Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Review of modification strategies in emerging inorganic solid-state electrolytes for lithium, sodium, and potassium batteries

Abstract

The design of solid-state electrolyte (SSE) entails controlling not only its bulk structure but also the internal (e.g., grain boundary and pore) and heterophase (e.g., anode-SSE reaction layer) interfaces. Moreover, defects are integral for establishing both the initial all-solid-state battery (ASSB) cell performance and its ultimate cycling lifetime. This topical review discusses 5 highly promising inorganic lithium-, sodium-, and potassium-based SSEs, providing case studies of strategies to enhance ionic conductivity, tune the internal and heterophase interfaces, and prevent dendrites and deleterious side reactions. The primary focus is on garnet LLZO (Li7La3Zr2O12), argyrodite (Li6AS5X, A = P, Sb and X = Cl, Br, I), Na3AB4 (A = P, Sb, As and B = S, Se), and NASICON-type electrolytes, with several exploratory potassium systems being presented as well. The article begins with a discussion of the superionic conduction mechanisms, which is assisted by defects, topology, correlation, and disorder. The discussion then shifts to the thermodynamic or kinetic phase stability of metastable SSEs, followed by the SSE internal interfaces (pores and grain boundaries), and finally the complex microstructure associated with the reactive boundaries between the SSE and the metal anode and the SSE and the high-voltage ceramic cathode. This review explores why SSEmore » systems with highly promising bulk ionic conductivity values do not demonstrate comparable performance in full cells. Additionally, a major cause is the cycling-induced formation of ionically insulating but electrically conducting new phases at both the anode and the cathode. For the SSEs that do not rapidly decompose when contacting the anode, site-specific variations in ionic conductivity/electrical resistivity lead to growth of metal dendrites. In each electrolyte class, creative fabrication strategies have been employed to minimize, but not fully eliminate, new phase formation and dendrites, creating ample opportunities for additional analytical and synthesis-focused research. The emphasis of the discussion is on the bulk doping strategies for SSEs, emerging simulation and characterization findings in relation to SSE performance and cell failure, and new synthesis approaches and cell architectures to improve cycling stability. Throughout the article, outstanding scientific questions are identified, and future research directions are proposed.« less

Authors:
; ; ; ; ; ;
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; National Science Foundation (NSF); USDOE Office of Electricity (OE)
OSTI Identifier:
1962248
Alternate Identifier(s):
OSTI ID: 1864430
Grant/Contract Number:  
AC0500OR22725; AC02-05CH11231; EE0008865; FG02-96ER45579; AC05-00OR22725; 1938833
Resource Type:
Published Article
Journal Name:
Joule
Additional Journal Information:
Journal Name: Joule Journal Volume: 6 Journal Issue: 3; Journal ID: ISSN 2542-4351
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; solid-state electrolytes; all-solid-state batteries; lithium-ion batteries; sodium-ion batteries; potassium-ion batteries; garnet Li7La3Zr2O12; Li-argyrodite Li6AS5X; Na3AB4; NASICON; grain boundary; interface; phase transition

Citation Formats

Feng, Xuyong, Fang, Hong, Wu, Nan, Liu, Pengcheng, Jena, Puru, Nanda, Jagjit, and Mitlin, David. Review of modification strategies in emerging inorganic solid-state electrolytes for lithium, sodium, and potassium batteries. United States: N. p., 2022. Web. doi:10.1016/j.joule.2022.01.015.
Copy to clipboard
Feng, Xuyong, Fang, Hong, Wu, Nan, Liu, Pengcheng, Jena, Puru, Nanda, Jagjit, & Mitlin, David. Review of modification strategies in emerging inorganic solid-state electrolytes for lithium, sodium, and potassium batteries. United States. https://doi.org/10.1016/j.joule.2022.01.015
Copy to clipboard
Feng, Xuyong, Fang, Hong, Wu, Nan, Liu, Pengcheng, Jena, Puru, Nanda, Jagjit, and Mitlin, David. Tue . "Review of modification strategies in emerging inorganic solid-state electrolytes for lithium, sodium, and potassium batteries". United States. https://doi.org/10.1016/j.joule.2022.01.015.
Copy to clipboard
@article{osti_1962248,
title = {Review of modification strategies in emerging inorganic solid-state electrolytes for lithium, sodium, and potassium batteries},
author = {Feng, Xuyong and Fang, Hong and Wu, Nan and Liu, Pengcheng and Jena, Puru and Nanda, Jagjit and Mitlin, David},
abstractNote = {The design of solid-state electrolyte (SSE) entails controlling not only its bulk structure but also the internal (e.g., grain boundary and pore) and heterophase (e.g., anode-SSE reaction layer) interfaces. Moreover, defects are integral for establishing both the initial all-solid-state battery (ASSB) cell performance and its ultimate cycling lifetime. This topical review discusses 5 highly promising inorganic lithium-, sodium-, and potassium-based SSEs, providing case studies of strategies to enhance ionic conductivity, tune the internal and heterophase interfaces, and prevent dendrites and deleterious side reactions. The primary focus is on garnet LLZO (Li7La3Zr2O12), argyrodite (Li6AS5X, A = P, Sb and X = Cl, Br, I), Na3AB4 (A = P, Sb, As and B = S, Se), and NASICON-type electrolytes, with several exploratory potassium systems being presented as well. The article begins with a discussion of the superionic conduction mechanisms, which is assisted by defects, topology, correlation, and disorder. The discussion then shifts to the thermodynamic or kinetic phase stability of metastable SSEs, followed by the SSE internal interfaces (pores and grain boundaries), and finally the complex microstructure associated with the reactive boundaries between the SSE and the metal anode and the SSE and the high-voltage ceramic cathode. This review explores why SSE systems with highly promising bulk ionic conductivity values do not demonstrate comparable performance in full cells. Additionally, a major cause is the cycling-induced formation of ionically insulating but electrically conducting new phases at both the anode and the cathode. For the SSEs that do not rapidly decompose when contacting the anode, site-specific variations in ionic conductivity/electrical resistivity lead to growth of metal dendrites. In each electrolyte class, creative fabrication strategies have been employed to minimize, but not fully eliminate, new phase formation and dendrites, creating ample opportunities for additional analytical and synthesis-focused research. The emphasis of the discussion is on the bulk doping strategies for SSEs, emerging simulation and characterization findings in relation to SSE performance and cell failure, and new synthesis approaches and cell architectures to improve cycling stability. Throughout the article, outstanding scientific questions are identified, and future research directions are proposed.},
doi = {10.1016/j.joule.2022.01.015},
journal = {Joule},
number = 3,
volume = 6,
place = {United States},
year = {Tue Mar 01 00:00:00 EST 2022},
month = {Tue Mar 01 00:00:00 EST 2022}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1016/j.joule.2022.01.015
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Revealing the Impact of Space-Charge Layers on the Li-Ion Transport in All-Solid-State Batteries
journal, June 2020

