, Liying; Wu, Chao Applied Surface Science, Vol. 525 https://doi.org/10.1016/j.apsusc.2020.146524	journal	September 2020
Impermeability of graphene and its applications Berry, Vikas Carbon, Vol. 62 https://doi.org/10.1016/j.carbon.2013.05.052	journal	October 2013
Carbon molecular sieve gas separation membranes based on an intrinsically microporous polyimide precursor Ma, Xiaohua; Swaidan, Raja; Teng, Baiyang Carbon, Vol. 62 https://doi.org/10.1016/j.carbon.2013.05.057	journal	October 2013
Hydrogen sieving from intrinsic defects of benzene-derived single-layer graphene Khan, Majharul Haque; Moradi, Mina; Dakhchoune, Mostapha Carbon, Vol. 153 https://doi.org/10.1016/j.carbon.2019.07.045	journal	November 2019
Polybenzimidazole copolymer derived lacey carbon film for graphene transfer and contamination removal strategies for imaging graphene nanopores Villalobos, Luis Francisco; Huang, Shiqi; Dakhchoune, Mostapha Carbon, Vol. 173 https://doi.org/10.1016/j.carbon.2020.11.068	journal	March 2021
Application of nanoporous graphene membranes in natural gas processing: Molecular simulations of CH 4 /CO 2 , CH 4 /H 2 S and CH 4 /N 2 separation Sun, Chengzhen; Wen, Boyao; Bai, Bofeng Chemical Engineering Science, Vol. 138 https://doi.org/10.1016/j.ces.2015.08.049	journal	December 2015
Fast mass transport across two-dimensional graphene nanopores: Nonlinear pressure-dependent gas permeation flux Sun, Chengzhen; Bai, Bofeng Chemical Engineering Science, Vol. 165 https://doi.org/10.1016/j.ces.2017.02.042	journal	June 2017
Understanding the colloidal dispersion stability of 1D and 2D materials: Perspectives from molecular simulations and theoretical modeling Lin, Shangchao; Shih, Chih-Jen; Sresht, Vishnu Advances in Colloid and Interface Science, Vol. 244 https://doi.org/10.1016/j.cis.2016.07.007	journal	June 2017
Graphene and graphene oxide membranes for gas separation applications Yoo, Byung Min; Shin, Jae Eun; Lee, Hee Dae Current Opinion in Chemical Engineering, Vol. 16 https://doi.org/10.1016/j.coche.2017.04.004	journal	May 2017
Two-dimensional materials: an emerging platform for gas separation membranes Moghadam, Farhad; Park, Ho Bum Current Opinion in Chemical Engineering, Vol. 20 https://doi.org/10.1016/j.coche.2018.02.004	journal	June 2018
The mechanisms study of the porous graphene for the purification of the mixed gases: A multi-scale computational method Wang, Yuhua; Wang, Weihua; Zhu, Shuyun Computational Materials Science, Vol. 143 https://doi.org/10.1016/j.commatsci.2017.11.016	journal	February 2018
Theoretical design of a strain-controlled nanoporous CN membrane for helium separation Rao, Yong-Chao; Chu, Zhao-Qin; Gu, Xiao Computational Materials Science, Vol. 161 https://doi.org/10.1016/j.commatsci.2019.01.017	journal	April 2019
Thermally-driven isotope separation across nanoporous graphene Schrier, Joshua; McClain, James Chemical Physics Letters, Vol. 521 https://doi.org/10.1016/j.cplett.2011.11.069	journal	January 2012
Separation of the hydrogen sulfide and methane mixture by the porous graphene membrane: Effect of the charges Lei, Guangping; Liu, Chao; Xie, Hui Chemical Physics Letters, Vol. 599 https://doi.org/10.1016/j.cplett.2014.03.040	journal	April 2014
Hydrogen separation by porous phosphorene: A periodical DFT study Zhang, Yayun; Hao, Feng; Xiao, Hang International Journal of Hydrogen Energy, Vol. 41, Issue 48 https://doi.org/10.1016/j.ijhydene.2016.10.108	journal	December 2016
Selectivity trend of gas separation through nanoporous graphene Liu, Hongjun; Chen, Zhongfang; Dai, Sheng Journal of Solid State Chemistry, Vol. 224 https://doi.org/10.1016/j.jssc.2014.01.030	journal	April 2015
Mixed matrix hollow fiber membranes made with modified HSSZ-13 zeolite in polyetherimide polymer matrix for gas separation Husain, Shabbir; Koros, William J. Journal of Membrane Science, Vol. 288, Issue 1-2 https://doi.org/10.1016/j.memsci.2006.11.016	journal	February 2007
Separation and permeation characteristics of a DD3R zeolite membrane van den Bergh, J.; Zhu, W.; Gascon, J. Journal of Membrane Science, Vol. 316, Issue 1-2 https://doi.org/10.1016/j.memsci.2007.12.051	journal	May 2008
The upper bound revisited Robeson, Lloyd M. Journal of Membrane Science, Vol. 320, Issue 1-2, p. 390-400 https://doi.org/10.1016/j.memsci.2008.04.030	journal	July 2008
Hydrogen-sieving single-layer graphene membranes obtained by crystallographic and morphological optimization of catalytic copper foil Rezaei, Mojtaba; Li, Shaoxian; Huang, Shiqi Journal of Membrane Science, Vol. 612 https://doi.org/10.1016/j.memsci.2020.118406	journal	October 2020
