Effect of Support on Oxygen Reduction Reaction Activity of Supported Iron Porphyrins

Hua, Qi; Madsen, Kenneth E.; Esposito, Anne Marie; Chen, Xinyi; Woods, Toby J.; Haasch, Richard T.; Xiang, Shuting; Frenkel, Anatoly I.; Fister, Timothy T.; Gewirth, Andrew A.

doi:10.1021/acscatal.1c04871

Title: Effect of Support on Oxygen Reduction Reaction Activity of Supported Iron Porphyrins

Journal Article · 03 January 2022 · ACS Catalysis

DOI: https://doi.org/10.1021/acscatal.1c04871 · OSTI ID:1846407

^[1]; Madsen, Kenneth E. ^[1]; Esposito, Anne Marie ^[1];

^[1];

^[2]; Xiang, Shuting ^[3];

^[4];

^[5];

^[1]

Univ. of Illinois at Urbana-Champaign, IL (United States)
Univ. of Illinois at Urbana-Champaign, IL (United States). Frederick Seitz Materials Research Lab.
Stony Brook Univ., NY (United States)
Stony Brook Univ., NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

In this work, we report the oxygen reduction reaction (ORR) activity in acid of an Fe porphyrin on different supports. While the activity is high (E_1/2 = 0.34 V vs RHE with n = 3.8) when the Fe porphyrin is adsorbed on XC72 (a graphitic carbon), this activity is much lower when the porphyrin is adsorbed on either MoS₂ (E_1/2 = -0.15 V vs RHE with n = 2.2) or g-C₃N₄ (E_1/2 = -0.24 V vs RHE with n = 3.1). Electron paramagnetic resonance (EPR), X-ray absorption fine structure (XAFS), and magnetometry measurements show the electronic structure around the Fe center is the same for all three supports. Only the Fe porphyrin supported on XC72 exhibits a pH dependence in its ORR activity. This observation, coupled with the increased hydrophilicity of XC72 relative to the other supports, suggests that the support-electrolyte interaction controls the ORR activity. Modification of MoS₂ to increase its hydrophilicity results in a more active ORR catalyst.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE; National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1846407

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Journal Issue: 2 Vol. 12; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (89)