Mechanistic Insights into Fast Charging and Discharging of the Sodium Metal Battery Anode: A Comparison with Lithium
journal, August 2021

  • Zhong, Yiren; Shi, Qiuwei; Zhu, Chongqin
  • Journal of the American Chemical Society, Vol. 143, Issue 34
  • DOI: 10.1021/jacs.1c06794

Nanoconfined LiBH 4 as a Fast Lithium Ion Conductor
journal, October 2014

  • Blanchard, Didier; Nale, Angeloclaudio; Sveinbjörnsson, Dadi
  • Advanced Functional Materials, Vol. 25, Issue 2
  • DOI: 10.1002/adfm.201402538

Manufacturing scalability implications of materials choice in inorganic solid-state batteries
journal, March 2021

Tunable Lithium-Ion Transport in Mixed-Halide Argyrodites Li 6– x PS 5– x ClBr x : An Unusual Compositional Space
journal, February 2021

Physicochemical Concepts of the Lithium Metal Anode in Solid-State Batteries
journal, July 2020

Size-controlled stabilization of the superionic phase to room temperature in polymer-coated AgI nanoparticles
journal, May 2009

  • Makiura, Rie; Yonemura, Takayuki; Yamada, Teppei
  • Nature Materials, Vol. 8, Issue 6
  • DOI: 10.1038/nmat2449

Interface-enhanced Li ion conduction in a LiBH 4 –SiO 2 solid electrolyte
journal, January 2016

  • Choi, Yong Seok; Lee, Young-Su; Oh, Kyu Hwan
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 32
  • DOI: 10.1039/C6CP03563A

Progress toward Solid State Synthesis by Design
journal, October 2018

A High‐Performance Monolithic Solid‐State Sodium Battery with Ca 2+ Doped Na 3 Zr 2 Si 2 PO 12 Electrolyte
journal, June 2019

Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations
journal, October 2015

  • Zhu, Yizhou; He, Xingfeng; Mo, Yifei
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 42
  • DOI: 10.1021/acsami.5b07517

Enabling “lithium-free” manufacturing of pure lithium metal solid-state batteries through in situ plating
journal, October 2020

Quasi-Solid Electrolytes for High Temperature Lithium Ion Batteries
journal, November 2015

  • Kalaga, Kaushik; Rodrigues, Marco-Tulio F.; Gullapalli, Hemtej
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 46
  • DOI: 10.1021/acsami.5b07636

From Liquid- to Solid-State Batteries: Ion Transfer Kinetics of Heteroionic Interfaces
journal, March 2020

  • Weiss, Manuel; Simon, Fabian J.; Busche, Martin R.
  • Electrochemical Energy Reviews, Vol. 3, Issue 2
  • DOI: 10.1007/s41918-020-00062-7

Structure, Chemistry, and Charge Transfer Resistance of the Interface between Li 7 La 3 Zr 2 O 12 Electrolyte and LiCoO 2 Cathode
journal, July 2018

Characterizing the Li–Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density
journal, January 2016

Solid state chemistry for developing better metal-ion batteries
journal, October 2020

  • Abakumov, Artem M.; Fedotov, Stanislav S.; Antipov, Evgeny V.
  • Nature Communications, Vol. 11, Issue 1
  • DOI: 10.1038/s41467-020-18736-7

Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte
journal, January 2017

Single-step synthesis of highly conductive Na3PS4 solid electrolyte for sodium all solid-state batteries
journal, September 2019

High-purity electrolytic lithium obtained from low-purity sources using solid electrolyte
journal, March 2020

Homogeneous Na+ transfer dynamic at Na/Na3Zr2Si2PO12 interface for all solid-state sodium metal batteries
journal, October 2021

Na 3 SbS 4 : A Solution Processable Sodium Superionic Conductor for All-Solid-State Sodium-Ion Batteries
journal, July 2016

  • Banerjee, Abhik; Park, Kern Ho; Heo, Jongwook W.
  • Angewandte Chemie International Edition, Vol. 55, Issue 33
  • DOI: 10.1002/anie.201604158

Li 10 Ge(P 1– x Sb x ) 2 S 12 Lithium-Ion Conductors with Enhanced Atmospheric Stability
journal, January 2020

Superionics: crystal structures and conduction processes
journal, June 2004

Facile Synthesis toward the Optimal Structure-Conductivity Characteristics of the Argyrodite Li 6 PS 5 Cl Solid-State Electrolyte
journal, September 2018

  • Yu, Chuang; Ganapathy, Swapna; Hageman, Jart
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 39
  • DOI: 10.1021/acsami.8b07476

Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review
journal, July 2017

Reducing Interfacial Resistance between Garnet-Structured Solid-State Electrolyte and Li-Metal Anode by a Germanium Layer
journal, April 2017

Observation of Chemomechanical Failure and the Influence of Cutoff Potentials in All-Solid-State Li–S Batteries
journal, March 2019

Superionic glass-ceramic electrolytes for room-temperature rechargeable sodium batteries
journal, January 2012

  • Hayashi, Akitoshi; Noi, Kousuke; Sakuda, Atsushi
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms1843

Synthesis and structure analysis of tetragonal Li7La3Zr2O12 with the garnet-related type structure
journal, August 2009

  • Awaka, Junji; Kijima, Norihito; Hayakawa, Hiroshi
  • Journal of Solid State Chemistry, Vol. 182, Issue 8, p. 2046-2052
  • DOI: 10.1016/j.jssc.2009.05.020

Vacancy-Driven Na + Superionic Conduction in New Ca-Doped Na 3 PS 4 for All-Solid-State Na-Ion Batteries
journal, September 2018

Inducing High Ionic Conductivity in the Lithium Superionic Argyrodites Li 6+ x P 1– x Ge x S 5 I for All-Solid-State Batteries
journal, October 2018

  • Kraft, Marvin A.; Ohno, Saneyuki; Zinkevich, Tatiana
  • Journal of the American Chemical Society, Vol. 140, Issue 47
  • DOI: 10.1021/jacs.8b10282

Electrolyte and Interface Engineering for Solid-State Sodium Batteries
journal, September 2018

Crystal Chemistry and Stability of “Li7La3Zr2O12 ” Garnet: A Fast Lithium-Ion Conductor
journal, February 2011

  • Geiger, Charles A.; Alekseev, Evgeny; Lazic, Biljana
  • Inorganic Chemistry, Vol. 50, Issue 3, p. 1089-1097
  • DOI: 10.1021/ic101914e

Lithium-ion conducting oxide single crystal as solid electrolyte for advanced lithium battery application
journal, July 2018

Critical stripping current leads to dendrite formation on plating in lithium anode solid electrolyte cells
journal, July 2019

