Copper(ii)-photocatalyzed decarboxylative oxygenation of carboxylic acids

Reichle, Alexander; Sterzel, Hannes; Kreitmeier, Peter; Fayad, Remi; Castellano, Felix N.; Rehbein, Julia; Reiser, Oliver

doi:10.1039/d2cc00570k

Title: Copper(ii)-photocatalyzed decarboxylative oxygenation of carboxylic acids

Journal Article · 15 February 2022 · ChemComm

DOI: https://doi.org/10.1039/d2cc00570k · OSTI ID:1863588

Reichle, Alexander ^[1]; Sterzel, Hannes ^[2]; Kreitmeier, Peter ^[2]; Fayad, Remi ^[3];

^[3]; Rehbein, Julia ^[2];

^[2]

Univ. of Regensburg (Germany); North Carolina State University
Univ. of Regensburg (Germany)
North Carolina State Univ., Raleigh, NC (United States)

Showcasing the concept of light-induced homolysis for the generation of radicals, the Cu^II-photocatalyzed decarboxylative oxygenation of carboxylic acids with molecular oxygen as the terminal oxidant is described. Here, two Cu^II-carboxylate complexes with different coordination geometries were synthesized and characterized by X-ray analysis, correlating their structure with their ability to initiate light-induced decarboxylations.

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Research Organization:: North Carolina State Univ., Raleigh, NC (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019370

OSTI ID:: 1863588

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 28 Vol. 58; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Carboxylic acids
copper catalysts
photoredox catalysis

CCDC 2144474: Experimental Crystal Structure Determination Alexander, Reichle,; Hannes, Sterzel,; Peter, Kreitmeier, https://doi.org/10.5517/ccdc.csd.cc29zhld The current record is supplemented by this dataset	dataset	January 2022
CCDC 2144480: Experimental Crystal Structure Determination Alexander, Reichle,; Hannes, Sterzel,; Peter, Kreitmeier, https://doi.org/10.5517/ccdc.csd.cc29zhsl The current record is supplemented by this dataset	dataset	January 2022
CCDC 2144482: Experimental Crystal Structure Determination Alexander, Reichle,; Hannes, Sterzel,; Peter, Kreitmeier, https://doi.org/10.5517/ccdc.csd.cc29zhvn The current record is supplemented by this dataset	dataset	January 2022
CCDC 2144485: Experimental Crystal Structure Determination Alexander, Reichle,; Hannes, Sterzel,; Peter, Kreitmeier, https://doi.org/10.5517/ccdc.csd.cc29zhyr The current record is supplemented by this dataset	dataset	January 2022

Title: Copper(ii)-photocatalyzed decarboxylative oxygenation of carboxylic acids

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References (23)

Linked Research (4)

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