Defect-Rich MoS ₂ Ultrathin Nanosheets with Additional Active Edge Sites for Enhanced Electrocatalytic Hydrogen Evolution Xie, Junfeng; Zhang, Hao; Li, Shuang Advanced Materials, Vol. 25, Issue 40 https://doi.org/10.1002/adma.201302685	journal	August 2013
Van der Waals Force Isolation of Monolayer MoS ₂ Gurarslan, Alper; Jiao, Shuping; Li, Tai-De Advanced Materials, Vol. 28, Issue 45 https://doi.org/10.1002/adma.201601581	journal	September 2016
Bioinspired Electrocatalysis of Oxygen Reduction Reaction in Fuel Cells Using Molecular Catalysts Zion, Noam; Friedman, Ariel; Levy, Naomi Advanced Materials, Vol. 30, Issue 41 https://doi.org/10.1002/adma.201800406	journal	April 2018
Honeycomb Carbon Nanofibers: A Superhydrophilic O ₂ ‐Entrapping Electrocatalyst Enables Ultrahigh Mass Activity for the Two‐Electron Oxygen Reduction Reaction Dong, Kai; Liang, Jie; Wang, Yuanyuan Angewandte Chemie, Vol. 133, Issue 19 https://doi.org/10.1002/ange.202101880	journal	March 2021
Molecular Architecture of Cobalt Porphyrin Multilayers on Reduced Graphene Oxide Sheets for High-Performance Oxygen Reduction Reaction Tang, Hongjie; Yin, Huajie; Wang, Jiangyan Angewandte Chemie International Edition, Vol. 52, Issue 21 https://doi.org/10.1002/anie.201300711	journal	April 2013
Elucidating the Structural Composition of an Fe–N–C Catalyst by Nuclear‐ and Electron‐Resonance Techniques Wagner, Stephan; Auerbach, Hendrik; Tait, Claudia E. Angewandte Chemie International Edition, Vol. 58, Issue 31 https://doi.org/10.1002/anie.201903753	journal	July 2019
Electrochemical Scanning Tunneling Microscopy Investigations of FeN ₄ ‐Based Macrocyclic Molecules Adsorbed on Au(111) and Their Implications in the Oxygen Reduction Reaction Facchin, Alessandro; Kosmala, Tomasz; Gennaro, Armando ChemElectroChem, Vol. 7, Issue 6 https://doi.org/10.1002/celc.202000137	journal	March 2020
Bioinspired Transition‐Metal Complexes as Electrocatalysts for the Oxygen Reduction Reaction Zhao, Ye‐Min; Yu, Guo‐Qiang; Wang, Fei‐Fei Chemistry – A European Journal, Vol. 25, Issue 15 https://doi.org/10.1002/chem.201803764	journal	December 2018
Engineering the Interface of Carbon Electrocatalysts at the Triple Point for Enhanced Oxygen Reduction Reaction Qiao, Mo; Titirici, Maria‐Magdalena Chemistry – A European Journal, Vol. 24, Issue 69 https://doi.org/10.1002/chem.201804610	journal	June 2018
Adsorption of 4,4′-Dithiodipyridine Axially Coordinated to Iron(II) Phthalocyanine on Au(111) as a New Strategy for Oxygen Reduction Electrocatalysis Herrera, Santiago; Tasca, Federico; Williams, Federico J. ChemPhysChem, Vol. 19, Issue 13 https://doi.org/10.1002/cphc.201800139	journal	May 2018
Highly Boosted Oxygen Reduction Reaction Activity by Tuning the Underwater Wetting State of the Superhydrophobic Electrode Wang, Pengwei; Hayashi, Toru; Meng, Qing'an Small, Vol. 13, Issue 4 https://doi.org/10.1002/smll.201601250	journal	August 2016
Proton transfer from glutamate 286 determines the transition rates between oxygen intermediates in cytochrome c oxidase Ådelroth, Pia; Karpefors, Martin; Gilderson, Gwen Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1459, Issue 2-3 https://doi.org/10.1016/S0005-2728(00)00194-8	journal	August 2000
Evaluation of H2O2 electrogeneration and decolorization of Orange II azo dye using tungsten oxide nanoparticle-modified carbon Paz, Edson C.; Aveiro, Luci R.; Pinheiro, Victor S. Applied Catalysis B: Environmental, Vol. 232 https://doi.org/10.1016/j.apcatb.2018.03.082	journal	September 2018
