Effect of amine type on acidic toxic gas adsorption at ambient conditions on modified CuBTC

Ebrahim, Amani M.; Bandosz, Teresa J.

doi:10.1016/j.jece.2022.107261

Title: Effect of amine type on acidic toxic gas adsorption at ambient conditions on modified CuBTC

Journal Article · 25 January 2022 · Journal of Environmental Chemical Engineering (Online)

DOI: https://doi.org/10.1016/j.jece.2022.107261 · OSTI ID:1872113

Ebrahim, Amani M. ^[1]; Bandosz, Teresa J. ^[1]

City College of New York, NY (United States)

We report two amine-modified copper-based Metal Organic Frameworks (MOF (CuBTC)) of different surface chemical and textural features were synthesized and used as adsorbents of acidic toxic gases (NO₂ and H₂S) in both moist (71% relative humidity (R.H.)) and dry conditions. The initial and exhausted samples were characterized by nitrogen adsorption, powder X-ray diffraction, scanning electron microscopy, thermal gravimetric analysis and Fourier transform infrared spectroscopy. The addition of melamine prevented full growth of CuBTC crystals and resulted in amorphous-like particles with sizes less than 200 nm. The material was non-porous with a small surface area. When urea was used as an amine source, the resulting particles maintained the overall octahedral shape of the parent CuBTC MOF and the material was more porous than the parent MOF. While the urea-modified CuBTC sample performed well as an NO₂ adsorbent in the presence of moisture, the reactivity of the melamine-modified sample and its physical properties provided a favorable environment for the removal of H₂S. The incorporation of amines into the MOF structure also resulted in surface defects /open copper sites that favored the removal of toxic gases in dry conditions. The reactivity of the adsorbents with toxic gases was demonstrated by the changes in the adsorbent colors, in texture, and in surface chemistry (organic salts, complexes, sulfides and nitrates were formed).

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: Army Research Office; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1872113

Journal Information:: Journal of Environmental Chemical Engineering (Online), Journal Name: Journal of Environmental Chemical Engineering (Online) Journal Issue: 3 Vol. 10; ISSN 2213-3437

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (83)

