Fluorinated Iron and Cobalt Phthalocyanine Nanowire Chemiresistors for Environmental Gas Monitoring at Parts-per-Billion Levels

Flores, Soraya Y.; Gonzalez-Espiet, Jean; Cintrón, Juan; Villanueva, Nerida De Jesus; Camino, Fernando E.; Kisslinger, Kim; Cruz, Dalice M. Piñero; Rivera, Ruben Díaz; Fonseca, Luis F.

doi:10.1021/acsanm.1c04039

Title: Fluorinated Iron and Cobalt Phthalocyanine Nanowire Chemiresistors for Environmental Gas Monitoring at Parts-per-Billion Levels

Journal Article · 13 February 2022 · ACS Applied Nano Materials

DOI: https://doi.org/10.1021/acsanm.1c04039 · OSTI ID:1845046

Flores, Soraya Y. ^[1];

^[2]; Cintrón, Juan ^[1]; Villanueva, Nerida De Jesus ^[3]; Camino, Fernando E. ^[4]; Kisslinger, Kim ^[4];

^[2]; Rivera, Ruben Díaz ^[3];

^[1]

University of Puerto Rico, Río Piedras Campus, Ponce de León Avenue, San Juan, Puerto Rico 00931, United States
University of Puerto Rico, Río Piedras Campus, Ponce de León Avenue, San Juan, Puerto Rico 00931, United States, Molecular Science Research Center, 1390 Ponce De León Avenue, San Juan, Puerto Rico 00926-2614, United States
University of Puerto Rico, Mayagüez Campus, Mayagüez, Puerto Rico 00682, United States
Center for Functional Nanomaterials, Brookhaven National Laboratory, Bldg 735, Upton, New York 11973-5000, United States

Not Available

View Journal Article

Cite

Export

Save

Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Univ. of Puerto Rico, Mayaguez (Puerto Rico)

Sponsoring Organization:: NSF-CREST CIRE2N; USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012704

OSTI ID:: 1845046

Report Number(s):: BNL-222881-2022-JAAM

Journal Information:: ACS Applied Nano Materials, Journal Name: ACS Applied Nano Materials Journal Issue: 4 Vol. 5; ISSN 2574-0970

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (49)