Defects modified in the exfoliation of g-C3N4 nanosheets via a self-assembly process for improved hydrogen evolution performance Wang, Jian; Yang, Zhuang; Yao, Wenqing Applied Catalysis B: Environmental, Vol. 238 https://doi.org/10.1016/j.apcatb.2018.07.017	journal	December 2018
Deuterium isotope effect of proton pumping in cytochrome c oxidase Salomonsson, Lina; Brändén, Gisela; Brzezinski, Peter Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1777, Issue 4 https://doi.org/10.1016/j.bbabio.2007.09.009	journal	April 2008
Proton-transport mechanisms in cytochrome c oxidase revealed by studies of kinetic isotope effects Johansson, Ann-Louise; Chakrabarty, Suman; Berthold, Catrine L. Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1807, Issue 9 https://doi.org/10.1016/j.bbabio.2011.03.012	journal	September 2011
EPR characterisation of carbon black in loose and tight contact with Al2O3 and CeO2 catalysts Saab, E.; Abi-Aad, E.; Bokova, M. N. Carbon, Vol. 45, Issue 3 https://doi.org/10.1016/j.carbon.2006.10.023	journal	March 2007
Modification of surface properties and enhancement of photocatalytic performance for g-C3N4 via plasma treatment Mao, Zhiyong; Chen, Jingjing; Yang, Yanfang Carbon, Vol. 123 https://doi.org/10.1016/j.carbon.2017.08.020	journal	October 2017
Does CO poison Fe-based catalysts for ORR? Birry, Laurent; Zagal, José H.; Dodelet, Jean-Pol Electrochemistry Communications, Vol. 12, Issue 5 https://doi.org/10.1016/j.elecom.2010.02.016	journal	May 2010
Oxygen reduction by Fe-based catalysts in PEM fuel cell conditions: Activity and selectivity of the catalysts obtained with two Fe precursors and various carbon supports Médard, C.; Lefèvre, M.; Dodelet, J. P. Electrochimica Acta, Vol. 51, Issue 16, p. 3202-3213 https://doi.org/10.1016/j.electacta.2005.09.012	journal	April 2006
Nitrogen-Doped Porous Carbon Derived from Malachium Aquaticum Biomass as a Highly Efficient Electrocatalyst for Oxygen Reduction Reaction Huang, Hui; Wei, Xianjun; Gao, Shuyan Electrochimica Acta, Vol. 220 https://doi.org/10.1016/j.electacta.2016.10.108	journal	December 2016
Biomimicking vitamin B12. A Co phthalocyanine pyridine axial ligand coordinated catalyst for the oxygen reduction reaction Riquelme, Jorge; Neira, Karinna; Marco, José F. Electrochimica Acta, Vol. 265 https://doi.org/10.1016/j.electacta.2018.01.177	journal	March 2018
Electrochemical behavior of the carbon black Vulcan XC-72R: Influence of the surface chemistry Pérez-Rodríguez, S.; Pastor, E.; Lázaro, M. J. International Journal of Hydrogen Energy, Vol. 43, Issue 16 https://doi.org/10.1016/j.ijhydene.2018.03.040	journal	April 2018
Engineering the nanoarchitecture and texture of polymeric carbon nitride semiconductor for enhanced visible light photocatalytic activity Dong, Fan; Wang, Zhenyu; Sun, Yanjuan Journal of Colloid and Interface Science, Vol. 401 https://doi.org/10.1016/j.jcis.2013.03.034	journal	July 2013
Potential dependence of the structure of water at the hydrophobic liquid interface Shaw, Scott K.; Gewirth, Andrew A. Journal of Electroanalytical Chemistry, Vol. 609, Issue 2 https://doi.org/10.1016/j.jelechem.2007.06.016	journal	November 2007