Centimeter-scale gas-sieving nanoporous single-layer graphene membrane Lee, Wan-Chi; Bondaz, Luc; Huang, Shiqi Journal of Membrane Science, Vol. 618 https://doi.org/10.1016/j.memsci.2020.118745	journal	January 2021
Systematic design of millisecond gasification reactor for the incorporation of gas-sieving nanopores in single-layer graphene Huang, Shiqi; Li, Shaoxian; Hsu, Kuang-Jung Journal of Membrane Science, Vol. 637 https://doi.org/10.1016/j.memsci.2021.119628	journal	November 2021
Mixed matrix membranes (MMMs) comprising organic polymers with dispersed inorganic fillers for gas separation Chung, Tai-Shung; Jiang, Lan Ying; Li, Yi Progress in Polymer Science, Vol. 32, Issue 4, p. 483-507 https://doi.org/10.1016/j.progpolymsci.2007.01.008	journal	April 2007
Molecular sieving through a graphene nanopore: non-equilibrium molecular dynamics simulation Sun, Chengzhen; Bai, Bofeng Science Bulletin, Vol. 62, Issue 8 https://doi.org/10.1016/j.scib.2017.03.004	journal	April 2017
Enhanced quality of transfer-free graphene membrane for He/CH4 separation Nikkho, Sepehr; Mirzaei, Maryam; Karimi Sabet, Javad Separation and Purification Technology, Vol. 232 https://doi.org/10.1016/j.seppur.2019.115972	journal	February 2020
Graphene with line defect as a membrane for gas separation: Design via a first-principles modeling Qin, Xian; Meng, Qingyuan; Feng, Yuanping Surface Science, Vol. 607 https://doi.org/10.1016/j.susc.2012.08.024	journal	January 2013
Two-Dimensional-Material Membranes: Manipulating the Transport Pathway for Molecular Separation Cheng, Long; Liu, Gongping; Zhao, Jing Accounts of Materials Research, Vol. 2, Issue 2 https://doi.org/10.1021/accountsmr.0c00092	journal	January 2021
Lithium–Oxygen Batteries and Related Systems: Potential, Status, and Future Kwak, Won-Jin; Sharon, Daniel Chemical Reviews, Vol. 120, Issue 14, p. 6626-6683 https://doi.org/10.1021/acs.chemrev.9b00609	journal	March 2020
Separation of 1-Butene and 2-Butene Isomers via Nanoporous Graphene: A Molecular Simulation Study Xu, Yinxiang; Zhu, Huajian; Wang, Min Industrial & Engineering Chemistry Research, Vol. 59, Issue 19 https://doi.org/10.1021/acs.iecr.0c00362	journal	April 2020
Multilayer Graphene Sheet with Conical Nanopores as a Membrane for High-Permeance Molecular Separation Sun, Chengzhen; Zhou, Runfeng; Bai, Bofeng The Journal of Physical Chemistry C, Vol. 125, Issue 5 https://doi.org/10.1021/acs.jpcc.0c10717	journal	February 2021
Hexagonal Boron Nitride with Designed Nanopores as a High-Efficiency Membrane for Separating Gaseous Hydrogen from Methane Zhang, Yadong; Shi, Qi; Liu, Yuzhen The Journal of Physical Chemistry C, Vol. 119, Issue 34 https://doi.org/10.1021/acs.jpcc.5b04918	journal	August 2015
Defect-Mediated Reduction in Barrier for Helium Tunneling through Functionalized Graphene Nanopores Lalitha, Murugan; Lakshmipathi, Senthilkumar; Bhatia, Suresh K. The Journal of Physical Chemistry C, Vol. 119, Issue 36 https://doi.org/10.1021/acs.jpcc.5b05567	journal	September 2015
Molecular Insights on the CH ₄ /CO ₂ Separation in Nanoporous Graphene and Graphene Oxide Separation Platforms: Adsorbents versus Membranes Khakpay, Amir; Rahmani, Farzin; Nouranian, Sasan The Journal of Physical Chemistry C, Vol. 121, Issue 22 https://doi.org/10.1021/acs.jpcc.7b03728	journal	May 2017
Theoretical Design of Highly Efficient CO ₂ /N ₂ Separation Membranes Based on Electric Quadrupole Distinction Qu, Yuanyuan; Li, Feng; Zhao, Mingwen The Journal of Physical Chemistry C, Vol. 121, Issue 33 https://doi.org/10.1021/acs.jpcc.7b04921	journal	August 2017
Improved CO ₂ /CH ₄ Separation Performance in Negatively Charged Nanoporous Graphene Membranes Sun, Chengzhen; Bai, Bofeng The Journal of Physical Chemistry C, Vol. 122, Issue 11 https://doi.org/10.1021/acs.jpcc.8b00181	journal	February 2018
Asymmetric Two-Layer Porous Membrane for Gas Separation Liu, Maochang; Song, Dongxing; Wang, Xin The Journal of Physical Chemistry Letters, Vol. 11, Issue 15 https://doi.org/10.1021/acs.jpclett.0c01797	journal	July 2020
Graphene-Based Membranes for Molecular Separation Huang, Liang; Zhang, Miao; Li, Chun The Journal of Physical Chemistry Letters, Vol. 6, Issue 14 https://doi.org/10.1021/acs.jpclett.5b00914	journal	July 2015
Facile Size-Selective Defect Sealing in Large-Area Atomically Thin Graphene Membranes for Sub-Nanometer Scale Separations Cheng, Peifu; Kelly, Mattigan M.; Moehring, Nicole K. Nano Letters, Vol. 20, Issue 8 https://doi.org/10.1021/acs.nanolett.0c01934	journal	July 2020
