MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

Liu, Jian; Goetjen, Timothy A.; Wang, Qining; Knapp, Julia G.; Wasson, Megan C.; Yang, Ying; Syed, Zoha H.; Delferro, Massimiliano; Notestein, Justin M.; Farha, Omar K.; Hupp, Joseph T.

doi:10.1039/d1cs00968k

Title: MOF-enabled confinement and related effects for chemical catalyst presentation and utilization

Journal Article · 10 January 2022 · Chemical Society Reviews

DOI: https://doi.org/10.1039/d1cs00968k · OSTI ID:1869967

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Northwestern Univ., Evanston, IL (United States)
Northwestern Univ., Evanston, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

A defining characteristic of nearly all catalytically functional MOFs is uniform, molecular-scale porosity. MOF pores, linkers and nodes that define them, help regulate reactant and product transport, catalyst siting, catalyst accessibility, catalyst stability, catalyst activity, co-catalyst proximity, composition of the chemical environment at and beyond the catalytic active site, chemical intermediate and transition-state conformations, thermodynamic affinity of molecular guests for MOF interior sites, framework charge and density of charge-compensating ions, pore hydrophobicity/hydrophilicity, pore and channel rigidity vs. flexibility, and other features and properties. Collectively and individually, these properties help define overall catalyst functional behaviour. Here, this review focuses on how porous, catalyst-containing MOFs capitalize on molecular-scale confinement, containment, isolation, environment modulation, energy delivery, and mobility to accomplish desired chemical transformations with potentially superior selectivity or other efficacy, especially in comparison to catalysts in homogeneous solution environments.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Defense Threat Reduction Agency (DTRA); National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357; SC0012702; FG02-87ER13808

OSTI ID:: 1869967

Journal Information:: Chemical Society Reviews, Journal Name: Chemical Society Reviews Journal Issue: 3 Vol. 51; ISSN 0306-0012

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Active Site-Directed Tandem Catalysis on Single Platinum Nanoparticles for Efficient and Stable Oxidation of Formaldehyde at Room Temperature Huang, Mengmeng; Li, Yingxuan; Li, Mengwei Environmental Science & Technology, Vol. 53, Issue 7 https://doi.org/10.1021/acs.est.9b01176	journal	March 2019
CO ₂ Hydrogenation over Pt-Containing UiO-67 Zr-MOFs—The Base Case Gutterød, Emil Sebastian; Øien-Ødegaard, Sigurd; Bossers, Koen Industrial & Engineering Chemistry Research, Vol. 56, Issue 45 https://doi.org/10.1021/acs.iecr.7b01457	journal	June 2017
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Stabilization of Photocatalytically Active Uranyl Species in a Uranyl–Organic Framework for Heterogeneous Alkane Fluorination Driven by Visible Light Zhang, Xuan; Li, Peng; Krzyaniak, Matthew Inorganic Chemistry, Vol. 59, Issue 23 https://doi.org/10.1021/acs.inorgchem.0c00850	journal	June 2020
Vapor-Phase Infiltration inside a Microporous Porphyrinic Metal–Organic Framework for Postsynthesis Modification De, Siddhartha; Quan, Gia Co; Gikonyo, Ben Inorganic Chemistry, Vol. 59, Issue 14 https://doi.org/10.1021/acs.inorgchem.0c01250	journal	July 2020
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Metal–Organic Framework (MOF) Defects under Control: Insights into the Missing Linker Sites and Their Implication in the Reactivity of Zirconium-Based Frameworks Gutov, Oleksii V.; Hevia, Miguel González; Escudero-Adán, Eduardo C. Inorganic Chemistry, Vol. 54, Issue 17 https://doi.org/10.1021/acs.inorgchem.5b01053	journal	August 2015
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Construction of 3-Fold-Interpenetrated Three-Dimensional Metal–Organic Frameworks of Nickel(II) for Highly Efficient Capture and Conversion of Carbon Dioxide Ugale, Bharat; Dhankhar, Sandeep Singh; Nagaraja, C. M. Inorganic Chemistry, Vol. 55, Issue 19 https://doi.org/10.1021/acs.inorgchem.6b01569	journal	September 2016
Controlled Synthesis of MOF-Encapsulated NiPt Nanoparticles toward Efficient and Complete Hydrogen Evolution from Hydrazine Borane and Hydrazine Zhang, Zhujun; Zhang, Shiliang; Yao, Qilu Inorganic Chemistry, Vol. 56, Issue 19 https://doi.org/10.1021/acs.inorgchem.7b01910	journal	September 2017
Palladium Nanoparticles Encapsulated in the MIL-101-Catalyzed One-Pot Reaction of Alcohol Oxidation and Aldimine Condensation Zhang, Yu-Yang; Li, Jia-Xin; Ding, Lin-Lin Inorganic Chemistry, Vol. 57, Issue 21 https://doi.org/10.1021/acs.inorgchem.8b02206	journal	October 2018
In Situ Imine-Based Linker Formation for the Synthesis of Zirconium MOFs: A Route to CO ₂ Capture Materials and Ethylene Oligomerization Catalysts Arrozi, Ubed S. F.; Bon, Volodymyr; Krause, Simon Inorganic Chemistry, Vol. 59, Issue 1 https://doi.org/10.1021/acs.inorgchem.9b02517	journal	December 2019
Visible-Light-Driven Photocatalytic Coupling of Benzylamine over Titanium-Based MIL-125-NH ₂ Metal–Organic Framework: A Mechanistic Study Vitillo, Jenny G.; Presti, Davide; Luz, Ignacio The Journal of Physical Chemistry C, Vol. 124, Issue 43 https://doi.org/10.1021/acs.jpcc.0c06950	journal	September 2020
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Adsorption Forms of CO ₂ on MIL-53(Al) and MIL-53(Al)–OH _x As Revealed by FTIR Spectroscopy Andonova, Stanislava; Ivanova, Elena; Yang, Jie The Journal of Physical Chemistry C, Vol. 121, Issue 34 https://doi.org/10.1021/acs.jpcc.7b05538	journal	August 2017
On the Electronic and Optical Properties of Metal–Organic Frameworks: Case Study of MIL-125 and MIL-125-NH ₂ Capano, Gloria; Ambrosio, Francesco; Kampouri, Stavroula The Journal of Physical Chemistry C, Vol. 124, Issue 7 https://doi.org/10.1021/acs.jpcc.9b09453	journal	January 2020
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Investigating the Process and Mechanism of Molecular Transport within a Representative Solvent-Filled Metal–Organic Framework Wang, Rui; Bukowski, Brandon C.; Duan, Jiaxin Langmuir, Vol. 36, Issue 36 https://doi.org/10.1021/acs.langmuir.0c01999	journal	August 2020
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Nickel–Carbon–Zirconium Material Derived from Nickel-Oxide Clusters Installed in a Metal–Organic Framework Scaffold by Atomic Layer Deposition Palmer, Rebecca H.; Kung, Chung-Wei; Liu, Jian Langmuir, Vol. 34, Issue 47 https://doi.org/10.1021/acs.langmuir.8b02166	journal	November 2018
A Smart Route for Encapsulating Pd Nanoparticles into a ZIF-8 Hollow Microsphere and Their Superior Catalytic Properties Zhao, Yaqian; Ni, Xinjiong; Ye, Sunjie Langmuir, Vol. 36, Issue 8 https://doi.org/10.1021/acs.langmuir.9b03731	journal	February 2020
Copper Nanocrystals Encapsulated in Zr-based Metal–Organic Frameworks for Highly Selective CO ₂ Hydrogenation to Methanol Rungtaweevoranit, Bunyarat; Baek, Jayeon; Araujo, Joyce R. Nano Letters, Vol. 16, Issue 12 https://doi.org/10.1021/acs.nanolett.6b03637	journal	November 2016
Ligand-Functionalization-Controlled Activity of Metal–Organic Framework-Encapsulated Pt Nanocatalyst toward Activation of Water Ogiwara, Naoki; Kobayashi, Hirokazu; Inukai, Munehiro Nano Letters, Vol. 20, Issue 1 https://doi.org/10.1021/acs.nanolett.9b04124	journal	December 2019
Pioneers and Influencers in Organometallic Chemistry: Professor Robert Crabtree’s Storied Career via an Unusual Journey to the Ivy League Dobereiner, Graham E.; Hazari, Nilay; Schley, Nathan D. Organometallics, Vol. 40, Issue 3 https://doi.org/10.1021/acs.organomet.0c00797	journal	January 2021
Convergent Synthesis of a Metal–Organic Framework Supported Olefin Metathesis Catalyst Yuan, Jian; Fracaroli, Alejandro M.; Klemperer, Walter G. Organometallics, Vol. 35, Issue 12 https://doi.org/10.1021/acs.organomet.6b00365	journal	June 2016