Gas Dielectric Transistor of CuPc Single Crystalline Nanowire for SO ₂ Detection Down to Sub-ppm Levels at Room Temperature Shaymurat, Talgar; Tang, Qingxin; Tong, Yanhong Advanced Materials, Vol. 25, Issue 16 https://doi.org/10.1002/adma.201204509	journal	January 2013
Porphyrin-Based Bulk Heterojunction Organic Photovoltaics: The Rise of the Colors of Life Kesters, Jurgen; Verstappen, Pieter; Kelchtermans, Mathias Advanced Energy Materials, Vol. 5, Issue 13 https://doi.org/10.1002/aenm.201500218	journal	May 2015
A simple synthesis of symmetric phthalocyanines and their respective perfluoro and transition‐metal complexes Denekamp, Ilse M.; Veenstra, Florentine L. P.; Jungbacker, Peter Applied Organometallic Chemistry, Vol. 33, Issue 5 https://doi.org/10.1002/aoc.4872	journal	February 2019
Cobalt phthalocyanine nanowires: Growth, crystal structure, and optical properties: Cobalt phthalocyanine nanowires: Growth, crystal structure, and optical properties Ji, Xiaolin; Zou, Taoyu; Gong, Hao Crystal Research and Technology, Vol. 51, Issue 2 https://doi.org/10.1002/crat.201500244	journal	December 2015
Chemically Sensitive Field-Effect Transistors and Chemiresistors: New Materials and Device Structures Katz, Howard?E. Electroanalysis, Vol. 16, Issue 22 https://doi.org/10.1002/elan.200403071	journal	November 2004
Sterically hindered phthalocyanines: solution–phase interactions with carbon monoxide Alarjah, M.; Paniwnyk, L.; Peterson, I. R. Journal of Materials Science, Vol. 44, Issue 16 https://doi.org/10.1007/s10853-009-3593-6	journal	August 2009
Ammonia sensing performance of thin films of cobalt(II) phthalocyanine bearing fluorinated substituents Kaya, Esra Nur; Şenocak, Ahmet; Klyamer, Darya D. Journal of Materials Science: Materials in Electronics, Vol. 30, Issue 8 https://doi.org/10.1007/s10854-019-01068-8	journal	March 2019
A non-linear diffusion-reaction model of electrical conduction in semiconductor gas sensors Gardner, Julian W. Sensors and Actuators B: Chemical, Vol. 1, Issue 1-6 https://doi.org/10.1016/0925-4005(90)80194-5	journal	January 1990
Applications of phthalocyanines in organic light emitting devices Hohnholz, D.; Steinbrecher, S.; Hanack, M. Journal of Molecular Structure, Vol. 521, Issue 1-3 https://doi.org/10.1016/S0022-2860(99)00438-X	journal	March 2000
The electrical response of evaporated cobalt phthalocyanine thin films on exposure to NO2 Gould, R. D.; Ibrahim, N. A. Thin Solid Films, Vol. 398-399 https://doi.org/10.1016/S0040-6090(01)01381-5	journal	November 2001
Diffusion-reaction theory for conductance response in metal oxide gas sensing thin films Lu, Honglong; Ma, Wencai; Gao, Jianhua Sensors and Actuators B: Chemical, Vol. 66, Issue 1-3 https://doi.org/10.1016/S0925-4005(00)00370-1	journal	July 2000
Phthalocyanine-based field-effect transistor as ozone sensor Bouvet, Marcel; Guillaud, Gérard; Leroy, Arnaud Sensors and Actuators B: Chemical, Vol. 73, Issue 1 https://doi.org/10.1016/S0925-4005(00)00682-1	journal	February 2001
Gas sensing behavior of metal-phthalocyanines: Effects of electronic structure on sensitivity Rana, Malay Kumar; Sinha, Mousumi; Panda, Siddhartha Chemical Physics, Vol. 513 https://doi.org/10.1016/j.chemphys.2018.06.021	journal	September 2018
Fluorosubstituted lead phthalocyanines: Crystal structure, spectral and sensing properties Kuprikova, Natalia M.; Klyamer, Darya D.; Sukhikh, Aleksandr S. Dyes and Pigments, Vol. 173 https://doi.org/10.1016/j.dyepig.2019.107939	journal	February 2020
Controllable gas selectivity at room temperature based on Ph5T2-modified CuPc nanowire field-effect transistors Song, Zhiqi; Liu, Guoming; Tang, Qingxin Organic Electronics, Vol. 48 https://doi.org/10.1016/j.orgel.2017.05.043	journal	September 2017
High-performance room-temperature NO2 sensors based on microstructures self-assembled from n-type phthalocyanines: Effect of fluorine–hydrogen bonding and metal–ligand coordination on morphology and sensing performance Wang, Xiangyang; Wang, Huiqiu; Ding, Xuefei Organic Electronics, Vol. 50 https://doi.org/10.1016/j.orgel.2017.08.021	journal	November 2017
NO2 sensors with room temperature operation and long term stability using copper phthalocyanine thin films Padma, N.; Joshi, Aditee; Singh, Ajay Sensors and Actuators B: Chemical, Vol. 143, Issue 1 https://doi.org/10.1016/j.snb.2009.07.044	journal	December 2009
Thin films of fluorinated 3d-metal phthalocyanines as chemical sensors of ammonia: An optical spectroscopy study Basova, Tamara V.; Mikhaleva, Natalia S.; Hassan, Aseel K. Sensors and Actuators B: Chemical, Vol. 227 https://doi.org/10.1016/j.snb.2015.12.079	journal	May 2016
Effect of covalent and non-covalent linking of zinc(II) phthalocyanine functionalised carbon nanomaterials on the sensor response to ammonia Polyakov, Maxim S.; Basova, Tamara V.; Göksel, Meltem Synthetic Metals, Vol. 227 https://doi.org/10.1016/j.synthmet.2017.02.024	journal	May 2017
Thin Films of Unsubstituted and Fluorinated Palladium Phthalocyanines: Structure and Sensor Response toward Ammonia and Hydrogen Parkhomenko, Roman G.; Sukhikh, Aleksandr S.; Klyamer, Darya D. The Journal of Physical Chemistry C, Vol. 121, Issue 2 https://doi.org/10.1021/acs.jpcc.6b10817	journal	January 2017
Orientational and Crystalline Order of Copper–Phthalocyanine Films on Gold: the Role of Substrate Roughness and Cleanliness Kothe, Michael; Witte, Gregor Langmuir, Vol. 35, Issue 42 https://doi.org/10.1021/acs.langmuir.9b02658	journal	September 2019
Phthalocyanine-Based Organic Thin-Film Transistors: A Review of Recent Advances Melville, Owen A.; Lessard, Benoît H.; Bender, Timothy P. ACS Applied Materials & Interfaces, Vol. 7, Issue 24 https://doi.org/10.1021/acsami.5b01718	journal	June 2015
Fast Response and High Sensitivity of ZnO Nanowires—Cobalt Phthalocyanine Heterojunction Based H ₂ S Sensor Kumar, Ashwini; Samanta, Soumen; Singh, Ajay ACS Applied Materials & Interfaces, Vol. 7, Issue 32 https://doi.org/10.1021/acsami.5b03652	journal	August 2015
Self-Assembled Molecular Nanowires for High-Performance Organic Transistors Fleet, Luke R.; Stott, James; Villis, Byron ACS Applied Materials & Interfaces, Vol. 9, Issue 24 https://doi.org/10.1021/acsami.7b01449	journal	June 2017
