Unblocking Oxygen Charge Compensation for Stabilized High‐Voltage Structure in P2‐Type Sodium‐Ion Cathode
Abstract
Abstract Layered transition‐metal (TM) oxides are ideal hosts for Li + charge carriers largely due to the occurrence of oxygen charge compensation that stabilizes the layered structure at high voltage. Hence, enabling charge compensation in sodium layered oxides is a fascinating task for extending the cycle life of sodium‐ion batteries. Herein a Ti/Mg co‐doping strategy for a model P2‐Na 2/3 Ni 1/3 Mn 2/3 O 2 cathode material is put forward to activate charge compensation through highly hybridized O 2 p TM 3 d covalent bonds. In this way, the interlayer OO electrostatic repulsion is weakened upon deeply charging, which strongly affects the systematic total energy that transforms the striking P2–O2 interlayer contraction into a moderate solid‐solution‐type evolution. Accordingly, the cycling stability of the codoped cathode material is improved superiorly over the pristine sample. This study starts a perspective way of optimizing the sodium layered cathodes by rational structural design coupling electrochemical reactions, which can be extended to widespread battery researches.
- Authors:
-
[10]
- Department of Physics City University of Hong Kong Hong Kong 999077 P. R. China
- Center of Hydrogen Science Shanghai Jiao Tong University Shanghai 200240 P. R. China, Innovation Center for Future Materials Zhangjiang Institute for Advanced Study Shanghai Jiao Tong University Shanghai 201203 P. R. China, The State Key Laboratory of Metal Matrix Composites School of Materials Science and Engineering Shanghai Jiao Tong University Shanghai 200240 P. R. China, Department of Chemistry and Chemical Biology Harvard University Cambridge MA 02138 USA
- School of Chemical Engineering and Light Industry Guangdong University of Technology Guangzhou 510006 P. R. China
- X‐Ray Science Division Argonne National Laboratory Argonne IL 60439 USA
- College of Physics and Materials Science Tianjin Normal University Tianjin 300387 P. R. China
- School of Materials Science and Engineering Tianjin University Tianjin 300072 P. R. China
- School of Material Science and Engineering Nanjing University of Science and Technology Nanjing 210094 P. R. China
- Institute of Physics Chinese Academy of Sciences Beijing 100190 P. R. China
- School of Material Science and Engineering Nanjing University of Science and Technology Nanjing 210094 P. R. China, Shenzhen Research Institute City University of Hong Kong Shenzhen 518057 P. R. China
- Department of Physics City University of Hong Kong Hong Kong 999077 P. R. China, Center for Neutron Scattering City University of Hong Kong Hong Kong 999077 P. R. China, Shenzhen Research Institute City University of Hong Kong Shenzhen 518057 P. R. China, Hong Kong Institute for Clean Energy City University of Hong Kong Hong Kong 999077 P. R. China
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Key Research and Development Program of China; Science, Technology and Innovation Commission of Shenzhen Municipality; City University of Hong Kong
- OSTI Identifier:
- 1859765
- Alternate Identifier(s):
- OSTI ID: 1859766; OSTI ID: 1962072
- Grant/Contract Number:
- AC02-06CH11357; SC0019300; 2020YFA0406203; SGDX2019081623240948; JCYJ20200109105618137; 21307019
- Resource Type:
- Published Article
- Journal Name:
- Advanced Science
- Additional Journal Information:
- Journal Name: Advanced Science Journal Volume: 9 Journal Issue: 16; Journal ID: ISSN 2198-3844
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; battery NMC; high-voltage structural stability; in situ synchrotron characterizations; layered transition-metal oxide cathodes; oxygen charge compensation; sodium-ion battery
Citation Formats
Zhu, He, Yao, Zhenpeng, Zhu, Hekang, Huang, Yalan, Zhang, Jian, Li, Cheng Chao, Wiaderek, Kamila M., Ren, Yang, Sun, Cheng‐Jun, Zhou, Hua, Fan, Longlong, Chen, Yanan, Xia, Hui, Gu, Lin, Lan, Si, and Liu, Qi. Unblocking Oxygen Charge Compensation for Stabilized High‐Voltage Structure in P2‐Type Sodium‐Ion Cathode. Germany: N. p., 2022.
Web. doi:10.1002/advs.202200498.
Zhu, He, Yao, Zhenpeng, Zhu, Hekang, Huang, Yalan, Zhang, Jian, Li, Cheng Chao, Wiaderek, Kamila M., Ren, Yang, Sun, Cheng‐Jun, Zhou, Hua, Fan, Longlong, Chen, Yanan, Xia, Hui, Gu, Lin, Lan, Si, & Liu, Qi. Unblocking Oxygen Charge Compensation for Stabilized High‐Voltage Structure in P2‐Type Sodium‐Ion Cathode. Germany. https://doi.org/10.1002/advs.202200498
Zhu, He, Yao, Zhenpeng, Zhu, Hekang, Huang, Yalan, Zhang, Jian, Li, Cheng Chao, Wiaderek, Kamila M., Ren, Yang, Sun, Cheng‐Jun, Zhou, Hua, Fan, Longlong, Chen, Yanan, Xia, Hui, Gu, Lin, Lan, Si, and Liu, Qi. Mon .
"Unblocking Oxygen Charge Compensation for Stabilized High‐Voltage Structure in P2‐Type Sodium‐Ion Cathode". Germany. https://doi.org/10.1002/advs.202200498.
@article{osti_1859765,
title = {Unblocking Oxygen Charge Compensation for Stabilized High‐Voltage Structure in P2‐Type Sodium‐Ion Cathode},
author = {Zhu, He and Yao, Zhenpeng and Zhu, Hekang and Huang, Yalan and Zhang, Jian and Li, Cheng Chao and Wiaderek, Kamila M. and Ren, Yang and Sun, Cheng‐Jun and Zhou, Hua and Fan, Longlong and Chen, Yanan and Xia, Hui and Gu, Lin and Lan, Si and Liu, Qi},
abstractNote = {Abstract Layered transition‐metal (TM) oxides are ideal hosts for Li + charge carriers largely due to the occurrence of oxygen charge compensation that stabilizes the layered structure at high voltage. Hence, enabling charge compensation in sodium layered oxides is a fascinating task for extending the cycle life of sodium‐ion batteries. Herein a Ti/Mg co‐doping strategy for a model P2‐Na 2/3 Ni 1/3 Mn 2/3 O 2 cathode material is put forward to activate charge compensation through highly hybridized O 2 p TM 3 d covalent bonds. In this way, the interlayer OO electrostatic repulsion is weakened upon deeply charging, which strongly affects the systematic total energy that transforms the striking P2–O2 interlayer contraction into a moderate solid‐solution‐type evolution. Accordingly, the cycling stability of the codoped cathode material is improved superiorly over the pristine sample. This study starts a perspective way of optimizing the sodium layered cathodes by rational structural design coupling electrochemical reactions, which can be extended to widespread battery researches.},
doi = {10.1002/advs.202200498},
journal = {Advanced Science},
number = 16,
volume = 9,
place = {Germany},
year = {Mon Mar 28 00:00:00 EDT 2022},
month = {Mon Mar 28 00:00:00 EDT 2022}
}
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