Effects of Charged Solute-Solvent Interaction on Reservoir Temperature during Subsurface CO2 Injection
A short-term side-effect of CO2 injection is a developing low-pH front that forms ahead of the bulk water injectant, due to differences in solute diffusivity. Observations of downhole well temperature show a reduction in aqueous-phase temperature with the arrival of a low-pH front, followed by a gradual rise in temperature upon the arrival of a high concentration of bicarbonate ion. In this work, we model aqueous-phase transient heat advection and diffusion, with the volumetric energy generation rate computed from solute-solvent interaction using the Helgeson–Kirkham–Flowers (HKF) model, which is based on the Born Solvation model, for computing specific molar heat capacity and the enthalpy of charged electrolytes. A computed injectant water temperature profile is shown to agree with the actual bottom hole sampled temperature acquired from sensors. The modeling of aqueous-phase temperature during subsurface injection simulation is important for the accurate modeling of mineral dissolution and precipitation because forward dissolution rates are governed by a temperature-dependent Arrhenius model.
- Sponsoring Organization:
- USDOE
- OSTI ID:
- 1872505
- Alternate ID(s):
- OSTI ID: 1981167
- Journal Information:
- Minerals, Journal Name: Minerals Journal Issue: 6 Vol. 12; ISSN MBSIBI; ISSN 2075-163X
- Publisher:
- MDPI AGCopyright Statement
- Country of Publication:
- Switzerland
- Language:
- English
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