Effects of Peripheral Substituents on the Electronic Structure and Properties of Unligated and Ligated Metal Phthalocyanines, Metal = Fe, Co, Zn Liao, Meng-Sheng; Watts, John D.; Huang, Ming-Ju Journal of Chemical Theory and Computation, Vol. 1, Issue 6 https://doi.org/10.1021/ct050105y	journal	August 2005
Electron-Donating or -Withdrawing Nature of Substituents Revealed by the Electrochemistry of Metal-Free Phthalocyanines Li, Renjie; Zhang, Xianxi; Zhu, Peihua Inorganic Chemistry, Vol. 45, Issue 5 https://doi.org/10.1021/ic051931k	journal	January 2006
New Air-Stable n -Channel Organic Thin Film Transistors Bao, Zhenan; Lovinger, Andrew J.; Brown, Janelle Journal of the American Chemical Society, Vol. 120, Issue 1 https://doi.org/10.1021/ja9727629	journal	January 1998
X-ray Powder Diffraction Structure Reinvestigation of the α and β Forms of Cobalt Phthalocyanine and Kinetics of the α → β Phase Transition Ballirano, Paolo; Caminiti, Ruggero; Ercolani, Claudio Journal of the American Chemical Society, Vol. 120, Issue 49 https://doi.org/10.1021/ja973815p	journal	December 1998
Polymorphism in Phthalocyanine Thin Films: Mechanism of the α → β Transition Heutz, S.; Bayliss, S. M.; Middleton, R. L. The Journal of Physical Chemistry B, Vol. 104, Issue 30 https://doi.org/10.1021/jp0000836	journal	July 2000
Electronic Energy Levels in Individual Molecules, Thin Films, and Organic Heterojunctions of Substituted Phthalocyanines Schlettwein, D.; Hesse, K.; Gruhn, N. E. The Journal of Physical Chemistry B, Vol. 105, Issue 21 https://doi.org/10.1021/jp001912q	journal	May 2001
Metal Phthalocyanine Nanoribbons and Nanowires Tong, W. Y.; Djurišić, A. B.; Xie, M. H. The Journal of Physical Chemistry B, Vol. 110, Issue 35 https://doi.org/10.1021/jp062951q	journal	August 2006
Nanoflowers Grown from Phthalocyanine Seeds: Organic Nanorectifiers Karan, Santanu; Mallik, Biswanath The Journal of Physical Chemistry C, Vol. 112, Issue 7 https://doi.org/10.1021/jp709780a	journal	January 2008
Polymorphic Transformation of Iron-Phthalocyanine and the Effect on Carbon Nanotube Synthesis Milev, Adriyan S.; Tran, Nguyen; Kamali Kannangara, G. S. The Journal of Physical Chemistry C, Vol. 112, Issue 14 https://doi.org/10.1021/jp710923f	journal	March 2008
Molecular Interactions in Thin Films of Hexadecafluorophthalocyaninatozinc (F ₁₆ PcZn) as Compared to Islands of N , N ‘-Dimethylperylene-3,4,9,10-biscarboximide (MePTCDI) Schlettwein, D.; Graaf, H.; Meyer, J. -P. The Journal of Physical Chemistry B, Vol. 103, Issue 16 https://doi.org/10.1021/jp983111h	journal	April 1999
Phthalocyanines as Semiconductors Eley, D. D. Nature, Vol. 162, Issue 4125 https://doi.org/10.1038/162819a0	journal	November 1948
The role of chemical design in the performance of organic semiconductors Bronstein, Hugo; Nielsen, Christian B.; Schroeder, Bob C. Nature Reviews Chemistry, Vol. 4, Issue 2 https://doi.org/10.1038/s41570-019-0152-9	journal	January 2020
Multi-mode humidity sensing with water-soluble copper phthalocyanine for increased sensitivity and dynamic range Muckley, Eric S.; Jacobs, Christopher B.; Vidal, Keith Scientific Reports, Vol. 7, Issue 1 https://doi.org/10.1038/s41598-017-10401-2	journal	August 2017
Fluorination of Metal Phthalocyanines: Single-Crystal Growth, Efficient N-Channel Organic Field-Effect Transistors and Structure-Property Relationships Jiang, Hui; Ye, Jun; Hu, Peng Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep07573	journal	December 2014
Phthalocyanine based nanowires and nanoflowers as highly sensitive room temperature Cl ₂ sensors Saini, Rajan; Mahajan, Aman; Bedi, R. K. RSC Advances, Vol. 4, Issue 31 https://doi.org/10.1039/C3RA47002D	journal	January 2014
Synthesis and characterization of fluorophthalocyanines bearing four 2-(2-thienyl)ethoxy moieties: from the optimization of the fluorine substitution to chemosensing Wannebroucq, Amélie; Meunier-Prest, Rita; Chambron, Jean-Claude RSC Advances, Vol. 7, Issue 65 https://doi.org/10.1039/C7RA05325H	journal	January 2017
Highly selective room-temperature NO ₂ sensors based on a fluoroalkoxy-substituted phthalocyanine Sun, Qiqi; Feng, Weigang; Yang, Pu New Journal of Chemistry, Vol. 42, Issue 9 https://doi.org/10.1039/C8NJ00622A	journal	January 2018
A phthalocyanine sensor array based on sensitivity and current changes for highly sensitive identification of three toxic gases at ppb levels Duan, Xueqian; Zhang, Yingze; Wang, Haoyuan New Journal of Chemistry, Vol. 44, Issue 31 https://doi.org/10.1039/D0NJ02025G	journal	January 2020
Iron phthalocyanine nanorods for ethanol sensoring Wang, Xiuhua; Wang, Xiuqin; Gao, Jie Micro & Nano Letters, Vol. 11, Issue 7 https://doi.org/10.1049/mnl.2016.0021	journal	July 2016
Controllable fabrication of copper phthalocyanine nanostructure crystals Liu, Fangmei; Sun, Jia; Xiao, Si Nanotechnology, Vol. 26, Issue 22 https://doi.org/10.1088/0957-4484/26/22/225601	journal	May 2015
Pyrene containing liquid crystalline asymmetric phthalocyanines and their composite materials with single-walled carbon nanotubes Kaya, Esra Nur; Polyakov, Maxim S.; Basova, Tamara V. Journal of Porphyrins and Phthalocyanines, Vol. 22, Issue 01n03 https://doi.org/10.1142/S1088424618500025	journal	January 2018
A Survey on Gas Sensing Technology Liu, Xiao; Cheng, Sitian; Liu, Hong Sensors, Vol. 12, Issue 7 https://doi.org/10.3390/s120709635	journal	July 2012
Fluorinated Metal Phthalocyanines: Interplay between Fluorination Degree, Films Orientation, and Ammonia Sensing Properties Klyamer, Darya; Sukhikh, Aleksandr; Gromilov, Sergey Sensors, Vol. 18, Issue 7 https://doi.org/10.3390/s18072141	journal	July 2018
Advanced Micro- and Nano-Gas Sensor Technology: A Review Nazemi, Haleh; Joseph, Aashish; Park, Jaewoo Sensors, Vol. 19, Issue 6 https://doi.org/10.3390/s19061285	journal	March 2019
Interannual variability of ammonia concentrations over the United States: sources and implications Schiferl, Luke D.; Heald, Colette L.; Van Damme, Martin Atmospheric Chemistry and Physics, Vol. 16, Issue 18 https://doi.org/10.5194/acp-16-12305-2016	journal	January 2016

