Single-atom implanted two-dimensional MOFs as efficient electrocatalysts for the oxygen evolution reaction
Abstract
The exploration of novel electrochemical energy conversion and storage devices has been extensively studied in recent decades for their specific advantages. Therefore, the design of highly efficient, stable, and noble-metal-free electrocatalysts for oxygen-related reactions (OER) is critical but challenging and is still worth improving. Herein, a facile and controllable synthesis strategy for bimetallic electrocatalysts for the OER from a two-dimensional iron-based metal–organic framework (HUST-8, HUST = Huazhong University of Science and Technology) precursor has been reported. The unoccupied porphyrin center has been disposed into the layer structure of HUST-8, which is very facile for the introduction of a second type of metal center via post-modification treatment. Guided by the synthesis strategy, Fe/Ni, Fe/Co, Fe/Zn, Fe/Mn and Fe/Fe species have been fabricated, and their electrocatalytic performance for the OER has been further characterized, among which the Fe/Ni type exhibits the best efficiency and conversion. For Fe/Ni species of HUST-8 (labeled as Ni@HUST-8), in 1 M KOH, the initial potential for OER activity performance is 170 mV (vs. RHE). At 10 mA cm-2, the corresponding overpotential is 240 mV and the Tafel slope is simulated as 60.8 mV dec-1. All of these experimental results of Ni@HUST-8 illustrate its better performance than commercialmore »
- Authors:
-
[2];
[1];
[2]
- Huazhong Univ. of Science and Technology, Wuhan (China)
- Texas A & M Univ., College Station, TX (United States)
- Publication Date:
- Research Org.:
- Texas A & M Univ., College Station, TX (United States)
- Sponsoring Org.:
- USDOE Office of Fossil Energy (FE); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1849175
- Alternate Identifier(s):
- OSTI ID: 1698216
- Grant/Contract Number:
- FE0026472; SC0001015; DESC0001015
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganic Chemistry Frontiers (Online)
- Additional Journal Information:
- Journal Name: Inorganic Chemistry Frontiers (Online); Journal Volume: 7; Journal Issue: 23; Journal ID: ISSN 2052-1553
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Peng, Rui-Li, Li, Jia-Luo, Wang, Xiao-Ning, Zhao, Yu-Meng, Li, Bao, Xia, Bao Yu, and Zhou, Hong-Cai. Single-atom implanted two-dimensional MOFs as efficient electrocatalysts for the oxygen evolution reaction. United States: N. p., 2020.
Web. doi:10.1039/d0qi00812e.
Peng, Rui-Li, Li, Jia-Luo, Wang, Xiao-Ning, Zhao, Yu-Meng, Li, Bao, Xia, Bao Yu, & Zhou, Hong-Cai. Single-atom implanted two-dimensional MOFs as efficient electrocatalysts for the oxygen evolution reaction. United States. https://doi.org/10.1039/d0qi00812e
Peng, Rui-Li, Li, Jia-Luo, Wang, Xiao-Ning, Zhao, Yu-Meng, Li, Bao, Xia, Bao Yu, and Zhou, Hong-Cai. Tue .
"Single-atom implanted two-dimensional MOFs as efficient electrocatalysts for the oxygen evolution reaction". United States. https://doi.org/10.1039/d0qi00812e. https://www.osti.gov/servlets/purl/1849175.
