High-Pressure Synthesis of Double Perovskite Ba2NiIrO6: In Search of a Ferromagnetic Insulator
Abstract
Double perovskite oxides with d8–d3 electronic configurations are expected to be ferromagnetic from the Goodenough–Kanamori rules, such as ferromagnetic La2NiMnO6. In search of new ferromagnetic insulators, double perovskite Ba2NiIrO6 was successfully synthesized by high-pressure and high-temperature methods (8 GPa and 1573 K). Ba2NiIrO6 crystallizes in a cubic double perovskite structure (space group: Fm$$\bar3$$m), with an ordered arrangement of NiO6 and IrO6 octahedra. X-ray absorption near-edge spectroscopy confirms the nominal Ni(II) and Ir(VI) valence states. Ba2NiIrO6 displays an antiferromagnetic order at 51 K. The positive Weiss temperature, however, indicates that ferromagnetic interactions are dominant. Finally, isothermal magnetization curves at low temperatures support a field-induced spin–flop transition.
- Authors:
-
[1];
[3];
[5];
[4]
- Rutgers Univ., Piscataway, NJ (United States); Chinese Academy of Sciences (CAS), Beijing (China)
- Chinese Academy of Sciences (CAS), Beijing (China)
- Illinois Institute of Technology, Chicago, IL (United States)
- Rutgers Univ., Piscataway, NJ (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Columbia Univ., New York, NY (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); MOST
- OSTI Identifier:
- 1845961
- Grant/Contract Number:
- AC02-06CH11357; DMR-1507252; SC0012704; 2018YFA03057001; 2017YFB0405703; 11974407
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganic Chemistry
- Additional Journal Information:
- Journal Volume: 60; Journal Issue: 2; Journal ID: ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; x-ray absorption near edge spectroscopy; oxides; magnetic properties; energy; transition metals
Citation Formats
Feng, Hai L., Deng, Zheng, Segre, Carlo U., Croft, Mark, Lapidus, Saul H., Frank, Corey E., Shi, Youguo, Jin, Changqing, Walker, David, and Greenblatt, Martha. High-Pressure Synthesis of Double Perovskite Ba2NiIrO6: In Search of a Ferromagnetic Insulator. United States: N. p., 2020.
Web. doi:10.1021/acs.inorgchem.0c03402.
Feng, Hai L., Deng, Zheng, Segre, Carlo U., Croft, Mark, Lapidus, Saul H., Frank, Corey E., Shi, Youguo, Jin, Changqing, Walker, David, & Greenblatt, Martha. High-Pressure Synthesis of Double Perovskite Ba2NiIrO6: In Search of a Ferromagnetic Insulator. United States. https://doi.org/10.1021/acs.inorgchem.0c03402
Feng, Hai L., Deng, Zheng, Segre, Carlo U., Croft, Mark, Lapidus, Saul H., Frank, Corey E., Shi, Youguo, Jin, Changqing, Walker, David, and Greenblatt, Martha. Tue .
"High-Pressure Synthesis of Double Perovskite Ba2NiIrO6: In Search of a Ferromagnetic Insulator". United States. https://doi.org/10.1021/acs.inorgchem.0c03402. https://www.osti.gov/servlets/purl/1845961.
@article{osti_1845961,
title = {High-Pressure Synthesis of Double Perovskite Ba2NiIrO6: In Search of a Ferromagnetic Insulator},
author = {Feng, Hai L. and Deng, Zheng and Segre, Carlo U. and Croft, Mark and Lapidus, Saul H. and Frank, Corey E. and Shi, Youguo and Jin, Changqing and Walker, David and Greenblatt, Martha},
abstractNote = {Double perovskite oxides with d8–d3 electronic configurations are expected to be ferromagnetic from the Goodenough–Kanamori rules, such as ferromagnetic La2NiMnO6. In search of new ferromagnetic insulators, double perovskite Ba2NiIrO6 was successfully synthesized by high-pressure and high-temperature methods (8 GPa and 1573 K). Ba2NiIrO6 crystallizes in a cubic double perovskite structure (space group: Fm$\bar3$m), with an ordered arrangement of NiO6 and IrO6 octahedra. X-ray absorption near-edge spectroscopy confirms the nominal Ni(II) and Ir(VI) valence states. Ba2NiIrO6 displays an antiferromagnetic order at 51 K. The positive Weiss temperature, however, indicates that ferromagnetic interactions are dominant. Finally, isothermal magnetization curves at low temperatures support a field-induced spin–flop transition.},
doi = {10.1021/acs.inorgchem.0c03402},
journal = {Inorganic Chemistry},
number = 2,
volume = 60,
place = {United States},
year = {Tue Dec 29 00:00:00 EST 2020},
month = {Tue Dec 29 00:00:00 EST 2020}
}
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