Removable coatings: Thermal stability and decontamination of steel surfaces from ²⁴¹Am

Journal Article · 22 April 2022 · Chemosphere

DOI: https://doi.org/10.1016/j.chemosphere.2022.134680 · OSTI ID:1869775

Lee, Eun Hee  ^[1]; Boglaienko, Daria ^[1]; McNamara, Bruce K. ^[1]; Levitskaia, Tatiana G.  ^[1]

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1. Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

This study presents a comparative analysis of several strippable materials for decontamination of steel surfaces from ²⁴¹Am. The strippable coatings were chosen to have a history of application, to be commercially available, easily handled and have different composition and formulation. Carbon steel and stainless steel surfaces (coupons) were utilized as the most representative industrial materials, and the experimental series were expanded to include the rusting treatment of these surfaces as it is common for decommissioned old nuclear facilities. The experiments followed the path of pre-screening of the strippable materials (easiness of application, peeling etc.), their characterization with Fourier-transform infrared (FTIR) spectroscopy and thermogravimetric analysis (TGA), decontamination factors (DF) or removal efficiencies for different types of steel surfaces, and enhancement of the removal efficiencies of the select strippable coatings via amendment with EDTA. As a result, DF and removal efficiencies for stainless steel (both pristine and with rusting treatment) are higher than for pristine carbon steel, and decontamination factors and removal efficiencies are higher for pristine than for rusted carbon steel across all the coatings. It is also shown that EDTA amendment can improve DF and removal efficiency for a strippable coating (i.e., CC Strip), however other factors should also be considered. Thus, the coating CC Strip exhibited easiness in handling and high DF (up to 97% when EDTA-amended), but its drying period was the longest among the rest of the materials and its thermal decomposition indicates on a risk of intense release of heat in case of a fire event.

• Research Organization: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
• Sponsoring Organization: USDOE
• Grant/Contract Number: AC05-76RL01830
• OSTI ID: 1869775
• Report Number(s): PNNL-SA-170113
• Journal Information: Chemosphere, Journal Name: Chemosphere Vol. 301; ISSN 0045-6535
• Publisher: ElsevierCopyright Statement
• Country of Publication: United States
• Language: English