Broadening the Gas Separation Utility of Monolayer Nanoporous Graphene Membranes by an Ionic Liquid Gating Guo, Wei; Mahurin, Shannon M.; Unocic, Raymond R. Nano Letters, Vol. 20, Issue 11 https://doi.org/10.1021/acs.nanolett.0c02860	journal	October 2020
Selective Gas Permeation in Defect-Engineered Bilayer Graphene Liu, Jiaman; Jin, Lei; Allen, Frances I. Nano Letters, Vol. 21, Issue 5 https://doi.org/10.1021/acs.nanolett.0c04989	journal	March 2021
Nanofiltration across Defect-Sealed Nanoporous Monolayer Graphene O’Hern, Sean C.; Jang, Doojoon; Bose, Suman Nano Letters, Vol. 15, Issue 5 https://doi.org/10.1021/acs.nanolett.5b00456	journal	April 2015
Formation and Dynamics of Electron-Irradiation-Induced Defects in Hexagonal Boron Nitride at Elevated Temperatures Pham, Thang; Gibb, Ashley L.; Li, Zhenglu Nano Letters, Vol. 16, Issue 11 https://doi.org/10.1021/acs.nanolett.6b03442	journal	October 2016
Single-Layer Graphene Membranes Withstand Ultrahigh Applied Pressure Wang, Luda; Williams, Christopher M.; Boutilier, Michael S. H. Nano Letters, Vol. 17, Issue 5 https://doi.org/10.1021/acs.nanolett.7b00442	journal	April 2017
Stable, Temperature-Dependent Gas Mixture Permeation and Separation through Suspended Nanoporous Single-Layer Graphene Membranes Yuan, Zhe; Benck, Jesse D.; Eatmon, Yannick Nano Letters, Vol. 18, Issue 8 https://doi.org/10.1021/acs.nanolett.8b01866	journal	July 2018
Separation Properties of Porous MoS ₂ Membranes Decorated with Small Molecules Li, Yuanzhen; Linghu, Yaoyao; Wu, Chao ACS Applied Materials & Interfaces, Vol. 12, Issue 17 https://doi.org/10.1021/acsami.0c02192	journal	April 2020
Selective Etching of Graphene Membrane Nanopores: From Molecular Sieving to Extreme Permeance Schlichting, Karl-Philipp; Poulikakos, Dimos ACS Applied Materials & Interfaces, Vol. 12, Issue 32 https://doi.org/10.1021/acsami.0c07277	journal	July 2020
Decimeter-Scale Atomically Thin Graphene Membranes for Gas–Liquid Separation Hou, Dandan; Zhang, Shengping; Chen, Xiaobo ACS Applied Materials & Interfaces, Vol. 13, Issue 8 https://doi.org/10.1021/acsami.0c23013	journal	February 2021
Expanded Porphyrins as Two-Dimensional Porous Membranes for CO ₂ Separation Tian, Ziqi; Dai, Sheng; Jiang, De-en ACS Applied Materials & Interfaces, Vol. 7, Issue 23 https://doi.org/10.1021/acsami.5b03275	journal	March 2015
Generating Sub-nanometer Pores in Single-Layer MoS 2 by Heavy-Ion Bombardment for Gas Separation: A Theoretical Perspective Yin, Kedi; Huang, Shengxi; Chen, Xiaofei ACS Applied Materials & Interfaces, Vol. 10, Issue 34 https://doi.org/10.1021/acsami.8b10569	journal	July 2018
Nanopores in 2D MoS ₂ : Defect-Mediated Formation and Density Modulation Ke, Jian-An; Garaj, Slaven; Gradečak, Silvija ACS Applied Materials & Interfaces, Vol. 11, Issue 29 https://doi.org/10.1021/acsami.9b03531	journal	June 2019
Computational Study on Strain-Engineered Graphene Nanopores for Selective Gas Separation Gao, Enlai; Zhang, Chunbo; Zhou, Ke ACS Applied Nano Materials, Vol. 3, Issue 11 https://doi.org/10.1021/acsanm.0c02340	journal	November 2020
Continuously Tunable Pore Size for Gas Separation via a Bilayer Nanoporous Graphene Membrane Wang, Song; Dai, Sheng; Jiang, De-en ACS Applied Nano Materials, Vol. 2, Issue 1 https://doi.org/10.1021/acsanm.8b01967	journal	December 2018
Predicting Gas Separation through Graphene Nanopore Ensembles with Realistic Pore Size Distributions Yuan, Zhe; Govind Rajan, Ananth; He, Guangwei ACS Nano, Vol. 15, Issue 1 https://doi.org/10.1021/acsnano.0c09420	journal	January 2021
Multipulsed Millisecond Ozone Gasification for Predictable Tuning of Nucleation and Nucleation-Decoupled Nanopore Expansion in Graphene for Carbon Capture Hsu, Kuang-Jung; Villalobos, Luis Francisco; Huang, Shiqi ACS Nano, Vol. 15, Issue 8 https://doi.org/10.1021/acsnano.1c02927	journal	July 2021
Molecular Sieving Across Centimeter-Scale Single-Layer Nanoporous Graphene Membranes Boutilier, Michael S. H.; Jang, Doojoon; Idrobo, Juan-Carlos ACS Nano, Vol. 11, Issue 6 https://doi.org/10.1021/acsnano.7b01231	journal	May 2017
Mechanism and Prediction of Gas Permeation through Sub-Nanometer Graphene Pores: Comparison of Theory and Simulation Yuan, Zhe; Govind Rajan, Ananth; Misra, Rahul Prasanna ACS Nano, Vol. 11, Issue 8 https://doi.org/10.1021/acsnano.7b02523	journal	July 2017
Analytical Prediction of Gas Permeation through Graphene Nanopores of Varying Sizes: Understanding Transitions across Multiple Transport Regimes Yuan, Zhe; Misra, Rahul Prasanna; Rajan, Ananth Govind ACS Nano, Vol. 13, Issue 10 https://doi.org/10.1021/acsnano.9b05779	journal	September 2019
