Slow Auger Recombination of Trapped Excitons Enables Efficient Multiple Electron Transfer in CdS–Pt Nanorod Heterostructures

Liu, Yawei; Cullen, David A.; Lian, Tianquan

doi:10.1021/jacs.1c09125

Title: Slow Auger Recombination of Trapped Excitons Enables Efficient Multiple Electron Transfer in CdS–Pt Nanorod Heterostructures

Journal Article · 18 November 2021 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.1c09125 · OSTI ID:1871108

Liu, Yawei ^[1];

^[2];

^[1]

Emory Univ., Atlanta, GA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

We report solar-to-fuel conversion reaction often requires multiple proton-coupled electron transfer (PCET) processes powered by the energetic electrons and/or holes generated by the absorption of multiple photons. The effective coupling of multiple electron transfer from the light absorber with the multiple PCET reactions at the catalytic center is one of the key challenges in efficient and selective conversion of solar energy to chemical fuels. In this paper, we examine the dynamics of multiple electron transfer in quantum confined CdS nanorods with a Pt tip, in which the CdS rod functions as the light absorber and the Pt tip the catalytic center. By excitation-fluence-dependent transient absorption spectroscopic measurements, we show that the multiexciton Auger recombination rate in CdS rods follows a carrier-collision model, k_n^A = n²(n – 1)/4k₂^A, with a biexciton lifetime (1/k₂^A) of 2.0 ± 0.2 ns. In CdS–Pt nanorods, electron transfer kinetics from the CdS conduction band edge to the Pt show negligible dependence on the excitation fluence, occurring with a half-life time of 5.6 ± 0.6 ps. The efficiency of multiple exciton dissociation by multiple electron transfer to Pt decreases from 100% in biexciton states to ~41% at 22 exciton state due to the competition with Auger recombination. The half-lifetime of the n-charge separated state recombination (with n electrons in the Pt and n holes in the CdS) decreases from 10 μs in the single charge separated state to 42 ns in nine charge separated states. Our findings suggest the possibility of driving multielectron photocatalytic reactions under intense illumination and controlling product selectivity through multielectron transfer.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; SC0008798

OSTI ID:: 1871108

Journal Information:: Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 48 Vol. 143; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (74)