Selective Dimerization of Propylene with Ni-MFU-4 l Comito, Robert J.; Metzger, Eric D.; Wu, Zhenwei Organometallics, Vol. 36, Issue 9 https://doi.org/10.1021/acs.organomet.7b00178	journal	April 2017
Heterogenization of Trinuclear Palladium Complex into an Anionic Metal–Organic Framework through Postsynthetic Cation Exchange Ren, Junyu; Lan, Pui Ching; Chen, Meng Organometallics, Vol. 38, Issue 18 https://doi.org/10.1021/acs.organomet.9b00286	journal	August 2019
Mechanistic Study on the Origin of the Trans Selectivity in Alkyne Semihydrogenation by a Heterobimetallic Rhodium–Gallium Catalyst in a Metal–Organic Framework Desai, Sai Puneet; Ye, Jingyun; Islamoglu, Timur Organometallics, Vol. 38, Issue 18 https://doi.org/10.1021/acs.organomet.9b00331	journal	August 2019
Mechanistic Insights into C–H Borylation of Arenes with Organoiridium Catalysts Embedded in a Microporous Metal–Organic Framework Syed, Zoha H.; Chen, Zhihengyu; Idrees, Karam B. Organometallics, Vol. 39, Issue 7 https://doi.org/10.1021/acs.organomet.9b00874	journal	March 2020
Vapor-Phase Fabrication and Condensed-Phase Application of a MOF-Node-Supported Iron Thiolate Photocatalyst for Nitrate Conversion to Ammonium Choi, Hyeju; Peters, Aaron W.; Noh, Hyunho ACS Applied Energy Materials, Vol. 2, Issue 12 https://doi.org/10.1021/acsaem.9b01664	journal	November 2019
Aluminum Metal–Organic Framework Triggers Carbon Dioxide Reduction Activity Lee, Michelle; De Riccardis, Alberto; Kazantsev, Roman V. ACS Applied Energy Materials, Vol. 3, Issue 2 https://doi.org/10.1021/acsaem.9b02210	journal	January 2020
Ammonia Capture within Zirconium Metal–Organic Frameworks: Reversible and Irreversible Uptake Liu, Jian; Lu, Zhiyong; Chen, Zhijie ACS Applied Materials & Interfaces, Vol. 13, Issue 17 https://doi.org/10.1021/acsami.1c02370	journal	April 2021
Zirconium Metal–Organic Frameworks Integrating Chloride Ions for Ammonia Capture and/or Chemical Separation Liu, Jian; Chen, Zhijie; Wang, Rui ACS Applied Materials & Interfaces, Vol. 13, Issue 19 https://doi.org/10.1021/acsami.1c03717	journal	May 2021
Product Inhibition and the Catalytic Destruction of a Nerve Agent Simulant by Zirconium-Based Metal–Organic Frameworks Liao, Yijun; Sheridan, Thomas; Liu, Jian ACS Applied Materials & Interfaces, Vol. 13, Issue 26 https://doi.org/10.1021/acsami.1c05062	journal	June 2021
Metalloenzyme-Inspired Ce-MOF Catalyst for Oxidative Halogenation Reactions Rojas-Buzo, Sergio; Concepción, Patricia; Olloqui-Sariego, José Luis ACS Applied Materials & Interfaces, Vol. 13, Issue 26 https://doi.org/10.1021/acsami.1c07496	journal	June 2021
Engineering Dendrimer-Templated, Metal–Organic Framework-Confined Zero-Valent, Transition-Metal Catalysts Yang, Ying; Noh, Hyunho; Ma, Qing ACS Applied Materials & Interfaces, Vol. 13, Issue 30 https://doi.org/10.1021/acsami.1c11541	journal	July 2021
Toward Inexpensive Photocatalytic Hydrogen Evolution: A Nickel Sulfide Catalyst Supported on a High-Stability Metal–Organic Framework Peters, Aaron W.; Li, Zhanyong; Farha, Omar K. ACS Applied Materials & Interfaces, Vol. 8, Issue 32 https://doi.org/10.1021/acsami.6b04729	journal	August 2016
Molecular Rhodium Complexes Supported on the Metal-Oxide-Like Nodes of Metal Organic Frameworks and on Zeolite HY: Catalysts for Ethylene Hydrogenation and Dimerization Bernales, Varinia; Yang, Dong; Yu, Jun ACS Applied Materials & Interfaces, Vol. 9, Issue 39 https://doi.org/10.1021/acsami.7b03858	journal	April 2017
Effect of Redox “Non-Innocent” Linker on the Catalytic Activity of Copper-Catecholate-Decorated Metal–Organic Frameworks Zhang, Xuan; Vermeulen, Nicolaas A.; Huang, Zhiyuan ACS Applied Materials & Interfaces, Vol. 10, Issue 1 https://doi.org/10.1021/acsami.7b15326	journal	December 2017
Site-Directed Synthesis of Cobalt Oxide Clusters in a Metal–Organic Framework Peters, Aaron W.; Otake, Kenichi; Platero-Prats, Ana E. ACS Applied Materials & Interfaces, Vol. 10, Issue 17 https://doi.org/10.1021/acsami.8b02825	journal	March 2018
Lewis-Basic Lanthanide Metal-Organic Framework-Derived Versatile Multi-Active-Site Synergistic Catalysts for Oxygen Reduction Reaction Zhang, Zhong; Liu, Shumei; Li, Xiaohui ACS Applied Materials & Interfaces, Vol. 10, Issue 26 https://doi.org/10.1021/acsami.8b03742	journal	June 2018
Photocatalytic Hydrogen Generation from a Visible-Light-Responsive Metal–Organic Framework System: Stability versus Activity of Molybdenum Sulfide Cocatalysts Nguyen, Tu N.; Kampouri, Stavroula; Valizadeh, Bardiya ACS Applied Materials & Interfaces, Vol. 10, Issue 36 https://doi.org/10.1021/acsami.8b10010	journal	August 2018
Creating Chemisorption Sites for Enhanced CO ₂ Photoreduction Activity through Alkylamine Modification of MIL-101-Cr Xie, Yue; Fang, Zhibin; Li, Lan ACS Applied Materials & Interfaces, Vol. 11, Issue 30 https://doi.org/10.1021/acsami.9b09436	journal	July 2019
Metal Hydroxide/Polymer Textiles for Decontamination of Toxic Organophosphates: An Extensive Study of Wettability, Catalytic Activity, and the Effects of Aggregation Dwyer, Derek B.; Liu, Jian; Gomez, Jasmine C. ACS Applied Materials & Interfaces, Vol. 11, Issue 34 https://doi.org/10.1021/acsami.9b10440	journal	August 2019
Metal–Organic-Framework-Supported and -Isolated Ceria Clusters with Mixed Oxidation States Liu, Jian; Redfern, Louis R.; Liao, Yijun ACS Applied Materials & Interfaces, Vol. 11, Issue 51 https://doi.org/10.1021/acsami.9b12261	journal	December 2019
Strategies for Incorporating Catalytically Active Polyoxometalates in Metal–Organic Frameworks for Organic Transformations Buru, Cassandra T.; Farha, Omar K. ACS Applied Materials & Interfaces, Vol. 12, Issue 5 https://doi.org/10.1021/acsami.9b19785	journal	January 2020
Palladium Nanoclusters Confined in MOF@COP as a Novel Nanoreactor for Catalytic Hydrogenation Zhu, Yangyang; Wang, Wei David; Sun, Xun ACS Applied Materials & Interfaces, Vol. 12, Issue 6 https://doi.org/10.1021/acsami.9b21802	journal	January 2020
Insight of MOF Environment-Dependent Enzyme Activity via MOFs-in-Nanochannels Configuration Guo, Junli; Yang, Lingling; Gao, Zhida ACS Catalysis, Vol. 10, Issue 10 https://doi.org/10.1021/acscatal.0c00591	journal	May 2020
S,O-Functionalized Metal–Organic Frameworks as Heterogeneous Single-Site Catalysts for the Oxidative Alkenylation of Arenes via C–H activation Van Velthoven, Niels; Henrion, Mickaël; Dallenes, Jesse ACS Catalysis, Vol. 10, Issue 9 https://doi.org/10.1021/acscatal.0c00801	journal	April 2020
Insights into the Structure–Activity Relationships in Metal–Organic Framework-Supported Nickel Catalysts for Ethylene Hydrogenation Wang, Xingjie; Zhang, Xuan; Pandharkar, Riddhish ACS Catalysis, Vol. 10, Issue 16 https://doi.org/10.1021/acscatal.0c01844	journal	July 2020
Cerium(IV) Enhances the Catalytic Oxidation Activity of Single-Site Cu Active Sites in MOFs He, Xin; Looker, Benjamin G.; Dinh, Kimberly T. ACS Catalysis, Vol. 10, Issue 14 https://doi.org/10.1021/acscatal.0c02493	journal	June 2020
Metal–Organic Framework Nodes as a Supporting Platform for Tailoring the Activity of Metal Catalysts Syed, Zoha H.; Sha, Fanrui; Zhang, Xuan ACS Catalysis, Vol. 10, Issue 19 https://doi.org/10.1021/acscatal.0c03056	journal	September 2020
Influence of First and Second Coordination Environment on Structural Fe(II) Sites in MIL-101 for C–H Bond Activation in Methane Vitillo, Jenny G.; Lu, Connie C.; Cramer, Christopher J. ACS Catalysis, Vol. 11, Issue 2 https://doi.org/10.1021/acscatal.0c03906	journal	December 2020
Rapid, Biomimetic Degradation of a Nerve Agent Simulant by Incorporating Imidazole Bases into a Metal–Organic Framework Luo, Hong-Bin; Castro, Anthony J.; Wasson, Megan C. ACS Catalysis, Vol. 11, Issue 3 https://doi.org/10.1021/acscatal.0c04565	journal	January 2021
Integration of Earth-Abundant Photosensitizers and Catalysts in Metal–Organic Frameworks Enhances Photocatalytic Aerobic Oxidation Feng, Xuanyu; Pi, Yunhong; Song, Yang ACS Catalysis, Vol. 11, Issue 3 https://doi.org/10.1021/acscatal.0c05053	journal	January 2021
