Amorphization of Pseudocapacitive T−Nb 2 O 5 Accelerates Lithium Diffusivity as Revealed Using Tunable Isomorphic Architectures

van den Bergh, Wessel; Wechsler, Sean; Lokupitiya, Hasala Nadeesini; Jarocha, Lauren; Kim, Kwangnam; Chapman, James; Kweon, Kyoung E.; Wood, Brandon C.; Heald, Steve; Stefik, Morgan

doi:10.1002/batt.202200056

Title: Amorphization of Pseudocapacitive T−Nb ₂ O ₅ Accelerates Lithium Diffusivity as Revealed Using Tunable Isomorphic Architectures

Journal Article · 08 March 2022 · Batteries & Supercaps

DOI: https://doi.org/10.1002/batt.202200056 · OSTI ID:1854056

van den Bergh, Wessel ^[1]; Wechsler, Sean ^[1]; Lokupitiya, Hasala Nadeesini ^[1]; Jarocha, Lauren ^[2];

^[3];

^[3]; Heald, Steve ^[4];

^[1]

Department of Chemistry and Biochemistry University of South Carolina Columbia South Carolina 29208 United States
Department of Chemistry Furman University Greenville South Carolina 29613 United States
Physical and Life Sciences Directorate Lawrence Livermore National Laboratory Livermore California 94550 United States
X-Ray Science Division Advanced Photon Source, Argonne National Lab Lemont IL 60439 United States

Abstract Intercalation pseudocapacitance can combine capacitor‐like power densities with battery‐like energy densities. Such surface‐limited behavior requires rapid diffusion where amorphization can increase solid‐state diffusivity. Here intercalation pseudocapacitive materials with tailored extents of amorphization in T‐Nb ₂ O ₅ are first reported. Amorphization was characterized with WAXS, XPS, XAFS, and EPR which suggested a peroxide‐rich (O ₂ ²⁻ ) surface that was consistent with DFT predictions. A series of tunable isomorphic architectures enabled comparisons while independently varying transport parameters. Through process of elimination, solid‐state lithium diffusion was identified as the dominant diffusive‐constraint dictating the maximum voltage sweep rate for surface‐limited kinetics ( v _SLT ), termed the Surface‐Limited Threshold (SLT). The v _SLT increased with amorphization however stable cycling required crystalline T‐Nb ₂ O ₅ . A current‐response model using series‐impedances well‐matched these observations. This perspective revealed that amorphization of T‐Nb ₂ O ₅ enhanced solid‐state diffusion by 12.2 % and increased surface‐limitations by 17.0 % (stable samples). This approach enabled retaining 95 % lithiation capacity at ∼800 mV s ⁻¹ (1,600 C‐rate equivalent).

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; University of South Carolina

Grant/Contract Number:: AC02-06CH11357; AC52-07NA27344

OSTI ID:: 1854056

Report Number(s):: LLNL-JRNL-831801; e202200056

Journal Information:: Batteries & Supercaps, Journal Name: Batteries & Supercaps Journal Issue: 6 Vol. 5; ISSN 2566-6223

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

References (129)