@article{osti_1849175,
title = {Single-atom implanted two-dimensional MOFs as efficient electrocatalysts for the oxygen evolution reaction},
author = {Peng, Rui-Li and Li, Jia-Luo and Wang, Xiao-Ning and Zhao, Yu-Meng and Li, Bao and Xia, Bao Yu and Zhou, Hong-Cai},
abstractNote = {The exploration of novel electrochemical energy conversion and storage devices has been extensively studied in recent decades for their specific advantages. Therefore, the design of highly efficient, stable, and noble-metal-free electrocatalysts for oxygen-related reactions (OER) is critical but challenging and is still worth improving. Herein, a facile and controllable synthesis strategy for bimetallic electrocatalysts for the OER from a two-dimensional iron-based metal–organic framework (HUST-8, HUST = Huazhong University of Science and Technology) precursor has been reported. The unoccupied porphyrin center has been disposed into the layer structure of HUST-8, which is very facile for the introduction of a second type of metal center via post-modification treatment. Guided by the synthesis strategy, Fe/Ni, Fe/Co, Fe/Zn, Fe/Mn and Fe/Fe species have been fabricated, and their electrocatalytic performance for the OER has been further characterized, among which the Fe/Ni type exhibits the best efficiency and conversion. For Fe/Ni species of HUST-8 (labeled as Ni@HUST-8), in 1 M KOH, the initial potential for OER activity performance is 170 mV (vs. RHE). At 10 mA cm-2, the corresponding overpotential is 240 mV and the Tafel slope is simulated as 60.8 mV dec-1. All of these experimental results of Ni@HUST-8 illustrate its better performance than commercial IrO2. Compared to the MOF parent and other bimetallic species, the higher electrocatalytic performance of Ni@HUST-8 should be ascribed to the special synergistic effect of Fe and Ni centers, which tends to greatly improve the reaction kinetics and charge transfer efficiency, while increasing the activity of the OER and achieving the best catalytic performances. The systematic investigation clearly manifests the important role of the synergistic effect of bimetallic centers in the OER and provides other insight into fabricating tailored electrocatalysts derived from MOF-based templates.},
doi = {10.1039/d0qi00812e},
journal = {Inorganic Chemistry Frontiers (Online)},
number = 23,
volume = 7,
place = {United States},
year = {Tue Sep 22 00:00:00 EDT 2020},
month = {Tue Sep 22 00:00:00 EDT 2020}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
In-situ synthesis of molecular magnetorefrigerant materials
journal, September 2019
- Liu, Sui-Jun; Han, Song-De; Zhao, Jiong-Peng
- Coordination Chemistry Reviews, Vol. 394
Nanoporous Nitrogen-Doped Graphene Oxide/Nickel Sulfide Composite Sheets Derived from a Metal-Organic Framework as an Efficient Electrocatalyst for Hydrogen and Oxygen Evolution
journal, July 2017
- Jayaramulu, Kolleboyina; Masa, Justus; Tomanec, Ondrej
- Advanced Functional Materials, Vol. 27, Issue 33
Creating coordinatively unsaturated metal sites in metal-organic-frameworks as efficient electrocatalysts for the oxygen evolution reaction: Insights into the active centers
journal, November 2017
- Tao, Li; Lin, Chun-Yu; Dou, Shuo
- Nano Energy, Vol. 41
π‐Conjugated Molecule Boosts Metal–Organic Frameworks as Efficient Oxygen Evolution Reaction Catalysts
journal, October 2018
- Zhu, Rongmei; Ding, Jiawei; Xu, Yuxia
- Small, Vol. 14, Issue 50
Semisacrificial Template Growth of Self‐Supporting MOF Nanocomposite Electrode for Efficient Electrocatalytic Water Oxidation
journal, December 2018
- Cao, Changsheng; Ma, Dong‐Dong; Xu, Qiang
- Advanced Functional Materials, Vol. 29, Issue 6
