Low‐temperature selective laser sintering 3D printing of PEEK‐Nylon blends: Impact of thermal post‐processing on mechanical properties and thermal stability
Abstract
Abstract A high‐performance polymer (HPP) (polyether ether ketone, PEEK) blended with a commercial low‐temperature polymer (polyamide 12, PA‐12) was fabricated using a low‐temperature selective laser sintering (SLS) 3D printer. Different post‐processing heat treatments were implemented after fabrication to tune the thermal and mechanical properties of printed blends. The specific mechanical modulus of the blend was increased up to 79% in comparison to printed PA‐12 samples with heat treatment. Additionally, the thermal resistance of the treated blends greatly exceeded the properties observed using PA‐12 alone. This research proposes a methodology to fabricate and engineer HPP using desktop SLS printers through a secondary lower melting temperature material and heat treatments.
- Authors:
-
- Department of Mechanical Engineering The University of Texas at El Paso El Paso Texas USA, W.M. Keck Center for 3D Innovation The University of Texas at El Paso El Paso Texas USA
- Mechanical Engineering Program University of Houston‐Clear Lake Houston Texas USA
- National Security Campus operated by Honeywell Kansas City Missouri USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1846503
- Grant/Contract Number:
- DE‐FE‐0027502; DE‐NA0003865
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Journal of Applied Polymer Science
- Additional Journal Information:
- Journal Name: Journal of Applied Polymer Science Journal Volume: 139 Journal Issue: 23; Journal ID: ISSN 0021-8995
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Chavez, Luis A., Ibave, Paulina, Hassan, Md Sahid, Hall‐Sanchez, Samuel E., Billah, Kazi Md Masum, Leyva, Alba, Marquez, Cory, Espalin, David, Torres, Sabrina, Robison, Thomas, and Lin, Yirong. Low‐temperature selective laser sintering 3D printing of PEEK‐Nylon blends: Impact of thermal post‐processing on mechanical properties and thermal stability. United States: N. p., 2022.
Web. doi:10.1002/app.52290.
Chavez, Luis A., Ibave, Paulina, Hassan, Md Sahid, Hall‐Sanchez, Samuel E., Billah, Kazi Md Masum, Leyva, Alba, Marquez, Cory, Espalin, David, Torres, Sabrina, Robison, Thomas, & Lin, Yirong. Low‐temperature selective laser sintering 3D printing of PEEK‐Nylon blends: Impact of thermal post‐processing on mechanical properties and thermal stability. United States. https://doi.org/10.1002/app.52290
Chavez, Luis A., Ibave, Paulina, Hassan, Md Sahid, Hall‐Sanchez, Samuel E., Billah, Kazi Md Masum, Leyva, Alba, Marquez, Cory, Espalin, David, Torres, Sabrina, Robison, Thomas, and Lin, Yirong. Fri .
"Low‐temperature selective laser sintering 3D printing of PEEK‐Nylon blends: Impact of thermal post‐processing on mechanical properties and thermal stability". United States. https://doi.org/10.1002/app.52290.
@article{osti_1846503,
title = {Low‐temperature selective laser sintering 3D printing of PEEK‐Nylon blends: Impact of thermal post‐processing on mechanical properties and thermal stability},
author = {Chavez, Luis A. and Ibave, Paulina and Hassan, Md Sahid and Hall‐Sanchez, Samuel E. and Billah, Kazi Md Masum and Leyva, Alba and Marquez, Cory and Espalin, David and Torres, Sabrina and Robison, Thomas and Lin, Yirong},
abstractNote = {Abstract A high‐performance polymer (HPP) (polyether ether ketone, PEEK) blended with a commercial low‐temperature polymer (polyamide 12, PA‐12) was fabricated using a low‐temperature selective laser sintering (SLS) 3D printer. Different post‐processing heat treatments were implemented after fabrication to tune the thermal and mechanical properties of printed blends. The specific mechanical modulus of the blend was increased up to 79% in comparison to printed PA‐12 samples with heat treatment. Additionally, the thermal resistance of the treated blends greatly exceeded the properties observed using PA‐12 alone. This research proposes a methodology to fabricate and engineer HPP using desktop SLS printers through a secondary lower melting temperature material and heat treatments.},
doi = {10.1002/app.52290},
journal = {Journal of Applied Polymer Science},
number = 23,
volume = 139,
place = {United States},
year = {Fri Feb 25 00:00:00 EST 2022},
month = {Fri Feb 25 00:00:00 EST 2022}
}
https://doi.org/10.1002/app.52290
Works referenced in this record:
Composite Implant for Bone Replacement
journal, August 1997
- Kelsey, Deborah J.; Springer, George S.; Goodman, Stuart B.
- Journal of Composite Materials, Vol. 31, Issue 16
Processability of PEEK, a new polymer for High Temperature Laser Sintering (HT-LS)
journal, July 2015
- Berretta, S.; Evans, K. E.; Ghita, O.