Mechanism-Guided Design of Metal–Organic Framework Composites for Selective Photooxidation of a Mustard Gas Simulant under Solvent-Free Conditions Hao, Yajiao; Papazyan, Edgar K.; Ba, Yong ACS Catalysis, Vol. 12, Issue 1 https://doi.org/10.1021/acscatal.1c04755	journal	December 2021
Gas-Phase Dimerization of Ethylene under Mild Conditions Catalyzed by MOF Materials Containing (bpy)Ni ^II Complexes Madrahimov, Sherzod T.; Gallagher, James R.; Zhang, Guanghui ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01604	journal	October 2015
Fe-Porphyrin-Based Metal–Organic Framework Films as High-Surface Concentration, Heterogeneous Catalysts for Electrochemical Reduction of CO ₂ Hod, Idan; Sampson, Matthew D.; Deria, Pravas ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01767	journal	September 2015
Controlling Catalytic Properties of Pd Nanoclusters through Their Chemical Environment at the Atomic Level Using Isoreticular Metal–Organic Frameworks Li, Xinle; Goh, Tian Wei; Li, Lei ACS Catalysis, Vol. 6, Issue 6 https://doi.org/10.1021/acscatal.6b00397	journal	April 2016
Rhodium Hydrogenation Catalysts Supported in Metal Organic Frameworks: Influence of the Framework on Catalytic Activity and Selectivity Genna, Douglas T.; Pfund, Laura Y.; Samblanet, Danielle C. ACS Catalysis, Vol. 6, Issue 6 https://doi.org/10.1021/acscatal.6b00404	journal	May 2016
Catalytic Zirconium/Hafnium-Based Metal–Organic Frameworks Rimoldi, Martino; Howarth, Ashlee J.; DeStefano, Matthew R. ACS Catalysis, Vol. 7, Issue 2 https://doi.org/10.1021/acscatal.6b02923	journal	December 2016
Coupling Molecular and Nanoparticle Catalysts on Single Metal–Organic Framework Microcrystals for the Tandem Reaction of H ₂ O ₂ Generation and Selective Alkene Oxidation Limvorapitux, Rungmai; Chou, Lien-Yang; Young, Allison P. ACS Catalysis, Vol. 7, Issue 10 https://doi.org/10.1021/acscatal.6b03632	journal	September 2017
Metal–Organic Frameworks as Heterogeneous Catalysts in Hydrogen Production from Lightweight Inorganic Hydrides Rossin, Andrea; Tuci, Giulia; Luconi, Lapo ACS Catalysis, Vol. 7, Issue 8 https://doi.org/10.1021/acscatal.7b01495	journal	July 2017
Selective Catalytic Olefin Epoxidation with Mn ^II -Exchanged MOF-5 Stubbs, Amanda W.; Braglia, Luca; Borfecchia, Elisa ACS Catalysis, Vol. 8, Issue 1 https://doi.org/10.1021/acscatal.7b02946	journal	December 2017
Isolated Fe Sites in Metal Organic Frameworks Catalyze the Direct Conversion of Methane to Methanol Osadchii, Dmitrii Y.; Olivos-Suarez, Alma I.; Szécsényi, Ágnes ACS Catalysis, Vol. 8, Issue 6 https://doi.org/10.1021/acscatal.8b00505	journal	May 2018
Redox-Mediator-Assisted Electrocatalytic Hydrogen Evolution from Water by a Molybdenum Sulfide-Functionalized Metal–Organic Framework Noh, Hyunho; Kung, Chung-Wei; Otake, Ken-ichi ACS Catalysis, Vol. 8, Issue 10 https://doi.org/10.1021/acscatal.8b02921	journal	September 2018
Stabilized Ru[(H ₂ O) ₆ ] ³⁺ in Confined Spaces (MOFs and Zeolites) Catalyzes the Imination of Primary Alcohols under Atmospheric Conditions with Wide Scope Mon, Marta; Adam, Rosa; Ferrando−Soria, Jesús ACS Catalysis, Vol. 8, Issue 11 https://doi.org/10.1021/acscatal.8b03228	journal	September 2018
Unveiling Charge-Separation Dynamics in CdS/Metal–Organic Framework Composites for Enhanced Photocatalysis Xu, Hai-Qun; Yang, Sizhuo; Ma, Xing ACS Catalysis, Vol. 8, Issue 12 https://doi.org/10.1021/acscatal.8b03233	journal	October 2018
Metal–Organic Frameworks in Solid–Gas Phase Catalysis Wang, Cheng; An, Bing; Lin, Wenbin ACS Catalysis, Vol. 9, Issue 1 https://doi.org/10.1021/acscatal.8b04055	journal	November 2018
Catalysis by Metal Organic Frameworks: Perspective and Suggestions for Future Research Yang, Dong; Gates, Bruce C. ACS Catalysis, Vol. 9, Issue 3 https://doi.org/10.1021/acscatal.8b04515	journal	January 2019
Metal–Organic Framework Nodes Support Single-Site Nickel(II) Hydride Catalysts for the Hydrogenolysis of Aryl Ethers Song, Yang; Li, Zhe; Ji, Pengfei ACS Catalysis, Vol. 9, Issue 2 https://doi.org/10.1021/acscatal.8b04611	journal	January 2019
Quantum Chemical Characterization of Structural Single Fe(II) Sites in MIL-Type Metal–Organic Frameworks for the Oxidation of Methane to Methanol and Ethane to Ethanol Vitillo, Jenny G.; Bhan, Aditya; Cramer, Christopher J. ACS Catalysis, Vol. 9, Issue 4 https://doi.org/10.1021/acscatal.8b04813	journal	January 2019
Introducing Nonstructural Ligands to Zirconia-like Metal–Organic Framework Nodes To Tune the Activity of Node-Supported Nickel Catalysts for Ethylene Hydrogenation Liu, Jian; Li, Zhanyong; Zhang, Xuan ACS Catalysis, Vol. 9, Issue 4 https://doi.org/10.1021/acscatal.8b04828	journal	March 2019
Porphyrinic Metal–Organic Frameworks Installed with Brønsted Acid Sites for Efficient Tandem Semisynthesis of Artemisinin Feng, Liang; Wang, Ying; Yuan, Shuai ACS Catalysis, Vol. 9, Issue 6 https://doi.org/10.1021/acscatal.8b04960	journal	March 2019
Aluminum Hydroxide Secondary Building Units in a Metal–Organic Framework Support Earth-Abundant Metal Catalysts for Broad-Scope Organic Transformations Feng, Xuanyu; Ji, Pengfei; Li, Zhe ACS Catalysis, Vol. 9, Issue 4 https://doi.org/10.1021/acscatal.9b00259	journal	March 2019
Enhanced Activity of Heterogeneous Pd(II) Catalysts on Acid-Functionalized Metal–Organic Frameworks Otake, Ken-ichi; Ye, Jingyun; Mandal, Mukunda ACS Catalysis, Vol. 9, Issue 6 https://doi.org/10.1021/acscatal.9b01043	journal	April 2019
Template-Directed Synthesis of Photocatalyst-Encapsulating Metal–Organic Frameworks with Boosted Photocatalytic Activity Yang, Xiaojie; Liang, Tao; Sun, Jiaxing ACS Catalysis, Vol. 9, Issue 8 https://doi.org/10.1021/acscatal.9b01783	journal	July 2019
Gas-Phase Ethylene Polymerization by Single-Site Cr Centers in a Metal–Organic Framework Park, Hoyoung D.; Comito, Robert J.; Wu, Zhenwei ACS Catalysis, Vol. 10, Issue 6 https://doi.org/10.1021/acscatal.9b03282	journal	March 2020
Heterogeneous Catalysis by Polyoxometalates in Metal–Organic Frameworks Samaniyan, Maryam; Mirzaei, Masoud; Khajavian, Ruhollah ACS Catalysis, Vol. 9, Issue 11 https://doi.org/10.1021/acscatal.9b03439	journal	September 2019
Tuning Zr ₁₂ O ₂₂ Node Defects as Catalytic Sites in the Metal–Organic Framework hcp UiO-66 Chen, Xi; Lyu, Yinghui; Wang, Zhengyan ACS Catalysis, Vol. 10, Issue 5 https://doi.org/10.1021/acscatal.9b04905	journal	January 2020
Demonstrating the Critical Role of Solvation in Supported Ti and Nb Epoxidation Catalysts via Vapor-Phase Kinetics Ahn, Sol; Nauert, Scott L.; Hicks, Kenton E. ACS Catalysis, Vol. 10, Issue 4 https://doi.org/10.1021/acscatal.9b04906	journal	January 2020
Metal–Organic Frameworks for Enzyme Immobilization: Beyond Host Matrix Materials Wang, Xiaoliang; Lan, Pui Ching; Ma, Shengqian ACS Central Science, Vol. 6, Issue 9 https://doi.org/10.1021/acscentsci.0c00687	journal	August 2020
Selective Dimerization of Ethylene to 1-Butene with a Porous Catalyst Metzger, Eric D.; Brozek, Carl K.; Comito, Robert J. ACS Central Science, Vol. 2, Issue 3 https://doi.org/10.1021/acscentsci.6b00012	journal	February 2016
Diffusion-Controlled Rotation of Triptycene in a Metal–Organic Framework (MOF) Sheds Light on the Viscosity of MOF-Confined Solvent Jiang, Xing; Duan, Hai-Bao; Khan, Saeed I. ACS Central Science, Vol. 2, Issue 9 https://doi.org/10.1021/acscentsci.6b00168	journal	August 2016
Metal–Organic Framework Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane at Low Temperature Li, Zhanyong; Peters, Aaron W.; Bernales, Varinia ACS Central Science, Vol. 3, Issue 1 https://doi.org/10.1021/acscentsci.6b00290	journal	November 2016
Electrically Induced Breathing of the MIL-53(Cr) Metal–Organic Framework Ghoufi, Aziz; Benhamed, Karima; Boukli-Hacene, Leila ACS Central Science, Vol. 3, Issue 5 https://doi.org/10.1021/acscentsci.6b00392	journal	April 2017