Carbon Dioxide Separation with a Two-Dimensional Polymer Membrane Schrier, Joshua ACS Applied Materials & Interfaces, Vol. 4, Issue 7 https://doi.org/10.1021/am300867d	journal	June 2012
Tunable Hydrogen Separation in Porous Graphene Membrane: First-Principle and Molecular Dynamic Simulation Tao, Yehan; Xue, Qingzhong; Liu, Zilong ACS Applied Materials & Interfaces, Vol. 6, Issue 11 https://doi.org/10.1021/am4058887	journal	March 2014
Future Directions of Membrane Gas Separation Technology Baker, Richard W. Industrial & Engineering Chemistry Research, Vol. 41, Issue 6 https://doi.org/10.1021/ie0108088	journal	March 2002
Synthesis and Permeation Properties of a DDR-Type Zeolite Membrane for Separation of CO ₂ /CH ₄ Gaseous Mixtures Himeno, Shuji; Tomita, Toshihiro; Suzuki, Kenji Industrial & Engineering Chemistry Research, Vol. 46, Issue 21 https://doi.org/10.1021/ie061682n	journal	October 2007
Natural Gas Processing with Membranes: An Overview Baker, Richard W.; Lokhandwala, Kaaeid Industrial & Engineering Chemistry Research, Vol. 47, Issue 7 https://doi.org/10.1021/ie071083w	journal	April 2008
Adsorption of Gases in Multimolecular Layers Brunauer, Stephen; Emmett, P. H.; Teller, Edward Journal of the American Chemical Society, Vol. 60, Issue 2, p. 309-319 https://doi.org/10.1021/ja01269a023	journal	February 1938
Formation and Healing of Vacancies in Graphene Chemical Vapor Deposition (CVD) Growth Wang, Lu; Zhang, Xiuyun; Chan, Helen L. W. Journal of the American Chemical Society, Vol. 135, Issue 11 https://doi.org/10.1021/ja312687a	journal	March 2013
Large Area Synthesis of a Nanoporous Two-Dimensional Polymer at the Air/Water Interface Murray, Daniel J.; Patterson, Dustin D.; Payamyar, Payam Journal of the American Chemical Society, Vol. 137, Issue 10 https://doi.org/10.1021/ja512018j	journal	March 2015
Separation of Hydrogen and Nitrogen Gases with Porous Graphene Membrane Du, Huailiang; Li, Jingyuan; Zhang, Jing The Journal of Physical Chemistry C, Vol. 115, Issue 47, p. 23261-23266 https://doi.org/10.1021/jp206258u	journal	November 2011
Asymmetrically Decorated, Doped Porous Graphene As an Effective Membrane for Hydrogen Isotope Separation Hankel, Marlies; Jiao, Yan; Du, Aijun The Journal of Physical Chemistry C, Vol. 116, Issue 11 https://doi.org/10.1021/jp211930a	journal	March 2012
Helium Tunneling through Nitrogen-Functionalized Graphene Pores: Pressure- and Temperature-Driven Approaches to Isotope Separation Hauser, Andreas W.; Schrier, Joshua; Schwerdtfeger, Peter The Journal of Physical Chemistry C, Vol. 116, Issue 19 https://doi.org/10.1021/jp302498d	journal	May 2012
The Parameter Space of Graphene Chemical Vapor Deposition on Polycrystalline Cu Kidambi, Piran R.; Ducati, Caterina; Dlubak, Bruno The Journal of Physical Chemistry C, Vol. 116, Issue 42 https://doi.org/10.1021/jp303597m	journal	October 2012
Tunable Hydrogen Separation in sp–sp ² Hybridized Carbon Membranes: A First-Principles Prediction Zhang, Hongyu; He, Xiujie; Zhao, Mingwen The Journal of Physical Chemistry C, Vol. 116, Issue 31 https://doi.org/10.1021/jp304908p	journal	July 2012
Prominently Improved Hydrogen Purification and Dispersive Metal Binding for Hydrogen Storage by Substitutional Doping in Porous Graphene Lu, Ruifeng; Rao, Dewei; Lu, Zelin The Journal of Physical Chemistry C, Vol. 116, Issue 40 https://doi.org/10.1021/jp308195m	journal	September 2012
Noble Gas Separation using PG-ES X ( X = 1, 2, 3) Nanoporous Two-Dimensional Polymers Brockway, Anna M.; Schrier, Joshua The Journal of Physical Chemistry C, Vol. 117, Issue 1 https://doi.org/10.1021/jp3101865	journal	December 2012
Entropy-Driven Molecular Separations in 2D-Nanoporous Materials, with Application to High-Performance Paraffin/Olefin Membrane Separations Solvik, Kylen; Weaver, Jessica A.; Brockway, Anna M. The Journal of Physical Chemistry C, Vol. 117, Issue 33 https://doi.org/10.1021/jp404903g	journal	August 2013
Fluorine-Modified Porous Graphene as Membrane for CO ₂ /N ₂ Separation: Molecular Dynamic and First-Principles Simulations Wu, Tiantian; Xue, Qingzhong; Ling, Cuicui The Journal of Physical Chemistry C, Vol. 118, Issue 14 https://doi.org/10.1021/jp4096776	journal	March 2014
Gas Separation in Nanoporous Graphene from First Principle Calculations Ambrosetti, Alberto; Silvestrelli, Pier Luigi The Journal of Physical Chemistry C, Vol. 118, Issue 33 https://doi.org/10.1021/jp504914u	journal	August 2014
Helium Separation Using Porous Graphene Membranes Schrier, Joshua The Journal of Physical Chemistry Letters, Vol. 1, Issue 15 https://doi.org/10.1021/jz100748x	journal	July 2010