Graphitic carbon nitrides supported by nitrogen-doped graphene as efficient metal-free electrocatalysts for oxygen reduction Wang, Min; Wu, Zhanpeng; Dai, Liming Journal of Electroanalytical Chemistry, Vol. 753 https://doi.org/10.1016/j.jelechem.2015.05.012	journal	September 2015
EasySpin, a comprehensive software package for spectral simulation and analysis in EPR Stoll, Stefan; Schweiger, Arthur Journal of Magnetic Resonance, Vol. 178, Issue 1, p. 42-55 https://doi.org/10.1016/j.jmr.2005.08.013	journal	January 2006
Ag modified g-C3N4 composites with enhanced visible-light photocatalytic activity for diclofenac degradation Zhang, Wei; Zhou, Li; Deng, Huiping Journal of Molecular Catalysis A: Chemical, Vol. 423 https://doi.org/10.1016/j.molcata.2016.07.021	journal	November 2016
Axial ligands tailoring the ORR activity of cobalt porphyrin Zhou, Yue; Xing, Yong-Fang; Wen, Jing Science Bulletin, Vol. 64, Issue 16 https://doi.org/10.1016/j.scib.2019.07.003	journal	August 2019
Multiscale Principles To Boost Reactivity in Gas-Involving Energy Electrocatalysis Tang, Cheng; Wang, Hao-Fan; Zhang, Qiang Accounts of Chemical Research, Vol. 51, Issue 4 https://doi.org/10.1021/acs.accounts.7b00616	journal	January 2018
Electrochemical Interaction of Few-Layer Molybdenum Disulfide Composites vs Sodium: New Insights on the Reaction Mechanism González, José R.; Alcántara, Ricardo; Tirado, José L. Chemistry of Materials, Vol. 29, Issue 14 https://doi.org/10.1021/acs.chemmater.7b01245	journal	July 2017
Nonprecious Metal Catalysts for Oxygen Reduction in Heterogeneous Aqueous Systems Gewirth, Andrew A.; Varnell, Jason A.; DiAscro, Angela M. Chemical Reviews, Vol. 118, Issue 5 https://doi.org/10.1021/acs.chemrev.7b00335	journal	December 2017
Oxo-Free Hydrocarbon Oxidation by an Iron(III)-Isoporphyrin Complex Gericke, Robert; Doyle, Lorna M.; Farquhar, Erik R. Inorganic Chemistry, Vol. 59, Issue 19 https://doi.org/10.1021/acs.inorgchem.0c01618	journal	September 2020
Elucidating Proton Involvement in the Rate-Determining Step for Pt/Pd-Based and Non-Precious-Metal Oxygen Reduction Reaction Catalysts Using the Kinetic Isotope Effect Tse, Edmund C. M.; Varnell, Jason A.; Hoang, Thao T. H. The Journal of Physical Chemistry Letters, Vol. 7, Issue 18 https://doi.org/10.1021/acs.jpclett.6b01235	journal	August 2016
Metal (Mn, Fe, Co, Ni, Cu, and Zn) Phthalocyanine-Immobilized Mesoporous Carbon Nitride Materials as Durable Electrode Modifiers for the Oxygen Reduction Reaction Singh, Devesh Kumar; Ganesan, Vellaichamy; Yadav, Dharmendra Kumar Langmuir, Vol. 36, Issue 41 https://doi.org/10.1021/acs.langmuir.0c01822	journal	September 2020
Boosting the Oxygen Reduction Electrocatalytic Performance of Nonprecious Metal Nanocarbons via Triple Boundary Engineering Using Protic Ionic Liquids Qiao, Mo; Ferrero, Guillermo A.; Fernández Velasco, Leticia ACS Applied Materials & Interfaces, Vol. 11, Issue 12 https://doi.org/10.1021/acsami.8b18375	journal	February 2019
O-Doping Boosts the Electrochemical Oxygen Reduction Activity of a Single Fe Site in Hydrophilic Carbon with Deep Mesopores Ni, Wenpeng; Gao, Yang; Zhang, Yi ACS Applied Materials & Interfaces, Vol. 11, Issue 49 https://doi.org/10.1021/acsami.9b18510	journal	November 2019
Effect of pH on the Activity of Platinum Group Metal-Free Catalysts in Oxygen Reduction Reaction Rojas-Carbonell, Santiago; Artyushkova, Kateryna; Serov, Alexey ACS Catalysis, Vol. 8, Issue 4 https://doi.org/10.1021/acscatal.7b03991	journal	March 2018
