Supported Lanthanum Borohydride Catalyzes CH Borylation Inside Zeolite Micropores

Li, Yuting; Kanbur, Uddhav; Cui, Jinlei; Wang, Guocang; Kobayashi, Takeshi; Sadow, Aaron D.; Qi, Long

doi:10.1002/anie.202117394

Title: Supported Lanthanum Borohydride Catalyzes CH Borylation Inside Zeolite Micropores

Journal Article · 17 February 2022 · Angewandte Chemie (International Edition)

DOI: https://doi.org/10.1002/anie.202117394 · OSTI ID:1845740

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U.S. DOE Ames Laboratory Iowa State University Ames IA 50011 USA
U.S. DOE Ames Laboratory Iowa State University Ames IA 50011 USA, Department of Chemistry Iowa State University Ames IA 50011 USA

Abstract The zeolite‐supported lanthanide La(BH ₄ ) _x ‐HY ₃₀ catalyzes C−H borylation of benzene with pinacolborane (HBpin), providing a complementary approach to precious, late transition metal‐catalyzed borylations. The reactive catalytic species are generated from La grafted at the Brønsted acid sites (BAS) in micropores of the zeolite, whereas silanoate‐ and aluminoate‐grafted sites are inactive under the reaction conditions. During typical catalytic borylations, conversion to phenyl pinacolborane (PhBpin) is zero‐order in HBpin concentration. A turnover number (TON) of 167 is accessed by capping external silanols, selectively grafting at BAS sites, and adding HBpin slowly to the reaction.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; AC02-07CH11358

OSTI ID:: 1845740

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Journal Issue: 15 Vol. 61; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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