  • Kasemchainan, Jitti; Zekoll, Stefanie; Spencer Jolly, Dominic
  • Nature Materials, Vol. 18, Issue 10
  • DOI: 10.1038/s41563-019-0438-9

Synthesis, structure determination, and ionic conductivity of sodium tetrathiophosphate
journal, July 1992

Multi-Scale Mechanical Behavior of the Li 3 PS 4 Solid-Phase Electrolyte
journal, October 2016

  • Baranowski, Lauryn L.; Heveran, Chelsea M.; Ferguson, Virginia L.
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 43
  • DOI: 10.1021/acsami.6b06612

Phase evolution during lithium–indium halide superionic conductor dehydration
journal, January 2021

  • Sacci, Robert L.; Bennett, Tyler H.; Drews, Andrew R.
  • Journal of Materials Chemistry A, Vol. 9, Issue 2
  • DOI: 10.1039/D0TA10012A

Grain Boundary Contributions to Li-Ion Transport in the Solid Electrolyte Li 7 La 3 Zr 2 O 12 (LLZO)
journal, November 2017

Unlocking the Energy Capabilities of Lithium Metal Electrode with Solid-State Electrolytes
journal, September 2018

Current limit diagrams for dendrite formation in solid-state electrolytes for Li-ion batteries
journal, March 2017

Nanostructured Silicon–Carbon 3D Electrode Architectures for High-Performance Lithium-Ion Batteries
journal, August 2018

Garnet-Type Solid-State Electrolytes: Materials, Interfaces, and Batteries
journal, April 2020

Diffusion Mechanism of the Sodium-Ion Solid Electrolyte Na 3 PS 4 and Potential Improvements of Halogen Doping
journal, April 2016

Enhanced Ion Conduction in Li 2.5 Zn 0.25 PS 4 via Anion Doping
journal, March 2020

Toward High‐Energy‐Density Lithium Metal Batteries: Opportunities and Challenges for Solid Organic Electrolytes
journal, January 2020

  • Wang, Xiaoen; Kerr, Robert; Chen, Fangfang
  • Advanced Materials, Vol. 32, Issue 18
  • DOI: 10.1002/adma.201905219

A New Family of Fast Sodium Ion Conductors: Na 2 M 2 TeO 6 (M = Ni, Co, Zn, Mg)
journal, March 2011

  • Evstigneeva, Maria A.; Nalbandyan, Vladimir B.; Petrenko, Aleksandr A.
  • Chemistry of Materials, Vol. 23, Issue 5
  • DOI: 10.1021/cm102629g

Effect of Pore Connectivity on Li Dendrite Propagation within LLZO Electrolytes Observed with Synchrotron X-ray Tomography
journal, March 2018

Halide-Stabilized LiBH 4 , a Room-Temperature Lithium Fast-Ion Conductor
journal, January 2009

  • Maekawa, Hideki; Matsuo, Motoaki; Takamura, Hitoshi
  • Journal of the American Chemical Society, Vol. 131, Issue 3
  • DOI: 10.1021/ja807392k

Na 2.44 Mn 1.79 (SO 4 ) 3 : a new member of the alluaudite family of insertion compounds for sodium ion batteries
journal, January 2015

  • Dwibedi, Debasmita; Araujo, Rafael B.; Chakraborty, Sudip
  • Journal of Materials Chemistry A, Vol. 3, Issue 36
  • DOI: 10.1039/C5TA04527D

Investigation of Complex Intermediates in Solvent-Mediated Synthesis of Thiophosphate Solid-State Electrolytes
journal, December 2020

  • Delnick, Frank M.; Yang, Guang; Self, Ethan C.
  • The Journal of Physical Chemistry C, Vol. 124, Issue 50
  • DOI: 10.1021/acs.jpcc.0c08761

Anomalous High Ionic Conductivity of Nanoporous β-Li3PS4
journal, January 2013

  • Liu, Zengcai; Fu, Wujun; Payzant, E. Andrew
  • Journal of the American Chemical Society, Vol. 135, Issue 3, p. 975-978
  • DOI: 10.1021/ja3110895

Defect-Mediated Conductivity Enhancements in Na 3– x Pn 1– x W x S 4 (Pn = P, Sb) Using Aliovalent Substitutions
journal, November 2019

Unravelling Li-Ion Transport from Picoseconds to Seconds: Bulk versus Interfaces in an Argyrodite Li 6 PS 5 Cl–Li 2 S All-Solid-State Li-Ion Battery
journal, August 2016

  • Yu, Chuang; Ganapathy, Swapna; de Klerk, Niek J. J.
  • Journal of the American Chemical Society, Vol. 138, Issue 35
  • DOI: 10.1021/jacs.6b05066

Probing Solid–Solid Interfacial Reactions in All-Solid-State Sodium-Ion Batteries with First-Principles Calculations
journal, December 2017

Interface Aspects in All‐Solid‐State Li‐Based Batteries Reviewed
journal, February 2021

  • Chen, Chunguang; Jiang, Ming; Zhou, Tao
  • Advanced Energy Materials, Vol. 11, Issue 13
  • DOI: 10.1002/aenm.202003939

Synthesis and Properties of a Photopatternable Lithium-Ion Conducting Solid Electrolyte
journal, November 2017

  • Choi, Christopher S.; Lau, Jonathan; Hur, Janet
  • Advanced Materials, Vol. 30, Issue 1
  • DOI: 10.1002/adma.201703772

The influence of silica surface groups on the Li-ion conductivity of LiBH 4 /SiO 2 nanocomposites
journal, January 2019

  • Ngene, Peter; Lambregts, Sander F. H.; Blanchard, Didier
  • Physical Chemistry Chemical Physics, Vol. 21, Issue 40
  • DOI: 10.1039/C9CP04235K

Review on solid electrolytes for all-solid-state lithium-ion batteries
journal, June 2018

First-Principles Calculation Study of Na + Superionic Conduction Mechanism in W- and Mo-Doped Na 3 SbS 4 Solid Electrolytes
journal, September 2020

Interfacial Electronic Properties Dictate Li Dendrite Growth in Solid Electrolytes
journal, August 2019

Room temperature elastic moduli and Vickers hardness of hot-pressed LLZO cubic garnet
journal, July 2012

  • Ni, Jennifer E.; Case, Eldon D.; Sakamoto, Jeffrey S.
  • Journal of Materials Science, Vol. 47, Issue 23, p. 7978-7985
  • DOI: 10.1007/s10853-012-6687-5

A K 2 Fe 4 O 7 superionic conductor for all-solid-state potassium metal batteries
journal, January 2018

  • Yuan, Hongming; Li, He; Zhang, Tingsong
  • Journal of Materials Chemistry A, Vol. 6, Issue 18
  • DOI: 10.1039/C8TA01418C

Stabilizing a High-Energy-Density Rechargeable Sodium Battery with a Solid Electrolyte
journal, April 2018