Building Pyridinium Molecular Wires as Axial Ligands for Tuning the Electrocatalytic Activity of Iron Phthalocyanines for the Oxygen Reduction Reaction Pizarro, Ana; Abarca, Gabriel; Gutiérrez-Cerón, Cristian ACS Catalysis, Vol. 8, Issue 9 https://doi.org/10.1021/acscatal.8b01479	journal	July 2018
Nanostructured Nonprecious Metal Catalysts for Oxygen Reduction Reaction Wu, Gang; Zelenay, Piotr Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar400011z	journal	April 2013
Electroreduction of Dioxygen for Fuel-Cell Applications: Materials and Challenges Gewirth, Andrew A.; Thorum, Matthew S. Inorganic Chemistry, Vol. 49, Issue 8 https://doi.org/10.1021/ic9022486	journal	April 2010
Phosphorus-Doped Carbon Nitride Solid: Enhanced Electrical Conductivity and Photocurrent Generation Zhang, Yuanjian; Mori, Toshiyuki; Ye, Jinhua Journal of the American Chemical Society, Vol. 132, Issue 18 https://doi.org/10.1021/ja101749y	journal	May 2010
A Bifunctional Nonprecious Metal Catalyst for Oxygen Reduction and Water Oxidation Gorlin, Yelena; Jaramillo, Thomas F. Journal of the American Chemical Society, Vol. 132, Issue 39, p. 13612-13614 https://doi.org/10.1021/ja104587v	journal	October 2010
Hybrid Bilayer Membrane: A Platform To Study the Role of Proton Flux on the Efficiency of Oxygen Reduction by a Molecular Electrocatalyst Hosseini, Ali; Barile, Christopher J.; Devadoss, Anando Journal of the American Chemical Society, Vol. 133, Issue 29 https://doi.org/10.1021/ja204418j	journal	July 2011
Electrocatalytically Active Graphene–Porphyrin MOF Composite for Oxygen Reduction Reaction Jahan, Maryam; Bao, Qiaoliang; Loh, Kian Ping Journal of the American Chemical Society, Vol. 134, Issue 15 https://doi.org/10.1021/ja211433h	journal	April 2012
Large-Scale Production of Edge-Selectively Functionalized Graphene Nanoplatelets via Ball Milling and Their Use as Metal-Free Electrocatalysts for Oxygen Reduction Reaction Jeon, In-Yup; Choi, Hyun-Jung; Jung, Sun-Min Journal of the American Chemical Society, Vol. 135, Issue 4 https://doi.org/10.1021/ja3091643	journal	November 2012
Controllable Disorder Engineering in Oxygen-Incorporated MoS ₂ Ultrathin Nanosheets for Efficient Hydrogen Evolution Xie, Junfeng; Zhang, Jiajia; Li, Shuang Journal of the American Chemical Society, Vol. 135, Issue 47 https://doi.org/10.1021/ja408329q	journal	November 2013
Carbon Nanotube-Templated Synthesis of Covalent Porphyrin Network for Oxygen Reduction Reaction Hijazi, Ismail; Bourgeteau, Tiphaine; Cornut, Renaud Journal of the American Chemical Society, Vol. 136, Issue 17 https://doi.org/10.1021/ja500984k	journal	April 2014
On an Easy Way To Prepare Metal–Nitrogen Doped Carbon with Exclusive Presence of MeN ₄ -type Sites Active for the ORR Kramm, Ulrike I.; Herrmann-Geppert, Iris; Behrends, Jan Journal of the American Chemical Society, Vol. 138, Issue 2 https://doi.org/10.1021/jacs.5b11015	journal	January 2016
A New Fuel Cell Cathode Catalyst Jasinski, Raymond Nature, Vol. 201, Issue 4925, p. 1212-1213 https://doi.org/10.1038/2011212a0	journal	March 1964
Pure and stable metallic phase molybdenum disulfide nanosheets for hydrogen evolution reaction Geng, Xiumei; Sun, Weiwei; Wu, Wei Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms10672	journal	February 2016