Electrochemical nitrogen fixation and utilization: theories, advanced catalyst materials and system design Guo, Wenhan; Zhang, Kexin; Liang, Zibin Chemical Society Reviews, Vol. 48, Issue 24 https://doi.org/10.1039/C9CS00159J	journal	January 2019
Size and Structure Matter: Enhanced CO ₂ Photoreduction Efficiency by Size-Resolved Ultrafine Pt Nanoparticles on TiO ₂ Single Crystals Wang, Wei-Ning; An, Woo-Jin; Ramalingam, Balavinayagam Journal of the American Chemical Society, Vol. 134, Issue 27 https://doi.org/10.1021/ja304075b	journal	June 2012
Mechanism of Efficient Viologen Radical Generation by Ultrafast Electron Transfer from CdS Quantum Dots Zhao, Fengjiao; Li, Qiuyang; Han, Keli The Journal of Physical Chemistry C, Vol. 122, Issue 30 https://doi.org/10.1021/acs.jpcc.8b06551	journal	March 2018
1D Exciton Spectroscopy of Semiconductor Nanorods Shabaev, A.; Efros, Al. L. Nano Letters, Vol. 4, Issue 10 https://doi.org/10.1021/nl049216f	journal	October 2004
CO ₂ photo-reduction: insights into CO ₂ activation and reaction on surfaces of photocatalysts Chang, Xiaoxia; Wang, Tuo; Gong, Jinlong Energy & Environmental Science, Vol. 9, Issue 7 https://doi.org/10.1039/C6EE00383D	journal	January 2016
Observing the Multiexciton State in Singlet Fission and Ensuing Ultrafast Multielectron Transfer Chan, W. -L.; Ligges, M.; Jailaubekov, A. Science, Vol. 334, Issue 6062 https://doi.org/10.1126/science.1213986	journal	December 2011
Two-Dimensional Morphology Enhances Light-Driven H ₂ Generation Efficiency in CdS Nanoplatelet-Pt Heterostructures Li, Qiuyang; Zhao, Fengjiao; Qu, Chen Journal of the American Chemical Society, Vol. 140, Issue 37 https://doi.org/10.1021/jacs.8b06100	journal	August 2018
Proton-Coupled Electron Transfer Cleavage of Heavy-Atom Bonds in Electrocatalytic Processes. Cleavage of a C–O Bond in the Catalyzed Electrochemical Reduction of CO ₂ Costentin, Cyrille; Drouet, Samuel; Passard, Guillaume Journal of the American Chemical Society, Vol. 135, Issue 24 https://doi.org/10.1021/ja4030148	journal	June 2013
Exciton Localization and Dissociation Dynamics in CdS and CdS–Pt Quantum Confined Nanorods: Effect of Nonuniform Rod Diameters Wu, Kaifeng; Rodríguez-Córdoba, William; Lian, Tianquan The Journal of Physical Chemistry B, Vol. 118, Issue 49 https://doi.org/10.1021/jp504703t	journal	July 2014
Photodriven Charge Separation Dynamics in CdSe/ZnS Core/Shell Quantum Dot/Cobaloxime Hybrid for Efficient Hydrogen Production Huang, Jier; Mulfort, Karen L.; Du, Pingwu Journal of the American Chemical Society, Vol. 134, Issue 40 https://doi.org/10.1021/ja3062584	journal	September 2012
Multicarrier Interactions in Semiconductor Nanocrystals in Relation to the Phenomena of Auger Recombination and Carrier Multiplication Klimov, Victor I. Annual Review of Condensed Matter Physics, Vol. 5, Issue 1 https://doi.org/10.1146/annurev-conmatphys-031113-133900	journal	March 2014
Exciton dissociation dynamics and light-driven H2 generation in colloidal 2D cadmium chalcogenide nanoplatelet heterostructures Li, Qiuyang; Lian, Tianquan Nano Research, Vol. 11, Issue 6 https://doi.org/10.1007/s12274-018-2024-x	journal	May 2018
Superposition Principle in Auger Recombination of Charged and Neutral Multicarrier States in Semiconductor Quantum Dots Wu, Kaifeng; Lim, Jaehoon; Klimov, Victor I. ACS Nano, Vol. 11, Issue 8 https://doi.org/10.1021/acsnano.7b04079	journal	August 2017
Picosecond Quantum Cutting Generates Photoluminescence Quantum Yields Over 100% in Ytterbium-Doped CsPbCl ₃ Nanocrystals Milstein, Tyler J.; Kroupa, Daniel M.; Gamelin, Daniel R. Nano Letters, Vol. 18, Issue 6 https://doi.org/10.1021/acs.nanolett.8b01066	journal	May 2018
Electron Transfer and Fluorescence Quenching of Nanoparticle Assemblies Wu, Mingyan; Mukherjee, Prasun; Lamont, Daniel N. The Journal of Physical Chemistry C, Vol. 114, Issue 13 https://doi.org/10.1021/jp9098667	journal	March 2010