High-Performance Sodium-Ion Hybrid Supercapacitor Based on Nb ₂ O ₅ @Carbon Core-Shell Nanoparticles and Reduced Graphene Oxide Nanocomposites Lim, Eunho; Jo, Changshin; Kim, Min Su Advanced Functional Materials, Vol. 26, Issue 21 https://doi.org/10.1002/adfm.201505548	journal	March 2016
In-Plane Assembled Orthorhombic Nb ₂ O ₅ Nanorod Films with High-Rate Li ⁺ Intercalation for High-Performance Flexible Li-Ion Capacitors Deng, Bohua; Lei, Tianyu; Zhu, Weihua Advanced Functional Materials, Vol. 28, Issue 1 https://doi.org/10.1002/adfm.201704330	journal	November 2017
Nanostructure Dependence of T‐Nb ₂ O ₅ Intercalation Pseudocapacitance Probed Using Tunable Isomorphic Architectures Bergh, Wessel; Lokupitiya, Hasala Nadeesini; Vest, Natalie Alicia Advanced Functional Materials, Vol. 31, Issue 1 https://doi.org/10.1002/adfm.202007826	journal	November 2020
Ultrafast and Stable Li‐(De)intercalation in a Large Single Crystal H‐Nb ₂ O ₅ Anode via Optimizing the Homogeneity of Electron and Ion Transport Song, Zihan; Li, Hui; Liu, Wei Advanced Materials, Vol. 32, Issue 22 https://doi.org/10.1002/adma.202001001	journal	April 2020
Amorphous VO ₂ : A Pseudocapacitive Platform for High‐Rate Symmetric Batteries Chao, Dongliang; DeBlock, Ryan; Lai, Chun‐Han Advanced Materials, Vol. 33, Issue 49 https://doi.org/10.1002/adma.202103736	journal	October 2021
Oxygen-Vacancy Abundant Ultrafine Co ₃ O ₄ /Graphene Composites for High-Rate Supercapacitor Electrodes Yang, Shuhua; Liu, Yuanyue; Hao, Yufeng Advanced Science, Vol. 5, Issue 4 https://doi.org/10.1002/advs.201700659	journal	January 2018
The Effect of Crystallinity on the Rapid Pseudocapacitive Response of Nb2O5 Kim, Jong Woung; Augustyn, Veronica; Dunn, Bruce Advanced Energy Materials, Vol. 2, Issue 1 https://doi.org/10.1002/aenm.201100494	journal	December 2011
Porous Electrode Materials for Lithium-Ion Batteries - How to Prepare Them and What Makes Them Special Vu, Anh; Qian, Yuqiang; Stein, Andreas Advanced Energy Materials, Vol. 2, Issue 9 https://doi.org/10.1002/aenm.201200320	journal	August 2012
Identification of Phase Control of Carbon‐Confined Nb ₂ O ₅ Nanoparticles toward High‐Performance Lithium Storage Meng, Jiashen; He, Qiu; Xu, Linhan Advanced Energy Materials, Vol. 9, Issue 18 https://doi.org/10.1002/aenm.201802695	journal	March 2019
3D Architectures for Batteries and Electrodes Long, Jeffrey W.; Dunn, Bruce; Rolison, Debra R. Advanced Energy Materials, Vol. 10, Issue 46 https://doi.org/10.1002/aenm.202002457	journal	October 2020
A Resol-Assisted Co-Assembly Approach to Crystalline Mesoporous Niobia Spheres for Electrochemical Biosensing Luo, Wei; Li, Yuhui; Dong, Junping Angewandte Chemie, Vol. 125, Issue 40 https://doi.org/10.1002/ange.201303353	journal	August 2013
A Hollow Multi‐Shelled Structure for Charge Transport and Active Sites in Lithium‐Ion Capacitors Bi, Ruyi; Xu, Nan; Ren, Hao Angewandte Chemie, Vol. 132, Issue 12 https://doi.org/10.1002/ange.201914680	journal	January 2020
High-Performance Hybrid Supercapacitor Based on Graphene-Wrapped Mesoporous T -Nb ₂ O ₅ Nanospheres Anode and Mesoporous Carbon-Coated Graphene Cathode Ma, Guoqiang; Li, Ke; Li, Yuanyuan ChemElectroChem, Vol. 3, Issue 9 https://doi.org/10.1002/celc.201600181	journal	June 2016
Nitrogenated Urchin-like Nb ₂ O ₅ Microspheres with Extraordinary Pseudocapacitive Properties for Lithium-Ion Capacitors Chen, Zhijie; Li, Hongsen; Lu, Xiaoxia ChemElectroChem, Vol. 5, Issue 11 https://doi.org/10.1002/celc.201701390	journal	April 2018
Microwave-Assisted Rapid Synthesis of Self-Assembled T-Nb ₂ O ₅ Nanowires for High-Energy Hybrid Supercapacitors Yang, Huiling; Xu, Henghui; Wang, Libin Chemistry - A European Journal, Vol. 23, Issue 17 https://doi.org/10.1002/chem.201700010	journal	February 2017
Laser‐Assisted Fabrication of Pseudohexagonal Phase Niobium Pentoxide Nanopillars for Lithium Ion Battery Anodes Liang, Dewei; Hu, Lei; Wang, Lili ChemNanoMat, Vol. 6, Issue 1 https://doi.org/10.1002/cnma.201900532	journal	October 2019
Enhanced pseudocapacitive energy storage properties of Nb ₂ O ₅ /C core‐shell structures with the surface modification Kim, Jong Woung; Kim, Sang‐Ok; Kim, Hyung‐Seok International Journal of Energy Research, Vol. 43, Issue 9 https://doi.org/10.1002/er.4561	journal	May 2019
Niobium‐Based Oxides Toward Advanced Electrochemical Energy Storage: Recent Advances and Challenges Deng, Qinglin; Fu, Yanpeng; Zhu, Changbao Small, Vol. 15, Issue 32 https://doi.org/10.1002/smll.201804884	journal	February 2019