Heterogeneous Epoxide Carbonylation by Cooperative Ion-Pair Catalysis in Co(CO) ₄ ^– -Incorporated Cr-MIL-101 Park, Hoyoung D.; Dincă, Mircea; Román-Leshkov, Yuriy ACS Central Science, Vol. 3, Issue 5 https://doi.org/10.1021/acscentsci.7b00075	journal	March 2017
Computational Design of Functionalized Metal–Organic Framework Nodes for Catalysis Bernales, Varinia; Ortuño, Manuel A.; Truhlar, Donald G. ACS Central Science, Vol. 4, Issue 1 https://doi.org/10.1021/acscentsci.7b00500	journal	December 2017
Nanoconfinement of Molecular Magnesium Borohydride Captured in a Bipyridine-Functionalized Metal–Organic Framework Schneemann, Andreas; Wan, Liwen F.; Lipton, Andrew S. ACS Nano, Vol. 14, Issue 8 https://doi.org/10.1021/acsnano.0c03764	journal	July 2020
Atomically Precise Growth of Catalytically Active Cobalt Sulfide on Flat Surfaces and within a Metal–Organic Framework via Atomic Layer Deposition Peters, Aaron W.; Li, Zhanyong; Farha, Omar K. ACS Nano, Vol. 9, Issue 8 https://doi.org/10.1021/acsnano.5b03429	journal	July 2015
Nanosizing a Metal–Organic Framework Enzyme Carrier for Accelerating Nerve Agent Hydrolysis Li, Peng; Moon, Su-Young; Guelta, Mark A. ACS Nano, Vol. 10, Issue 10 https://doi.org/10.1021/acsnano.6b04996	journal	October 2016
Metal–Organic Framework Supported Single Site Chromium(III) Catalyst for Ethylene Oligomerization at Low Pressure and Temperature Goetjen, Timothy A.; Zhang, Xuan; Liu, Jian ACS Sustainable Chemistry & Engineering, Vol. 7, Issue 2 https://doi.org/10.1021/acssuschemeng.8b05524	journal	December 2018
CAF@ZIF-8: One-Step Encapsulation of Caffeine in MOF Liédana, Nuria; Galve, Alejandro; Rubio, César ACS Applied Materials & Interfaces, Vol. 4, Issue 9 https://doi.org/10.1021/am301365h	journal	August 2012
Hollow Metal–Organic Framework Nanospheres via Emulsion-Based Interfacial Synthesis and Their Application in Size-Selective Catalysis Yang, Yufen; Wang, Fengwei; Yang, Qihao ACS Applied Materials & Interfaces, Vol. 6, Issue 20 https://doi.org/10.1021/am505145d	journal	October 2014
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Oxygen Defects and Surface Chemistry of Ceria: Quantum Chemical Studies Compared to Experiment Paier, Joachim; Penschke, Christopher; Sauer, Joachim Chemical Reviews, Vol. 113, Issue 6 https://doi.org/10.1021/cr3004949	journal	December 2012
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Pt Nanoclusters Confined within Metal–Organic Framework Cavities for Chemoselective Cinnamaldehyde Hydrogenation Guo, Zhiyong; Xiao, Chaoxian; Maligal-Ganesh, Raghu V. ACS Catalysis, Vol. 4, Issue 5, p. 1340-1348 https://doi.org/10.1021/cs400982n	journal	April 2014
Heterogeneous Catalysis for Tandem Reactions Climent, Maria J.; Corma, Avelino; Iborra, Sara ACS Catalysis, Vol. 4, Issue 3 https://doi.org/10.1021/cs401052k	journal	January 2014
Spatial Confinement of a Co ₃ O ₄ Catalyst in Hollow Metal–Organic Frameworks as a Nanoreactor for Improved Degradation of Organic Pollutants Zeng, Tao; Zhang, Xiaole; Wang, Saihua Environmental Science & Technology, Vol. 49, Issue 4 https://doi.org/10.1021/es505014z	journal	January 2015
Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks Morris, William; Volosskiy, Boris; Demir, Selcuk Inorganic Chemistry, Vol. 51, Issue 12, p. 6443-6445 https://doi.org/10.1021/ic300825s	journal	June 2012
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Why Does Enzyme Not Leach from Metal–Organic Frameworks (MOFs)? Unveiling the Interactions between an Enzyme Molecule and a MOF Chen, Yao; Han, Sungyub; Li, Xiao Inorganic Chemistry, Vol. 53, Issue 19 https://doi.org/10.1021/ic501062r	journal	September 2014
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Metal−Organic Frameworks as Sensors: A ZIF-8 Based Fabry−Pérot Device as a Selective Sensor for Chemical Vapors and Gases Lu, Guang; Hupp, Joseph T. Journal of the American Chemical Society, Vol. 132, Issue 23 https://doi.org/10.1021/ja101415b	journal	June 2010
The Nature of Surface Barriers on Nanoporous Solids Explored by Microimaging of Transient Guest Distributions Hibbe, Florian; Chmelik, Christian; Heinke, Lars Journal of the American Chemical Society, Vol. 133, Issue 9 https://doi.org/10.1021/ja108625z	journal	March 2011
Synergistic Catalysis of Metal–Organic Framework-Immobilized Au–Pd Nanoparticles in Dehydrogenation of Formic Acid for Chemical Hydrogen Storage Gu, Xiaojun; Lu, Zhang-Hui; Jiang, Hai-Long Journal of the American Chemical Society, Vol. 133, Issue 31 https://doi.org/10.1021/ja200122f	journal	August 2011
Opening the Gate: Framework Flexibility in ZIF-8 Explored by Experiments and Simulations Fairen-Jimenez, D.; Moggach, S. A.; Wharmby, M. T. Journal of the American Chemical Society, Vol. 133, Issue 23 https://doi.org/10.1021/ja202154j	journal	June 2011
An Exceptional 54-Fold Interpenetrated Coordination Polymer with 10 ³ -srs Network Topology Wu, Hua; Yang, Jin; Su, Zhong-Min Journal of the American Chemical Society, Vol. 133, Issue 30 https://doi.org/10.1021/ja202303b	journal	August 2011
Doping Metal–Organic Frameworks for Water Oxidation, Carbon Dioxide Reduction, and Organic Photocatalysis Wang, Cheng; Xie, Zhigang; deKrafft, Kathryn E. Journal of the American Chemical Society, Vol. 133, Issue 34, p. 13445-13454 https://doi.org/10.1021/ja203564w	journal	August 2011
Immobilization of MP-11 into a Mesoporous Metal–Organic Framework, MP-11@mesoMOF: A New Platform for Enzymatic Catalysis Lykourinou, Vasiliki; Chen, Yao; Wang, Xi-Sen Journal of the American Chemical Society, Vol. 133, Issue 27 https://doi.org/10.1021/ja2038003	journal	July 2011
Reversible Alteration of CO ₂ Adsorption upon Photochemical or Thermal Treatment in a Metal–Organic Framework Park, Jinhee; Yuan, Daqiang; Pham, Khanh T. Journal of the American Chemical Society, Vol. 134, Issue 1 https://doi.org/10.1021/ja209197f	journal	December 2011
Postsynthetic Ligand and Cation Exchange in Robust Metal–Organic Frameworks Kim, Min; Cahill, John F.; Fei, Honghan Journal of the American Chemical Society, Vol. 134, Issue 43 https://doi.org/10.1021/ja3079219	journal	October 2012
Stepwise Transformation of the Molecular Building Blocks in a Porphyrin-Encapsulating Metal–Organic Material Zhang, Zhenjie; Wojtas, Lukasz; Eddaoudi, Mohamed Journal of the American Chemical Society, Vol. 135, Issue 16 https://doi.org/10.1021/ja4015666	journal	April 2013
Heterogenization of Homogeneous Catalysts in Metal–Organic Frameworks via Cation Exchange Genna, Douglas T.; Wong-Foy, Antek G.; Matzger, Adam J. Journal of the American Chemical Society, Vol. 135, Issue 29 https://doi.org/10.1021/ja402577s	journal	July 2013
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297 https://doi.org/10.1021/ja4050828	journal	May 2013
Engineering the Optical Response of the Titanium-MIL-125 Metal–Organic Framework through Ligand Functionalization Hendon, Christopher H.; Tiana, Davide; Fontecave, Marc Journal of the American Chemical Society, Vol. 135, Issue 30 https://doi.org/10.1021/ja405350u	journal	July 2013
Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination Feng, Dawei; Chung, Wan-Chun; Wei, Zhangwen Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja408084j	journal	October 2013
Systematic Modulation of Quantum (Electron) Tunneling Behavior by Atomic Layer Deposition on Nanoparticulate SnO ₂ and TiO ₂ Photoanodes Prasittichai, Chaiya; Avila, Jason R.; Farha, Omar K. Journal of the American Chemical Society, Vol. 135, Issue 44 https://doi.org/10.1021/ja4089555	journal	October 2013
Reusable Oxidation Catalysis Using Metal-Monocatecholato Species in a Robust Metal–Organic Framework Fei, Honghan; Shin, JaeWook; Meng, Ying Shirley Journal of the American Chemical Society, Vol. 136, Issue 13 https://doi.org/10.1021/ja411627z	journal	March 2014