Carbon Dioxide Dimer Radical Anion as Surface Intermediate of Photoinduced CO ₂ Reduction at Aqueous Cu and CdSe Nanoparticle Catalysts by Rapid-Scan FT-IR Spectroscopy Sheng, Hua; Oh, Myoung Hwan; Osowiecki, Wojciech T. Journal of the American Chemical Society, Vol. 140, Issue 12 https://doi.org/10.1021/jacs.8b00271	journal	February 2018
The Electronic Structure of Semiconductor Nanocrystals Efros, Al. L.; Rosen, M. Annual Review of Materials Science, Vol. 30, Issue 1 https://doi.org/10.1146/annurev.matsci.30.1.475	journal	August 2000
Robust Photogeneration of H2 in Water Using Semiconductor Nanocrystals and a Nickel Catalyst Han, Z.; Qiu, F.; Eisenberg, R. Science, Vol. 338, Issue 6112 https://doi.org/10.1126/science.1227775	journal	November 2012
A Review of Electrocatalytic Reduction of Dinitrogen to Ammonia under Ambient Conditions Cui, Xiaoyang; Tang, Cheng; Zhang, Qiang Advanced Energy Materials, Vol. 8, Issue 22 https://doi.org/10.1002/aenm.201800369	journal	May 2018
Optimal metal domain size for photocatalysis with hybrid semiconductor-metal nanorods Ben-Shahar, Yuval; Scotognella, Francesco; Kriegel, Ilka Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10413	journal	January 2016
Coulomb Barrier for Sequential Two-Electron Transfer in a Nanoengineered Photocatalyst Wang, Junhui; Ding, Tao; Wu, Kaifeng Journal of the American Chemical Society, Vol. 142, Issue 32 https://doi.org/10.1021/jacs.0c06256	journal	July 2020
Noncovalent Control of the Electrostatic Potential of Quantum Dots through the Formation of Interfacial Ion Pairs He, Chen; Nguyen, Trung D.; Edme, Kedy Journal of the American Chemical Society, Vol. 139, Issue 29 https://doi.org/10.1021/jacs.7b05501	journal	July 2017
Multiple Exciton Generation in Colloidal Silicon Nanocrystals Beard, Matthew C.; Knutsen, Kelly P.; Yu, Pingrong Nano Letters, Vol. 7, Issue 8 https://doi.org/10.1021/nl071486l	journal	August 2007
Wave Function Engineering for Efficient Extraction of up to Nineteen Electrons from One CdSe/CdS Quasi-Type II Quantum Dot Zhu, Haiming; Song, Nianhui; Rodríguez-Córdoba, William Journal of the American Chemical Society, Vol. 134, Issue 9 https://doi.org/10.1021/ja210312s	journal	February 2012
Electrochemical Photolysis of Water at a Semiconductor Electrode Fujishima, Akira; Honda, Kenichi Nature, Vol. 238, Issue 5358, p. 37-38 https://doi.org/10.1038/238037a0	journal	July 1972
Energy transfer-enhanced photocatalytic reduction of protons within quantum dot light-harvesting–catalyst assemblies Kodaimati, Mohamad S.; Lian, Shichen; Schatz, George C. Proceedings of the National Academy of Sciences, Vol. 115, Issue 33 https://doi.org/10.1073/pnas.1805625115	journal	August 2018
Area- and Thickness-Dependent Biexciton Auger Recombination in Colloidal CdSe Nanoplatelets: Breaking the “Universal Volume Scaling Law” Li, Qiuyang; Lian, Tianquan Nano Letters, Vol. 17, Issue 5 https://doi.org/10.1021/acs.nanolett.7b00587	journal	April 2017
Balancing electron transfer rate and driving force for efficient photocatalytic hydrogen production in CdSe/CdS nanorod–[NiFe] hydrogenase assemblies Chica, Bryant; Wu, Chang-Hao; Liu, Yuhgene Energy & Environmental Science, Vol. 10, Issue 10 https://doi.org/10.1039/C7EE01738C	journal	January 2017
Size Matters: Cocatalyst Size Effect on Charge Transfer and Photocatalytic Activity Nakibli, Yifat; Mazal, Yair; Dubi, Yonatan Nano Letters, Vol. 18, Issue 1 https://doi.org/10.1021/acs.nanolett.7b04210	journal	December 2017
Multiple exciton generation in semiconductor quantum dots Nozik, Arthur J. Chemical Physics Letters, Vol. 457, Issue 1-3, p. 3-11 https://doi.org/10.1016/j.cplett.2008.03.094	journal	May 2008
Perfect Photon-to-Hydrogen Conversion Efficiency Kalisman, Philip; Nakibli, Yifat; Amirav, Lilac Nano Letters, Vol. 16, Issue 3 https://doi.org/10.1021/acs.nanolett.5b04813	journal	February 2016