Full Gamut Wall Tunability from Persistent Micelle Templates via Ex Situ Hydrolysis Lantz, Kayla A.; Clamp, Nicholas Blake; van den Bergh, Wessel Small, Vol. 15, Issue 18 https://doi.org/10.1002/smll.201900393	journal	March 2019
Controllable synthesis of gossamer-like Nb2O5-RGO nanocomposite and its application to supercapacitor Hu, Weibing; Zhang, Sumeng; Zhang, Wen Journal of Nanoparticle Research, Vol. 22, Issue 3 https://doi.org/10.1007/s11051-020-4779-8	journal	February 2020
Highly bonded T-Nb2O5/rGO nanohybrids for 4 V quasi-solid state asymmetric supercapacitors with improved electrochemical performance Jiao, Yuzhi; Zhang, Haitao; Zhang, Hailang Nano Research, Vol. 11, Issue 9 https://doi.org/10.1007/s12274-018-2049-1	journal	April 2018
Structural changes of Nb2O5 and V2O5 as rechargeable cathodes for lithium battery Kumagai, Naoaki; Tanno, Kazuo; Nakajima, Tsuyoshi Electrochimica Acta, Vol. 28, Issue 1 https://doi.org/10.1016/0013-4686(83)85081-6	journal	January 1983
EXAFS study of the hydrolysis of niobium pentaethoxide Vandenborre, M. T.; Poumellec, B.; Alquier, C. Journal of Non-Crystalline Solids, Vol. 108, Issue 3 https://doi.org/10.1016/0022-3093(89)90305-0	journal	April 1989
Etude EXAFS de la formation d'oxyde Nb2O5 par hydrolyse-condensation de chloroethoxyde de niobium Vandenborre, Marie Thérèse; Poumellec, Bertrand; Livage, Jacques Journal of Solid State Chemistry, Vol. 83, Issue 1 https://doi.org/10.1016/0022-4596(89)90059-5	journal	November 1989
Characterization of sol-gel deposited niobium pentoxide films for electrochromic devices Özer, Nilgün; Barreto, Timothy; Büyüklimanli, Temel Solar Energy Materials and Solar Cells, Vol. 36, Issue 4 https://doi.org/10.1016/0927-0248(94)00197-9	journal	April 1995
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Ruthenium dioxide: A new interesting electrode material. Solid state structure and electrochemical behaviour Trasatti, Sergio; Buzzanca, Giovanni Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 29, Issue 2 https://doi.org/10.1016/S0022-0728(71)80111-0	journal	February 1971
The role and utilization of pseudocapacitance for energy storage by supercapacitors Conway, B. E.; Birss, V.; Wojtowicz, J. Journal of Power Sources, Vol. 66, Issue 1-2 https://doi.org/10.1016/S0378-7753(96)02474-3	journal	May 1997
Chemical vapour deposition — a new approach to reactive surface defects of uniform geometry on high surface area magnesium oxide Knözinger, E.; Diwald, O.; Sterrer, M. Journal of Molecular Catalysis A: Chemical, Vol. 162, Issue 1-2 https://doi.org/10.1016/S1381-1169(00)00323-X	journal	November 2000
Electrochemistry and biosensing reactivity of heme proteins adsorbed on the structure-tailored mesoporous Nb2O5 matrix Xu, Xin; Tian, Bozhi; Zhang, Song Analytica Chimica Acta, Vol. 519, Issue 1 https://doi.org/10.1016/j.aca.2004.05.061	journal	August 2004
Structural and electrical properties of Bi2O3–Nb2O5 thin films grown at low temperatures by pulsed laser deposition Sun, Jong-Woo; Kang, Lee-Seung; Kim, Jin-Seong Acta Materialia, Vol. 59, Issue 14 https://doi.org/10.1016/j.actamat.2011.05.017	journal	August 2011
Oxygen vacancy boosted the electrochemistry performance of Ti4+ doped Nb2O5 toward lithium ion battery Zhai, Ximei; Liu, Jialin; Zhao, Yongjie Applied Surface Science, Vol. 499 https://doi.org/10.1016/j.apsusc.2019.143905	journal	January 2020
Controlling the morphology, size and phase of Nb2O5 crystals for high electrochemical performance Liao, Jiaqin; Tan, Rou; Kuang, Zhixiang Chinese Chemical Letters, Vol. 29, Issue 12 https://doi.org/10.1016/j.cclet.2018.11.018	journal	December 2018
Pseudocapacitive material with 928 mAh cm−3 particle-level volumetric specific capacity enabled by continuous phase-transition Ge, Xiang; Gu, Changdong; Yao, Zhujun Chemical Engineering Journal, Vol. 338 https://doi.org/10.1016/j.cej.2018.01.001	journal	April 2018
Probing the dominance of interstitial oxygen defects in ZnO nanoparticles through structural and optical characterizations Sahai, Anshuman; Goswami, Navendu Ceramics International, Vol. 40, Issue 9 https://doi.org/10.1016/j.ceramint.2014.06.041	journal	November 2014
Box-implanted Nb2O5 nanorods as superior anode materials in lithium ion batteries Shi, Chongfu; Xiang, Kaixiong; Zhu, Yirong Ceramics International, Vol. 43, Issue 15 https://doi.org/10.1016/j.ceramint.2017.06.105	journal	October 2017