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials Furukawa, Hiroyasu; Gándara, Felipe; Zhang, Yue-Biao Journal of the American Chemical Society, Vol. 136, Issue 11, p. 4369-4381 https://doi.org/10.1021/ja500330a	journal	March 2014
Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis Sampson, Matthew D.; Nguyen, An D.; Grice, Kyle A. Journal of the American Chemical Society, Vol. 136, Issue 14 https://doi.org/10.1021/ja501252f	journal	February 2014
Postsynthetic Metalation of Bipyridyl-Containing Metal–Organic Frameworks for Highly Efficient Catalytic Organic Transformations Manna, Kuntal; Zhang, Teng; Lin, Wenbin Journal of the American Chemical Society, Vol. 136, Issue 18 https://doi.org/10.1021/ja5018267	journal	April 2014
Molecular Encapsulation beyond the Aperture Size Limit through Dissociative Linker Exchange in Metal–Organic Framework Crystals Morabito, Joseph V.; Chou, Lien-Yang; Li, Zhehui Journal of the American Chemical Society, Vol. 136, Issue 36 https://doi.org/10.1021/ja5054779	journal	August 2014
Superacidity in Sulfated Metal–Organic Framework-808 Jiang, Juncong; Gándara, Felipe; Zhang, Yue-Biao Journal of the American Chemical Society, Vol. 136, Issue 37 https://doi.org/10.1021/ja507119n	journal	September 2014
Bipyridine- and Phenanthroline-Based Metal–Organic Frameworks for Highly Efficient and Tandem Catalytic Organic Transformations via Directed C–H Activation Manna, Kuntal; Zhang, Teng; Greene, Francis X. Journal of the American Chemical Society, Vol. 137, Issue 7 https://doi.org/10.1021/ja512478y	journal	February 2015
Metalation of a Thiocatechol-Functionalized Zr(IV)-Based Metal–Organic Framework for Selective C–H Functionalization Fei, Honghan; Cohen, Seth M. Journal of the American Chemical Society, Vol. 137, Issue 6 https://doi.org/10.1021/ja5126885	journal	February 2015
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953	journal	October 2008
Postsynthetic Modification Switches an Achiral Framework to Catalytically Active Homochiral Metal−Organic Porous Materials Banerjee, Mainak; Das, Sunirban; Yoon, Minyoung Journal of the American Chemical Society, Vol. 131, Issue 22 https://doi.org/10.1021/ja901440g	journal	June 2009
A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate Dan-Hardi, Meenakshi; Serre, Christian; Frot, Théo Journal of the American Chemical Society, Vol. 131, Issue 31, p. 10857-10859 https://doi.org/10.1021/ja903726m	journal	July 2009
Quest for an Optimal Methane Hydrate Formation in the Pores of Hydrolytically Stable Metal–Organic Frameworks Cuadrado-Collados, Carlos; Mouchaham, Georges; Daemen, Luke Journal of the American Chemical Society, Vol. 142, Issue 31 https://doi.org/10.1021/jacs.0c01459	journal	July 2020
Metal–Organic Frameworks Integrate Cu Photosensitizers and Secondary Building Unit-Supported Fe Catalysts for Photocatalytic Hydrogen Evolution Pi, Yunhong; Feng, Xuanyu; Song, Yang Journal of the American Chemical Society, Vol. 142, Issue 23 https://doi.org/10.1021/jacs.0c03906	journal	May 2020
Boosting Interfacial Charge-Transfer Kinetics for Efficient Overall CO ₂ Photoreduction via Rational Design of Coordination Spheres on Metal–Organic Frameworks Fang, Zhi-Bin; Liu, Ting-Ting; Liu, Junxue Journal of the American Chemical Society, Vol. 142, Issue 28 https://doi.org/10.1021/jacs.0c05530	journal	June 2020
Extension of Surface Organometallic Chemistry to Metal–Organic Frameworks: Development of a Well-Defined Single Site [(≡Zr–O−)W(═O)(CH ₂ ^t Bu) ₃ ] Olefin Metathesis Catalyst Thiam, Zeynabou; Abou-Hamad, Edy; Dereli, Busra Journal of the American Chemical Society, Vol. 142, Issue 39 https://doi.org/10.1021/jacs.0c06925	journal	September 2020
Influence of Defects and H ₂ O on the Hydrogenation of CO ₂ to Methanol over Pt Nanoparticles in UiO-67 Metal–Organic Framework Gutterød, Emil Sebastian; Pulumati, Sri Harsha; Kaur, Gurpreet Journal of the American Chemical Society, Vol. 142, Issue 40 https://doi.org/10.1021/jacs.0c07153	journal	September 2020
Acid Catalysis in Confined Channels of Metal–Organic Frameworks: Boosting Orthoformate Hydrolysis in Basic Solutions Zhou, Guojun; Wang, Bo; Cao, Rui Journal of the American Chemical Society, Vol. 142, Issue 35 https://doi.org/10.1021/jacs.0c07257	journal	August 2020
Node-Accessible Zirconium MOFs Lu, Zhiyong; Liu, Jian; Zhang, Xuan Journal of the American Chemical Society, Vol. 142, Issue 50 https://doi.org/10.1021/jacs.0c09782	journal	December 2020
Unexpected “Spontaneous” Evolution of Catalytic, MOF-Supported Single Cu(II) Cations to Catalytic, MOF-Supported Cu(0) Nanoparticles Yang, Ying; Zhang, Xuan; Kanchanakungwankul, Siriluk Journal of the American Chemical Society, Vol. 142, Issue 50 https://doi.org/10.1021/jacs.0c10367	journal	December 2020
Structural Diversity of Zirconium Metal–Organic Frameworks and Effect on Adsorption of Toxic Chemicals Chen, Yongwei; Zhang, Xuan; Mian, Mohammad Rasel Journal of the American Chemical Society, Vol. 142, Issue 51 https://doi.org/10.1021/jacs.0c10400	journal	December 2020
Peptide–Metal Frameworks with Metal Strings Guided by Dispersion Interactions Schnitzer, Tobias; Paenurk, Eno; Trapp, Nils Journal of the American Chemical Society, Vol. 143, Issue 2 https://doi.org/10.1021/jacs.0c11793	journal	January 2021
Rational Construction of an Artificial Binuclear Copper Monooxygenase in a Metal–Organic Framework Feng, Xuanyu; Song, Yang; Chen, Justin S. Journal of the American Chemical Society, Vol. 143, Issue 2 https://doi.org/10.1021/jacs.0c11920	journal	January 2021
High Ammonia Adsorption in MFM-300 Materials: Dynamics and Charge Transfer in Host–Guest Binding Han, Xue; Lu, Wanpeng; Chen, Yinlin Journal of the American Chemical Society, Vol. 143, Issue 8 https://doi.org/10.1021/jacs.0c11930	journal	February 2021
Systematic Ligand Modulation Enhances the Moisture Stability and Gas Sorption Characteristics of Quaternary Metal–Organic Frameworks Liu, Lujia; Telfer, Shane G. Journal of the American Chemical Society, Vol. 137, Issue 11 https://doi.org/10.1021/jacs.5b00365	journal	March 2015
Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes Yang, Dong; Odoh, Samuel O.; Wang, Timothy C. Journal of the American Chemical Society, Vol. 137, Issue 23, p. 7391-7396 https://doi.org/10.1021/jacs.5b02956	journal	June 2015
Chemical Environment Control and Enhanced Catalytic Performance of Platinum Nanoparticles Embedded in Nanocrystalline Metal–Organic Frameworks Choi, Kyung Min; Na, Kyungsu; Somorjai, Gabor A. Journal of the American Chemical Society, Vol. 137, Issue 24 https://doi.org/10.1021/jacs.5b03540	journal	June 2015
Single-Site Organozirconium Catalyst Embedded in a Metal–Organic Framework Klet, Rachel C.; Tussupbayev, Samat; Borycz, Joshua Journal of the American Chemical Society, Vol. 137, Issue 50 https://doi.org/10.1021/jacs.5b11350	journal	December 2015
Sintering-Resistant Single-Site Nickel Catalyst Supported by Metal–Organic Framework Li, Zhanyong; Schweitzer, Neil M.; League, Aaron B. Journal of the American Chemical Society, Vol. 138, Issue 6 https://doi.org/10.1021/jacs.5b12515	journal	February 2016
A Triazole-Containing Metal–Organic Framework as a Highly Effective and Substrate Size-Dependent Catalyst for CO ₂ Conversion Li, Pei-Zhou; Wang, Xiao-Jun; Liu, Jia Journal of the American Chemical Society, Vol. 138, Issue 7 https://doi.org/10.1021/jacs.5b13335	journal	February 2016
Metal–Organic Frameworks Stabilize Solution-Inaccessible Cobalt Catalysts for Highly Efficient Broad-Scope Organic Transformations Zhang, Teng; Manna, Kuntal; Lin, Wenbin Journal of the American Chemical Society, Vol. 138, Issue 9 https://doi.org/10.1021/jacs.6b00849	journal	February 2016
Encapsulation of a Nerve Agent Detoxifying Enzyme by a Mesoporous Zirconium Metal–Organic Framework Engenders Thermal and Long-Term Stability Li, Peng; Moon, Su-Young; Guelta, Mark A. Journal of the American Chemical Society, Vol. 138, Issue 26 https://doi.org/10.1021/jacs.6b03673	journal	June 2016