Identification of carbon-encapsulated iron nanoparticles as active species in non-precious metal oxygen reduction catalysts Varnell, Jason A.; Tse, Edmund C. M.; Schulz, Charles E. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms12582	journal	August 2016
Promotion of oxygen reduction by a bio-inspired tethered iron phthalocyanine carbon nanotube-based catalyst Cao, Ruiguo; Thapa, Ranjit; Kim, Hyejung Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3076	journal	June 2013
Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials Zitolo, Andrea; Goellner, Vincent; Armel, Vanessa Nature Materials, Vol. 14, Issue 9 https://doi.org/10.1038/nmat4367	journal	August 2015
Proton transfer dynamics control the mechanism of O2 reduction by a non-precious metal electrocatalyst Tse, Edmund C. M.; Barile, Christopher J.; Kirchschlager, Nicholas A. Nature Materials, Vol. 15, Issue 7 https://doi.org/10.1038/nmat4636	journal	May 2016
Semiconductor SERS enhancement enabled by oxygen incorporation Zheng, Zuhui; Cong, Shan; Gong, Wenbin Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02166-z	journal	December 2017
A review of oxygen reduction mechanisms for metal-free carbon-based electrocatalysts Ma, Ruguang; Lin, Gaoxin; Zhou, Yao npj Computational Materials, Vol. 5, Issue 1 https://doi.org/10.1038/s41524-019-0210-3	journal	July 2019
Ordered mesoporous porphyrinic carbons with very high electrocatalytic activity for the oxygen reduction reaction Cheon, Jae Yeong; Kim, Taeyoung; Choi, YongMan Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep02715	journal	September 2013
Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions Jiao, Yan; Zheng, Yao; Jaroniec, Mietek Chemical Society Reviews, Vol. 44, Issue 8 https://doi.org/10.1039/C4CS00470A	journal	January 2015
A radar-like iron based nanohybrid as an efficient and stable electrocatalyst for oxygen reduction Zhong, Xing; Liu, Lin; Wang, Xinde J. Mater. Chem. A, Vol. 2, Issue 19 https://doi.org/10.1039/C4TA00647J	journal	January 2014
Electron transfer kinetics on natural crystals of MoS ₂ and graphite Velický, Matěj; Bissett, Mark A.; Toth, Peter S. Physical Chemistry Chemical Physics, Vol. 17, Issue 27 https://doi.org/10.1039/C5CP02490K	journal	January 2015
Highly efficient nonprecious metal catalysts towards oxygen reduction reaction based on three-dimensional porous carbon nanostructures Zhu, Chengzhou; Li, He; Fu, Shaofang Chemical Society Reviews, Vol. 45, Issue 3 https://doi.org/10.1039/C5CS00670H	journal	January 2016
Oxidized carbon nanotubes as an efficient metal-free electrocatalyst for the oxygen reduction reaction Wang, Xin; Ouyang, Canbin; Dou, Shuo RSC Advances, Vol. 5, Issue 52 https://doi.org/10.1039/C5RA05172J	journal	January 2015
Nitrogen self-doped graphitic carbon nitride as efficient visible light photocatalyst for hydrogen evolution Fang, Jiawen; Fan, Huiqing; Li, Mengmeng Journal of Materials Chemistry A, Vol. 3, Issue 26 https://doi.org/10.1039/C5TA02257F	journal	January 2015
Effect of the N content of Fe/N/graphene catalysts for the oxygen reduction reaction in alkaline media Domínguez, Carlota; Pérez-Alonso, F. J.; Salam, Mohamed Abdel Journal of Materials Chemistry A, Vol. 3, Issue 48 https://doi.org/10.1039/C5TA04355G	journal	January 2015
Growth mechanism and active site probing of Fe ₃ C@N-doped carbon nanotubes/C catalysts: guidance for building highly efficient oxygen reduction electrocatalysts Zhu, Jianbing; Xiao, Meiling; Liu, Changpeng Journal of Materials Chemistry A, Vol. 3, Issue 43 https://doi.org/10.1039/C5TA06181D	journal	January 2015
