Magnetic cations doped into a double perovskite semiconductor

Jin, Lun; Ni, Danrui; Gui, Xin; Straus, Daniel B.; Zhang, Qiang; Cava, Robert J.

doi:10.1039/d1tc05585b

Title: Magnetic cations doped into a double perovskite semiconductor

Journal Article · 25 January 2022 · Journal of Materials Chemistry C

DOI: https://doi.org/10.1039/d1tc05585b · OSTI ID:1845755

^[1]; Ni, Danrui ^[1]; Gui, Xin ^[1];

^[1];

^[2]; Cava, Robert J. ^[1]

Princeton Univ., NJ (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Here we report two solid solutions based on the magnetic ion doping of the double perovskite oxide Sr₂GaSbO₆: Sr₂Ga_1-xCr_xSbO₆ (0.1 ≤ x ≤ 0.4) and Sr₂Ga_1-xFe_xSbO₆ (0.1 ≤ x ≤ 0.4). All compositions crystallize in the same space group ($I4/m$) as their undoped parent phase Sr₂GaSbO₆, with the trivalent magnetic cations Cr³⁺ or Fe³⁺ partially substituting for non-magnetic Ga³⁺ in one of the B-cation sites. The Cr- and Fe-doped phases display dominant antiferromagnetic coupling among the dopant magnetic moments, and exhibit decreasing band gaps with increasing substitution level.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: National Science Foundation (NSF); USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; FG02-98ER45706

OSTI ID:: 1845755

Journal Information:: Journal of Materials Chemistry C, Journal Name: Journal of Materials Chemistry C Journal Issue: 8 Vol. 10; ISSN 2050-7526

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Magnetic cations doped into a double perovskite semiconductor

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