Template-free synthesis of highly ordered 3D-hollow hierarchical Nb 2 O 5 superstructures as an asymmetric supercapacitor by using inorganic electrolyte Idrees, Faryal; Hou, Jianhua; Cao, Chuanbao Electrochimica Acta, Vol. 216 https://doi.org/10.1016/j.electacta.2016.09.031	journal	October 2016
A template-free synthesis via alkaline route for Nb2O5/carbon nanotubes composite as pseudo-capacitor material with high-rate performance Luo, Guoming; Li, Heshun; Zhang, Daquan Electrochimica Acta, Vol. 235 https://doi.org/10.1016/j.electacta.2017.03.112	journal	May 2017
Construction of T-Nb2O5 nanoparticles on/in N-doped carbon hollow tubes for Li-ion hybrid supercapacitors Lian, Yue; Wang, Dawei; Hou, Shuangyue Electrochimica Acta, Vol. 330 https://doi.org/10.1016/j.electacta.2019.135204	journal	January 2020
Self-assembly Nb2O5 microsphere with hollow and carbon coated structure as high rate capability lithium-ion electrode materials Hu, Jiajun; Li, Jiajia; Wang, Kai Electrochimica Acta, Vol. 331 https://doi.org/10.1016/j.electacta.2019.135364	journal	January 2020
Synthesis of T-Nb2O5 thin-films deposited by Atomic Layer Deposition for miniaturized electrochemical energy storage devices Ouendi, Saliha; Arico, Cassandra; Blanchard, Florent Energy Storage Materials, Vol. 16 https://doi.org/10.1016/j.ensm.2018.08.022	journal	January 2019
Architecturing aligned orthorhombic Nb2O5 nanowires toward sodium-ion hybrid capacitor and Lithium–Sulfur battery applications Jin, Jia; Cai, Jingsheng; Wang, Xiangguo FlatChem, Vol. 27 https://doi.org/10.1016/j.flatc.2021.100236	journal	May 2021
Orthorhombic Nb2O5- for Durable High-Rate Anode of Li-Ion Batteries Liu, Zichao; Dong, Wujie; Wang, Jianbo iScience, Vol. 23, Issue 1 https://doi.org/10.1016/j.isci.2019.100767	journal	January 2020
Facile preparation of flower-like hierarchical Nb2O5 microspheres self-assembled by nanorod for high-power anodes in advanced hybrid supercapacitor Zhai, Jing; Wu, Yanbo; Zhao, Xiaomin Journal of Alloys and Compounds, Vol. 715 https://doi.org/10.1016/j.jallcom.2017.04.314	journal	August 2017
Design of Nb2O5@rGO composites to optimize the lithium-ion storage performance Kang, Rong; Li, Sheng; Zou, Bobo Journal of Alloys and Compounds, Vol. 865 https://doi.org/10.1016/j.jallcom.2021.158824	journal	June 2021
Oxygen vacancies enhance the lithium ion intercalation pseudocapacitive properties of orthorhombic niobium pentoxide Zhang, Songmin; Liu, Guanglan; Qiao, Wenming Journal of Colloid and Interface Science, Vol. 562 https://doi.org/10.1016/j.jcis.2019.12.015	journal	March 2020
Electrospun Nb2O5 nanorods/microporous multichannel carbon nanofiber film anode for Na+ ion capacitors with good performance She, Liaona; Zhang, Feng; Jia, Congying Journal of Colloid and Interface Science, Vol. 573 https://doi.org/10.1016/j.jcis.2020.03.122	journal	August 2020
Pseudocapacitive T-Nb2O5/N-doped carbon nanosheets anode enable high performance lithium-ion capacitors Jiang, Songbai; Dong, Shengyang; Wu, Langyuan Journal of Electroanalytical Chemistry, Vol. 842 https://doi.org/10.1016/j.jelechem.2019.04.042	journal	June 2019
Flexible Nb2O5 nanowires/graphene film electrode for high-performance hybrid Li-ion supercapacitors Song, Hao; Fu, Jijiang; Ding, Kang Journal of Power Sources, Vol. 328 https://doi.org/10.1016/j.jpowsour.2016.08.052	journal	October 2016
High-rate capability of three-dimensionally ordered macroporous T-Nb2O5 through Li+ intercalation pseudocapacitance Lou, Shuaifeng; Cheng, Xinqun; Wang, Long Journal of Power Sources, Vol. 361 https://doi.org/10.1016/j.jpowsour.2017.06.023	journal	September 2017
Mesoporous orthorhombic Nb2O5 nanofibers as pseudocapacitive electrodes with ultra-stable Li storage characteristics Cheong, Jun Young; Jung, Ji-Won; Youn, Doo-Young Journal of Power Sources, Vol. 360 https://doi.org/10.1016/j.jpowsour.2017.06.030	journal	August 2017
Constructing T-Nb2O5@Carbon hollow core-shell nanostructures for high-rate hybrid supercapacitor Zhang, Songmin; Wu, Jiawen; Wang, Jitong Journal of Power Sources, Vol. 396 https://doi.org/10.1016/j.jpowsour.2018.06.007	journal	August 2018
Controlled synthesis of pure-phase metastable tetragonal Nb2O5 anode material for high-performance lithium batteries Ding, Huibin; Song, Zihan; Feng, Kai Journal of Solid State Chemistry, Vol. 299 https://doi.org/10.1016/j.jssc.2021.122136	journal	July 2021