Materials Science of Membranes for Gas and Vapor Separation Yampolskii, Yuri; Pinnau, Ingo; Freeman, Benny https://doi.org/10.1002/047002903X	book	June 2006
MOF/graphite oxide hybrid materials: exploring the new concept of adsorbents and catalysts Bandosz, Teresa J.; Petit, Camille Adsorption, Vol. 17, Issue 1 https://doi.org/10.1007/s10450-010-9267-5	journal	August 2010
Mesoporous SBA-15 Supported Iron Oxide: A Potent Catalyst for Hydrogen Sulfide Removal Wang, Xiaohui; Jia, Jinping; Zhao, Ling Water, Air, and Soil Pollution, Vol. 193, Issue 1-4 https://doi.org/10.1007/s11270-008-9686-z	journal	April 2008
Vibrational spectra of melamine diborate, C3N6H62H3BO3 Panicker, C. Yohannan; Varghese, Hema Tresa; John, Annamma Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 58, Issue 8 https://doi.org/10.1016/S1386-1425(01)00608-4	journal	June 2002
Adsorption and desorption of NO and NO2 on Cu-ZSM-5 Despres, Joël; Koebel, Manfred; Kröcher, Oliver Microporous and Mesoporous Materials, Vol. 58, Issue 2 https://doi.org/10.1016/S1387-1811(02)00627-3	journal	March 2003
Preparation and characterization of CuO/CeO2 catalysts and their applications in low-temperature CO oxidation Zheng, Xiucheng; Zhang, Xiaoli; Wang, Xiangyu Applied Catalysis A: General, Vol. 295, Issue 2 https://doi.org/10.1016/j.apcata.2005.07.048	journal	November 2005
Hydrogen sulfide adsorption on nano-sized zinc oxide/reduced graphite oxide composite at ambient condition Song, Hoon Sub; Park, Moon Gyu; Kwon, Soon Jin Applied Surface Science, Vol. 276 https://doi.org/10.1016/j.apsusc.2013.03.147	journal	July 2013
Adsorption of hydrogen sulfide by amine-functionalized metal organic framework (MOF-199): An experimental and simulation study Zhang, Hong-Yan; Yang, Chao; Geng, Qiang Applied Surface Science, Vol. 497 https://doi.org/10.1016/j.apsusc.2019.143815	journal	December 2019
The synthesis and characterization of copper-based metal–organic framework/graphite oxide composites Petit, Camille; Burress, Jacob; Bandosz, Teresa J. Carbon, Vol. 49, Issue 2 https://doi.org/10.1016/j.carbon.2010.09.059	journal	February 2011
NO2 adsorption at ambient temperature on urea-modified ordered mesoporous carbon Florent, Marc; Tocci, Marialaura; Bandosz, Teresa J. Carbon, Vol. 63 https://doi.org/10.1016/j.carbon.2013.06.081	journal	November 2013
Exceptional activity for direct synthesis of phenol from benzene over PMoV@MOF with O2 Yang, Hua; Li, Jun; Wang, Lianyue Catalysis Communications, Vol. 35 https://doi.org/10.1016/j.catcom.2013.02.013	journal	May 2013
Preparation of MOFs and MOFs derived materials and their catalytic application in air pollution: A review He, Hanbing; Li, Ren; Yang, Zhihui Catalysis Today, Vol. 375 https://doi.org/10.1016/j.cattod.2020.02.033	journal	September 2021
Experimental strategies on enhancing toxic gases uptake of metal–organic frameworks Binaeian, Ehsan; El-Sayed, El-Sayed M.; Khanpour Matikolaei, Mojtaba Coordination Chemistry Reviews, Vol. 430 https://doi.org/10.1016/j.ccr.2020.213738	journal	March 2021
Mapping the Cu-BTC metal–organic framework (HKUST-1) stability envelope in the presence of water vapour for CO2 adsorption from flue gases Al-Janabi, Nadeen; Hill, Patrick; Torrente-Murciano, Laura Chemical Engineering Journal, Vol. 281 https://doi.org/10.1016/j.cej.2015.07.020	journal	December 2015
Adsorption of hydrogen sulfide (H2S) on zeolite (Z): Retention mechanism Sigot, Léa; Ducom, Gaëlle; Germain, Patrick Chemical Engineering Journal, Vol. 287 https://doi.org/10.1016/j.cej.2015.11.010	journal	March 2016
Adsorption/reduction of nitrogen dioxide on activated carbons: Textural properties versus surface chemistry – A review Jeguirim, Mejdi; Belhachemi, Meriem; Limousy, Lionel Chemical Engineering Journal, Vol. 347 https://doi.org/10.1016/j.cej.2018.04.063	journal	September 2018