Oxygen-Tolerant H ₂ Production by [FeFe]-H ₂ ase Active Site Mimics Aided by Second Sphere Proton Shuttle Ahmed, Md Estak; Dey, Subal; Darensbourg, Marcetta Y. Journal of the American Chemical Society, Vol. 140, Issue 39 https://doi.org/10.1021/jacs.8b05983	journal	September 2018
Semiconductor Clusters, Nanocrystals, and Quantum Dots Alivisatos, A. P. Science, Vol. 271, Issue 5251, p. 933-937 https://doi.org/10.1126/science.271.5251.933	journal	February 1996
Excitation-Rate Determines Product Stoichiometry in Photochemical Ammonia Production by CdS Quantum Dot-Nitrogenase MoFe Protein Complexes Brown, Katherine A.; Ruzicka, Jesse; Kallas, Hayden ACS Catalysis, Vol. 10, Issue 19 https://doi.org/10.1021/acscatal.0c02933	journal	September 2020
Catalytic Proton Coupled Electron Transfer from Metal Hydrides to Titanocene Amides, Hydrazides and Imides: Determination of Thermodynamic Parameters Relevant to Nitrogen Fixation Pappas, Iraklis; Chirik, Paul J. Journal of the American Chemical Society, Vol. 138, Issue 40 https://doi.org/10.1021/jacs.6b08009	journal	September 2016
Observation of trapped-hole diffusion on the surfaces of CdS nanorods Utterback, James K.; Grennell, Amanda N.; Wilker, Molly B. Nature Chemistry, Vol. 8, Issue 11 https://doi.org/10.1038/nchem.2566	journal	July 2016
Quantization of Multiparticle Auger Rates in Semiconductor Quantum Dots Klimov, V. I. Science, Vol. 287, Issue 5455 https://doi.org/10.1126/science.287.5455.1011	journal	February 2000
Electron Transfer into Electron-Accumulated Nanocrystals: Mimicking Intermediate Events in Multielectron Photocatalysis II Wang, Junhui; Ding, Tao; Wu, Kaifeng Journal of the American Chemical Society, Vol. 140, Issue 32 https://doi.org/10.1021/jacs.8b05942	journal	July 2018
The Unusual Mechanism of Partial Fermi Level Pinning at Metal–MoS ₂ Interfaces Gong, Cheng; Colombo, Luigi; Wallace, Robert M. Nano Letters, Vol. 14, Issue 4 https://doi.org/10.1021/nl403465v	journal	March 2014
Photocatalytic Hydrogen Production with Tunable Nanorod Heterostructures Amirav, Lilac; Alivisatos, A. Paul The Journal of Physical Chemistry Letters, Vol. 1, Issue 7 https://doi.org/10.1021/jz100075c	journal	March 2010
Solar Hydrogen Production Using Carbon Quantum Dots and a Molecular Nickel Catalyst Martindale, Benjamin C. M.; Hutton, Georgina A. M.; Caputo, Christine A. Journal of the American Chemical Society, Vol. 137, Issue 18 https://doi.org/10.1021/jacs.5b01650	journal	April 2015
Uncovering the Role of Hole Traps in Promoting Hole Transfer from Multiexcitonic Quantum Dots to Molecular Acceptors Yan, Chang; Weinberg, Daniel; Jasrasaria, Dipti ACS Nano, Vol. 15, Issue 2 https://doi.org/10.1021/acsnano.0c08158	journal	December 2020
Quantum confined colloidal nanorod heterostructures for solar-to-fuel conversion Wu, Kaifeng; Lian, Tianquan Chemical Society Reviews, Vol. 45, Issue 14 https://doi.org/10.1039/C5CS00472A	journal	January 2016
Defining Intermediates of Nitrogenase MoFe Protein during N ₂ Reduction under Photochemical Electron Delivery from CdS Quantum Dots Chica, Bryant; Ruzicka, Jesse; Kallas, Hayden Journal of the American Chemical Society, Vol. 142, Issue 33 https://doi.org/10.1021/jacs.0c06343	journal	July 2020
Redox shuttle mechanism enhances photocatalytic H2 generation on Ni-decorated CdS nanorods Simon, Thomas; Bouchonville, Nicolas; Berr, Maximilian J. Nature Materials, Vol. 13, Issue 11 https://doi.org/10.1038/nmat4049	journal	August 2014
Multiple Exciton Collection in a Sensitized Photovoltaic System Sambur, J. B.; Novet, T.; Parkinson, B. A. Science, Vol. 330, Issue 6000 https://doi.org/10.1126/science.1191462	journal	September 2010
Proton-Coupled Electron Transfer Huynh, My Hang V.; Meyer, Thomas J. Chemical Reviews, Vol. 107, Issue 11 https://doi.org/10.1021/cr0500030	journal	November 2007
Multiple Exciton Generation in Semiconductor Quantum Dots Beard, Matthew C. The Journal of Physical Chemistry Letters, Vol. 2, Issue 11 https://doi.org/10.1021/jz200166y	journal	May 2011
