Excellent antioxidizing, thermally insulating and flame resistance silica‐polybenzoxazine aerogels for aircraft ablative materials

Xiao, Yunyun; Liu, Saihui; Hu, Yangbiao; Zhang, Sizhao; Li, Zhenquan; Li, Liangjun; Feng, Jian

doi:10.1002/app.52499

Title: Excellent antioxidizing, thermally insulating and flame resistance silica‐polybenzoxazine aerogels for aircraft ablative materials

Journal Article · 05 May 2022 · Journal of Applied Polymer Science

DOI: https://doi.org/10.1002/app.52499 · OSTI ID:1866889

Xiao, Yunyun ^[1]; Liu, Saihui ^[1]; Hu, Yangbiao ^[1];

^[1]; Li, Zhenquan ^[1]; Li, Liangjun ^[2]; Feng, Jian ^[2]

Polymer Aerogels Research Center Jiangxi University of Science and Technology Ganzhou China
Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, College of Aerospace Science and Technology, National University of Defense Technology Changsha 410073 China

Abstract High‐performance thermal protective composites with lightweight, micro‐ ablation and high‐efficient thermal insulation are urgently required for thermal protection systems in advanced hypersonic speed vehicles. However, the practical applications of thermal protective composites have long been hampered by the main issues such as low mass residual rate and poor long‐term antioxidation of the matrix in high‐temperature aerobic environments. Here, we report a novel silica‐polybenz oxazine (SiO ₂ ‐PBO) aerogels with interpenetrated networks, possessing the ability to antioxidation, thermal insulation, and flame‐retardant properties. The resulting SiO ₂ ‐PBO aerogels exhibit low density (0.25 g/cm ³ ), low thermal conductivity (0.035 W/(m·K)), and superior peak heat release rate value (15.3 W/g). Moreover, the mass residual rate is up to 70.46 wt% in the N ₂ atmosphere and remains 57.83 wt% despite existing in the air atmosphere and experiencing the highest temperature of 800°C. Briefly, SiO ₂ ‐PBO aerogels as‐prepared could be a potential matrix for a new gene ration of high‐performance thermal protective composites in the future.

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Sponsoring Organization:: USDOE

OSTI ID:: 1866889

Journal Information:: Journal of Applied Polymer Science, Journal Name: Journal of Applied Polymer Science Journal Issue: 27 Vol. 139; ISSN 0021-8995

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United States

Language:: English

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