Metal–Organic Framework Nodes Support Single-Site Magnesium–Alkyl Catalysts for Hydroboration and Hydroamination Reactions Manna, Kuntal; Ji, Pengfei; Greene, Francis X. Journal of the American Chemical Society, Vol. 138, Issue 24 https://doi.org/10.1021/jacs.6b03689	journal	June 2016
Seven Post-synthetic Covalent Reactions in Tandem Leading to Enzyme-like Complexity within Metal–Organic Framework Crystals Fracaroli, Alejandro M.; Siman, Peter; Nagib, David A. Journal of the American Chemical Society, Vol. 138, Issue 27 https://doi.org/10.1021/jacs.6b04204	journal	June 2016
Self-Healing of Molecular Catalyst and Photosensitizer on Metal–Organic Framework: Robust Molecular System for Photocatalytic H ₂ Evolution from Water Kim, Dongha; Whang, Dong Ryeol; Park, Soo Young Journal of the American Chemical Society, Vol. 138, Issue 28 https://doi.org/10.1021/jacs.6b04552	journal	July 2016
Single-Site Heterogeneous Catalysts for Olefin Polymerization Enabled by Cation Exchange in a Metal-Organic Framework Comito, Robert J.; Fritzsching, Keith J.; Sundell, Benjamin J. Journal of the American Chemical Society, Vol. 138, Issue 32 https://doi.org/10.1021/jacs.6b05200	journal	August 2016
Metal–Organic Frameworks Stabilize Mono(phosphine)–Metal Complexes for Broad-Scope Catalytic Reactions Sawano, Takahiro; Lin, Zekai; Boures, Dean Journal of the American Chemical Society, Vol. 138, Issue 31 https://doi.org/10.1021/jacs.6b06239	journal	July 2016
Catalytically Active Bimetallic Nanoparticles Supported on Porous Carbon Capsules Derived From Metal–Organic Framework Composites Yang, Hui; Bradley, Siobhan J.; Chan, Andrew Journal of the American Chemical Society, Vol. 138, Issue 36 https://doi.org/10.1021/jacs.6b06736	journal	August 2016
Pore Environment Effects on Catalytic Cyclohexane Oxidation in Expanded Fe ₂ (dobdc) Analogues Xiao, Dianne J.; Oktawiec, Julia; Milner, Phillip J. Journal of the American Chemical Society, Vol. 138, Issue 43 https://doi.org/10.1021/jacs.6b08417	journal	October 2016
Framework-Topology-Dependent Catalytic Activity of Zirconium-Based (Porphinato)zinc(II) MOFs Deria, Pravas; Gómez-Gualdrón, Diego A.; Hod, Idan Journal of the American Chemical Society, Vol. 138, Issue 43 https://doi.org/10.1021/jacs.6b09113	journal	October 2016
Cerium-Hydride Secondary Building Units in a Porous Metal–Organic Framework for Catalytic Hydroboration and Hydrophosphination Ji, Pengfei; Sawano, Takahiro; Lin, Zekai Journal of the American Chemical Society, Vol. 138, Issue 45 https://doi.org/10.1021/jacs.6b10055	journal	November 2016
Mechanism of Single-Site Molecule-Like Catalytic Ethylene Dimerization in Ni-MFU-4 l Metzger, Eric D.; Comito, Robert J.; Hendon, Christopher H. Journal of the American Chemical Society, Vol. 139, Issue 2 https://doi.org/10.1021/jacs.6b10300	journal	January 2017
Confinement of Ultrasmall Cu/ZnO _x Nanoparticles in Metal–Organic Frameworks for Selective Methanol Synthesis from Catalytic Hydrogenation of CO ₂ An, Bing; Zhang, Jingzheng; Cheng, Kang Journal of the American Chemical Society, Vol. 139, Issue 10 https://doi.org/10.1021/jacs.7b00058	journal	March 2017
Bridging Zirconia Nodes within a Metal–Organic Framework via Catalytic Ni-Hydroxo Clusters to Form Heterobimetallic Nanowires Platero-Prats, Ana E.; League, Aaron B.; Bernales, Varinia Journal of the American Chemical Society, Vol. 139, Issue 30 https://doi.org/10.1021/jacs.7b04997	journal	July 2017
Transformation of Metal–Organic Framework Secondary Building Units into Hexanuclear Zr-Alkyl Catalysts for Ethylene Polymerization Ji, Pengfei; Solomon, Joseph B.; Lin, Zekai Journal of the American Chemical Society, Vol. 139, Issue 33 https://doi.org/10.1021/jacs.7b05761	journal	August 2017
Pore Breathing of Metal–Organic Frameworks by Environmental Transmission Electron Microscopy Parent, Lucas R.; Pham, C. Huy; Patterson, Joseph P. Journal of the American Chemical Society, Vol. 139, Issue 40 https://doi.org/10.1021/jacs.7b06585	journal	September 2017
Highly Stereoselective Heterogeneous Diene Polymerization by Co-MFU-4 l : A Single-Site Catalyst Prepared by Cation Exchange Dubey, Romain J. -C.; Comito, Robert J.; Wu, Zhenwei Journal of the American Chemical Society, Vol. 139, Issue 36 https://doi.org/10.1021/jacs.7b06841	journal	August 2017
Modulating the Performance of an Asymmetric Organocatalyst by Tuning Its Spatial Environment in a Metal–Organic Framework Liu, Lujia; Zhou, Tian-You; Telfer, Shane G. Journal of the American Chemical Society, Vol. 139, Issue 39 https://doi.org/10.1021/jacs.7b07921	journal	September 2017
Trivalent Zirconium and Hafnium Metal–Organic Frameworks for Catalytic 1,4-Dearomative Additions of Pyridines and Quinolines Ji, Pengfei; Feng, Xuanyu; Veroneau, Samuel S. Journal of the American Chemical Society, Vol. 139, Issue 44 https://doi.org/10.1021/jacs.7b09093	journal	October 2017
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Metal–Organic Frameworks Invert Molecular Reactivity: Lewis Acidic Phosphonium Zwitterions Catalyze the Aldol-Tishchenko Reaction Bauer, Gerald; Ongari, Daniele; Xu, Xiaoying Journal of the American Chemical Society, Vol. 139, Issue 50 https://doi.org/10.1021/jacs.7b10928	journal	December 2017
Titanium(III)-Oxo Clusters in a Metal–Organic Framework Support Single-Site Co(II)-Hydride Catalysts for Arene Hydrogenation Ji, Pengfei; Song, Yang; Drake, Tasha Journal of the American Chemical Society, Vol. 140, Issue 1 https://doi.org/10.1021/jacs.7b11241	journal	December 2017
Structure and Dynamics of Zr ₆ O ₈ Metal–Organic Framework Node Surfaces Probed with Ethanol Dehydration as a Catalytic Test Reaction Yang, Dong; Ortuño, Manuel A.; Bernales, Varinia Journal of the American Chemical Society, Vol. 140, Issue 10 https://doi.org/10.1021/jacs.7b13330	journal	February 2018
Acid-Resistant Mesoporous Metal–Organic Framework toward Oral Insulin Delivery: Protein Encapsulation, Protection, and Release Chen, Yijing; Li, Peng; Modica, Justin A. Journal of the American Chemical Society, Vol. 140, Issue 17 https://doi.org/10.1021/jacs.8b02089	journal	April 2018
Protecting-Group-Free Site-Selective Reactions in a Metal–Organic Framework Reaction Vessel Huxley, Michael. T.; Burgun, Alexandre; Ghodrati, Hanieh Journal of the American Chemical Society, Vol. 140, Issue 20 https://doi.org/10.1021/jacs.8b02896	journal	April 2018
Aperture-Opening Encapsulation of a Transition Metal Catalyst in a Metal–Organic Framework for CO ₂ Hydrogenation Li, Zhehui; Rayder, Thomas M.; Luo, Lianshun Journal of the American Chemical Society, Vol. 140, Issue 26 https://doi.org/10.1021/jacs.8b04047	journal	June 2018
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Beyond the Active Site: Tuning the Activity and Selectivity of a Metal–Organic Framework-Supported Ni Catalyst for Ethylene Dimerization Liu, Jian; Ye, Jingyun; Li, Zhanyong Journal of the American Chemical Society, Vol. 140, Issue 36 https://doi.org/10.1021/jacs.8b06006	journal	August 2018
A Flexible Metal–Organic Framework with 4-Connected Zr ₆ Nodes Zhang, Yuanyuan; Zhang, Xuan; Lyu, Jiafei Journal of the American Chemical Society, Vol. 140, Issue 36 https://doi.org/10.1021/jacs.8b06789	journal	August 2018
Well-Defined Rhodium–Gallium Catalytic Sites in a Metal–Organic Framework: Promoter-Controlled Selectivity in Alkyne Semihydrogenation to E -Alkenes Desai, Sai Puneet; Ye, Jingyun; Zheng, Jian Journal of the American Chemical Society, Vol. 140, Issue 45 https://doi.org/10.1021/jacs.8b08550	journal	October 2018
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Reversible Metalation and Catalysis with a Scorpionate-like Metallo-ligand in a Metal–Organic Framework Sun, Chenyue; Skorupskii, Grigorii; Dou, Jin-Hu Journal of the American Chemical Society, Vol. 140, Issue 50 https://doi.org/10.1021/jacs.8b11085	journal	November 2018