Tuning secondary building unit of Cu-BTC to simultaneously enhance its CO2 selective adsorption and stability under moisture Wu, Yufang; Lv, Zhenqiang; Zhou, Xin Chemical Engineering Journal, Vol. 355 https://doi.org/10.1016/j.cej.2018.08.179	journal	January 2019
Use of zeolites for the removal of H 2 S: A mini-review Ozekmekci, Mehtap; Salkic, Gozde; Fellah, Mehmet Ferdi Fuel Processing Technology, Vol. 139 https://doi.org/10.1016/j.fuproc.2015.08.015	journal	November 2015
Melamine-promoted crystal growth of calcium oxalate monohydrate from calcium nitrate and oxalic acid Thanasekaran, Pounraj; Liu, Chih-Ming; Cho, Jhen-Fu Inorganic Chemistry Communications, Vol. 17 https://doi.org/10.1016/j.inoche.2011.12.020	journal	March 2012
Investigation of thermal degradation characteristics of polyamide-6 containing melamine or melamine cyanurate via direct pyrolysis mass spectrometry Isbasar, Ceyda; Hacaloglu, Jale Journal of Analytical and Applied Pyrolysis, Vol. 98 https://doi.org/10.1016/j.jaap.2012.09.002	journal	November 2012
Inelastic neutron scattering of H2 adsorbed in HKUST-1 Liu, Y.; Brown, C. M.; Neumann, D. A. Journal of Alloys and Compounds, Vol. 446-447 https://doi.org/10.1016/j.jallcom.2006.12.106	journal	October 2007
Electrochemical behavior of [Cu3(BTC)2] metal–organic framework: The effect of the method of synthesis Loera-Serna, Sandra; Oliver-Tolentino, Miguel A.; de Lourdes López-Núñez, Ma. Journal of Alloys and Compounds, Vol. 540 https://doi.org/10.1016/j.jallcom.2012.06.030	journal	November 2012
Engineering the surface of a new class of adsorbents: Metal–organic framework/graphite oxide composites Petit, Camille; Bandosz, Teresa J. Journal of Colloid and Interface Science, Vol. 447 https://doi.org/10.1016/j.jcis.2014.08.026	journal	June 2015
Adsorptive Performance of MOFs and MOF Containing Composites for Clean Energy and Safe Environment Emam, Hossam E.; Abdelhameed, Reda M.; Ahmed, Hanan B. Journal of Environmental Chemical Engineering, Vol. 8, Issue 5 https://doi.org/10.1016/j.jece.2020.104386	journal	October 2020
Thermal removal of nitrogen species from wood waste containing urea formaldehyde and melamine formaldehyde resins Girods, P.; Dufour, A.; Rogaume, Y. Journal of Hazardous Materials, Vol. 159, Issue 2-3 https://doi.org/10.1016/j.jhazmat.2008.02.003	journal	November 2008
Interactions of NO2 at ambient temperature with cerium–zirconium mixed oxides supported on SBA-15 Levasseur, Benoit; Ebrahim, Amani M.; Burress, Jacob Journal of Hazardous Materials, Vol. 197 https://doi.org/10.1016/j.jhazmat.2011.09.087	journal	December 2011
High-throughput screening of synthesis parameters in the formation of the metal-organic frameworks MOF-5 and HKUST-1 Biemmi, Enrica; Christian, Sandra; Stock, Norbert Microporous and Mesoporous Materials, Vol. 117, Issue 1-2 https://doi.org/10.1016/j.micromeso.2008.06.040	journal	January 2009
High pressure adsorption of hydrogen, nitrogen, carbon dioxide and methane on the metal–organic framework HKUST-1 Moellmer, J.; Moeller, A.; Dreisbach, F. Microporous and Mesoporous Materials, Vol. 138, Issue 1-3 https://doi.org/10.1016/j.micromeso.2010.09.013	journal	February 2011
H2S adsorption by Ag and Cu ion exchanged faujasites Kumar, Parveen; Sung, Chun-Yi; Muraza, Oki Microporous and Mesoporous Materials, Vol. 146, Issue 1-3 https://doi.org/10.1016/j.micromeso.2011.05.014	journal	December 2011
Reactive adsorption of acidic gases on MOF/graphite oxide composites Petit, Camille; Levasseur, Benoit; Mendoza, Barbara Microporous and Mesoporous Materials, Vol. 154 https://doi.org/10.1016/j.micromeso.2011.09.012	journal	May 2012