Similar Records

Cathodic pulse stripping analysis of iodine at the parts-per-billion level

Journal Article · 1977 · Anal. Chem.; (United States) · OSTI ID:7220876

Propst, R C

Analysis and monitoring of steam and water impurities in the parts per billion range

Journal Article · 1983 · J. Mater. Energy Syst.; (United States) · OSTI ID:5283006

Bellows, J S; Carlson, G L; Pensenstadler, D F

Measurement of trace impurities in ultra pure hydrogen and deuterium at the parts-per-billion level using gas chromatography

Journal Article · 2018 · Nuclear Instruments and Methods in Physics Research. Section A, Accelerators, Spectrometers, Detectors and Associated Equipment · OSTI ID:1549434

Ganzha, V.; Ivshin, K.; Kammel, P.; +8 more

Related Subjects

77 NANOSCIENCE AND NANOTECHNOLOGY
ammonia
conductometric gas sensors
conductometric gas sensors
ammonia
metal phthalocyanine
nanowire
parts-per-billion (ppb)
recovery zones
metal phthalocyanine
nanowire
parts-per-billion (ppb)
recovery zones

Title: Fluorinated Iron and Cobalt Phthalocyanine Nanowire Chemiresistors for Environmental Gas Monitoring at Parts-per-Billion Levels

Citation Formats

References (49)

Similar Records

Related Subjects