NMR relaxometry as a versatile tool to study Li ion dynamics in potential battery materials
journal, April 2012

Opportunities for Rechargeable Solid-State Batteries Based on Li-Intercalation Cathodes
journal, November 2018

Synthesis of cubic Na3SbS4 solid electrolyte with enhanced ion transport for all-solid-state sodium-ion batteries
journal, January 2018

Reactivity-Guided Interface Design in Na Metal Solid-State Batteries
journal, April 2019

Beyond Lithium Ion Batteries
journal, January 2015

  • Luntz, Alan
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 2
  • DOI: 10.1021/jz502665r

Interfaces and Interphases in All-Solid-State Batteries with Inorganic Solid Electrolytes
journal, June 2020

Accessing the bottleneck in all-solid state batteries, lithium-ion transport over the solid-electrolyte-electrode interface
journal, October 2017

Ultrastable All-Solid-State Sodium Rechargeable Batteries
journal, August 2020

Design Strategies to Enable the Efficient Use of Sodium Metal Anodes in High‐Energy Batteries
journal, October 2019

Influence of Lattice Polarizability on the Ionic Conductivity in the Lithium Superionic Argyrodites Li 6 PS 5 X (X = Cl, Br, I)
journal, July 2017

  • Kraft, Marvin A.; Culver, Sean P.; Calderon, Mario
  • Journal of the American Chemical Society, Vol. 139, Issue 31
  • DOI: 10.1021/jacs.7b06327

Comprehensive Investigation into Garnet Electrolytes Toward Application-Oriented Solid Lithium Batteries
journal, July 2020

Solid-state thin-film rechargeable batteries
journal, February 2005

Incorporating the Nanoscale Encapsulation Concept from Liquid Electrolytes into Solid-State Lithium–Sulfur Batteries
journal, June 2020

Challenges for and Pathways toward Li-Metal-Based All-Solid-State Batteries
journal, March 2021

Sodium Superionic Conductors Based on Clusters
journal, December 2018

Lightest Borohydride Probed by Synchrotron X-ray Diffraction: Experiment Calls for a New Theoretical Revision
journal, June 2008

  • Filinchuk, Yaroslav; Chernyshov, Dmitry; Cerny, Radovan
  • The Journal of Physical Chemistry C, Vol. 112, Issue 28
  • DOI: 10.1021/jp8025623

Superionic Conductivity in Lithium-Rich Anti-Perovskites
journal, August 2012

  • Zhao, Yusheng; Daemen, Luke L.
  • Journal of the American Chemical Society, Vol. 134, Issue 36
  • DOI: 10.1021/ja305709z

Silicon-based anodes for lithium-ion batteries: Effectiveness of materials synthesis and electrode preparation
journal, September 2016

High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes
journal, January 2019

Low temperature and rapid microwave sintering of Na3Zr2Si2PO12 solid electrolytes for Na-Ion batteries
journal, January 2021

Dopant‐Dependent Stability of Garnet Solid Electrolyte Interfaces with Lithium Metal
journal, January 2019

  • Zhu, Yisi; Connell, Justin G.; Tepavcevic, Sanja
  • Advanced Energy Materials, Vol. 9, Issue 12
  • DOI: 10.1002/aenm.201803440

Development of an all-solid-state lithium battery by slurry-coating procedures using a sulfidic electrolyte
journal, February 2019

Rapid Thermal Annealing of Cathode-Garnet Interface toward High-Temperature Solid State Batteries
journal, July 2017

Elucidating the mobility of H + and Li + ions in (Li 6.25−x H x Al 0.25 )La 3 Zr 2 O 12 via correlative neutron and electron spectroscopy
journal, January 2019

  • Liu, Xiaoming; Chen, Yan; Hood, Zachary D.
  • Energy & Environmental Science, Vol. 12, Issue 3
  • DOI: 10.1039/C8EE02981D

Electrolytes and Interphases in Sodium‐Based Rechargeable Batteries: Recent Advances and Perspectives
journal, April 2020

  • Eshetu, Gebrekidan Gebresilassie; Elia, Giuseppe Antonio; Armand, Michel
  • Advanced Energy Materials, Vol. 10, Issue 20
  • DOI: 10.1002/aenm.202000093

Enhanced ion conduction by enforcing structural disorder in Li-deficient argyrodites Li6−xPS5−xCl1+x
journal, September 2020

Crystal Structure of Fast Lithium-ion-conducting Cubic Li 7 La 3 Zr 2 O 12
journal, January 2011

  • Awaka, Junji; Takashima, Akira; Kataoka, Kunimitsu
  • Chemistry Letters, Vol. 40, Issue 1
  • DOI: 10.1246/cl.2011.60

Interfacial Stability of Li Metal–Solid Electrolyte Elucidated via in Situ Electron Microscopy
journal, October 2016

Classical and Emerging Characterization Techniques for Investigation of Ion Transport Mechanisms in Crystalline Fast Ionic Conductors
journal, April 2020

The Thermal Stability of Lithium Solid Electrolytes with Metallic Lithium
journal, April 2020

The 2021 battery technology roadmap
journal, February 2021

  • Ma, Jianmin; Li, Yutao; Grundish, Nicholas S.
  • Journal of Physics D: Applied Physics, Vol. 54, Issue 18
  • DOI: 10.1088/1361-6463/abd353

Addressing Interfacial Issues in Liquid-Based and Solid-State Batteries by Atomic and Molecular Layer Deposition
journal, December 2018

Ultrastable Anode Interface Achieved by Fluorinating Electrolytes for All-Solid-State Li Metal Batteries
journal, March 2020

Superionic conductivity in lithium argyrodite solid-state electrolyte by controlled Cl-doping
journal, March 2020

Solid Electrolyte Interphases on Sodium Metal Anodes
journal, September 2020

  • Bao, Changyuan; Wang, Bo; Liu, Peng
  • Advanced Functional Materials, Vol. 30, Issue 52
  • DOI: 10.1002/adfm.202004891

Tape‐Casting Li 0.34 La 0.56 TiO 3 Ceramic Electrolyte Films Permit High Energy Density of Lithium‐Metal Batteries
journal, November 2019

  • Jiang, Zhouyang; Wang, Suqing; Chen, Xinzhi
  • Advanced Materials, Vol. 32, Issue 6
  • DOI: 10.1002/adma.201906221

Lithium-Ion Battery Supply Chain Considerations: Analysis of Potential Bottlenecks in Critical Metals
journal, October 2017

Fundamentals of inorganic solid-state electrolytes for batteries
journal, August 2019

  • Famprikis, Theodosios; Canepa, Pieremanuele; Dawson, James A.
  • Nature Materials, Vol. 18, Issue 12
  • DOI: 10.1038/s41563-019-0431-3