Ordered-mesoporous Nb2O5/carbon composite as a sodium insertion material Kim, Haegyeom; Lim, Eunho; Jo, Changshin Nano Energy, Vol. 16 https://doi.org/10.1016/j.nanoen.2015.05.015	journal	September 2015
Intercalation pseudocapacitance of amorphous titanium dioxide@nanoporous graphene for high-rate and large-capacity energy storage Han, Jiuhui; Hirata, Akihiko; Du, Jing Nano Energy, Vol. 49 https://doi.org/10.1016/j.nanoen.2018.04.063	journal	July 2018
3D N-doped hybrid architectures assembled from 0D T-Nb2O5 embedded in carbon microtubes toward high-rate Li-ion capacitors Hemmati, Sahar; Li, Ge; Wang, Xiaolei Nano Energy, Vol. 56 https://doi.org/10.1016/j.nanoen.2018.10.048	journal	February 2019
XPS spectroscopy, structural, magnetic and dielectric investigations of CaGdAlO4 and Yb:CaGdAlO4 single crystals Talik, E.; Kisielewski, J.; Zajdel, P. Optical Materials, Vol. 91 https://doi.org/10.1016/j.optmat.2019.03.041	journal	May 2019
Holy Grails in Chemistry: Investigating and Understanding Fast Electron/Cation Coupled Transport within Inorganic Ionic Matrices Smith, Paul F.; Takeuchi, Kenneth J.; Marschilok, Amy C. Accounts of Chemical Research, Vol. 50, Issue 3 https://doi.org/10.1021/acs.accounts.6b00540	journal	March 2017
Ordered Mesoporous to Macroporous Oxides with Tunable Isomorphic Architectures: Solution Criteria for Persistent Micelle Templates Lokupitiya, Hasala N.; Jones, Alexis; Reid, Barry Chemistry of Materials, Vol. 28, Issue 6 https://doi.org/10.1021/acs.chemmater.5b04407	journal	February 2016
Amorphization as a Pathway to Fast Charging Kinetics in Atomic Layer Deposition-Derived Titania Films for Lithium Ion Batteries Ye, Jianchao; Shea, Patrick; Baumgaertel, Andreas C. Chemistry of Materials, Vol. 30, Issue 24 https://doi.org/10.1021/acs.chemmater.8b04002	journal	November 2018
An Unavoidable Challenge for Ni-Rich Positive Electrode Materials for Lithium-Ion Batteries Li, Hongyang; Liu, Aaron; Zhang, Ning Chemistry of Materials, Vol. 31, Issue 18 https://doi.org/10.1021/acs.chemmater.9b02372	journal	August 2019
Pseudocapacitance: From Fundamental Understanding to High Power Energy Storage Materials Fleischmann, Simon; Mitchell, James B.; Wang, Ruocun Chemical Reviews, Vol. 120, Issue 14 https://doi.org/10.1021/acs.chemrev.0c00170	journal	June 2020
Synthesis of High Reversibility Anode Composite Materials Using T-Nb ₂ O ₅ and Coal-Based Graphite for Lithium-Ion Battery Applications Qu, Xiaoxiao; Liu, Yuhao; Li, Binbin Energy & Fuels, Vol. 34, Issue 3 https://doi.org/10.1021/acs.energyfuels.9b04106	journal	February 2020
Physical Interpretations of Electrochemical Impedance Spectroscopy of Redox Active Electrodes for Electrical Energy Storage Mei, Bing-Ang; Lau, Jonathan; Lin, Terri The Journal of Physical Chemistry C, Vol. 122, Issue 43 https://doi.org/10.1021/acs.jpcc.8b05241	journal	September 2018
Expanded Kinetic Control for Persistent Micelle Templates with Solvent Selection Sarkar, Amrita; Evans, Laurel; Stefik, Morgan Langmuir, Vol. 34, Issue 20 https://doi.org/10.1021/acs.langmuir.8b00417	journal	April 2018
Construction of a Flexible Nb ₂ O ₅ /Carboxyl Multiwalled Carbon Nanotube Film as Anode for Lithium and Sodium Storages Kang, Jinwei; Zhang, Huiwen; Zhan, Ziyi ACS Applied Energy Materials, Vol. 3, Issue 12 https://doi.org/10.1021/acsaem.0c01988	journal	November 2020
Carbon-Coated Self-Assembled Ultrathin T-Nb ₂ O ₅ Nanosheets for High-Rate Lithium-Ion Storage with Superior Cycling Stability Li, Yang; Wang, Yan; Cui, Guirong ACS Applied Energy Materials, Vol. 3, Issue 12 https://doi.org/10.1021/acsaem.0c02180	journal	December 2020
Differentiating Double-Layer, Psuedocapacitance, and Battery-like Mechanisms by Analyzing Impedance Measurements in Three Dimensions Ko, Jesse S.; Lai, Chun-Han; Long, Jeffrey W. ACS Applied Materials & Interfaces, Vol. 12, Issue 12 https://doi.org/10.1021/acsami.0c02020	journal	March 2020
Atomistic Insights into Lithium Storage Mechanisms in Anatase, Rutile, and Amorphous TiO ₂ Electrodes Yuwono, Jodie A.; Burr, Patrick; Galvin, Conor ACS Applied Materials & Interfaces, Vol. 13, Issue 1 https://doi.org/10.1021/acsami.0c17097	journal	January 2021
Precisely Tunable T-Nb ₂ O ₅ Nanotubes via Atomic Layer Deposition for Fast-Charging Lithium-Ion Batteries Li, Na; Lan, Xiwei; Wang, Libin ACS Applied Materials & Interfaces, Vol. 13, Issue 14 https://doi.org/10.1021/acsami.1c02207	journal	April 2021
