A Microporous Metal–Organic Framework Incorporating Both Primary and Secondary Building Units for Splitting Alkane Isomers
Abstract
We demonstrate the assembly of a mononuclear metal center, a hexanuclear cluster, and a V-shaped, trapezoidal tetracarboxylate linker into a microporous MOF featuring an unprecedented 3-nodal (4,4,8)-c lyu topology. Here, the compound, HIAM-302, represents the first example that incorporates both primary building unit (PBU) and hexanuclear secondary building unit (SBU) in one structure, which should be attributed to the desymmetrized geometry of the organic linker. HIAM-302 possesses optimal pore dimensions and can separate mono-branched and di-branched alkanes through selective molecular sieving, which is of significant value in petrochemical industry.
- Authors:
-
[2];
[4];
[3];
[3];
[2];
[5]
- South China Univ. of Technology, Guangzhou (China); Shenzhen Polytechnic, Guangdong (China)
- Wake Forest Univ., Winston-Salem, NC (United States)
- Shenzhen Polytechnic, Guangdong (China)
- South China Univ. of Technology, Guangzhou (China)
- Rutgers Univ., Piscataway, NJ (United States); Shenzhen Polytechnic, Guangdong (China)
- Publication Date:
- Research Org.:
- Wake Forest Univ., Winston-Salem, NC (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1863575
- Grant/Contract Number:
- SC0019902
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 144; Journal Issue: 9; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Molecular structure; Mathematical methods; Adsorption; Chemical structure; Metal organic frameworks
Citation Formats
Yu, Liang, Ullah, Saif, Zhou, Kang, Xia, Qibin, Wang, Hao, Tu, Shi, Huang, Jiajin, Xia, Hai-Lun, Liu, Xiao-Yuan, Thonhauser, Timo, and Li, Jing. A Microporous Metal–Organic Framework Incorporating Both Primary and Secondary Building Units for Splitting Alkane Isomers. United States: N. p., 2022.
Web. doi:10.1021/jacs.1c12068.
Yu, Liang, Ullah, Saif, Zhou, Kang, Xia, Qibin, Wang, Hao, Tu, Shi, Huang, Jiajin, Xia, Hai-Lun, Liu, Xiao-Yuan, Thonhauser, Timo, & Li, Jing. A Microporous Metal–Organic Framework Incorporating Both Primary and Secondary Building Units for Splitting Alkane Isomers. United States. https://doi.org/10.1021/jacs.1c12068
Yu, Liang, Ullah, Saif, Zhou, Kang, Xia, Qibin, Wang, Hao, Tu, Shi, Huang, Jiajin, Xia, Hai-Lun, Liu, Xiao-Yuan, Thonhauser, Timo, and Li, Jing. Fri .
"A Microporous Metal–Organic Framework Incorporating Both Primary and Secondary Building Units for Splitting Alkane Isomers". United States. https://doi.org/10.1021/jacs.1c12068. https://www.osti.gov/servlets/purl/1863575.
@article{osti_1863575,
title = {A Microporous Metal–Organic Framework Incorporating Both Primary and Secondary Building Units for Splitting Alkane Isomers},
author = {Yu, Liang and Ullah, Saif and Zhou, Kang and Xia, Qibin and Wang, Hao and Tu, Shi and Huang, Jiajin and Xia, Hai-Lun and Liu, Xiao-Yuan and Thonhauser, Timo and Li, Jing},
abstractNote = {We demonstrate the assembly of a mononuclear metal center, a hexanuclear cluster, and a V-shaped, trapezoidal tetracarboxylate linker into a microporous MOF featuring an unprecedented 3-nodal (4,4,8)-c lyu topology. Here, the compound, HIAM-302, represents the first example that incorporates both primary building unit (PBU) and hexanuclear secondary building unit (SBU) in one structure, which should be attributed to the desymmetrized geometry of the organic linker. HIAM-302 possesses optimal pore dimensions and can separate mono-branched and di-branched alkanes through selective molecular sieving, which is of significant value in petrochemical industry.},
doi = {10.1021/jacs.1c12068},
journal = {Journal of the American Chemical Society},
number = 9,
volume = 144,
place = {United States},
year = {Fri Jan 28 00:00:00 EST 2022},
month = {Fri Jan 28 00:00:00 EST 2022}
}
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