- European Polymer Journal, Vol. 68
Effects of Cutter Geometrical Features on Machining Polyetheretherketones (PEEK) Engineering Plastic [English]
journal, June 2014
- Izamshah, R.; Husna, N.; Hadzley, M.
- JOURNAL OF MECHANICAL ENGINEERING AND SCIENCES, Vol. 6
Additive manufacturing (3D printing): A review of materials, methods, applications and challenges
journal, June 2018
- Ngo, Tuan D.; Kashani, Alireza; Imbalzano, Gabriele
- Composites Part B: Engineering, Vol. 143
Synthesis and properties of polyaryletherketones
journal, August 1981
- Attwood, T. E.; Dawson, P. C.; Freeman, J. L.
- Polymer, Vol. 22, Issue 8
A targeted material selection process for polymers in laser sintering
journal, October 2014
- Vasquez, G. M.; Majewski, C. E.; Haworth, B.
- Additive Manufacturing, Vol. 1-4
Electrical and Thermal Characterization of 3D Printed Thermoplastic Parts With Embedded Wires for High Current-Carrying Applications
journal, January 2019
- Billah, Kazi Md Masum; Coronel, Jose L.; Halbig, Michael C.
- IEEE Access, Vol. 7
Modeling of reflection-type laser-driven white lighting considering phosphor particles and surface topography
journal, January 2015
- Lee, Dong-Ho; Joo, Jae-Young; Lee, Sun-Kyu
- Optics Express, Vol. 23, Issue 15
Non-Isothermal Crystallization Behavior of PEEK/Graphene Nanoplatelets Composites from Melt and Glass States
journal, January 2019
- Alvaredo, Ángel; Martín, María; Castell, Pere
- Polymers, Vol. 11, Issue 1
Miscibility of polyamide blends: effects of configuration
journal, January 1995
- Ellis, Thomas S.
- Polymer, Vol. 36, Issue 20
Additive Manufacturing Processes: Selective Laser Melting, Electron Beam Melting and Binder Jetting—Selection Guidelines
journal, June 2017
- Gokuldoss, Prashanth Konda; Kolla, Sri; Eckert, Jürgen
- Materials, Vol. 10, Issue 6
Performance Limitations in Polymer Laser Sintering
journal, January 2014
- Bourell, David L.; Watt, Trevor J.; Leigh, David K.
- Physics Procedia, Vol. 56
The Effects of Crystallinity on the Mechanical Properties of PEEK Polymer and Graphite Fiber Reinforced PEEK
journal, November 1987
- Talbott, Margaret F.; Springer, George S.; Berglund, Lars A.
- Journal of Composite Materials, Vol. 21, Issue 11
Polyetheretherketone (PEEK) for medical applications
journal, June 2016
- Panayotov, Ivan Vladislavov; Orti, Valérie; Cuisinier, Frédéric
- Journal of Materials Science: Materials in Medicine, Vol. 27, Issue 7
On the molecular weight determination of a poly(aryl-ether-ether-ketone) (PEEK)
journal, December 1985
- Devaux, J.; Delimoy, D.; Daoust, D.
- Polymer, Vol. 26, Issue 13
Mixing relationships in aliphatic polyamide blends
journal, January 1992
- Ellis, Thomas S.
- Polymer, Vol. 33, Issue 7
Influence of molecular weight on rheological, thermal, and mechanical properties of PEEK
journal, August 2010
- Yuan, Mingjun; Galloway, Jeffrey A.; Hoffman, Richard J.
- Polymer Engineering & Science, Vol. 51, Issue 1
High performance polymer nanocomposites for additive manufacturing applications
journal, June 2016
- de Leon, Al C.; Chen, Qiyi; Palaganas, Napolabel B.
- Reactive and Functional Polymers, Vol. 103
Suitability and limitations of carbon fiber reinforced PEEK composites as bearing surfaces for total joint replacements
journal, April 1999
- Wang, A.; Lin, R.; Stark, C.
- Wear, Vol. 225-229
Binary blends of poly(ether ether ketone) and poly(ether imide): miscibility, crystallization behavior and semicrystalline morphology
journal, March 1991
- Crevecoeur, G.; Groeninckx, G.
- Macromolecules, Vol. 24, Issue 5
Microcellular foams from high performance miscible blends based on PEEK and PEI
journal, May 2016
- Cafiero, Livia; Iannace, Salvatore; Sorrentino, Luigi
- European Polymer Journal, Vol. 78
A review of welding technologies for thermoplastic composites in aerospace applications
journal, January 2012
- Costa, Anahi Pereira da; Botelho, Edson Cocchieri; Costa, Michelle Leali
- Journal of Aerospace Technology and Management, Vol. 4, Issue 3