No Graphene Etching in Purified Hydrogen Choubak, Saman; Biron, Maxime; Levesque, Pierre L. The Journal of Physical Chemistry Letters, Vol. 4, Issue 7 https://doi.org/10.1021/jz400400u	journal	March 2013
Mechanisms of Gas Permeation through Single Layer Graphene Membranes Drahushuk, Lee W.; Strano, Michael S. Langmuir, Vol. 28, Issue 48 https://doi.org/10.1021/la303468r	journal	November 2012
Mechanisms of Molecular Permeation through Nanoporous Graphene Membranes Sun, Chengzhen; Boutilier, Michael S. H.; Au, Harold Langmuir, Vol. 30, Issue 2 https://doi.org/10.1021/la403969g	journal	January 2014
Basis of Permeability/Selectivity Tradeoff Relations in Polymeric Gas Separation Membranes Freeman, Benny D. Macromolecules, Vol. 32, Issue 2 https://doi.org/10.1021/ma9814548	journal	January 1999
Synthesis of Few-Layer Hexagonal Boron Nitride Thin Film by Chemical Vapor Deposition Shi, Yumeng; Hamsen, Christoph; Jia, Xiaoting Nano Letters, Vol. 10, Issue 10 https://doi.org/10.1021/nl1023707	journal	October 2010
Atomic-Scale Electron-Beam Sculpting of Near-Defect-Free Graphene Nanostructures Song, Bo; Schneider, Grégory F.; Xu, Qiang Nano Letters, Vol. 11, Issue 6 https://doi.org/10.1021/nl200369r	journal	June 2011
Selective Ionic Transport through Tunable Subnanometer Pores in Single-Layer Graphene Membranes O’Hern, Sean C.; Boutilier, Michael S. H.; Idrobo, Juan-Carlos Nano Letters, Vol. 14, Issue 3 https://doi.org/10.1021/nl404118f	journal	February 2014
Impermeable Atomic Membranes from Graphene Sheets Bunch, J. Scott; Verbridge, Scott S.; Alden, Jonathan S. Nano Letters, Vol. 8, Issue 8 https://doi.org/10.1021/nl801457b	journal	August 2008
Selective Sputtering and Atomic Resolution Imaging of Atomically Thin Boron Nitride Membranes Meyer, Jannik C.; Chuvilin, Andrey; Algara-Siller, Gerardo Nano Letters, Vol. 9, Issue 7 https://doi.org/10.1021/nl9011497	journal	July 2009
Porous Graphene as the Ultimate Membrane for Gas Separation Jiang, De-en; Cooper, Valentino R.; Dai, Sheng Nano Letters, Vol. 9, Issue 12, p. 4019-4024 https://doi.org/10.1021/nl9021946	journal	December 2009
Structural Defects in Graphene Banhart, Florian; Kotakoski, Jani; Krasheninnikov, Arkady V. ACS Nano, Vol. 5, Issue 1 https://doi.org/10.1021/nn102598m	journal	November 2010
Implications of Permeation through Intrinsic Defects in Graphene on the Design of Defect-Tolerant Membranes for Gas Separation Boutilier, Michael S. H.; Sun, Chengzhen; O’Hern, Sean C. ACS Nano, Vol. 8, Issue 1, p. 841-849 https://doi.org/10.1021/nn405537u	journal	December 2013
Seven chemical separations to change the world Sholl, David S.; Lively, Ryan P. Nature, Vol. 532, Issue 7600 https://doi.org/10.1038/532435a	journal	April 2016
2D transition metal dichalcogenides Manzeli, Sajedeh; Ovchinnikov, Dmitry; Pasquier, Diego Nature Reviews Materials, Vol. 2, Issue 8 https://doi.org/10.1038/natrevmats.2017.33	journal	June 2017
Single-layer MoS2 nanopores as nanopower generators Feng, Jiandong; Graf, Michael; Liu, Ke Nature, Vol. 536, Issue 7615 https://doi.org/10.1038/nature18593	journal	July 2016
Engineering of nanostructured carbon materials with electron or ion beams Krasheninnikov, A. V.; Banhart, F. Nature Materials, Vol. 6, Issue 10 https://doi.org/10.1038/nmat1996	journal	October 2007
Materials for next-generation molecularly selective synthetic membranes Koros, William J.; Zhang, Chen Nature Materials, Vol. 16, Issue 3 https://doi.org/10.1038/nmat4805	journal	January 2017
From water to organics in membrane separations Lively, Ryan P.; Sholl, David S. Nature Materials, Vol. 16, Issue 3 https://doi.org/10.1038/nmat4860	journal	February 2017
Graphene nanomesh Bai, Jingwei; Zhong, Xing; Jiang, Shan Nature Nanotechnology, Vol. 5, Issue 3 https://doi.org/10.1038/nnano.2010.8	journal	February 2010
Selective molecular sieving through porous graphene Koenig, Steven P.; Wang, Luda; Pellegrino, John Nature Nanotechnology, Vol. 7, Issue 11 https://doi.org/10.1038/nnano.2012.162	journal	October 2012
Molecular valves for controlling gas phase transport made from discrete ångström-sized pores in graphene Wang, Luda; Drahushuk, Lee W.; Cantley, Lauren Nature Nanotechnology, Vol. 10, Issue 9 https://doi.org/10.1038/nnano.2015.158	journal	August 2015
Water desalination using nanoporous single-layer graphene Surwade, Sumedh P.; Smirnov, Sergei N.; Vlassiouk, Ivan V. Nature Nanotechnology, Vol. 10, Issue 5 https://doi.org/10.1038/nnano.2015.37	journal	March 2015