Structural and mechanistic basis for the high activity of Fe–N–C catalysts toward oxygen reduction Li, Jingkun; Ghoshal, Shraboni; Liang, Wentao Energy & Environmental Science, Vol. 9, Issue 7 https://doi.org/10.1039/C6EE01160H	journal	January 2016
2D molybdenum disulphide (2D-MoS ₂ ) modified electrodes explored towards the oxygen reduction reaction Rowley-Neale, Samuel J.; Fearn, Jamie M.; Brownson, Dale A. C. Nanoscale, Vol. 8, Issue 31 https://doi.org/10.1039/C6NR04073J	journal	January 2016
A reduced graphene oxide/covalent cobalt porphyrin framework for efficient oxygen reduction reaction Zuo, Quan; Cheng, Gongzhen; Luo, Wei Dalton Transactions, Vol. 46, Issue 29 https://doi.org/10.1039/C7DT01694H	journal	January 2017
Functional adlayers on Au electrodes: some recent applications in hydrogen evolution and oxygen reduction Chattopadhyay, Samir; Sarkar, Ankita; Chatterjee, Sudipta Journal of Materials Chemistry A, Vol. 6, Issue 4 https://doi.org/10.1039/C7TA09179F	journal	January 2018
Defect mediated magnetic transitions in Fe and Mn doped MoS ₂ Singh, Manish Kumar; Chettri, Prajwal; Tripathi, Ajay Physical Chemistry Chemical Physics, Vol. 20, Issue 23 https://doi.org/10.1039/C8CP02882F	journal	January 2018
High-quality vanadium-doped MoS ₂ ultrathin nanosheets as an efficient ORR catalyst He, Tianyu; Xu, Ling; Zhang, Ying New Journal of Chemistry, Vol. 43, Issue 3 https://doi.org/10.1039/C8NJ05365K	journal	January 2019
Two-dimensional MoS ₂ /Fe-phthalocyanine hybrid nanostructures as excellent electrocatalysts for hydrogen evolution and oxygen reduction reactions Kwon, Ik Seon; Kwak, In Hye; Kim, Ju Yeon Nanoscale, Vol. 11, Issue 30 https://doi.org/10.1039/C9NR04156G	journal	January 2019
Mesoporous carbon nitride supported 5,10,15,20-tetrakis(4-methoxyphenyl)-21 H ,23 H -porphine cobalt( ii ) as a selective and durable electrocatalyst for the production of hydrogen peroxide via two-electron oxygen reduction Singh, Devesh Kumar; Ganesan, Vellaichamy; Yadav, Dharmendra Kumar Catalysis Science & Technology, Vol. 11, Issue 3 https://doi.org/10.1039/D0CY01801E	journal	January 2021
CXCVIII.—Universal buffer solutions and the dissociation constant of veronal Britton, Hubert Thomas Stanley; Robinson, Robert Anthony J. Chem. Soc., Vol. 0, Issue 0 https://doi.org/10.1039/JR9310001456	journal	January 1931
A review on non-precious metal electrocatalysts for PEM fuel cells Chen, Zhongwei; Higgins, Drew; Yu, Aiping Energy & Environmental Science, Vol. 4, Issue 9 https://doi.org/10.1039/c0ee00558d	journal	January 2011
Selective four electron reduction of O2 by an iron porphyrin electrocatalyst under fast and slow electron fluxes Samanta, Subhra; Sengupta, Kushal; Mittra, Kaustuv Chemical Communications, Vol. 48, Issue 61 https://doi.org/10.1039/c2cc32832a	journal	January 2012
High-performance pyrolyzed iron corrole as a potential non-precious metal catalyst for PEMFCs Huang, Hsin-Chih; Wang, Chen-Hao; Shown, Indrajit Journal of Materials Chemistry A, Vol. 1, Issue 46 https://doi.org/10.1039/c3ta13515b	journal	January 2013
The Amplitude Reduction Factor in EXAFS Roy, M.; Gurman, S. J.; van Dorssen, G. Le Journal de Physique IV, Vol. 7, Issue C2 https://doi.org/10.1051/jp4/1997146	journal	April 1997