Surface Chemistry Mechanism of Ultra-Low Interfacial Resistance in the Solid-State Electrolyte Li 7 La 3 Zr 2 O 12
journal, September 2017

New Insights into the Interphase between the Na Metal Anode and Sulfide Solid-State Electrolytes: A Joint Experimental and Computational Study
journal, March 2018

  • Wu, Erik A.; Kompella, Christopher S.; Zhu, Zhuoying
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 12
  • DOI: 10.1021/acsami.7b19037

Computational Screening of Cathode Coatings for Solid-State Batteries
journal, May 2019

Promise and reality of post-lithium-ion batteries with high energy densities
journal, March 2016

Data-Driven Safety Envelope of Lithium-Ion Batteries for Electric Vehicles
journal, November 2019

Frontiers of solid-state batteries
journal, October 2018

  • Nanda, Jagjit; Wang, Chongmin; Liu, Ping
  • MRS Bulletin, Vol. 43, Issue 10
  • DOI: 10.1557/mrs.2018.234

Emerging Potassium Metal Anodes: Perspectives on Control of the Electrochemical Interfaces
journal, May 2020

Energy storage emerging: A perspective from the Joint Center for Energy Storage Research
journal, June 2020

  • Trahey, Lynn; Brushett, Fikile R.; Balsara, Nitash P.
  • Proceedings of the National Academy of Sciences, Vol. 117, Issue 23
  • DOI: 10.1073/pnas.1821672117

Fast Na+-ion transport in skeleton structures
journal, February 1976

Performance and cost of materials for lithium-based rechargeable automotive batteries
journal, April 2018

Electrolyte/Electrode Interfaces in All-Solid-State Lithium Batteries: A Review
journal, April 2021

Liquid Alloy Enabled Solid‐State Batteries for Conformal Electrode–Electrolyte Interfaces
journal, February 2021

  • Guo, Xuelin; Bae, Jiwoong; Ding, Yu
  • Advanced Functional Materials, Vol. 31, Issue 17
  • DOI: 10.1002/adfm.202010863

New horizons for inorganic solid state ion conductors
journal, January 2018

  • Zhang, Zhizhen; Shao, Yuanjun; Lotsch, Bettina
  • Energy & Environmental Science, Vol. 11, Issue 8
  • DOI: 10.1039/C8EE01053F

Transitioning solid-state batteries from lab to market: Linking electro-chemo-mechanics with practical considerations
journal, June 2021

Controlling Ionic Transport through the PEO-LiTFSI/LLZTO Interface
journal, January 2019

  • Gupta, Arushi; Sakamoto, Jeff
  • The Electrochemical Society Interface, Vol. 28, Issue 2
  • DOI: 10.1149/2.F06192if

Exceptional Superionic Conductivity in Disordered Sodium Decahydro- closo -decaborate
journal, October 2014

  • Udovic, Terrence J.; Matsuo, Motoaki; Tang, Wan Si
  • Advanced Materials, Vol. 26, Issue 45
  • DOI: 10.1002/adma.201403157

Assessment of utility energy storage options for increased renewable energy penetration
journal, August 2012

  • Evans, Annette; Strezov, Vladimir; Evans, Tim J.
  • Renewable and Sustainable Energy Reviews, Vol. 16, Issue 6
  • DOI: 10.1016/j.rser.2012.03.048

Interface Stability of Argyrodite Li 6 PS 5 Cl toward LiCoO 2 , LiNi 1/3 Co 1/3 Mn 1/3 O 2 , and LiMn 2 O 4 in Bulk All-Solid-State Batteries
journal, April 2017

Room-Temperature All-solid-state Rechargeable Sodium-ion Batteries with a Cl-doped Na3PS4 Superionic Conductor
journal, September 2016

  • Chu, Iek-Heng; Kompella, Christopher S.; Nguyen, Han
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep33733

Chemical stability of Nasicon
journal, February 1982

Computation-Accelerated Design of Materials and Interfaces for All-Solid-State Lithium-Ion Batteries
journal, October 2018

First Principles Study of the Li10GeP2S12 Lithium Super Ionic Conductor Material
journal, December 2011

  • Mo, Yifei; Ong, Shyue Ping; Ceder, Gerbrand
  • Chemistry of Materials, Vol. 24, Issue 1, p. 15-17
  • DOI: 10.1021/cm203303y

Solid Garnet Batteries
journal, May 2019

Sodium Ion Diffusion in Nasicon (Na 3 Zr 2 Si 2 PO 12 ) Solid Electrolytes: Effects of Excess Sodium
journal, October 2016

  • Park, Heetaek; Jung, Keeyoung; Nezafati, Marjan
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 41
  • DOI: 10.1021/acsami.6b09992

Molecular design for electrolyte solvents enabling energy-dense and long-cycling lithium metal batteries
journal, June 2020

Structural Investigation of Monoclinic‐Rhombohedral Phase Transition in Na 3 Zr 2 Si 2 PO 12 and Doped NASICON
journal, June 2015

  • Jolley, Adam G.; Taylor, Daniel D.; Schreiber, Nathaniel J.
  • Journal of the American Ceramic Society, Vol. 98, Issue 9
  • DOI: 10.1111/jace.13692

Structure and Dynamics — An Atomic View of Materials
journal, June 2003

Recent Progress in Graphite Intercalation Compounds for Rechargeable Metal (Li, Na, K, Al)-Ion Batteries
journal, June 2017

Nanoscale Mapping of Extrinsic Interfaces in Hybrid Solid Electrolytes
journal, January 2020

Protected Lithium-Metal Anodes in Batteries: From Liquid to Solid
journal, July 2017

Fabrication and performances of all solid-state symmetric sodium battery based on NASICON-related compounds
journal, July 2013

Li-ion battery materials: present and future
journal, June 2015

Ionic Conductivities and Melting Transition Studies of NaBHM 4 , KBH 4 , and Their Mixtures
journal, September 2019

A New General Paradigm for Understanding and Preventing Li Metal Penetration through Solid Electrolytes
journal, December 2020

Local Tetragonal Structure of the Cubic Superionic Conductor Na 3 PS 4
journal, March 2018

Challenges and opportunities towards fast-charging battery materials
journal, June 2019

Vacancy-Contained Tetragonal Na 3 SbS 4 Superionic Conductor
journal, April 2016

Boosting Solid‐State Diffusivity and Conductivity in Lithium Superionic Argyrodites by Halide Substitution
journal, May 2019

  • Adeli, Parvin; Bazak, J. David; Park, Kern Ho
  • Angewandte Chemie, Vol. 131, Issue 26
  • DOI: 10.1002/ange.201814222

New Family of Argyrodite Thioantimonate Lithium Superionic Conductors
journal, October 2019

  • Zhou, Laidong; Assoud, Abdeljalil; Zhang, Qiang
  • Journal of the American Chemical Society, Vol. 141, Issue 48
  • DOI: 10.1021/jacs.9b08357