Formation of a nanohybrid composite between mesostructured cellular silica foam and microporous copper trimesate Seo, You-Kyong; Yoon, Ji Woong; Lee, U-Hwang Microporous and Mesoporous Materials, Vol. 155 https://doi.org/10.1016/j.micromeso.2011.12.053	journal	June 2012
The controlled regulation of morphology and size of HKUST-1 by “coordination modulation method” Wang, Fangli; Guo, Hailing; Chai, Yongming Microporous and Mesoporous Materials, Vol. 173 https://doi.org/10.1016/j.micromeso.2013.02.023	journal	June 2013
The influence of the pore size in Metal−Organic Frameworks in adsorption and separation of hydrogen sulphide: A molecular simulation study Al-Jadir, Thaer M.; Siperstein, Flor R. Microporous and Mesoporous Materials, Vol. 271 https://doi.org/10.1016/j.micromeso.2018.06.002	journal	November 2018
Upgrading of a chalcopyrite concentrate by reaction with copper(II) and sulfite – Unexpected formation of Chevreul’s salt, Cu2SO3·CuSO3·2H2O Fischmann, Adam J.; Dixon, David G. Minerals Engineering, Vol. 23, Issue 9 https://doi.org/10.1016/j.mineng.2010.05.007	journal	August 2010
Formation of nanoporous and non-porous organic–inorganic hybrid materials incorporating α-Keggin phosphotungstate anion: X-ray crystal structure of a 3D polymeric complex [{Na6(C9H5O6)3(H2O)15}{PW12O40}]∞ with a ‘Ball-in-Bowl’ type molecular structure Hundal, Geeta; Hwang, Young Kyu; Chang, Jong-San Polyhedron, Vol. 28, Issue 12 https://doi.org/10.1016/j.poly.2009.04.025	journal	August 2009
Molecular structure and vibrational spectra of melamine diborate by density functional theory and ab initio Hartree–Fock calculations Atalay, Yusuf; Avcı, Davut; Başoğlu, Adil Journal of Molecular Structure: THEOCHEM, Vol. 713, Issue 1-3 https://doi.org/10.1016/j.theochem.2004.09.044	journal	January 2005
Multivariate CuBTC Metal–Organic Framework with Enhanced Selectivity, Stability, Compatibility, and Processability Peterson, Gregory W.; Au, Kathleen; Tovar, Trenton M. Chemistry of Materials, Vol. 31, Issue 20 https://doi.org/10.1021/acs.chemmater.9b02756	journal	September 2019
Hydrogen Sulfide Capture: From Absorption in Polar Liquids to Oxide, Zeolite, and Metal–Organic Framework Adsorbents and Membranes Shah, Mansi S.; Tsapatsis, Michael; Siepmann, J. Ilja Chemical Reviews, Vol. 117, Issue 14 https://doi.org/10.1021/acs.chemrev.7b00095	journal	May 2017
Correction to Hydrogen Sulfide Capture: From Absorption in Polar Liquids to Oxide, Zeolite, and Metal–Organic Framework Adsorbents and Membranes Shah, Mansi S.; Tsapatsis, Michael; Siepmann, J. Ilja Chemical Reviews, Vol. 118, Issue 4 https://doi.org/10.1021/acs.chemrev.7b00768	journal	January 2018
Metal–Organic Frameworks against Toxic Chemicals Islamoglu, Timur; Chen, Zhijie; Wasson, Megan C. Chemical Reviews, Vol. 120, Issue 16 https://doi.org/10.1021/acs.chemrev.9b00828	journal	March 2020
Role of Amine Structure on Hydrogen Sulfide Capture from Dilute Gas Streams Using Solid Adsorbents Okonkwo, Claudia N.; Okolie, Chukwuemeka; Sujan, Achintya Energy & Fuels, Vol. 32, Issue 6 https://doi.org/10.1021/acs.energyfuels.8b00936	journal	May 2018
HONO Emissions from Western U.S. Wildfires Provide Dominant Radical Source in Fresh Wildfire Smoke Peng, Qiaoyun; Palm, Brett B.; Melander, Kira E. Environmental Science & Technology, Vol. 54, Issue 10 https://doi.org/10.1021/acs.est.0c00126	journal	April 2020
Distinct NO ₂ Effects on Cu-SSZ-13 and Cu-SSZ-39 in the Selective Catalytic Reduction of NO _x with NH ₃ Zhu, Na; Shan, Yulong; Shan, Wenpo Environmental Science & Technology, Vol. 54, Issue 23 https://doi.org/10.1021/acs.est.0c06256	journal	November 2020
