Insights into the Enhanced Oxidative Thermal Stability of Nanoparticle Organic Hybrid Materials Developed for Carbon Capture and Energy Storage

Feric, Tony G.; Hamilton, Sara T.; Park, Ah-Hyung Alissa

doi:10.1021/acs.energyfuels.1c03243

Title: Insights into the Enhanced Oxidative Thermal Stability of Nanoparticle Organic Hybrid Materials Developed for Carbon Capture and Energy Storage

Journal Article · 21 November 2021 · Energy and Fuels

DOI: https://doi.org/10.1021/acs.energyfuels.1c03243 · OSTI ID:1865388

^[1]; Hamilton, Sara T. ^[1];

^[1]

Columbia Univ., New York, NY (United States)

Due to the growing need for Direct Air Capture (DAC) and integrated carbon capture and conversion technologies, CO₂ capture materials that can withstand a wide range of environmental conditions, including fluctuating ambient temperatures and high concentrations of oxidizing agents (i.e., oxygen and moisture), are critically needed. Liquid-like Nanoparticle Organic Hybrid Materials (NOHMs) have been proposed as candidates for DAC and electrolyte additives enabling sustainable energy storage (i.e., integrated CO₂ capture and conversion and flow batteries). Liquid-like NOHMs functionalized with an ionic bond have been shown to display greatly enhanced oxidative thermal stability compared to the untethered polymer. However, these studies were limited in terms of reaction conditions and the detailed mechanisms of the oxidative thermal degradation were not reported. In this work, a kinetic thermal degradation analysis was performed on NOHM-I-HPE and the neat polymer, Jeffamine M2070 (HPE), in both non-oxidative and oxidative conditions. NOHM-I-HPE displayed similar thermal stability to the untethered polymer in a nitrogen environment, but interestingly, the thermal stability of the ionically tethered polymer was significantly enhanced in the presence of air. This observed enhancement of oxidative thermal stability is attributed to the orders of magnitude larger viscosity of the liquid-like NOHMs compared to untethered polymer and the bond stabilization of the ionically tethered polymer in the NOHMs canopy. Further, spectroscopic analyses of the liquid residue revealed that in the presence of oxygen, the degradation of HPE and NOHM-I-HPE occurs through the formation of trace amounts of carbonyls. This study illustrated that NOHMs can serve as functional materials for sustainable energy storage applications because of their excellent oxidative thermal stability.

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Research Organization:: Case Western Reserve Univ., Cleveland, OH (United States); Energy Frontier Research Centers (EFRC) (United States). Breakthrough Electrolytes for Energy Storage (BEES)

Sponsoring Organization:: Shell’s Long Range Research and Experimentation (LRRE) Program; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019409

OSTI ID:: 1865388

Journal Information:: Energy and Fuels, Vol. 35, Issue 23; ISSN 0887-0624

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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