Long-Lasting Nb ₂ O ₅ -Based Nanocomposite Materials for Li-Ion Storage Song, Min Yeong; Kim, Na Rae; Yoon, Hyeon Ji ACS Applied Materials & Interfaces, Vol. 9, Issue 3 https://doi.org/10.1021/acsami.6b11444	journal	January 2017
How Do Pseudocapacitors Store Energy? Theoretical Analysis and Experimental Illustration Costentin, Cyrille; Porter, Thomas R.; Savéant, Jean-Michel ACS Applied Materials & Interfaces, Vol. 9, Issue 10 https://doi.org/10.1021/acsami.6b14100	journal	March 2017
Challenges for and Pathways toward Li-Metal-Based All-Solid-State Batteries Albertus, Paul; Anandan, Venkataramani; Ban, Chunmei ACS Energy Letters https://doi.org/10.1021/acsenergylett.1c00445	journal	March 2021
Facile Synthesis of Nb ₂ O ₅ @Carbon Core–Shell Nanocrystals with Controlled Crystalline Structure for High-Power Anodes in Hybrid Supercapacitors Lim, Eunho; Jo, Changshin; Kim, Haegyeom ACS Nano, Vol. 9, Issue 7 https://doi.org/10.1021/acsnano.5b02601	journal	June 2015
Oxygen-Deficient TiO _2−δ Nanoparticles via Hydrogen Reduction for High Rate Capability Lithium Batteries Shin, Ji-Yong; Joo, Jong Hoon; Samuelis, Dominik Chemistry of Materials, Vol. 24, Issue 3 https://doi.org/10.1021/cm2031009	journal	December 2011
Challenges for Rechargeable Li Batteries Goodenough, John B.; Kim, Youngsik Chemistry of Materials, Vol. 22, Issue 3, p. 587-603 https://doi.org/10.1021/cm901452z	journal	February 2010
Ultrasmall Titania Nanocrystals and Their Direct Assembly into Mesoporous Structures Showing Fast Lithium Insertion Szeifert, Johann M.; Feckl, Johann M.; Fattakhova-Rohlfing, Dina Journal of the American Chemical Society, Vol. 132, Issue 36 https://doi.org/10.1021/ja101810e	journal	September 2010
Pseudocapacitive Contributions to Charge Storage in Highly Ordered Mesoporous Group V Transition Metal Oxides with Iso-Oriented Layered Nanocrystalline Domains Brezesinski, Kirstin; Wang, John; Haetge, Jan Journal of the American Chemical Society, Vol. 132, Issue 20, p. 6982-6990 https://doi.org/10.1021/ja9106385	journal	May 2010
High-Rate Intercalation without Nanostructuring in Metastable Nb ₂ O ₅ Bronze Phases Griffith, Kent J.; Forse, Alexander C.; Griffin, John M. Journal of the American Chemical Society, Vol. 138, Issue 28 https://doi.org/10.1021/jacs.6b04345	journal	July 2016
Unraveling the Nature of Anomalously Fast Energy Storage in T-Nb ₂ O ₅ Chen, Dongchang; Wang, Jeng-Han; Chou, Tsung-Fu Journal of the American Chemical Society, Vol. 139, Issue 20 https://doi.org/10.1021/jacs.7b03141	journal	May 2017
Drying of Organic Solvents: Quantitative Evaluation of the Efficiency of Several Desiccants Williams, D. Bradley G.; Lawton, Michelle The Journal of Organic Chemistry, Vol. 75, Issue 24 https://doi.org/10.1021/jo101589h	journal	December 2010
Nanostructured Nb ₂ O ₅ Polymorphs by Electrospinning for Rechargeable Lithium Batteries Viet, A. Le; Reddy, M. V.; Jose, R. The Journal of Physical Chemistry C, Vol. 114, Issue 1 https://doi.org/10.1021/jp9088589	journal	November 2009
Li ⁺ Ion Insertion in TiO ₂ (Anatase). 2. Voltammetry on Nanoporous Films Lindström, Henrik; Södergren, Sven; Solbrand, Anita The Journal of Physical Chemistry B, Vol. 101, Issue 39 https://doi.org/10.1021/jp970490q	journal	September 1997
Vacancies and Electron Deficient Surface Anions on the Surface of MgO Nanoparticles Sterrer, M.; Diwald, O.; Knözinger, E. The Journal of Physical Chemistry B, Vol. 104, Issue 15 https://doi.org/10.1021/jp993924l	journal	March 2000
EPR Study of the Surface Characteristics of Nanostructured TiO ₂ under UV Irradiation Coronado, Juan M.; Maira, A. Javier; Conesa, José Carlos Langmuir, Vol. 17, Issue 17 https://doi.org/10.1021/la010153f	journal	August 2001
Connection between Polymer Molecular Weight, Density, Chain Dimensions, and Melt Viscoelastic Properties Fetters, L. J.; Lohse, D. J.; Richter, D. Macromolecules, Vol. 27, Issue 17 https://doi.org/10.1021/ma00095a001	journal	August 1994
Advanced Hybrid Supercapacitor Based on a Mesoporous Niobium Pentoxide/Carbon as High-Performance Anode Lim, Eunho; Kim, Haegyeom; Jo, Changshin ACS Nano, Vol. 8, Issue 9 https://doi.org/10.1021/nn501972w	journal	August 2014
Multidimensional materials and device architectures for future hybrid energy storage Lukatskaya, Maria R.; Dunn, Bruce; Gogotsi, Yury Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12647	journal	September 2016