The Difficult Chore of Measuring Coordination by EXAFS Ravel, B.; Kelly, S. D. X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference, AIP Conference Proceedings https://doi.org/10.1063/1.2644458	conference	January 2007
Absorbency properties and electron paramagnetic resonance characterization of polymeric carbon black composites Boulic, Françoise; Brosseau, Christian; Mest, Yves Le Journal of Physics D: Applied Physics, Vol. 31, Issue 15 https://doi.org/10.1088/0022-3727/31/15/020	journal	August 1998
Multiple-scattering calculations of x-ray-absorption spectra Zabinsky, S. I.; Rehr, J. J.; Ankudinov, A. Physical Review B, Vol. 52, Issue 4 https://doi.org/10.1103/PhysRevB.52.2995	journal	July 1995
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT Ravel, B.; Newville, M. Journal of Synchrotron Radiation, Vol. 12, Issue 4 https://doi.org/10.1107/S0909049505012719	journal	June 2005
A Cytochrome c Oxidase Model Catalyzes Oxygen to Water Reduction Under Rate-Limiting Electron Flux Collman, J. P.; Devaraj, N. K.; Decreau, R. A. Science, Vol. 315, Issue 5818, p. 1565-1568 https://doi.org/10.1126/science.1135844	journal	March 2007
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt Wu, G.; More, K. L.; Johnston, C. M. Science, Vol. 332, Issue 6028, p. 443-447 https://doi.org/10.1126/science.1200832	journal	April 2011
Cobalt Phthalocyanine as a Fuel Cell Cathode Jasinski, Raymond Journal of The Electrochemical Society, Vol. 112, Issue 5 https://doi.org/10.1149/1.2423590	journal	January 1965
The Effect of Tuning the Coordination Sphere of Iron Complexes for the Oxygen Reduction Reaction in Acidic Media Wang, Xiaojiang; Zheng, Tianlong; Tang, Yizhao Journal of The Electrochemical Society, Vol. 168, Issue 4 https://doi.org/10.1149/1945-7111/abf21b	journal	April 2021
Tuning the Covering on Gold Surfaces by Grafting Amino-Aryl Films Functionalized with Fe(II) Phthalocyanine: Performance on the Electrocatalysis of Oxygen Reduction Olguín, Camila F.; Agurto, Nicolás; Silva, Carlos P. Molecules, Vol. 26, Issue 6 https://doi.org/10.3390/molecules26061631	journal	March 2021
Explosive Chromospheric Evaporation in a Circular-Ribbon Flare Zhang, Q. M.; Li, D.; Ning, Z. J. The Astrophysical Journal, Vol. 827, Issue 1 https://doi.org/10.3847/0004-637X/827/1/27	journal	August 2016

Similar Records

Use of in Situ Synchrotron Techniques to Probe the Oxidized Surface of Molybdenum Nitride Oxygen Reduction Electrocatalysis

Conference · 2020 · OSTI ID:1817402

Kreider, Melissa; Stevens, Michaela B.; Gibbons, Brenna; +6 more

Electrocatalytic reduction of nitrite to ammonia based on a water-soluble iron porphyrin

Journal Article · 1986 · J. Am. Chem. Soc.; (United States) · OSTI ID:5365477

Barley, M H; Takeuchi, K J; Meyer, T J

Heat-Treated Aerogel as a Catalyst for the Oxygen Reduction Reaction

Journal Article · 2019 · Angewandte Chemie (International Edition) · OSTI ID:1709106

Zion, Noam; Cullen, David A.; Zelenay, Piotr; +1 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
MoS2
carbon
carbon nitride
catalysts
electron paramagnetic resonance spectroscopy
hydrophilicity
iron porphyrin
materials
oxygen reduction reaction
pyrroles
redox reactions

Title: Effect of Support on Oxygen Reduction Reaction Activity of Supported Iron Porphyrins

Citation Formats

References (89)

Similar Records

Related Subjects