Binary Fe/Mn-Based Nanocomposites as Li-Free Cathode Materials for Li Batteries Assembled in Charged State

Punyapu, Venkata Rohit; Ding, Yi; Simon Ng, Ka Yuen; Deng, Da

doi:10.1021/acs.iecr.1c04661

Title: Binary Fe/Mn-Based Nanocomposites as Li-Free Cathode Materials for Li Batteries Assembled in Charged State

Journal Article · 19 January 2022 · Industrial and Engineering Chemistry Research

DOI: https://doi.org/10.1021/acs.iecr.1c04661 · OSTI ID:1844948

Punyapu, Venkata Rohit ^[1]; Ding, Yi ^[2]; Simon Ng, Ka Yuen ^[3];

^[3]

Wayne State Univ., Detroit, MI (United States); Wayne State University
United States Army Combat Capabilities Development Command (DEVCOM), Warren, MI (United States). Ground Vehicle Systems Center (GVCS)
Wayne State Univ., Detroit, MI (United States)

Li-ion batteries play important roles in this mobile society. The ever-increasing demand for energy storage, particularly from electric vehicles, requires next-generation Li batteries with higher energy density and better safety. In contrast to existing Li-ion batteries using lithiated cathodes and Li-free anodes, we explore Li-free cathodes coupled with lithium/ lithiated anodes in order to construct new Li batteries assembled in a charged state. Here, two highly promising Li-free cathode materials of 1-D FeOF nanorods and 2-D monolayer MnO₂ nanosheets are integrated to make FeOF@MnO₂ nanocomposites. FeOF nanorods are sandwiched by monolayer MnO₂ nanosheets where FeOF nanoparticles could prevent the restacking of the monolayer MnO₂ nanosheets and the presence of monolayer MnO₂ nanosheets could enhance the electrical integration of the FeOF nanorods. Synergistic effects of the binary Fe/Mn-based cathodes can lead to both high voltage and high capacity, compared to individual components. Electrochemical evaluation reveals that binary Fe/Mn-based Li-free cathodes demonstrate promising performances and are worthy of further investigation and optimization.

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Research Organization:: Wayne State Univ., Detroit, MI (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

Grant/Contract Number:: EE0008236

OSTI ID:: 1844948

Journal Information:: Industrial and Engineering Chemistry Research, Journal Name: Industrial and Engineering Chemistry Research Journal Issue: 22 Vol. 61; ISSN 0888-5885

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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