Catalysts Confined in Programmed Framework Pores Enable New Transformations and Tune Reaction Efficiency and Selectivity Zhou, Tian-You; Auer, Bernhard; Lee, Seok J. Journal of the American Chemical Society, Vol. 141, Issue 4 https://doi.org/10.1021/jacs.8b11221	journal	January 2019
Highly Active and Stable Single-Atom Cu Catalysts Supported by a Metal–Organic Framework Abdel-Mageed, Ali M.; Rungtaweevoranit, Bunyarat; Parlinska-Wojtan, Magdalena Journal of the American Chemical Society, Vol. 141, Issue 13 https://doi.org/10.1021/jacs.8b11386	journal	March 2019
Bioinspired Metal–Organic Framework Catalysts for Selective Methane Oxidation to Methanol Baek, Jayeon; Rungtaweevoranit, Bunyarat; Pei, Xiaokun Journal of the American Chemical Society, Vol. 140, Issue 51 https://doi.org/10.1021/jacs.8b11525	journal	December 2018
Tuning the Ionicity of Stable Metal–Organic Frameworks through Ionic Linker Installation Pang, Jiandong; Yuan, Shuai; Qin, Jun-Sheng Journal of the American Chemical Society, Vol. 141, Issue 7 https://doi.org/10.1021/jacs.8b12530	journal	January 2019
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Metal–Organic Frameworks as Catalysts for Organic Synthesis: A Critical Perspective Pascanu, Vlad; González Miera, Greco; Inge, A. Ken Journal of the American Chemical Society, Vol. 141, Issue 18 https://doi.org/10.1021/jacs.9b00733	journal	April 2019
Highly Stable Zr(IV)-Based Metal–Organic Frameworks with Chiral Phosphoric Acids for Catalytic Asymmetric Tandem Reactions Gong, Wei; Chen, Xu; Jiang, Hong Journal of the American Chemical Society, Vol. 141, Issue 18 https://doi.org/10.1021/jacs.9b02294	journal	April 2019
Vanadium Catalyst on Isostructural Transition Metal, Lanthanide, and Actinide Based Metal–Organic Frameworks for Alcohol Oxidation Wang, Xingjie; Zhang, Xuan; Li, Peng Journal of the American Chemical Society https://doi.org/10.1021/jacs.9b02603	journal	May 2019
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Metal–Organic Framework Stabilizes a Low-Coordinate Iridium Complex for Catalytic Methane Borylation Feng, Xuanyu; Song, Yang; Li, Zhe Journal of the American Chemical Society, Vol. 141, Issue 28 https://doi.org/10.1021/jacs.9b04285	journal	June 2019
Crystallographic Visualization of Postsynthetic Nickel Clusters into Metal–Organic Framework Wang, Xiao-Ning; Zhang, Peng; Kirchon, Angelo Journal of the American Chemical Society, Vol. 141, Issue 34 https://doi.org/10.1021/jacs.9b06711	journal	August 2019
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A metal–organic framework immobilised iridium pincer complex Rimoldi, Martino; Nakamura, Akitake; Vermeulen, Nicolaas A. Chemical Science, Vol. 7, Issue 8 https://doi.org/10.1039/C6SC01376G	journal	January 2016
Coupling two enzymes into a tandem nanoreactor utilizing a hierarchically structured MOF Lian, Xizhen; Chen, Ying-Pin; Liu, Tian-Fu Chemical Science, Vol. 7, Issue 12 https://doi.org/10.1039/C6SC01438K	journal	January 2016
Engineering catalytic coordination space in a chemically stable Ir-porphyrin MOF with a confinement effect inverting conventional Si–H insertion chemoselectivity Wang, Yingxia; Cui, Hao; Wei, Zhang-Wen Chemical Science, Vol. 8, Issue 1 https://doi.org/10.1039/C6SC03288E	journal	January 2017
Cooperative electrochemical water oxidation by Zr nodes and Ni–porphyrin linkers of a PCN-224 MOF thin film Usov, P. M.; Ahrenholtz, S. R.; Maza, W. A. Journal of Materials Chemistry A, Vol. 4, Issue 43 https://doi.org/10.1039/C6TA05877A	journal	January 2016
Metal–organic and covalent organic frameworks as single-site catalysts Rogge, S. M. J.; Bavykina, A.; Hajek, J. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C7CS00033B	journal	January 2017
Metal–organic frameworks for the removal of toxic industrial chemicals and chemical warfare agents Bobbitt, N. Scott; Mendonca, Matthew L.; Howarth, Ashlee J. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C7CS00108H	journal	January 2017
A new superacid hafnium-based metal–organic framework as a highly active heterogeneous catalyst for the synthesis of benzoxazoles under solvent-free conditions Nguyen, Linh H. T.; Nguyen, The T.; Nguyen, Ha L. Catalysis Science & Technology, Vol. 7, Issue 19 https://doi.org/10.1039/C7CY01668A	journal	January 2017
Phenanthroline-based metal–organic frameworks for Fe-catalyzed C _sp3 –H amination Thacker, Nathan C.; Ji, Pengfei; Lin, Zekai Faraday Discussions, Vol. 201 https://doi.org/10.1039/C7FD00030H	journal	January 2017
Addressing the characterisation challenge to understand catalysis in MOFs: the case of nanoscale Cu supported in NU-1000 Platero-Prats, Ana E.; Li, Zhanyong; Gallington, Leighanne C. Faraday Discussions, Vol. 201 https://doi.org/10.1039/C7FD00110J	journal	January 2017
Electrospun metal–organic framework polymer composites for the catalytic degradation of methyl paraoxon McCarthy, Danielle L.; Liu, Jian; Dwyer, Derek B. New Journal of Chemistry, Vol. 41, Issue 17 https://doi.org/10.1039/C7NJ00525C	journal	January 2017
Improved activity of palladium nanoparticles using a sulfur-containing metal–organic framework as an efficient catalyst for selective aerobic oxidation in water Abedi, Sedigheh; Morsali, Ali New Journal of Chemistry, Vol. 41, Issue 13 https://doi.org/10.1039/C7NJ00709D	journal	January 2017
Size effect of the active sites in UiO-66-supported nickel catalysts synthesized via atomic layer deposition for ethylene hydrogenation Li, Zhanyong; Peters, Aaron W.; Liu, Jian Inorganic Chemistry Frontiers, Vol. 4, Issue 5 https://doi.org/10.1039/C7QI00056A	journal	January 2017
Systematic variation of the optical bandgap in titanium based isoreticular metal–organic frameworks for photocatalytic reduction of CO ₂ under blue light Logan, Matthew W.; Ayad, Suliman; Adamson, Jeremy D. Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/C7TA00437K	journal	January 2017
Photocatalytic hydrogen generation from a visible-light responsive metal–organic framework system: the impact of nickel phosphide nanoparticles Kampouri, Stavroula; Nguyen, Tu N.; Ireland, Christopher P. Journal of Materials Chemistry A, Vol. 6, Issue 6 https://doi.org/10.1039/C7TA10225A	journal	January 2018
Confinement of Fe–Al-PMOF catalytic sites favours the formation of pyrazoline from ethyl diazoacetate with an unusual sharp increase of selectivity upon recycling Abeykoon, Brian; Devic, Thomas; Grenèche, Jean-Marc Chemical Communications, Vol. 54, Issue 73 https://doi.org/10.1039/C8CC06082G	journal	January 2018
Controlled polymerizations using metal–organic frameworks Mochizuki, Shuto; Kitao, Takashi; Uemura, Takashi Chemical Communications, Vol. 54, Issue 84 https://doi.org/10.1039/C8CC06415F	journal	January 2018
Revisiting the structural homogeneity of NU-1000, a Zr-based metal–organic framework Islamoglu, Timur; Otake, Ken-ichi; Li, Peng CrystEngComm, Vol. 20, Issue 39 https://doi.org/10.1039/C8CE00455B	journal	January 2018
Co( ii )-cluster-based metal–organic frameworks as efficient heterogeneous catalysts for selective oxidation of arylalkanes Fan, Yanru; Li, Xiao; Gao, Kuan CrystEngComm, Vol. 21, Issue 10 https://doi.org/10.1039/C8CE02151A	journal	January 2019
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Carbon capture and conversion using metal–organic frameworks and MOF-based materials Ding, Meili; Flaig, Robinson W.; Jiang, Hai-Long Chemical Society Reviews, Vol. 48, Issue 10 https://doi.org/10.1039/C8CS00829A	journal	January 2019
Heterogenization of homogeneous chiral polymers in metal–organic frameworks with enhanced catalytic performance for asymmetric catalysis Dong, Xiao-Wu; Yang, Yong; Che, Jin-Xin Green Chemistry, Vol. 20, Issue 17 https://doi.org/10.1039/C8GC01323C	journal	January 2018
Encapsulation of C–N-decorated metal sub-nanoclusters/single atoms into a metal–organic framework for highly efficient catalysis Qiu, Xuan; Chen, Jianmin; Zou, Xinwei Chemical Science, Vol. 9, Issue 48 https://doi.org/10.1039/C8SC03549K	journal	January 2018