High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes
journal, March 2020

Anode-free, Lean-Electrolyte Lithium-Sulfur Batteries Enabled by Tellurium-Stabilized Lithium Deposition
journal, May 2020

Protons Enhance Conductivities in Lithium Halide Hydroxide/Lithium Oxyhalide Solid Electrolytes by Forming Rotating Hydroxy Groups
journal, December 2017

  • Song, Ah-Young; Xiao, Yiran; Turcheniuk, Kostiantyn
  • Advanced Energy Materials, Vol. 8, Issue 3
  • DOI: 10.1002/aenm.201700971

Gradiently Sodiated Alucone as an Interfacial Stabilizing Strategy for Solid‐State Na Metal Batteries
journal, April 2020

  • Zhang, Shumin; Zhao, Yang; Zhao, Feipeng
  • Advanced Functional Materials, Vol. 30, Issue 22
  • DOI: 10.1002/adfm.202001118

Interface Issues and Challenges in All‐Solid‐State Batteries: Lithium, Sodium, and Beyond
journal, July 2020

Batteries and fuel cells for emerging electric vehicle markets
journal, April 2018

Compatibility issues between electrodes and electrolytes in solid-state batteries
journal, January 2017

  • Tian, Yaosen; Shi, Tan; Richards, William D.
  • Energy & Environmental Science, Vol. 10, Issue 5
  • DOI: 10.1039/C7EE00534B

Interfacial Reactions and Performance of Li 7 La 3 Zr 2 O 12 -Stabilized Li–Sulfur Hybrid Cell
journal, October 2019

  • Naguib, Michael; Sharafi, Asma; Self, Ethan C.
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 45
  • DOI: 10.1021/acsami.9b11439

The origin of high electrolyte–electrode interfacial resistances in lithium cells containing garnet type solid electrolytes
journal, January 2014

  • Cheng, Lei; Crumlin, Ethan J.; Chen, Wei
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 34
  • DOI: 10.1039/C4CP02921F

Lithium-Metal Growth Kinetics on LLZO Garnet-Type Solid Electrolytes
journal, August 2019

Lithium Argyrodites with Phosphorus and Arsenic: Order and Disorder of Lithium Atoms, Crystal Chemistry, and Phase Transitions
journal, February 2010

  • Kong, Shiao-Tong; Deiseroth, Hans-Jörg; Reiner, Christof
  • Chemistry - A European Journal, Vol. 16, Issue 7
  • DOI: 10.1002/chem.200902470

Exceptionally High Ionic Conductivity in Na 3 P 0.62 As 0.38 S 4 with Improved Moisture Stability for Solid-State Sodium-Ion Batteries
journal, February 2017

  • Yu, Zhaoxin; Shang, Shun-Li; Seo, Joo-Hwan
  • Advanced Materials, Vol. 29, Issue 16
  • DOI: 10.1002/adma.201605561

Chemical Evolution in Silicon–Graphite Composite Anodes Investigated by Vibrational Spectroscopy
journal, May 2018

  • Ruther, Rose E.; Hays, Kevin A.; An, Seong Jin
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 22
  • DOI: 10.1021/acsami.8b02197

All-Solid-State Batteries Using Rationally Designed Garnet Electrolyte Frameworks
journal, December 2019

  • Yi, Eongyu; Shen, Hao; Heywood, Stephen
  • ACS Applied Energy Materials, Vol. 3, Issue 1
  • DOI: 10.1021/acsaem.9b02101

Characterizing the Li-Solid-Electrolyte Interface Dynamics as a Function of Stack Pressure and Current Density
journal, September 2019

Design and synthesis of room temperature stable Li-argyrodite superionic conductors via cation doping
journal, January 2019

  • Zhang, Zhuoran; Sun, Yulong; Duan, Xianbao
  • Journal of Materials Chemistry A, Vol. 7, Issue 6
  • DOI: 10.1039/C8TA10790D

Dielectric properties, conductivity and Li+ ion motion in LiPON thin films
journal, December 2013

  • Le Van-Jodin, Lucie; Ducroquet, Frédérique; Sabary, Frédéric
  • Solid State Ionics, Vol. 253
  • DOI: 10.1016/j.ssi.2013.09.031

An analysis of rechargeable lithium-ion batteries after prolonged cycling
journal, May 2002

Superhalogen-based lithium superionic conductors
journal, January 2017

  • Fang, Hong; Wang, Shuo; Liu, Junyi
  • Journal of Materials Chemistry A, Vol. 5, Issue 26
  • DOI: 10.1039/C7TA01648D

Sulfide Solid Electrolytes for Lithium Battery Applications
journal, August 2018

  • Lau, Jonathan; DeBlock, Ryan H.; Butts, Danielle M.
  • Advanced Energy Materials, Vol. 8, Issue 27
  • DOI: 10.1002/aenm.201800933

Li7PS6 and Li6PS5X (X: Cl, Br, I): Possible Three-dimensional Diffusion Pathways for Lithium Ions and Temperature Dependence of the Ionic Conductivity by Impedance Measurements
journal, August 2011

  • Deiseroth, Hans-Jörg; Maier, Joachim; Weichert, Katja
  • Zeitschrift für anorganische und allgemeine Chemie, Vol. 637, Issue 10
  • DOI: 10.1002/zaac.201100158

Compatibility of Li[sub 7]La[sub 3]Zr[sub 2]O[sub 12] Solid Electrolyte to All-Solid-State Battery Using Li Metal Anode
journal, January 2010

  • Kotobuki, Masashi; Munakata, Hirokazu; Kanamura, Kiyoshi
  • Journal of The Electrochemical Society, Vol. 157, Issue 10
  • DOI: 10.1149/1.3474232

Promising All-Solid-State Batteries for Future Electric Vehicles
journal, October 2020

Solvent-Mediated Synthesis of Amorphous Li 3 PS 4 /Polyethylene Oxide Composite Solid Electrolytes with High Li + Conductivity
journal, September 2020

All-solid-state lithium batteries enabled by sulfide electrolytes: from fundamental research to practical engineering design
journal, January 2021

  • Wang, Changhong; Liang, Jianwen; Zhao, Yang
  • Energy & Environmental Science, Vol. 14, Issue 5
  • DOI: 10.1039/D1EE00551K

High-Performance Solid-State Lithium-Ion Battery with Mixed 2D and 3D Electrodes
journal, July 2020

  • Ashby, David S.; Choi, Christopher S.; Edwards, Martin A.
  • ACS Applied Energy Materials, Vol. 3, Issue 9
  • DOI: 10.1021/acsaem.0c01029

A General Strategy of Anion-Rich High-Concentration Polymeric Interlayer for High-Voltage, All-Solid-State Batteries
journal, January 2021