Transition metal (Fe, Co, Ni, and Mn) oxides for oxygen reduction and evolution bifunctional catalysts in alkaline media
journal, October 2016
- Osgood, Hannah; Devaguptapu, Surya V.; Xu, Hui
- Nano Today, Vol. 11, Issue 5
Transition-Metal (Co, Ni, and Fe)-Based Electrocatalysts for the Water Oxidation Reaction
journal, August 2016
- Han, Lei; Dong, Shaojun; Wang, Erkang
- Advanced Materials, Vol. 28, Issue 42
A Zn II -Based Metal–Organic Framework with a Rare tcj Topology as a Turn-On Fluorescent Sensor for Acetylacetone
journal, February 2019
- Yao, Shu-Li; Liu, Sui-Jun; Tian, Xue-Mei
- Inorganic Chemistry, Vol. 58, Issue 6
Large‐Scale, Bottom‐Up Synthesis of Binary Metal–Organic Framework Nanosheets for Efficient Water Oxidation
journal, May 2019
- Li, Fei‐Long; Wang, Pengtang; Huang, Xiaoqing
- Angewandte Chemie International Edition, Vol. 58, Issue 21
Three-dimensional metal–organic framework derived porous CoP 3 concave polyhedrons as superior bifunctional electrocatalysts for the evolution of hydrogen and oxygen
journal, January 2017
- Wu, Tianli; Pi, Mingyu; Wang, Xiaodeng
- Physical Chemistry Chemical Physics, Vol. 19, Issue 3
Pt nanoparticles embedded metal-organic framework nanosheets: A synergistic strategy towards bifunctional oxygen electrocatalysis
journal, May 2019
- Xia, Zhangxun; Fang, Jian; Zhang, Xiaoming
- Applied Catalysis B: Environmental, Vol. 245
Rational construction of self-supported triangle-like MOF-derived hollow (Ni,Co)Se 2 arrays for electrocatalysis and supercapacitors
journal, January 2019
- Song, Wenjiao; Teng, Xue; Liu, Yangyang
- Nanoscale, Vol. 11, Issue 13
Generation of Nanoparticle, Atomic‐Cluster, and Single‐Atom Cobalt Catalysts from Zeolitic Imidazole Frameworks by Spatial Isolation and Their Use in Zinc–Air Batteries
journal, April 2019
- Han, Xiaopeng; Ling, Xiaofei; Wang, Ying
- Angewandte Chemie International Edition, Vol. 58, Issue 16
Atomic Co/Ni dual sites and Co/Ni alloy nanoparticles in N-doped porous Janus-like carbon frameworks for bifunctional oxygen electrocatalysis
journal, January 2019
- Li, Zehui; He, Hongyan; Cao, Hongbin
- Applied Catalysis B: Environmental, Vol. 240
Fe 3 O 4 -Decorated Co 9 S 8 Nanoparticles In Situ Grown on Reduced Graphene Oxide: A New and Efficient Electrocatalyst for Oxygen Evolution Reaction
journal, May 2016
- Yang, Jing; Zhu, Guoxing; Liu, Yuanjun
- Advanced Functional Materials, Vol. 26, Issue 26
A Cd II ‐Based Metal‐Organic Framework with pcu Topology as Turn‐On Fluorescent Sensor for Al 3+
journal, July 2019
- Yao, Shu‐Li; Tian, Xue‐Mei; Li, Le‐Qian
- Chemistry – An Asian Journal, Vol. 14, Issue 20
Polyoxometalate-assisted formation of CoSe/MoSe 2 heterostructures with enhanced oxygen evolution activity
journal, January 2019
- Yuan, Menglei; Dipazir, Sobia; Wang, Meng
- Journal of Materials Chemistry A, Vol. 7, Issue 7
Thermodynamic theory of multi-electron transfer reactions: Implications for electrocatalysis
journal, September 2011
- Koper, Marc T. M.
- Journal of Electroanalytical Chemistry, Vol. 660, Issue 2
Rapid room-temperature synthesis of nanocrystalline spinels as oxygen reduction and evolution electrocatalysts
journal, December 2010
- Cheng, Fangyi; Shen, Jian; Peng, Bo
- Nature Chemistry, Vol. 3, Issue 1
Nanoscale Trimetallic Metal-Organic Frameworks Enable Efficient Oxygen Evolution Electrocatalysis
journal, December 2017
- Li, Fei-Long; Shao, Qi; Huang, Xiaoqing
- Angewandte Chemie International Edition, Vol. 57, Issue 7
Turn-On Luminescent Sensor toward Fe 3+ , Cr 3+ , and Al 3+ Based on a Co(II) Metal–Organic Framework with Open Functional Sites
journal, February 2020