Towards artificial photosynthesis: ruthenium–manganese chemistry for energy production Sun, Licheng; Hammarström, Leif; Åkermark, Björn Chemical Society Reviews, Vol. 30, Issue 1 https://doi.org/10.1039/a801490f	journal	January 2001
On the Nature of Trapped-Hole States in CdS Nanocrystals and the Mechanism of Their Diffusion Cline, R. Peyton; Utterback, James K.; Strong, Steven E. The Journal of Physical Chemistry Letters, Vol. 9, Issue 12 https://doi.org/10.1021/acs.jpclett.8b01148	journal	June 2018
Photoinduced Electron Transfer Coupled to Donor Deprotonation and Acceptor Protonation in a Molecular Triad Mimicking Photosystem II Pannwitz, Andrea; Wenger, Oliver S. Journal of the American Chemical Society, Vol. 139, Issue 38 https://doi.org/10.1021/jacs.7b08761	journal	September 2017
Hole Removal Rate Limits Photodriven H ₂ Generation Efficiency in CdS-Pt and CdSe/CdS-Pt Semiconductor Nanorod–Metal Tip Heterostructures Wu, Kaifeng; Chen, Zheyuan; Lv, Hongjin Journal of the American Chemical Society, Vol. 136, Issue 21 https://doi.org/10.1021/ja5023893	journal	May 2014
Absorption Spectrum and Some Chemical Reactions of Colloidal Platinum in Aqueous Solution Henglein, A.; Ershov, B. G.; Malow, M. The Journal of Physical Chemistry, Vol. 99, Issue 38 https://doi.org/10.1021/j100038a053	journal	September 1995
Selective Photocatalytic CO ₂ Reduction in Water through Anchoring of a Molecular Ni Catalyst on CdS Nanocrystals Kuehnel, Moritz F.; Orchard, Katherine L.; Dalle, Kristian E. Journal of the American Chemical Society, Vol. 139, Issue 21 https://doi.org/10.1021/jacs.7b00369	journal	May 2017
Ultrafast Photoinduced Interfacial Proton Coupled Electron Transfer from CdSe Quantum Dots to 4,4′-Bipyridine Chen, Jinquan; Wu, Kaifeng; Rudshteyn, Benjamin Journal of the American Chemical Society, Vol. 138, Issue 3 https://doi.org/10.1021/jacs.5b10354	journal	January 2016
CdSe quantum dots/molecular cobalt catalyst co-grafted open porous NiO film as a photocathode for visible light driven H ₂ evolution from neutral water Meng, Peng; Wang, Mei; Yang, Yong Journal of Materials Chemistry A, Vol. 3, Issue 37 https://doi.org/10.1039/C5TA06255A	journal	January 2015
Controlling the Electron-Transfer Kinetics of Quantum-Dot Assemblies Liu, Ruibin; Bloom, Brian P.; Waldeck, David H. The Journal of Physical Chemistry C, Vol. 121, Issue 27 https://doi.org/10.1021/acs.jpcc.7b02261	journal	June 2017
Charge Transfer Dynamics from Photoexcited Semiconductor Quantum Dots Zhu, Haiming; Yang, Ye; Wu, Kaifeng Annual Review of Physical Chemistry, Vol. 67, Issue 1 https://doi.org/10.1146/annurev-physchem-040215-112128	journal	May 2016
Selective Placement of Faceted Metal Tips on Semiconductor Nanorods Schlicke, Hendrik; Ghosh, Debraj; Fong, Lam-Kiu Angewandte Chemie International Edition, Vol. 52, Issue 3 https://doi.org/10.1002/anie.201205958	journal	November 2012
Enhanced Multiple Exciton Dissociation from CdSe Quantum Rods: The Effect of Nanocrystal Shape Zhu, Haiming; Lian, Tianquan Journal of the American Chemical Society, Vol. 134, Issue 27 https://doi.org/10.1021/ja304724u	journal	June 2012
Space-separated quantum cutting with silicon nanocrystals for photovoltaic applications Timmerman, D.; Izeddin, I.; Stallinga, P. Nature Photonics, Vol. 2, Issue 2 https://doi.org/10.1038/nphoton.2007.279	journal	January 2008
Ultrafast Exciton Dynamics and Light-Driven H ₂ Evolution in Colloidal Semiconductor Nanorods and Pt-Tipped Nanorods Wu, Kaifeng; Zhu, Haiming; Lian, Tianquan Accounts of Chemical Research, Vol. 48, Issue 3 https://doi.org/10.1021/ar500398g	journal	February 2015
Ultrafast Charge Separation and Long-Lived Charge Separated State in Photocatalytic CdS–Pt Nanorod Heterostructures Wu, Kaifeng; Zhu, Haiming; Liu, Zheng Journal of the American Chemical Society, Vol. 134, Issue 25 https://doi.org/10.1021/ja303306u	journal	June 2012
