Synthesis and Characterization of Mesoporous Silica Nanoparticles Loaded with Pt Catalysts

Lyu, Xingyi; Wu, Xun; Liu, Yuzi; Huang, Wenyu; Lee, Byeongdu; Li, Tao

doi:10.3390/catal12020183

Title: Synthesis and Characterization of Mesoporous Silica Nanoparticles Loaded with Pt Catalysts

Journal Article · 30 January 2022 · Catalysts

DOI: https://doi.org/10.3390/catal12020183 · OSTI ID:1846431

Lyu, Xingyi ^[1]; Wu, Xun ^[2]; Liu, Yuzi ^[3]; Huang, Wenyu ^[4]; Lee, Byeongdu ^[3];

^[5]

Northern Illinois Univ., DeKalb, IL (United States)
Iowa State Univ., Ames, IA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Iowa State Univ., Ames, IA (United States); Ames Lab., Ames, IA (United States)
Northern Illinois Univ., DeKalb, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States)

Coating the catalyst with a nanoporous layer has been demonstrated to be an effective approach to improve catalyst stability. Herein, we systematically investigate two types of core-shell mesoporous silica nanoparticles with a platinum nanocatalyst using a variety of characterization methods. One of the mesoporous particles has a unique amine ring structure in the middle of a shell (Ring-mSiO₂/Pt-5.0/SiO₂), and the other one has no ring structure (mSiO₂/Pt-5.0/SiO₂). Brunauer–Emmett–Teller/Barrett–Joyner–Halenda (BET/BJH) presented a similar surface area for both particles, and the pore size was 2.4 nm. Ultra-Small-Angle X-ray Scattering (USAXS)/ Small-Angle X-ray Scattering (SAXS) showed the size of mSiO₂/Pt-5.0/SiO₂ and Ring-mSiO₂/Pt-5.0/SiO₂ were 420 nm and 272 nm, respectively. It also showed that the ring structure was 30 nm above the silica core. Using high-resolution Transmission Electron Microscopy (TEM), it was found that the platinum nanoparticles are loaded evenly on the surface of the silica. In situ SAXS heating experiments and Thermogravimetric Analysis (TGA) indicated that the mSiO₂/Pt-5.0/SiO₂ were more stable during the high temperature, while the Ring-mSiO₂/Pt-5.0/SiO₂ had more change in the particle.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC02-07CH11358; AC02-06CH11357

OSTI ID:: 1846431

Report Number(s):: Is-J-10,710

Journal Information:: Catalysts, Journal Name: Catalysts Journal Issue: 2 Vol. 12; ISSN 2073-4344

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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Title: Synthesis and Characterization of Mesoporous Silica Nanoparticles Loaded with Pt Catalysts

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