Relaxation Effects in Nuclear Magnetic Resonance Absorption
journal, April 1948

Direct laser writing of micro-supercapacitors on hydrated graphite oxide films
journal, July 2011

Sulfide‐Based Solid‐State Electrolytes: Synthesis, Stability, and Potential for All‐Solid‐State Batteries
journal, August 2019

A New Superionic Plastic Polymorph of the Na + Conductor Na 3 PS 4
journal, October 2019

Ab initio investigation of the stability of electrolyte/electrode interfaces in all-solid-state Na batteries
journal, January 2019

  • Lacivita, Valentina; Wang, Yan; Bo, Shou-Hang
  • Journal of Materials Chemistry A, Vol. 7, Issue 14
  • DOI: 10.1039/C8TA10498K

High performance room temperature all-solid-state Na-Se S battery with Na3SbS4–coated cathode via aqueous solution
journal, September 2020

Phase transition in nasicon (Na3Zr2Si2PO12)
journal, October 1979

Na 3 PSe 4 : A Novel Chalcogenide Solid Electrolyte with High Ionic Conductivity
journal, October 2015

Non‐Flammable Liquid and Quasi‐Solid Electrolytes toward Highly‐Safe Alkali Metal‐Based Batteries
journal, December 2020

  • Jaumaux, Pauline; Wu, Junru; Shanmukaraj, Devaraj
  • Advanced Functional Materials, Vol. 31, Issue 10
  • DOI: 10.1002/adfm.202008644

Atomic-Scale Influence of Grain Boundaries on Li-Ion Conduction in Solid Electrolytes for All-Solid-State Batteries
journal, December 2017

  • Dawson, James A.; Canepa, Pieremanuele; Famprikis, Theodosios
  • Journal of the American Chemical Society, Vol. 140, Issue 1
  • DOI: 10.1021/jacs.7b10593

Rechargeable Sodium All-Solid-State Battery
journal, January 2017

Li6PS5X: A Class of Crystalline Li-Rich Solids With an Unusually High Li+ Mobility
journal, January 2008

  • Deiseroth, Hans-Jörg; Kong, Shiao-Tong; Eckert, Hellmut
  • Angewandte Chemie International Edition, Vol. 47, Issue 4
  • DOI: 10.1002/anie.200703900

Overcoming the Interfacial Limitations Imposed by the Solid–Solid Interface in Solid‐State Batteries Using Ionic Liquid‐Based Interlayers
journal, April 2020

  • Pervez, Syed Atif; Kim, Guktae; Vinayan, Bhaghavathi P.
  • Small, Vol. 16, Issue 14
  • DOI: 10.1002/smll.202000279

Plating a Dendrite-Free Lithium Anode with a Polymer/Ceramic/Polymer Sandwich Electrolyte
journal, July 2016

  • Zhou, Weidong; Wang, Shaofei; Li, Yutao
  • Journal of the American Chemical Society, Vol. 138, Issue 30
  • DOI: 10.1021/jacs.6b05341

Solid-State Electrolytes for Lithium-Ion Batteries: Fundamentals, Challenges and Perspectives
journal, August 2019

Negating interfacial impedance in garnet-based solid-state Li metal batteries
journal, December 2016

  • Han, Xiaogang; Gong, Yunhui; Fu, Kun (Kelvin)
  • Nature Materials, Vol. 16, Issue 5
  • DOI: 10.1038/nmat4821

Role of Na + Interstitials and Dopants in Enhancing the Na + Conductivity of the Cubic Na 3 PS 4 Superionic Conductor
journal, December 2015

A safe and non-flammable sodium metal battery based on an ionic liquid electrolyte
journal, July 2019

Revealing the Short‐Circuiting Mechanism of Garnet‐Based Solid‐State Electrolyte
journal, April 2019

  • Song, Yongli; Yang, Luyi; Zhao, Wenguang
  • Advanced Energy Materials, Vol. 9, Issue 21
  • DOI: 10.1002/aenm.201900671

Structural, Chemical, and Dynamical Frustration: Origins of Superionic Conductivity in closo -Borate Solid Electrolytes
journal, October 2017

In-situ visualization of the space-charge-layer effect on interfacial lithium-ion transport in all-solid-state batteries
journal, November 2020

Targeting Superionic Conductivity by Turning on Anion Rotation at Room Temperature in Fast Ion Conductors
journal, June 2020

Interfacial compatibility issues in rechargeable solid-state lithium metal batteries: a review
journal, March 2021

Practical Challenges and Future Perspectives of All-Solid-State Lithium-Metal Batteries
journal, April 2019

A lithium superionic conductor
journal, July 2011

  • Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro
  • Nature Materials, Vol. 10, Issue 9, p. 682-686
  • DOI: 10.1038/nmat3066

A sodium-ion sulfide solid electrolyte with unprecedented conductivity at room temperature
journal, November 2019

From nanoscale interface characterization to sustainable energy storage using all-solid-state batteries
journal, March 2020

Li 2 CO 3 : A Critical Issue for Developing Solid Garnet Batteries
journal, November 2019

Temperature‐dependent electrical transport behavior and structural evolution in hollandite‐type titanium‐based oxide
journal, May 2019

  • Feng, Tao; Li, Liping; Lv, Zhe
  • Journal of the American Ceramic Society, Vol. 102, Issue 11
  • DOI: 10.1111/jace.16520

High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016

Origin of fast ion diffusion in super-ionic conductors
journal, June 2017

  • He, Xingfeng; Zhu, Yizhou; Mo, Yifei
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms15893

A High-Performance All-Solid-State Sodium Battery with a Poly(ethylene oxide)–Na 3 Zr 2 Si 2 PO 12 Composite Electrolyte
journal, May 2019

Paddle-wheel versus percolation mechanism for cation transport in some sulphate phases☆
journal, October 1992

The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces
journal, January 2005

  • Monroe, Charles; Newman, John
  • Journal of The Electrochemical Society, Vol. 152, Issue 2
  • DOI: 10.1149/1.1850854

Composite NASICON (Na 3 Zr 2 Si 2 PO 12 ) Solid-State Electrolyte with Enhanced Na + Ionic Conductivity: Effect of Liquid Phase Sintering
journal, September 2019

  • Oh, Jin An Sam; He, Linchun; Plewa, Anna
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 43
  • DOI: 10.1021/acsami.9b14986

Relation structure-fast ion conduction in the NASICON solid solution
journal, March 1988

Interphase Engineering Enabled All-Ceramic Lithium Battery
journal, March 2018

Synthesis, structure, and conduction mechanism of the lithium superionic conductor Li 10+δ Ge 1+δ P 2−δ S 12
journal, January 2015

  • Kwon, Ohmin; Hirayama, Masaaki; Suzuki, Kota
  • Journal of Materials Chemistry A, Vol. 3, Issue 1
  • DOI: 10.1039/C4TA05231E

