Title: Theory of superconductivity in doped quantum paraelectrics

Journal Article · · npj Quantum Materials

Abstract Recent experiments on Nb-doped SrTiO 3 have shown that the superconducting energy gap to the transition temperature ratio maintains the Bardeen–Cooper–Schrieffer (BCS) value throughout its superconducting dome. Motivated by these and related studies, we show that the Cooper pairing mediated by a single soft transverse-optical phonon is the most natural mechanism for such a superconducting dome given experimental constraints, and present the microscopic theory for this pairing mechanism. Furthermore, we show that this mechanism is consistent with the T 2 resistivity in the normal state. Lastly, we discuss what physical insights SrTiO 3 provides for superconductivity in other quantum paraelectrics such as KTaO 3 .

Research Organization:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Organization:
Ministry of Education; Ministry of Science, ICT and Future Planning (MSIT); National Research Foundation of Korea (NRF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division
Grant/Contract Number:
AC02-76SF00515
OSTI ID:
1872239
Journal Information:
npj Quantum Materials, Journal Name: npj Quantum Materials Journal Issue: 1 Vol. 7; ISSN 2397-4648
Publisher:
Nature Publishing GroupCopyright Statement
Country of Publication:
United Kingdom
Language:
English

References (55)

Soft modes in semiconducting SrTiO3: II. The ferroelectric mode journal December 1980
Superconductivity in SrTiO3: Dielectric Function Method for Non-Parabolic Bands journal January 2019
Superconductivity in dilute SrTiO 3 : A review journal June 2020
Eliashberg theory of phonon-mediated superconductivity — When it is valid and how it breaks down journal June 2020
Three-Dimensional Limit of Bulk Rashba Effect in Ferroelectric Semiconductor GeTe journal December 2020
Discovery of superconductivity in KTaO3 by electrostatic carrier doping journal May 2011
Superconductivity mediated by polar modes in ferroelectric metals journal September 2020
Rationalizing and engineering Rashba spin-splitting in ferroelectric oxides journal September 2019
Phonon mechanism in the most dilute superconductor n -type SrTiO 3 journal April 2016
Polaronic behavior in a weak-coupling superconductor journal January 2018
Superconducting Transition Temperatures of Semiconducting SrTi O 3 journal November 1967
Soft-Mode Superconductivity in SrTi O 3 − x journal April 1969
Anisotropic superconductivity mediated by ferroelectric fluctuations in cubic systems with spin-orbit coupling journal May 2020
Nonadiabatic superconductivity. I. Vertex corrections for the electron-phonon interactions journal October 1995
Nonadiabatic superconductivity. II. Generalized Eliashberg equations beyond Migdal’s theorem journal October 1995
Type II superconducting parameters of Tl-doped PbTe determined from heat capacity and electronic transport measurements journal October 2006
Large phonon band gap in Sr Ti O 3 and the vibrational signatures of ferroelectricity in A Ti O 3 perovskites: First-principles lattice dynamics and inelastic neutron scattering journal April 2008
Electronic structure of doped d 0 perovskite semiconductors journal March 2011
Common Fermi-liquid origin of T 2 resistivity and superconductivity in n -type SrTiO 3 journal November 2011
Theory of spin-orbit coupling at LaAlO 3 /SrTiO 3 interfaces and SrTiO 3 surfaces journal April 2013
Odd-parity superconductivity from phonon-mediated pairing: Application to Cu x Bi 2 Se 3 journal November 2014
Topological superconducting phases from inversion symmetry breaking order in spin-orbit-coupled systems journal April 2016
Mechanism, time-reversal symmetry, and topology of superconductivity in noncentrosymmetric systems journal May 2016
Strongly enhanced Rashba splittings in an oxide heterostructure: A tantalate monolayer on BaHfO 3 journal September 2016
Superconductivity at very low density: The case of strontium titanate journal December 2016
Modulation of the superconducting critical temperature due to quantum confinement at the LaAlO 3 / SrTiO 3 interface journal September 2017
Superconductivity at low density near a ferroelectric quantum critical point: Doped SrTiO 3 journal September 2018
Novel pairing mechanism for superconductivity at a vanishing level of doping driven by critical ferroelectric modes journal December 2018
Phonon-mediated superconductivity in low carrier-density systems journal March 2019
Electron-Phonon Interaction and Charge Carrier Mass Enhancement in SrTiO 3 journal June 2008
Orbital-Angular-Momentum Based Origin of Rashba-Type Surface Band Splitting journal October 2011
Critical Doping for the Onset of a Two-Band Superconducting Ground State in SrTiO 3 − δ journal May 2014
Intrinsic Mobility Limiting Mechanisms in Lanthanum-Doped Strontium Titanate journal May 2014
Odd-Parity Superconductivity in the Vicinity of Inversion Symmetry Breaking in Spin-Orbit-Coupled Systems journal November 2015
Quantum Critical Origin of the Superconducting Dome in SrTiO 3 journal December 2015
Superconductivity in Semiconducting SrTi O 3 journal April 1964
Single-Gap Superconductivity and Dome of Superfluid Density in Nb-Doped SrTi O 3 journal June 2018
Electron-Phonon Scattering in the Presence of Soft Modes and Electron Mobility in SrTiO 3 Perovskite from First Principles journal November 2018
Multiband Quantum Criticality of Polar Metals journal June 2020
Two-Dimensional Superconductivity at the LaAlO 3 / KTaO 3 ( 110 ) Heterointerface journal January 2021
Quasiparticle and Nonquasiparticle Transport in Doped Quantum Paraelectrics journal February 2021
Symmetry Considerations on Martensitic Transformations: "Ferroelectric" Metals? journal February 1965
Two-Phonon Deformation Potential and Superconductivity in Degenerate Semiconductors journal February 1974
Superconductivity without Inversion Symmetry: MnSi versus C e P t 3 S i journal March 2004
Topological superconductivity from transverse optical phonons in oxide heterostructures journal March 2020
Possible mechanism for superconductivity in doped SrTiO 3 journal August 2019
Beyond triplet: Unconventional superconductivity in a spin-3/2 topological semimetal journal April 2018
Superconducting Interfaces Between Insulating Oxides journal August 2007
Scalable T2 resistivity in a small single-component Fermi surface journal August 2015
Two-dimensional superconductivity and anisotropic transport at KTaO 3 (111) interfaces journal January 2021
Electric field control of superconductivity at the LaAlO 3 /KTaO 3 (111) interface journal May 2021
Theory of Superconductivity in Polar Semiconductors and Its Application to N-Type Semiconducting SrTiO 3 journal October 1980
Low-density superconductivity in SrTiO$_3$ bounded by the adiabatic criterion preprint January 2021
Superconductivity from energy fluctuations in dilute quantum critical polar metals preprint January 2021
Theory of superconductivity mediated by Rashba coupling in incipient ferroelectrics text January 2021

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