Methyl-Shield Cu-BTC with High Water Stability through One-Step Synthesis and In Situ Functionalization Xu, Shanshan; Guo, Xiangyu; Qiao, Zhihua Industrial & Engineering Chemistry Research, Vol. 59, Issue 27 https://doi.org/10.1021/acs.iecr.0c02156	journal	June 2020
Adsorption of NO _x with NH ₃ on γ-Al ₂ O ₃ and Its Effects on the Adsorption of As ₂ O ₃ Based on DFT Hu, Pengbo; Wang, Shujuan; Zhuo, Yuqun Industrial & Engineering Chemistry Research, Vol. 60, Issue 6 https://doi.org/10.1021/acs.iecr.0c05856	journal	February 2021
Multifunctional Purification and Sensing of Toxic Hydride Gases by CuBTC Metal–Organic Framework Peterson, Gregory W.; Britt, David K.; Sun, Daniel T. Industrial & Engineering Chemistry Research, Vol. 54, Issue 14 https://doi.org/10.1021/acs.iecr.5b00458	journal	April 2015
Partial Oxidation of NO by H ₂ O ₂ and afterward Reduction by NH ₃ -Selective Catalytic Reduction: An Efficient Method for NO Removal Xue, Zongguo; Du, Xuesen; Rac, Vladislav Industrial & Engineering Chemistry Research, Vol. 59, Issue 20 https://doi.org/10.1021/acs.iecr.9b06896	journal	April 2020
Reaction of NO ₂ with Groups IV and VI Transition Metal Oxide Clusters Lee, Zachary R.; Flores, Luis A.; Copeland, William B. The Journal of Physical Chemistry A, Vol. 124, Issue 44 https://doi.org/10.1021/acs.jpca.0c06760	journal	October 2020
Computational Study of the Adsorption of NO ₂ on Monolayer MoS ₂ Bermudez, V. M. The Journal of Physical Chemistry C, Vol. 124, Issue 28 https://doi.org/10.1021/acs.jpcc.0c03786	journal	July 2020
Adsorption of NO ₂ and NO ₃ on Cobalt Spinel Nanocubes and Interfacial Dynamics of the Resultant NO _x Adspecies ( x = 1, 2, and 3): DFT, Atomistic Thermodynamic, IR, and Isotopic Exchange Study Zasada, Filip; Pinho, Pâmella Vasconcelos Borges; Piskorz, Witold The Journal of Physical Chemistry C, Vol. 124, Issue 36 https://doi.org/10.1021/acs.jpcc.0c06195	journal	July 2020
Magnetic Tunability in RE-DOBDC MOFs via NO _x Acid Gas Adsorption Henkelis, Susan E.; Huber, Dale L.; Vogel, Dayton J. ACS Applied Materials & Interfaces, Vol. 12, Issue 17 https://doi.org/10.1021/acsami.0c01813	journal	April 2020
Fiber-Based Gas Filter Assembled via In Situ Synthesis of ZIF-8 Metal Organic Frameworks for an Optimal Adsorption of SO ₂ : Experimental and Theoretical Approaches Lee, Jinwook; Lee, Kyeongeun; Kim, Jooyoun ACS Applied Materials & Interfaces, Vol. 13, Issue 1 https://doi.org/10.1021/acsami.0c19957	journal	January 2021
Zirconium and Aluminum MOFs for Low-Pressure SO ₂ Adsorption and Potential Separation: Elucidating the Effect of Small Pores and NH ₂ Groups Brandt, Philipp; Xing, Shang-Hua; Liang, Jun ACS Applied Materials & Interfaces, Vol. 13, Issue 24 https://doi.org/10.1021/acsami.1c06003	journal	June 2021
NO ₂ Removal under Ambient Conditions by Nanoporous Multivariate Zirconium-Based Metal–Organic Framework Wang, Xinbo; Xu, Zhenzhu; Li, Li ACS Applied Nano Materials, Vol. 3, Issue 11 https://doi.org/10.1021/acsanm.0c02533	journal	October 2020
A Complete Multisite Reaction Mechanism for Low-Temperature NH ₃ -SCR over Cu-CHA Chen, Lin; Janssens, Ton V. W.; Vennestrøm, Peter N. R. ACS Catalysis, Vol. 10, Issue 10 https://doi.org/10.1021/acscatal.0c00440	journal	April 2020
NO ₂ Removal by Adsorption on Transition-Metal-Based Layered Double Hydroxides Shang, Shanshan; Yang, Chao; Tian, Yuanmeng ACS ES&T Engineering, Vol. 1, Issue 3 https://doi.org/10.1021/acsestengg.0c00121	journal	December 2020
An Amidoxime-Functionalized Porous Reactive Fiber against Toxic Chemicals Jung, Dahee; Kirlikovali, Kent O.; Chen, Zhijie ACS Materials Letters, Vol. 3, Issue 4 https://doi.org/10.1021/acsmaterialslett.0c00598	journal	February 2021
