Thermal dynamics of P2-Na0.67Ni0.33Mn0.67O2 cathode materials for sodium ion batteries studied by in situ analysis

Hou, Dewen; Gabriel, Eric; Graff, Kincaid; Li, Tianyi; Ren, Yang; Wang, Zihongbo; Liu, Yuzi; Xiong, Hui

doi:10.1557/s43578-022-00519-z

Title: Thermal dynamics of P2-Na_0.67Ni_0.33Mn_0.67O₂ cathode materials for sodium ion batteries studied by in situ analysis

Journal Article · 03 March 2022 · Journal of Materials Research

DOI: https://doi.org/10.1557/s43578-022-00519-z · OSTI ID:1859754

Hou, Dewen ^[1]; Gabriel, Eric ^[2]; Graff, Kincaid ^[2]; Li, Tianyi ^[3]; Ren, Yang ^[4]; Wang, Zihongbo ^[2]; Liu, Yuzi ^[3]; Xiong, Hui ^[5]

Boise State Univ., ID (United States); Argonne National Lab. (ANL), Argonne, IL (United States); Boise State University
Boise State Univ., ID (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
City Univ. of Hong Kong (China)
Boise State Univ., ID (United States); Center for Advanced Energy Studies, Idaho Falls, ID (United States)

Cobalt-free layered Na_0.67Ni_0.33Mn_0.67O₂ is an attractive cathode material for sodium ion batteries. The thermal stability of cathode materials is crucial to their practical applications. In the current work, we investigate structural and morphological evolution in P2-type Na_0.67Ni_0.33Mn_0.67O₂ cathode materials during annealing via in situ synchrotron X-ray diffraction and transmission electron microscopy. Insights are obtained from the two complementary in situ characterizations (at different length scales) in term of the thermal stability of P2-Na_0.67Ni_0.33Mn_0.67O₂ cathode materials. Here, the results indicate that the hexagonal P2 phase remains unchanged during the heat treatment process, and thermally driven expansion/contraction of lattice parameters exhibit an anisotropic character in the a and c directions. In addition, interfaces/grain boundaries play an important role in the structural stability, which leads to the distinct morphological evolution between the polycrystalline and single-crystal particles.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Boise State Univ., ID (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division

Grant/Contract Number:: AC02-06CH11357; SC0019121

OSTI ID:: 1859754

Journal Information:: Journal of Materials Research, Journal Name: Journal of Materials Research Journal Issue: 6 Vol. 37; ISSN 0884-2914

Publisher:: Materials Research SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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25 ENERGY STORAGE
in situ TEM
in situ synchrotron XRD
sodium ion batteries
thermal behavior

Title: Thermal dynamics of P2-Na0.67Ni0.33Mn0.67O2 cathode materials for sodium ion batteries studied by in situ analysis

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Title: Thermal dynamics of P2-Na_0.67Ni_0.33Mn_0.67O₂ cathode materials for sodium ion batteries studied by in situ analysis