Driving Zn-MnO2 grid-scale batteries: A roadmap to cost-effective energy storage

Journal Article · 16 February 2022 · MRS Energy & Sustainability

DOI: https://doi.org/10.1557/s43581-021-00018-4 · OSTI ID:1845357

Spoerke, Erik D. ; Passell, Howard; Cowles, Gabriel; Lambert, Timothy N. ; Yadav, Gautam G. ; Huang, Jinchao; Banerjee, Sanjoy; Chalamala, Babu

Highlights Zn-MnO ₂ batteries promise safe, reliable energy storage, and this roadmap outlines a combination of manufacturing strategies and technical innovations that could make this goal achievable. Approaches such as improved efficiency of manufacturing and increasing active material utilization will be important to getting costs as low as $100/kWh, but key materials innovations that facilitate the full 2-electron capacity utilization of MnO ₂ , the use of high energy density 3D electrodes, and the promise of a separator-free battery with greater than 2V potential offer a route to batteries at $50/kWh or less. Abstract Large-scale energy storage is certain to play a significant, enabling role in the evolution of the emerging electrical grid. Battery-based storage, while not a dominant form of storage today, has opportunity to expand its utility through safe, reliable, and cost-effective technologies. Here, secondary Zn–MnO ₂ batteries are highlighted as a promising extension of ubiquitous primary alkaline batteries, offering a safe, environmentally friendly chemistry in a scalable and practical energy dense technology. Importantly, there is a very realistic pathway to also making such batteries cost-effective at price points of $50/kWh or lower. By examining manufacturing examples at the Zn–MnO ₂ battery manufacturer Urban Electric Power, a roadmap has been created to realize such low-cost systems. By focusing on manufacturing optimization through reduced materials waste, scalable manufacturing, and effective materials selection, costs can be significantly reduced. Ultimately, though, coupling these approaches with emerging research and development advances to enable full capacity active materials utilization and battery voltages greater than 2V are likely needed to drive costs below a target of $50/kWh. Reaching this commercially important goal, especially with a chemistry that is safe, well-known, and reliably effective stands to inject Zn–MnO ₂ batteries in the storage landscape at a critical time in energy storage development and deployment. Graphical abstract

• Sponsoring Organization: USDOE Office of Electricity (OE)
• OSTI ID: 1845357
• Journal Information: MRS Energy & Sustainability, Journal Name: MRS Energy & Sustainability Journal Issue: 1 Vol. 9; ISSN 2329-2229
• Publisher: Cambridge University Press (CUP)Copyright Statement
• Country of Publication: United States
• Language: English