High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance Augustyn, Veronica; Come, Jérémy; Lowe, Michael A. Nature Materials, Vol. 12, Issue 6 https://doi.org/10.1038/nmat3601	journal	April 2013
Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3−x Kim, Hyung-Seok; Cook, John B.; Lin, Hao Nature Materials, Vol. 16, Issue 4 https://doi.org/10.1038/nmat4810	journal	December 2016
The misuse of colour in science communication Crameri, Fabio; Shephard, Grace E.; Heron, Philip J. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-19160-7	journal	October 2020
Achieving high energy density and high power density with pseudocapacitive materials Choi, Christopher; Ashby, David S.; Butts, Danielle M. Nature Reviews Materials, Vol. 5, Issue 1 https://doi.org/10.1038/s41578-019-0142-z	journal	October 2019
Block copolymer based composition and morphology control in nanostructured hybrid materials for energy conversion and storage: solar cells, batteries, and fuel cells Orilall, M. Christopher; Wiesner, Ulrich Chem. Soc. Rev., Vol. 40, Issue 2 https://doi.org/10.1039/C0CS00034E	journal	January 2011
Control parameters for electrochemically relevant materials: the significance of size and complexity Maier, J. Faraday Discuss., Vol. 176 https://doi.org/10.1039/C4FD00135D	journal	January 2014
High-power and high-energy asymmetric supercapacitors based on Li ⁺ -intercalation into a T-Nb ₂ O ₅ /graphene pseudocapacitive electrode Kong, Lingping; Zhang, Chuanfang; Zhang, Songmin J. Mater. Chem. A, Vol. 2, Issue 42 https://doi.org/10.1039/C4TA03604B	journal	January 2014
Comparison of amorphous, pseudohexagonal and orthorhombic Nb ₂ O ₅ for high-rate lithium ion insertion Li, Shuang; Xu, Qian; Uchaker, Evan CrystEngComm, Vol. 18, Issue 14 https://doi.org/10.1039/C5CE02069G	journal	January 2016
Cavitation-enabled rapid and tunable evolution of high-χN micelles as templates for ordered mesoporous oxides Lokupitiya, Hasala N.; Stefik, Morgan Nanoscale, Vol. 9, Issue 4 https://doi.org/10.1039/C6NR07313A	journal	January 2017
How to make persistent micelle templates in 24 hours and know it using X-ray scattering Sarkar, Amrita; Stefik, Morgan Journal of Materials Chemistry A, Vol. 5, Issue 23 https://doi.org/10.1039/C7TA01034F	journal	January 2017
T -Nb ₂ O ₅ nanoparticle enabled pseudocapacitance with fast Li-ion intercalation Kong, Lingping; Liu, Xiaoteng; Wei, Jinjia Nanoscale, Vol. 10, Issue 29 https://doi.org/10.1039/C8NR03495H	journal	January 2018
T-Nb ₂ O ₅ embedded carbon nanosheets with superior reversibility and rate capability as an anode for high energy Li-ion capacitors Li, Dong; Shi, Jing; Liu, Haolin Sustainable Energy & Fuels, Vol. 3, Issue 4 https://doi.org/10.1039/C9SE00052F	journal	January 2019
Widely tunable persistent micelle templates via homopolymer swelling Sarkar, Amrita; Thyagarajan, Akshay; Cole, August Soft Matter, Vol. 15, Issue 26 https://doi.org/10.1039/C9SM00484J	journal	January 2019
Self-assembly of block copolymers towards mesoporous materials for energy storage and conversion systems Li, Chen; Li, Qian; Kaneti, Yusuf Valentino Chemical Society Reviews, Vol. 49, Issue 14 https://doi.org/10.1039/D0CS00021C	journal	January 2020
Oxygen-deficient metal oxide nanostructures for photoelectrochemical water oxidation and other applications Wang, Gongming; Ling, Yichuan; Li, Yat Nanoscale, Vol. 4, Issue 21 https://doi.org/10.1039/c2nr32222f	journal	January 2012
Pseudocapacitive oxide materials for high-rate electrochemical energy storage Augustyn, Veronica; Simon, Patrice; Dunn, Bruce Energy & Environmental Science, Vol. 7, Issue 5 https://doi.org/10.1039/c3ee44164d	journal	January 2014
Understanding the origin of high-rate intercalation pseudocapacitance in Nb2O5 crystals Lubimtsev, Andrew A.; Kent, Paul R. C.; Sumpter, Bobby G. Journal of Materials Chemistry A, Vol. 1, Issue 47 https://doi.org/10.1039/c3ta13316h	journal	January 2013
Solution of the Percus–Yevick approximation of the multicomponent adhesive spheres system applied to the small angle x‐ray scattering from microemulsions Robertus, C.; Philipse, W. H.; Joosten, J. G. H. The Journal of Chemical Physics, Vol. 90, Issue 8 https://doi.org/10.1063/1.456635	journal	April 1989
Design of Nb ₂ O ₅ /graphene hybrid aerogel as polymer binder-free electrodes for lithium-ion capacitors Li, Yanni; Wang, Ronghua; Zheng, Weikang Materials Technology, Vol. 35, Issue 9-10 https://doi.org/10.1080/10667857.2020.1734720	journal	March 2020