Charge Transfer from n -Doped Nanocrystals: Mimicking Intermediate Events in Multielectron Photocatalysis Wang, Junhui; Ding, Tao; Wu, Kaifeng Journal of the American Chemical Society, Vol. 140, Issue 25 https://doi.org/10.1021/jacs.8b04263	journal	May 2018
Hole scavenger redox potentials determine quantum efficiency and stability of Pt-decorated CdS nanorods for photocatalytic hydrogen generation Berr, Maximilian J.; Wagner, Peter; Fischbach, Stefan Applied Physics Letters, Vol. 100, Issue 22 https://doi.org/10.1063/1.4723575	journal	May 2012
Selective Growth of Metal and Binary Metal Tips on CdS Nanorods Habas, Susan E.; Yang, Peidong; Mokari, Taleb Journal of the American Chemical Society, Vol. 130, Issue 11 https://doi.org/10.1021/ja800104w	journal	March 2008
Effect of Zero- to One-Dimensional Transformation on Multiparticle Auger Recombination in Semiconductor Quantum Rods Htoon, H.; Hollingsworth, J. A.; Dickerson, R. Physical Review Letters, Vol. 91, Issue 22 https://doi.org/10.1103/PhysRevLett.91.227401	journal	November 2003
Exploiting Potential Inversion for Photoinduced Multielectron Transfer and Accumulation of Redox Equivalents in a Molecular Heptad Nomrowski, Julia; Wenger, Oliver S. Journal of the American Chemical Society, Vol. 140, Issue 16 https://doi.org/10.1021/jacs.8b02443	journal	April 2018
Simultaneous Determination of Spectral Signatures and Decay Kinetics of Excited State Species in Semiconductor Nanocrystals Probed by Transient Absorption Spectroscopy Labrador, Tais; Dukovic, Gordana The Journal of Physical Chemistry C, Vol. 124, Issue 15 https://doi.org/10.1021/acs.jpcc.0c01701	journal	March 2020
Cocatalysts for Selective Photoreduction of CO ₂ into Solar Fuels Li, Xin; Yu, Jiaguo; Jaroniec, Mietek Chemical Reviews, Vol. 119, Issue 6 https://doi.org/10.1021/acs.chemrev.8b00400	journal	January 2019
Cyborgian Material Design for Solar Fuel Production: The Emerging Photosynthetic Biohybrid Systems Sakimoto, Kelsey K.; Kornienko, Nikolay; Yang, Peidong Accounts of Chemical Research, Vol. 50, Issue 3 https://doi.org/10.1021/acs.accounts.6b00483	journal	March 2017
Light-driven dinitrogen reduction catalyzed by a CdS:nitrogenase MoFe protein biohybrid Brown, K. A.; Harris, D. F.; Wilker, M. B. Science, Vol. 352, Issue 6284 https://doi.org/10.1126/science.aaf2091	journal	April 2016
Charge Carrier Dynamics in Photocatalytic Hybrid Semiconductor–Metal Nanorods: Crossover from Auger Recombination to Charge Transfer Ben-Shahar, Yuval; Philbin, John P.; Scotognella, Francesco Nano Letters, Vol. 18, Issue 8 https://doi.org/10.1021/acs.nanolett.8b02169	journal	July 2018
Colloidal Dual-Diameter and Core-Position-Controlled Core/Shell Cadmium Chalcogenide Nanorods Kim, Dahin; Lee, Young Kuk; Lee, Dongkyu ACS Nano, Vol. 11, Issue 12 https://doi.org/10.1021/acsnano.7b06542	journal	November 2017

Similar Records

Uncovering the Role of Hole Traps in Promoting Hole Transfer from Multiexcitonic Quantum Dots to Molecular Acceptors

Journal Article · 2020 · ACS Nano · OSTI ID:1844520

Yan, Chang; Weinberg, Daniel; Jasrasaria, Dipti; +8 more

Low-threshold laser medium utilizing semiconductor nanoshell quantum dots

Journal Article · 2020 · Nanoscale · OSTI ID:1756891

Porotnikov, Dmitry; Diroll, Benjamin T.; Harankahage, Dulanjan; +9 more

Suppression of auger recombination in ""giant"" core/shell nanocrystals

Journal Article · 2009 · Science · OSTI ID:956462

Garcia Santamaria, Florencio; Vela, Javier; Schaller, Richard D; +3 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
multiple electron transfer
multiple charge recombination
proton-coupled electron transfer
solar fuels
CdS nanorods
CdS-Pt nanorods
photocatalysis

Title: Slow Auger Recombination of Trapped Excitons Enables Efficient Multiple Electron Transfer in CdS–Pt Nanorod Heterostructures

Citation Formats

References (74)

Similar Records

Related Subjects