- Tian, Xue-Mei; Yao, Shu-Li; Qiu, Cheng-Qiang
- Inorganic Chemistry, Vol. 59, Issue 5
Role of renewable energy sources in environmental protection: A review
journal, April 2011
- Panwar, N. L.; Kaushik, S. C.; Kothari, Surendra
- Renewable and Sustainable Energy Reviews, Vol. 15, Issue 3
Graphitic nanostructures in a porous carbon framework significantly enhance electrocatalytic oxygen evolution
journal, January 2017
- Gadipelli, Srinivas; Li, Zhuangnan; Zhao, Tingting
- Journal of Materials Chemistry A, Vol. 5, Issue 47
Expediting in-Situ Electrochemical Activation of Two-Dimensional Metal–Organic Frameworks for Enhanced OER Intrinsic Activity by Iron Incorporation
journal, June 2019
- Zou, Zehua; Wang, Tongtong; Zhao, Xiaohua
- ACS Catalysis, Vol. 9, Issue 8
A novel two-dimensional nickel phthalocyanine-based metal–organic framework for highly efficient water oxidation catalysis
journal, January 2018
- Jia, Hongxing; Yao, Yuchuan; Zhao, Jiangtao
- Journal of Materials Chemistry A, Vol. 6, Issue 3
Carbon-Incorporated Nickel-Cobalt Mixed Metal Phosphide Nanoboxes with Enhanced Electrocatalytic Activity for Oxygen Evolution
journal, February 2017
- He, Peilei; Yu, Xin-Yao; Lou, Xiong Wen David
- Angewandte Chemie International Edition, Vol. 56, Issue 14
Multiscale Principles To Boost Reactivity in Gas-Involving Energy Electrocatalysis
journal, January 2018
- Tang, Cheng; Wang, Hao-Fan; Zhang, Qiang
- Accounts of Chemical Research, Vol. 51, Issue 4
Recent advances in pristine tri-metallic metal–organic frameworks toward the oxygen evolution reaction
journal, January 2020
- Xue, Jiang-Yan; Li, Cong; Li, Fei-Long
- Nanoscale, Vol. 12, Issue 8
Effective force coarse-graining
journal, January 2009
- Wang, Yanting; Noid, W. G.; Liu, Pu
- Physical Chemistry Chemical Physics, Vol. 11, Issue 12
Driving the Oxygen Evolution Reaction by Nonlinear Cooperativity in Bimetallic Coordination Catalysts
journal, March 2016
- Wurster, Benjamin; Grumelli, Doris; Hötger, Diana
- Journal of the American Chemical Society, Vol. 138, Issue 11
First-principles design of bifunctional oxygen reduction and evolution catalysts through bimetallic centers in metal–organic frameworks
journal, January 2018
- Zhang, Peng; Yang, Xuejing; Gao, Wang
- Catalysis Science & Technology, Vol. 8, Issue 14
Carbon coated porous nickel phosphides nanoplates for highly efficient oxygen evolution reaction
journal, January 2016
- Yu, Xin-Yao; Feng, Yi; Guan, Buyuan
- Energy & Environmental Science, Vol. 9, Issue 4
Iron-doped NiCo-MOF hollow nanospheres for enhanced electrocatalytic oxygen evolution
journal, January 2020
- Li, Cong; Li, Xing-Jia; Zhao, Zhong-Yin
- Nanoscale, Vol. 12, Issue 26
Nanostructured hydrotreating catalysts for electrochemical hydrogen evolution
journal, January 2014
- Morales-Guio, Carlos G.; Stern, Lucas-Alexandre; Hu, Xile
- Chemical Society Reviews, Vol. 43, Issue 18
Metal-organic framework based nanomaterials for electrocatalytic oxygen redox reaction
journal, March 2019
- Zhang, Kexin; Guo, Wenhan; Liang, Zibin
- Science China Chemistry, Vol. 62, Issue 4
Recent Progress on Multimetal Oxide Catalysts for the Oxygen Evolution Reaction
journal, January 2018
- Kim, Ju Seong; Kim, Byunghoon; Kim, Hyunah
- Advanced Energy Materials, Vol. 8, Issue 11
Single Co Atoms Anchored in Porous N-Doped Carbon for Efficient Zinc−Air Battery Cathodes
journal, August 2018
- Zang, Wenjie; Sumboja, Afriyanti; Ma, Yuanyuan
- ACS Catalysis, Vol. 8, Issue 10
Cobalt/iron bimetal-organic frameworks as efficient electrocatalysts for the oxygen evolution reaction
journal, August 2019
- Xie, Shili; Li, Fei; Xu, Suxian
- Chinese Journal of Catalysis, Vol. 40, Issue 8