Subtle local structural variations in oxygen deficient niobium germanate thin film glasses as revealed by x-ray absorption spectroscopy Sahiner, M. A.; Nabizadeh, A.; Rivella, D. Journal of Physics: Conference Series, Vol. 712 https://doi.org/10.1088/1742-6596/712/1/012103	journal	May 2016
The Scherrer Formula for X-Ray Particle Size Determination Patterson, A. L. Physical Review, Vol. 56, Issue 10 https://doi.org/10.1103/PhysRev.56.978	journal	November 1939
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Projector augmented-wave method Blöchl, P. E. Physical Review B, Vol. 50, Issue 24, p. 17953-17979 https://doi.org/10.1103/PhysRevB.50.17953	journal	December 1994
Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Mechanism of Interstitial Oxygen Diffusion in Hafnia Foster, A. S.; Shluger, A. L.; Nieminen, R. M. Physical Review Letters, Vol. 89, Issue 22 https://doi.org/10.1103/PhysRevLett.89.225901	journal	November 2002
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
Polymer blend directed anisotropic self-assembly toward mesoporous inorganic bowls and nanosheets Kim, Seongseop; Hwang, Jongkook; Lee, Jisung Science Advances, Vol. 6, Issue 33 https://doi.org/10.1126/sciadv.abb3814	journal	August 2020
Three-dimensional holey-graphene/niobia composite architectures for ultrahigh-rate energy storage Sun, Hongtao; Mei, Lin; Liang, Junfei Science, Vol. 356, Issue 6338 https://doi.org/10.1126/science.aam5852	journal	May 2017
Issues and challenges facing rechargeable lithium batteries Tarascon, J. -M.; Armand, M. Materials for Sustainable Energy https://doi.org/10.1142/9789814317665_0024	book	October 2010
Verification of Interstitial Oxygen in Gd: PbWO4 Huang, Hong-Wei; Ye, Zuo-Guang; Dong, Ming Japanese Journal of Applied Physics, Vol. 41, Issue Part 2, No. 6B https://doi.org/10.1143/JJAP.41.L713	journal	June 2002
Behavior of Molybdenum Nitrides as Materials for Electrochemical Capacitors Liu, T. -C. Journal of The Electrochemical Society, Vol. 145, Issue 6 https://doi.org/10.1149/1.1838571	journal	January 1998
A New Charge Storage Mechanism for Electrochemical Capacitors Zheng, J. P. Journal of The Electrochemical Society, Vol. 142, Issue 1 https://doi.org/10.1149/1.2043984	journal	January 1995
Hydrous Ruthenium Oxide as an Electrode Material for Electrochemical Capacitors Zheng, J. P. Journal of The Electrochemical Society, Vol. 142, Issue 8 https://doi.org/10.1149/1.2050077	journal	January 1995
Transition from “Supercapacitor” to “Battery” Behavior in Electrochemical Energy Storage Conway, B. E. Journal of The Electrochemical Society, Vol. 138, Issue 6, p. 1539-1548 https://doi.org/10.1149/1.2085829	journal	January 1991
A Guide to Li-Ion Coin-Cell Electrode Making for Academic Researchers Marks, Thomas; Trussler, Simon; Smith, A. J. Journal of The Electrochemical Society, Vol. 158, Issue 1 https://doi.org/10.1149/1.3515072	journal	January 2011
TiO2-Based Thin Film Transistors with Amorphous and Anatase Channel Layer Shih, W. S.; Young, S. J.; Ji, L. W. Journal of The Electrochemical Society, Vol. 158, Issue 6 https://doi.org/10.1149/1.3561271	journal	January 2011
Superior Electrochemical Performance of Amorphous Titanium Niobium Oxide Thin Films for Li-Ion Thin Film Batteries Daramalla, V.; Venkatesh, G.; Kishore, B. Journal of The Electrochemical Society, Vol. 165, Issue 5 https://doi.org/10.1149/2.0161805jes	journal	January 2018
To Be or Not To Be Pseudocapacitive? Brousse, Thierry; Bélanger, Daniel; Long, Jeffrey W. Journal of The Electrochemical Society, Vol. 162, Issue 5 https://doi.org/10.1149/2.0201505jes	journal	January 2015
Investigation of the Li-Ion Insertion Mechanism for Amorphous and Anatase TiO ₂ Thin-Films Moitzheim, S.; De Gendt, S.; Vereecken, P. M. Journal of The Electrochemical Society, Vol. 166, Issue 2 https://doi.org/10.1149/2.1091816jes	journal	January 2019
A Guide to Full Coin Cell Making for Academic Researchers Murray, Vivian; Hall, David S.; Dahn, J. R. Journal of The Electrochemical Society, Vol. 166, Issue 2 https://doi.org/10.1149/2.1171902jes	journal	January 2019
Surfactant-Free Synthesis of Nb2O5 Nanoparticles Anchored Graphene Nanocomposites with Enhanced Electrochemical Performance for Supercapacitor Electrodes Nagaraju, P.; Vasudevan, R.; Alsalme, A. Nanomaterials, Vol. 10, Issue 1 https://doi.org/10.3390/nano10010160	journal	January 2020

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