Fundamental transport mechanisms, fabrication and potential applications of nanoporous atomically thin membranes Wang, Luda; Boutilier, Michael S. H.; Kidambi, Piran R. Nature Nanotechnology, Vol. 12, Issue 6 https://doi.org/10.1038/nnano.2017.72	journal	June 2017
Air separation with graphene mediated by nanowindow-rim concerted motion Vallejos-Burgos, Fernando; Coudert, François-Xavier; Kaneko, Katsumi Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04224-6	journal	May 2018
Single-layer graphene membranes by crack-free transfer for gas mixture separation Huang, Shiqi; Dakhchoune, Mostapha; Luo, Wen Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04904-3	journal	July 2018
Reversible defect engineering in graphene grain boundaries Balasubramanian, Krishna; Biswas, Tathagatha; Ghosh, Priyadarshini Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09000-8	journal	March 2019
High-frequency gas effusion through nanopores in suspended graphene Rosłoń, I. E.; Dolleman, R. J.; Licona, H. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-19893-5	journal	November 2020
Addressing the isomer cataloguing problem for nanopores in two-dimensional materials Govind Rajan, Ananth; Silmore, Kevin S.; Swett, Jacob Nature Materials, Vol. 18, Issue 2 https://doi.org/10.1038/s41563-018-0258-3	journal	January 2019
Limits on gas impermeability of graphene Sun, P. Z.; Yang, Q.; Kuang, W. J. Nature, Vol. 579, Issue 7798 https://doi.org/10.1038/s41586-020-2070-x	journal	March 2020
Fabrication of Subnanometer-Precision Nanopores in Hexagonal Boron Nitride Gilbert, S. Matt; Dunn, Gabriel; Azizi, Amin Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-12684-x	journal	November 2017
Reactive molecular dynamic simulations on the gas separation performance of porous graphene membrane Esfandiarpoor, Somaye; Fazli, Mostafa; Ganji, Masoud Darvish Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-14297-w	journal	November 2017
Impact of growth rate on graphene lattice-defect formation within a single crystalline domain Chin, Hao-Ting; Lee, Jian-Jhang; Hofmann, Mario Scientific Reports, Vol. 8, Issue 1 https://doi.org/10.1038/s41598-018-22512-5	journal	March 2018
Alumina-supported cobalt–adeninate MOF membranes for CO ₂ /CH ₄ separation Xie, Zhenzhen; Li, Tao; Rosi, Nathaniel L. J. Mater. Chem. A, Vol. 2, Issue 5 https://doi.org/10.1039/C3TA14058J	journal	January 2014
Alkane separation using nanoporous graphene membranes Nieszporek, Krzysztof; Drach, Mateusz Physical Chemistry Chemical Physics, Vol. 17, Issue 2 https://doi.org/10.1039/C4CP02745K	journal	January 2015
Improved permeability and selectivity in porous graphene for hydrogen purification Huang, Chengxi; Wu, Haiping; Deng, Kaiming Phys. Chem. Chem. Phys., Vol. 16, Issue 47 https://doi.org/10.1039/C4CP04385E	journal	January 2014
Graphene-based membranes Liu, Gongping; Jin, Wanqin; Xu, Nanping Chemical Society Reviews, Vol. 44, Issue 15 https://doi.org/10.1039/C4CS00423J	journal	January 2015
A promising monolayer membrane for oxygen separation from harmful gases: nitrogen-substituted polyphenylene Lu, Ruifeng; Meng, Zhaoshun; Rao, Dewei Nanoscale, Vol. 6, Issue 17 https://doi.org/10.1039/C4NR02315C	journal	January 2014
Inhibition effect of a non-permeating component on gas permeability of nanoporous graphene membranes Wen, Boyao; Sun, Chengzhen; Bai, Bofeng Physical Chemistry Chemical Physics, Vol. 17, Issue 36 https://doi.org/10.1039/C5CP03195H	journal	January 2015
Exploration of nanoporous graphene membranes for the separation of N ₂ from CO ₂ : a multi-scale computational study Wang, Yong; Yang, Qingyuan; Li, Jinping Physical Chemistry Chemical Physics, Vol. 18, Issue 12 https://doi.org/10.1039/C5CP06569K	journal	January 2016
Atomic-scale dynamics of triangular hole growth in monolayer hexagonal boron nitride under electron irradiation Ryu, Gyeong Hee; Park, Hyo Ju; Ryou, Junga Nanoscale, Vol. 7, Issue 24 https://doi.org/10.1039/C5NR01473E	journal	January 2015
C ₂ N: an excellent two-dimensional monolayer membrane for He separation Zhu, Lei; Xue, Qingzhong; Li, Xiaofang Journal of Materials Chemistry A, Vol. 3, Issue 42 https://doi.org/10.1039/C5TA05700K	journal	January 2015
Separation of carbon dioxide and nitrogen gases through modified boron nitride nanosheets as a membrane: insights from molecular dynamics simulations Azamat, Jafar; Khataee, Alireza; Sadikoglu, Fahreddin RSC Advances, Vol. 6, Issue 97 https://doi.org/10.1039/C6RA18396D	journal	January 2016
Porous germanene as a highly efficient gas separation membrane Bian, Ang; Dai, Yafei; Yang, Jinlong Nanoscale, Vol. 9, Issue 44 https://doi.org/10.1039/C7NR05805E	journal	January 2017