Electrochemical Stability of Li 10 GeP 2 S 12 and Li 7 La 3 Zr 2 O 12 Solid Electrolytes
journal, January 2016

  • Han, Fudong; Zhu, Yizhou; He, Xingfeng
  • Advanced Energy Materials, Vol. 6, Issue 8
  • DOI: 10.1002/aenm.201501590

Post-lithium-ion battery cell production and its compatibility with lithium-ion cell production infrastructure
journal, January 2021

Abnormally Low Activation Energy in Cubic Na 3 SbS 4 Superionic Conductors
journal, January 2020

A 500 Wh/kg Lithium-Metal Cell Based on Anionic Redox
journal, July 2020

Stable all-solid-state battery enabled with Li6.25PS5.25Cl0.75 as fast ion-conducting electrolyte
journal, February 2021

Studies of Functional Defects for Fast Na-Ion Conduction in Na 3− y PS 4− x Cl x with a Combined Experimental and Computational Approach
journal, January 2019

  • Feng, Xuyong; Chien, Po-Hsiu; Zhu, Zhuoying
  • Advanced Functional Materials, Vol. 29, Issue 9
  • DOI: 10.1002/adfm.201807951

Li-rich antiperovskite superionic conductors based on cluster ions
journal, October 2017

  • Fang, Hong; Jena, Puru
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 42
  • DOI: 10.1073/pnas.1704086114

Design principles for solid-state lithium superionic conductors
journal, August 2015

  • Wang, Yan; Richards, William Davidson; Ong, Shyue Ping
  • Nature Materials, Vol. 14, Issue 10
  • DOI: 10.1038/nmat4369

Tetragonal vs. cubic phase stability in Al – free Ta doped Li 7 La 3 Zr 2 O 12 (LLZO)
journal, January 2014

  • Thompson, Travis; Wolfenstine, Jeff; Allen, Jan L.
  • J. Mater. Chem. A, Vol. 2, Issue 33
  • DOI: 10.1039/C4TA02099E

All-Solid-State Na/S Batteries with a Na 3 PS 4 Electrolyte Operating at Room Temperature
journal, May 2017

Benchmarking the performance of all-solid-state lithium batteries
journal, March 2020

Preparation and characterization of highly sodium ion conducting Na 3 PS 4 –Na 4 SiS 4 solid electrolytes
journal, January 2014

  • Tanibata, Naoto; Noi, Kousuke; Hayashi, Akitoshi
  • RSC Adv., Vol. 4, Issue 33
  • DOI: 10.1039/C4RA00996G

Critical Current Density in Solid‐State Lithium Metal Batteries: Mechanism, Influences, and Strategies
journal, February 2021

  • Lu, Yang; Zhao, Chen‐Zi; Yuan, Hong
  • Advanced Functional Materials, Vol. 31, Issue 18
  • DOI: 10.1002/adfm.202009925

Polymer Electrolytes for Lithium-Based Batteries: Advances and Prospects
journal, September 2019

Processing thin but robust electrolytes for solid-state batteries
journal, February 2021

Durability of the Li 1+ x Ti 2– x Al x (PO 4 ) 3 Solid Electrolyte in Lithium–Sulfur Batteries
journal, November 2016

Sulfide Solid Electrolyte with Favorable Mechanical Property for All-Solid-State Lithium Battery
journal, July 2013

  • Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro
  • Scientific Reports, Vol. 3, Issue 1
  • DOI: 10.1038/srep02261

Facile Solid-State Growth of 3D Well-Interconnected Nitrogen-Rich Carbon Nanotube-Graphene Hybrid Architectures for Lithium-Sulfur Batteries
journal, December 2015

  • Ding, Yuan-Li; Kopold, Peter; Hahn, Kersten
  • Advanced Functional Materials, Vol. 26, Issue 7
  • DOI: 10.1002/adfm.201504294

A highly stable sodium solid-state electrolyte based on a dodeca/deca-borate equimolar mixture
journal, January 2017

  • Duchêne, L.; Kühnel, R. -S.; Rentsch, D.
  • Chemical Communications, Vol. 53, Issue 30
  • DOI: 10.1039/C7CC00794A

Garnet Electrolyte with an Ultralow Interfacial Resistance for Li-Metal Batteries
journal, April 2018

  • Li, Yutao; Chen, Xi; Dolocan, Andrei
  • Journal of the American Chemical Society, Vol. 140, Issue 20
  • DOI: 10.1021/jacs.8b03106

A Decade of Progress on Solid‐State Electrolytes for Secondary Batteries: Advances and Contributions
journal, April 2021

  • Sheng, Ouwei; Jin, Chengbin; Ding, Xufen
  • Advanced Functional Materials, Vol. 31, Issue 27
  • DOI: 10.1002/adfm.202100891

Live Scanning Electron Microscope Observations of Dendritic Growth in Lithium/Polymer Cells
journal, January 2002

  • Dollé, Mickaël; Sannier, Lucas; Beaudoin, Bernard
  • Electrochemical and Solid-State Letters, Vol. 5, Issue 12
  • DOI: 10.1149/1.1519970

Lithium-ion conductive ceramic textile: A new architecture for flexible solid-state lithium metal batteries
journal, July 2018

Drawing a Soft Interface: An Effective Interfacial Modification Strategy for Garnet-Type Solid-State Li Batteries
journal, May 2018

LiNbO3-coated LiNi0.7Co0.1Mn0.2O2 and chlorine-rich argyrodite enabling high-performance solid-state batteries under different temperatures
journal, December 2021

Electrochemical performance of an all-solid-state lithium ion battery with garnet-type oxide electrolyte
journal, March 2012

Interfaces in Solid-State Lithium Batteries
journal, October 2018

Stack Pressure Considerations for Room‐Temperature All‐Solid‐State Lithium Metal Batteries
journal, November 2019

  • Doux, Jean‐Marie; Nguyen, Han; Tan, Darren H. S.
  • Advanced Energy Materials, Vol. 10, Issue 1
  • DOI: 10.1002/aenm.201903253

An Air-Stable Na 3 SbS 4 Superionic Conductor Prepared by a Rapid and Economic Synthetic Procedure
journal, June 2016

An Air‐Stable and Li‐Metal‐Compatible Glass‐Ceramic Electrolyte enabling High‐Performance All‐Solid‐State Li Metal Batteries
journal, January 2021

  • Zhao, Feipeng; Alahakoon, Sandamini H.; Adair, Keegan
  • Advanced Materials, Vol. 33, Issue 8
  • DOI: 10.1002/adma.202006577

Macromolecular Design of Lithium Conductive Polymer as Electrolyte for Solid‐State Lithium Batteries
journal, December 2020

    Sort by:
    [ × clear filter / sort ]

    Similar Records in DOE PAGES and OSTI.GOV collections: