Membrane design for non-aqueous redox flow batteries: Current status and path forward

Lehmann, Michelle L.; Tyler, Landon; Self, Ethan C.; Yang, Guang; Nanda, Jagjit; Saito, Tomonori

doi:10.1016/j.chempr.2022.04.005

Title: Membrane design for non-aqueous redox flow batteries: Current status and path forward

Journal Article · 28 April 2022 · Chem

DOI: https://doi.org/10.1016/j.chempr.2022.04.005 · OSTI ID:1870254

Lehmann, Michelle L. ^[1]; Tyler, Landon ^[1];

^[2];

^[3];

^[2]

Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)

Redox flow batteries are promising technologies for large-scale, long-duration energy storage applications. Among them, non-aqueous redox flow batteries (NARFB) represent a transformative flow battery system since NARFBs potentially offer a higher energy density than aqueous flow batteries. However, many technical challenges remain for NARFBs, including the lack of high-performance membranes, low solubility of redox materials, and poor cycling efficiencies. Membranes serve a vital function in NARFBs, as they allow for selective ion transport while providing separation between the anolyte and catholyte. NARFB membrane development is an emerging research area, and this article reviews their design and critical factors that influence membrane properties, including solvent uptake, ion transport, and redox species permeability. A greater understanding of membrane behavior in non-aqueous solutions provides design principles for developing next-generation membranes for NARFB. In conclusion, we summarize the challenges, target metrics, and future perspectives for NARFBs.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Electricity (OE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1870254

Journal Information:: Chem, Journal Name: Chem Journal Issue: 6 Vol. 8; ISSN 2451-9294

Publisher:: Cell PressCopyright Statement

Country of Publication:: United States

Language:: English

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