Effect of pore density on gas permeation through nanoporous graphene membranes Wang, Song; Tian, Ziqi; Dai, Sheng Nanoscale, Vol. 10, Issue 30 https://doi.org/10.1039/C8NR02625D	journal	January 2018
Two-dimensional nanosheet-based gas separation membranes Liu, Min; Gurr, Paul A.; Fu, Qiang Journal of Materials Chemistry A, Vol. 6, Issue 46 https://doi.org/10.1039/C8TA09070J	journal	January 2018
⁴ He/ ³ He separation using oxygen-functionalized nanoporous graphene Motallebiour, Maryam S.; Karimi-Sabet, Javad; Maghari, Ali Physical Chemistry Chemical Physics, Vol. 21, Issue 23 https://doi.org/10.1039/C9CP01364D	journal	January 2019
Entropic selectivity in air separation via a bilayer nanoporous graphene membrane Wang, Song; Dai, Sheng; Jiang, De-en Physical Chemistry Chemical Physics, Vol. 21, Issue 29 https://doi.org/10.1039/C9CP02670C	journal	January 2019
High-permeance polymer-functionalized single-layer graphene membranes that surpass the postcombustion carbon capture target He, Guangwei; Huang, Shiqi; Villalobos, Luis Francisco Energy & Environmental Science, Vol. 12, Issue 11 https://doi.org/10.1039/C9EE01238A	journal	January 2019
Hidden porous boron nitride as a high-efficiency membrane for hydrogen purification Lin, Shuyi; Xu, Meiling; Qu, Ziyang Physical Chemistry Chemical Physics, Vol. 22, Issue 39 https://doi.org/10.1039/D0CP03785K	journal	January 2020
Theoretical description of molecular permeation via surface diffusion through graphene nanopores Sun, Chengzhen; Luo, Kailin; Zhou, Runfeng Physical Chemistry Chemical Physics, Vol. 23, Issue 12 https://doi.org/10.1039/D0CP05629D	journal	January 2021
Multicomponent gas separation and purification using advanced 2D carbonaceous nanomaterials Mahdizadeh, Sayyed Jalil; Goharshadi, Elaheh K. RSC Advances, Vol. 10, Issue 41 https://doi.org/10.1039/D0RA04286B	journal	January 2020
Porous graphenes: two-dimensional polymer synthesis with atomic precision Bieri, Marco; Treier, Matthias; Cai, Jinming Chemical Communications, Issue 45 https://doi.org/10.1039/b915190g	journal	January 2009
Architecture of graphdiyne nanoscale films Li, Guoxing; Li, Yuliang; Liu, Huibiao Chemical Communications, Vol. 46, Issue 19 https://doi.org/10.1039/b922733d	journal	January 2010
Two-dimensional polyphenylene: experimentally available porous graphene as a hydrogen purification membrane Li, Yafei; Zhou, Zhen; Shen, Panwen Chemical Communications, Vol. 46, Issue 21 https://doi.org/10.1039/b926313f	journal	January 2010
Graphdiyne: a versatile nanomaterial for electronics and hydrogen purification Jiao, Yan; Du, Aijun; Hankel, Marlies Chemical Communications, Vol. 47, Issue 43 https://doi.org/10.1039/c1cc15129k	journal	January 2011
Synthesis and CO2/CH4 separation performance of Bio-MOF-1 membranes Bohrman, Joseph A.; Carreon, Moises A. Chemical Communications, Vol. 48, Issue 42 https://doi.org/10.1039/c2cc31821k	journal	January 2012
Methane-selective nanoporous graphene membranes for gas purification Hauser, Andreas W.; Schwerdtfeger, Peter Physical Chemistry Chemical Physics, Vol. 14, Issue 38 https://doi.org/10.1039/c2cp41889d	journal	January 2012
Selective hydrogen purification through graphdiyne under ambient temperature and pressure Cranford, Steven W.; Buehler, Markus J. Nanoscale, Vol. 4, Issue 15 https://doi.org/10.1039/c2nr30921a	journal	January 2012
Influence of chemical functionalization on the CO2/N2 separation performance of porous graphene membranes Shan, Meixia; Xue, Qingzhong; Jing, Nuannuan Nanoscale, Vol. 4, Issue 17 https://doi.org/10.1039/c2nr31402a	journal	January 2012
Porous silicene as a hydrogen purification membrane Hu, Wei; Wu, Xiaojun; Li, Zhenyu Physical Chemistry Chemical Physics, Vol. 15, Issue 16 https://doi.org/10.1039/c3cp00066d	journal	January 2013
Insights into CO2/N2 separation through nanoporous graphene from molecular dynamics Liu, Hongjun; Dai, Sheng; Jiang, De-en Nanoscale, Vol. 5, Issue 20 https://doi.org/10.1039/c3nr02852f	journal	January 2013
Statistical mechanics of isomerization dynamics in liquids and the transition state approximation Chandler, David The Journal of Chemical Physics, Vol. 68, Issue 6 https://doi.org/10.1063/1.436049	journal	January 1978
Flow rate through microfilters: Influence of the pore size distribution, hydrodynamic interactions, wall slip, and inertia Jensen, Kaare H.; Valente, André X. C. N.; Stone, Howard A. Physics of Fluids, Vol. 26, Issue 5 https://doi.org/10.1063/1.4876937	journal	May 2014
Electrical pulse fabrication of graphene nanopores in electrolyte solution Kuan, Aaron T.; Lu, Bo; Xie, Ping Applied Physics Letters, Vol. 106, Issue 20 https://doi.org/10.1063/1.4921620	journal	May 2015