Identifying Promising Covalent-Organic Frameworks for Decarburization and Desulfurization from Biogas via Computational Screening Wang, Ying; Wang, Guanyu; Liu, Yuan ACS Sustainable Chemistry & Engineering, Vol. 9, Issue 26 https://doi.org/10.1021/acssuschemeng.1c02696	journal	June 2021
Reactive Adsorption of NO ₂ on Copper-Based Metal−Organic Framework and Graphite Oxide/Metal−Organic Framework Composites Levasseur, Benoit; Petit, Camille; Bandosz, Teresa J. ACS Applied Materials & Interfaces, Vol. 2, Issue 12 https://doi.org/10.1021/am100790v	journal	November 2010
Template-Free Synthesis of Well-Defined Truncated Edge Polyhedral Cu ₂ O Architectures Sun, Shaodong; Zhou, Feiyu; Wang, Liqun Crystal Growth & Design, Vol. 10, Issue 2 https://doi.org/10.1021/cg900756u	journal	December 2009
Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering Cravillon, Janosch; Nayuk, Roman; Springer, Sergej Chemistry of Materials, Vol. 23, Issue 8 https://doi.org/10.1021/cm103571y	journal	April 2011
Sewage Sludge-Derived Materials as Efficient Adsorbents for Removal of Hydrogen Sulfide Bagreev, Andrey; Bashkova, Svetlana; Locke, David C. Environmental Science & Technology, Vol. 35, Issue 7 https://doi.org/10.1021/es001678h	journal	March 2001
Efficient Hydrogen Sulfide Adsorbents Obtained by Pyrolysis of Sewage Sludge Derived Fertilizer Modified with Spent Mineral Oil Bagreev, Andrey; Bandosz, Teresa J. Environmental Science & Technology, Vol. 38, Issue 1 https://doi.org/10.1021/es0303438	journal	November 2003
Adsorption of Hydrogen Sulfide onto Activated Carbon Fibers: Effect of Pore Structure and Surface Chemistry Feng, Wenguo; Kwon, Seokjoon; Borguet, Eric Environmental Science & Technology, Vol. 39, Issue 24 https://doi.org/10.1021/es0507158	journal	November 2005
Reactive Adsorption of NO ₂ at Dry Conditions on Sewage Sludge-Derived Materials Pietrzak, Robert; Bandosz, Teresa J. Environmental Science & Technology, Vol. 41, Issue 21 https://doi.org/10.1021/es071863w	journal	October 2007
Chemisorption and decomposition of hydrogen sulfide on rhodium(100) Hegde, R. I.; White, J. M. The Journal of Physical Chemistry, Vol. 90, Issue 2 https://doi.org/10.1021/j100274a019	journal	January 1986
Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room Temperature Millward, Andrew R.; Yaghi, Omar M. Journal of the American Chemical Society, Vol. 127, Issue 51, p. 17998-17999 https://doi.org/10.1021/ja0570032	journal	December 2005
Oriented Growth of the Metal Organic Framework Cu ₃ (BTC) ₂ (H ₂ O) ₃ · x H ₂ O Tunable with Functionalized Self-Assembled Monolayers Biemmi, Enrica; Scherb, Camilla; Bein, Thomas Journal of the American Chemical Society, Vol. 129, Issue 26 https://doi.org/10.1021/ja0701208	journal	July 2007
Thermal Decomposition of Metal Nitrates in Air and Hydrogen Environments Yuvaraj, Shanmugam; Fan-Yuan, Lin; Tsong-Huei, Chang The Journal of Physical Chemistry B, Vol. 107, Issue 4 https://doi.org/10.1021/jp026961c	journal	January 2003
Insights into Adsorption of NH ₃ on HKUST-1 Metal–Organic Framework: A Multitechnique Approach Borfecchia, Elisa; Maurelli, Sara; Gianolio, Diego The Journal of Physical Chemistry C, Vol. 116, Issue 37 https://doi.org/10.1021/jp305756k	journal	September 2012
Adsorption and Separation of Xylene Isomers: CPO-27-Ni vs HKUST-1 vs NaY Peralta, David; Barthelet, Karin; Pérez-Pellitero, Javier The Journal of Physical Chemistry C, Vol. 116, Issue 41 https://doi.org/10.1021/jp306828x	journal	October 2012
Investigation on Hydrogenation of Metal–Organic Frameworks HKUST-1, MIL-53, and ZIF-8 by Hydrogen Spillover Chen, Hao; Wang, Lifeng; Yang, Jun The Journal of Physical Chemistry C, Vol. 117, Issue 15 https://doi.org/10.1021/jp401367k	journal	April 2013
