Spin Reorientation in Antiferromagnetic MnPd5Se with an Anti-CeCoIn5 Structure Type

Dissanayaka Mudiyanselage, Ranuri S.; Zhang, Qiang; Marshall, Madalynn; Croft, Mark; Shu, Zhixue; Kong, Tai; Xie, Weiwei

doi:10.1021/acs.inorgchem.1c03637

Title: Spin Reorientation in Antiferromagnetic MnPd₅Se with an Anti-CeCoIn₅ Structure Type

Journal Article · 21 February 2022 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.1c03637 · OSTI ID:1854450

Dissanayaka Mudiyanselage, Ranuri S. ^[1];

^[2]; Marshall, Madalynn ^[1]; Croft, Mark ^[1]; Shu, Zhixue ^[3]; Kong, Tai ^[3];

^[1]

Rutgers Univ., Piscataway, NJ (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Arizona, Tucson, AZ (United States)

MnPd₅Se, a derivative of the anti-CeCoIn₅-type phase, was synthesized from a high-temperature solid-state reaction, structurally determined by X-ray diffraction, and magnetically characterized with a combined magnetic measurement and neutron powder diffraction (NPD). According to the X-ray diffraction results, MnPd₅Se crystallizes in a layered tetragonal structure with the same space group as CeCoIn₅, P4/mmm (No. 123). MnPd5Se shows antiferromagnetic ordering around 80 K on the basis of the magnetic property measurements. An A-type antiferromagnetic structure was revealed from the analysis of neutron powder diffraction results at 300, 50, and 6 K. Moreover, a spin orientation rotation was observed as the temperature decreased. Pd L₃ X-ray absorption near edge spectroscopy results for MnPd5Se semiqualitatively correlate with the calculated density of states supporting a nominal 0.2 electron transfer into the Pd d orbital from either Se or Mn in the compound. The discovery of MnPd₅Se, along with our previously reported MnT₅Pn (T = Pd or Pt; Pn = P or As), provides a tunable system for studying the magnetic ordering from ferromagnetism to antiferromagnetism with the strong spin–orbit coupling effect.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1854450

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 9 Vol. 61; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Spin Reorientation in Antiferromagnetic MnPd₅Se with an Anti-CeCoIn₅ Structure Type