Atom-by-atom nucleation and growth of graphene nanopores Russo, C. J.; Golovchenko, J. A. Proceedings of the National Academy of Sciences, Vol. 109, Issue 16, p. 5953-5957 https://doi.org/10.1073/pnas.1119827109	journal	April 2012
Theory and simulation of jump dynamics, diffusion and phase equilibrium in nanopores Auerbach, Scott M. International Reviews in Physical Chemistry, Vol. 19, Issue 2 https://doi.org/10.1080/01442350050020879	journal	April 2000
Nanoporous MoS ₂ monolayer as a promising membrane for purifying hydrogen and enriching methane Zhang, Yadong; Meng, Zhaoshun; Shi, Qi Journal of Physics: Condensed Matter, Vol. 29, Issue 37 https://doi.org/10.1088/1361-648X/aa7d5e	journal	August 2017
Knudsen effusion through polymer-coated three-layer porous graphene membranes Boutilier, Michael S. H.; Hadjiconstantinou, Nicolas G.; Karnik, Rohit Nanotechnology, Vol. 28, Issue 18 https://doi.org/10.1088/1361-6528/aa680f	journal	April 2017
Graphene-based membranes: status and prospects Yoon, Hee Wook; Cho, Young Hoon; Park, Ho Bum Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 374, Issue 2060, Article No. 20150024 https://doi.org/10.1098/rsta.2015.0024	journal	December 2015
Path-integral Monte Carlo techniques for rotational motion in two dimensions: Quenched, annealed, and no-spin quantum-statistical averages Marx, D.; Nielaba, P. Physical Review A, Vol. 45, Issue 12 https://doi.org/10.1103/PhysRevA.45.8968	journal	June 1992
Electron knock-on damage in hexagonal boron nitride monolayers Kotakoski, J.; Jin, C. H.; Lehtinen, O. Physical Review B, Vol. 82, Issue 11 https://doi.org/10.1103/PhysRevB.82.113404	journal	September 2010
Mechanical properties of suspended graphene sheets Frank, I. W.; Tanenbaum, D. M.; van der Zande, A. M. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 25, Issue 6 https://doi.org/10.1116/1.2789446	journal	January 2007
Multifunctional wafer-scale graphene membranes for fast ultrafiltration and high permeation gas separation Choi, Kyoungjun; Droudian, Amirhossein; Wyss, Roman M. Science Advances, Vol. 4, Issue 11 https://doi.org/10.1126/sciadv.aau0476	journal	November 2018
Etching gas-sieving nanopores in single-layer graphene with an angstrom precision for high-performance gas mixture separation Zhao, J.; He, G.; Huang, S. Science Advances, Vol. 5, Issue 1 https://doi.org/10.1126/sciadv.aav1851	journal	January 2019
Gas flow through atomic-scale apertures Thiruraman, Jothi Priyanka; Dar, Sidra Abbas; Masih Das, Paul Science Advances, Vol. 6, Issue 51 https://doi.org/10.1126/sciadv.abc7927	journal	December 2020
Millisecond lattice gasification for high-density CO ₂ - and O ₂ -sieving nanopores in single-layer graphene Huang, Shiqi; Li, Shaoxian; Villalobos, Luis Francisco Science Advances, Vol. 7, Issue 9 https://doi.org/10.1126/sciadv.abf0116	journal	February 2021
Electric Field Effect in Atomically Thin Carbon Films Novoselov, K. S. Science, Vol. 306, Issue 5696, p. 666-669 https://doi.org/10.1126/science.1102896	journal	October 2004
Graphene: Status and Prospects Geim, A. K. Science, Vol. 324, Issue 5934, p. 1530-1534 https://doi.org/10.1126/science.1158877	journal	June 2009
Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils Li, X.; Cai, W.; An, J. Science, Vol. 324, Issue 5932, p. 1312-1314 https://doi.org/10.1126/science.1171245	journal	May 2009
Ultimate Permeation Across Atomically Thin Porous Graphene Celebi, K.; Buchheim, J.; Wyss, R. M. Science, Vol. 344, Issue 6181 https://doi.org/10.1126/science.1249097	journal	April 2014
High-Selectivity, High-Flux Silica Membranes for Gas Separation de Vos, R. M. Science, Vol. 279, Issue 5357 https://doi.org/10.1126/science.279.5357.1710	journal	March 1998
Large-area graphene-nanomesh/carbon-nanotube hybrid membranes for ionic and molecular nanofiltration Yang, Yanbing; Yang, Xiangdong; Liang, Ling Science, Vol. 364, Issue 6445 https://doi.org/10.1126/science.aau5321	journal	June 2019
Scaling up nanoporous graphene membranes Mi, Baoxia Science, Vol. 364, Issue 6445 https://doi.org/10.1126/science.aax3103	journal	June 2019
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984) Sing, K. S. W. Pure and Applied Chemistry, Vol. 57, Issue 4, p. 603-619 https://doi.org/10.1351/pac198557040603	journal	January 1985
Theoretical Study of Nanoporous Graphene Membranes for Natural Gas Purification Tronci, Giovanni; Raffone, Federico; Cicero, Giancarlo Applied Sciences, Vol. 8, Issue 9 https://doi.org/10.3390/app8091547	journal	September 2018

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