Proton transfer in hydrogen-bonded degenerate systems of water and ammonia in metal–organic frameworks Lim, Dae-Woon; Sadakiyo, Masaaki; Kitagawa, Hiroshi Chemical Science, Vol. 10, Issue 1 https://doi.org/10.1039/C8SC04475A	journal	January 2019
Charge transfer dependence on CO ₂ hydrogenation activity to methanol in Cu nanoparticles covered with metal–organic framework systems Kobayashi, Hirokazu; Taylor, Jared M.; Mitsuka, Yuko Chemical Science, Vol. 10, Issue 11 https://doi.org/10.1039/C8SC05441J	journal	January 2019
Single-site metal–organic framework catalysts for the oxidative coupling of arenes via C–H/C–H activation Van Velthoven, Niels; Waitschat, Steve; Chavan, Sachin M. Chemical Science, Vol. 10, Issue 12 https://doi.org/10.1039/C8SC05510F	journal	January 2019
Thermally induced migration of a polyoxometalate within a metal–organic framework and its catalytic effects Buru, Cassandra T.; Platero-Prats, Ana. E.; Chica, Daniel G. Journal of Materials Chemistry A, Vol. 6, Issue 17 https://doi.org/10.1039/C8TA02562B	journal	January 2018
High stability of ultra-small and isolated gold nanoparticles in metal–organic framework materials Cure, Jérémy; Mattson, Eric; Cocq, Kévin Journal of Materials Chemistry A, Vol. 7, Issue 29 https://doi.org/10.1039/C8TA12334A	journal	January 2019
Halogen bonding in UiO-66 frameworks promotes superior chemical warfare agent simulant degradation Kalaj, Mark; Momeni, Mohammad R.; Bentz, Kyle C. Chemical Communications, Vol. 55, Issue 24 https://doi.org/10.1039/C9CC00642G	journal	January 2019
MOF-templated self-polymerization of p -phenylenediamine to a polymer with a hollow box-assembled spherical structure Zhou, Chunli; Li, Ang; Wang, Dengke Chemical Communications, Vol. 55, Issue 28 https://doi.org/10.1039/C9CC01081E	journal	January 2019
MOF-derived electrocatalysts for oxygen reduction, oxygen evolution and hydrogen evolution reactions Wang, Hao-Fan; Chen, Liyu; Pang, Huan Chemical Society Reviews, Vol. 49, Issue 5 https://doi.org/10.1039/C9CS00906J	journal	January 2020
An effective strategy for creating asymmetric MOFs for chirality induction: a chiral Zr-based MOF for enantioselective epoxidation Berijani, Kayhaneh; Morsali, Ali; Hupp, Joseph T. Catalysis Science & Technology, Vol. 9, Issue 13 https://doi.org/10.1039/C9CY00565J	journal	January 2019
Network topology and cavity confinement-controlled diastereoselectivity in cyclopropanation reactions catalyzed by porphyrin-based MOFs Epp, Konstantin; Bueken, Bart; Hofmann, Benjamin J. Catalysis Science & Technology, Vol. 9, Issue 22 https://doi.org/10.1039/C9CY00893D	journal	January 2019
Cooperative catalysis at the metal–MOF interface: hydrodeoxygenation of vanillin over Pd nanoparticles covered with a UiO-66(Hf) MOF Bakuru, Vasudeva Rao; Davis, Deljo; Kalidindi, Suresh Babu Dalton Transactions, Vol. 48, Issue 24 https://doi.org/10.1039/C9DT01371G	journal	January 2019
Efficient reductive amination of HMF with well dispersed Pd nanoparticles immobilized in a porous MOF/polymer composite Karve, Vikram V.; Sun, Daniel T.; Trukhina, Olga Green Chemistry, Vol. 22, Issue 2 https://doi.org/10.1039/C9GC03140E	journal	January 2020
Investigating the origin of high efficiency in confined multienzyme catalysis Cao, Yufei; Li, Xiaoyang; Xiong, Jiarong Nanoscale, Vol. 11, Issue 45 https://doi.org/10.1039/C9NR07381G	journal	January 2019
IRMOF-74( n )–Mg: a novel catalyst series for hydrogen activation and hydrogenolysis of C–O bonds Stavila, Vitalie; Foster, Michael E.; Brown, Jonathan W. Chemical Science, Vol. 10, Issue 42 https://doi.org/10.1039/C9SC01018A	journal	January 2019
Zirconium metal–organic frameworks incorporating tetrathiafulvalene linkers: robust and redox-active matrices for in situ confinement of metal nanoparticles Su, Jian; Yuan, Shuai; Wang, Tao Chemical Science, Vol. 11, Issue 7 https://doi.org/10.1039/C9SC06009J	journal	January 2020
Engineering the pore environment of metal–organic framework membranes via modification of the secondary building unit for improved gas separation Feng, Yang; Wang, Zhikun; Fan, Weidong Journal of Materials Chemistry A, Vol. 8, Issue 26 https://doi.org/10.1039/C9TA13547B	journal	January 2020
Metal–organic framework (MOF) materials as polymerization catalysts: a review and recent advances Goetjen, Timothy A.; Liu, Jian; Wu, Yufang Chemical Communications, Vol. 56, Issue 72 https://doi.org/10.1039/D0CC03790G	journal	January 2020
Heterometal incorporation in NH ₂ -MIL-125(Ti) and its participation in the photoinduced charge-separated excited state Hanna, Lauren; Long, Conor L.; Zhang, Xiaoyi Chemical Communications, Vol. 56, Issue 78 https://doi.org/10.1039/D0CC05339B	journal	January 2020
Mechanochemistry: an efficient and versatile toolbox for synthesis, transformation, and functionalization of porous metal–organic frameworks Stolar, Tomislav; Užarević, Krunoslav CrystEngComm, Vol. 22, Issue 27 https://doi.org/10.1039/D0CE00091D	journal	January 2020
Controlling water structure and behavior: design principles from metal organic nanotubular materials Applegate, Lindsey C.; Forbes, Tori Z. CrystEngComm, Vol. 22, Issue 20 https://doi.org/10.1039/D0CE00331J	journal	January 2020
Heterogenisation of polyoxometalates and other metal-based complexes in metal–organic frameworks: from synthesis to characterisation and applications in catalysis Mialane, P.; Mellot-Draznieks, C.; Gairola, P. Chemical Society Reviews, Vol. 50, Issue 10 https://doi.org/10.1039/D0CS00323A	journal	January 2021
The chemistry and applications of hafnium and cerium( iv ) metal–organic frameworks Hu, Zhigang; Wang, Yuxiang; Zhao, Dan Chemical Society Reviews, Vol. 50, Issue 7 https://doi.org/10.1039/D0CS00920B	journal	January 2021
A historical overview of the activation and porosity of metal–organic frameworks Zhang, Xuan; Chen, Zhijie; Liu, Xinyao Chemical Society Reviews, Vol. 49, Issue 20 https://doi.org/10.1039/D0CS00997K	journal	January 2020
Silver nanoparticles stabilized by a metal–organic framework (MIL-101(Cr)) as an efficient catalyst for imine production from the dehydrogenative coupling of alcohols and amines Gumus, Ilkay; Karataş, Yaşar; Gülcan, Mehmet Catalysis Science & Technology, Vol. 10, Issue 15 https://doi.org/10.1039/D0CY00974A	journal	January 2020
The chemistry of Ce-based metal–organic frameworks Jacobsen, Jannick; Ienco, Andrea; D'Amato, Roberto Dalton Transactions, Vol. 49, Issue 46 https://doi.org/10.1039/D0DT02813D	journal	January 2020
Photoelectrochemical alcohol oxidation by mixed-linker metal–organic frameworks Lin, Shaoyang; Cairnie, Daniel R.; Davis, Dylan Faraday Discussions, Vol. 225 https://doi.org/10.1039/D0FD00021C	journal	January 2021
Mechanochemical synthesis of highly porous materials Szczęśniak, Barbara; Borysiuk, Sylwia; Choma, Jerzy Materials Horizons, Vol. 7, Issue 6 https://doi.org/10.1039/D0MH00081G	journal	January 2020
Isolating reactive metal-based species in Metal–Organic Frameworks – viable strategies and opportunities Young, Rosemary J.; Huxley, Michael T.; Pardo, Emilio Chemical Science, Vol. 11, Issue 16 https://doi.org/10.1039/D0SC00485E	journal	January 2020
A cofacial metal–organic framework based photocathode for carbon dioxide reduction Ding, Bowen; Chan, Bun; Proschogo, Nicholas Chemical Science, Vol. 12, Issue 10 https://doi.org/10.1039/D0SC04691D	journal	January 2021
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Anomaly in the Chain Length Dependence of n-Alkane Diffusion in ZIF-4 Metal-Organic Frameworks Hwang, Seungtaik; Gopalan, Arun; Hovestadt, Maximilian Molecules, Vol. 23, Issue 3 https://doi.org/10.3390/molecules23030668	journal	March 2018
Encapsulation of Metal Nanoparticles within Metal–Organic Frameworks for the Reduction of Nitro Compounds Navalón, Sergio; Álvaro, Mercedes; Dhakshinamoorthy, Amarajothi Molecules, Vol. 24, Issue 17 https://doi.org/10.3390/molecules24173050	journal	August 2019

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