Reactive Adsorption of Ammonia on Cu-Based MOF/Graphene Composites Petit, Camille; Mendoza, Barbara; Bandosz, Teresa J. Langmuir, Vol. 26, Issue 19 https://doi.org/10.1021/la1021092	journal	October 2010
CO ₂ /H ₂ O Adsorption Equilibrium and Rates on Metal−Organic Frameworks: HKUST-1 and Ni/DOBDC Liu, Jian; Wang, Yu; Benin, Annabelle I. Langmuir, Vol. 26, Issue 17 https://doi.org/10.1021/la102359q	journal	September 2010
Toward Understanding Reactive Adsorption of Ammonia on Cu-MOF/Graphite Oxide Nanocomposites Petit, Camille; Huang, Liangliang; Jagiello, Jacek Langmuir, Vol. 27, Issue 21 https://doi.org/10.1021/la202924y	journal	November 2011
Nanoscale Shape and Size Control of Cubic, Cuboctahedral, and Octahedral Cu−Cu ₂ O Core−Shell Nanoparticles on Si(100) by One-Step, Templateless, Capping-Agent-Free Electrodeposition Radi, Abdullah; Pradhan, Debabrata; Sohn, Youngku ACS Nano, Vol. 4, Issue 3 https://doi.org/10.1021/nn100023h	journal	February 2010
Enhanced reactive adsorption of H ₂ S on Cu–BTC/ S- and N-doped GO composites Ebrahim, Amani M.; Jagiello, Jacek; Bandosz, Teresa J. Journal of Materials Chemistry A, Vol. 3, Issue 15 https://doi.org/10.1039/C5TA01359C	journal	January 2015
Simultaneous electrosynthesis of Cu–BTC and Zn–BTC metal–organic frameworks on brass Jabarian, Sedigheh; Ghaffarinejad, Ali New Journal of Chemistry, Vol. 44, Issue 45 https://doi.org/10.1039/D0NJ04303F	journal	January 2020
Capture of toxic gases in MOFs: SO ₂ , H ₂ S, NH ₃ and NO _x Martínez-Ahumada, Eva; Díaz-Ramírez, Mariana L.; Velásquez-Hernández, Miriam de J. Chemical Science, Vol. 12, Issue 20 https://doi.org/10.1039/D1SC01609A	journal	January 2021
MOF–graphite oxide nanocomposites: surface characterization and evaluation as adsorbents of ammonia Petit, Camille; Bandosz, Teresa J. Journal of Materials Chemistry, Vol. 19, Issue 36 https://doi.org/10.1039/b908862h	journal	January 2009
Exploring the coordination chemistry of MOF–graphite oxide composites and their applications as adsorbents Petit, Camille; Bandosz, Teresa J. Dalton Transactions, Vol. 41, Issue 14 https://doi.org/10.1039/c2dt12017h	journal	January 2012
The effect of water adsorption on the structure of the carboxylate containing metal–organic frameworks Cu-BTC, Mg-MOF-74, and UiO-66 DeCoste, Jared B.; Peterson, Gregory W.; Schindler, Bryan J. Journal of Materials Chemistry A, Vol. 1, Issue 38 https://doi.org/10.1039/c3ta12497e	journal	January 2013
Chemical Adsorption of Nitrogen Dioxide with an Activated Carbon Adsorption System Fang, Mei-Ling; Chang, Hsiao-Yu; Chen, Chih-Hsiang Aerosol and Air Quality Research, Vol. 19, Issue 11 https://doi.org/10.4209/aaqr.2019.09.0439	journal	January 2019

Similar Records

Atomically detailed models of gas mixture diffusion through CuBTC membranes

Journal Article · 2009 · MICROPOROUS AND MESOPOROUS MATERIALS · OSTI ID:1012961

S, Keskin; JC, Liu; Johnson, JK

Role of Amine Structure on Hydrogen Sulfide Capture from Dilute Gas Streams Using Solid Adsorbents

Journal Article · 2018 · Energy and Fuels · OSTI ID:1470627

Okonkwo, Claudia N.; Okolie, Chukwuemeka; Sujan, Achintya; +2 more

Phenanthroline-based metal–organic frameworks for Fe-catalyzed C _sp3 –H amination

Journal Article · 2017 · Faraday Discussions · OSTI ID:1393654

Thacker, Nathan C.; Ji, Pengfei; Lin, Zekai; +2 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
CuBTC
amines
metal organic framework
surface reactivity
toxic gas removal

Title: Effect of amine type on acidic toxic gas adsorption at ambient conditions on modified CuBTC

Citation Formats

References (83)

Similar Records

Related Subjects