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Title: Atom probe analysis of electrode materials for Li-ion batteries: challenges and ways forward

Journal Article · · Journal of Materials Chemistry. A
DOI: https://doi.org/10.1039/D1TA10050E · OSTI ID:1844448
ORCiD logo [1]; ORCiD logo [1];  [1];  [1]; ORCiD logo [1];  [1];  [2];  [3];  [4]
  1. Max-Planck-Institut für Eisenforschung, Düsseldorf, Germany
  2. Energy and Environment Directorate, Pacific Northwest National Laboratory, P.O. Box 999, Richland, WA 99352, USA
  3. Department of Materials, Royal School of Mines, Imperial College London, London, UK
  4. Max-Planck-Institut für Eisenforschung, Düsseldorf, Germany, Department of Materials, Royal School of Mines, Imperial College London, London, UK

Atom probe results of the NMC811 sample from an ultra-high vacuum vs. air transferring.

Sponsoring Organization:
USDOE
OSTI ID:
1844448
Journal Information:
Journal of Materials Chemistry. A, Journal Name: Journal of Materials Chemistry. A Journal Issue: 9 Vol. 10; ISSN JMCAET; ISSN 2050-7488
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English

References (72)

Graphene‐Enhanced 3D Chemical Mapping of Biological Specimens at Near‐Atomic Resolution journal June 2018
Direct Imaging of Dopant and Impurity Distributions in 2D MoS 2 journal January 2020
Understanding the Degradation Mechanisms of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Material in Lithium Ion Batteries journal August 2013
Atomic‐Scale Mapping of Impurities in Partially Reduced Hollow TiO 2 Nanowires journal February 2020
Three-Dimensional Microstructural Characterization of Lithium Manganese Oxide with Atom Probe Tomography journal September 2016
Quantitative binomial distribution analyses of nanoscale like‐solute atom clustering and segregation in atom probe tomography data journal July 2008
A reproducible method for damage-free site-specific preparation of atom probe tips from interfaces journal September 2011
Local Electrode Atom Probe Tomography: A User's Guide book January 2013
Controlled Ag-driven superior rate-capability of Li4Ti5O12 anodes for lithium rechargeable batteries journal April 2013
LixCoO2 (0<-1): A new cathode material for batteries of high energy density journal June 1980
The post-ionization of field evaporated ions: A theoretical explanation of multiple charge states journal April 1982
Metrology of small particles and solute clusters by atom probe tomography journal April 2020
Understanding of the field evaporation of surface modified oxide materials through transmission electron microscopy and atom probe tomography journal April 2016
Contribution of atom-probe tomography to a better understanding of glass alteration mechanisms: Application to a nuclear glass specimen altered 25years in a granitic environment journal June 2013
Characterization of Pd and Pd@Au core-shell nanoparticles using atom probe tomography and field evaporation simulation journal August 2020
Long-Duration Electricity Storage Applications, Economics, and Technologies journal January 2020
Aging of LiFePO4 upon exposure to H2O journal December 2008
Microstructural study on degradation mechanism of layered LiNi0.6Co0.2Mn0.2O2 cathode materials by analytical transmission electron microscopy journal March 2016
Three-dimensional evaluation of compositional and structural changes in cycled LiNi1/3Co1/3Mn1/3O2 by atom probe tomography journal March 2018
Hydride growth mechanism in zircaloy-4: Investigation of the partitioning of alloying elements journal March 2021
Resolving the degradation pathways in high-voltage oxides for high-energy-density lithium-ion batteries; Alternation in chemistry, composition and crystal structures journal June 2017
Spatially correlated electron microscopy and atom probe tomography: Current possibilities and future perspectives journal April 2018
DFT study of the adsorption and dissociation of water on Ni(111), Ni(110) and Ni(100) surfaces journal September 2014
Optimization of pulsed laser atom probe (PLAP) for the analysis of nanocomposite Ti–Si–N films journal June 2010
Correlated ion analysis and the interpretation of atom probe mass spectra journal May 2011
Atom probe tomography of lithium-doped network glasses journal June 2014
Effects of laser energy and wavelength on the analysis of LiFePO4 using laser assisted atom probe tomography journal January 2015
A new method for mapping the three-dimensional atomic distribution within nanoparticles by atom probe tomography (APT) journal July 2018
Graphene encapsulation enabled high-throughput atom probe tomography of liquid specimens journal September 2020
Atom-Probe Field Ion Microscopy: Field Ion Emission, and Surfaces and Interfaces at Atomic Resolution book January 2009
Three-Dimensional Nanoscale Characterization of Pt Deposition from an Organometallic Precursor Induced by a Focused Ion Beam journal July 2006
Improved Mass Resolving Power and Yield in Atom Probe Tomography journal August 2013
Electron Beam-Induced Deposition for Atom Probe Tomography Specimen Capping Layers journal October 2016
In Situ Atom Probe Deintercalation of Lithium-Manganese-Oxide journal January 2017
Dictionary Indexing of Electron Channeling Patterns journal February 2017
Reflections on the Analysis of Interfaces and Grain Boundaries by Atom Probe Tomography journal March 2020
Understanding the Effects of Graphene Coating on the Electrostatic Field at the Tip of an Atom Probe Tomography Specimen journal July 2021
Anatase TiO 2 : Better Anode Material Than Amorphous and Rutile Phases of TiO 2 for Na-Ion Batteries journal August 2015
Dissociation Dynamics of Molecular Ions in High dc Electric Field journal May 2016
An Outlook on Lithium Ion Battery Technology journal September 2017
Molecular Simulation for Gas Adsorption at NiO (100) Surface journal October 2012
Structurally and Electronically Designed TiO 2 N x Nanofibers for Lithium Rechargeable Batteries journal January 2013
Polarization effects upon adsorptive and catalytic properties. 2. Surface electrical conductivity of nickel(II) oxide deposited on lithium niobate (LiNbO3) and its changes upon gas adsorption journal June 1985
The Li-Ion Rechargeable Battery: A Perspective journal January 2013
Rapid Synthesis of Li 4 Ti 5 O 12 Microspheres as Anode Materials and Its Binder Effect for Lithium-Ion Battery journal July 2011
Composition of Wide Bandgap Semiconductor Materials and Nanostructures Measured by Atom Probe Tomography and Its Dependence on the Surface Electric Field journal October 2014
Do Dielectric Nanostructures Turn Metallic in High-Electric dc Fields? journal October 2014
Issues and challenges facing rechargeable lithium batteries journal November 2001
Building better batteries journal February 2008
Designing metallic glass matrix composites with high toughness and tensile ductility journal February 2008
Visualizing nanoscale 3D compositional fluctuation of lithium in advanced lithium-ion battery cathodes journal August 2015
Ti and its alloys as examples of cryogenic focused ion beam milling of environmentally-sensitive materials journal February 2019
Evolution and expansion of Li concentration gradient during charge–discharge cycling journal June 2021
Three-dimensional atomic mapping of ligands on palladium nanoparticles by atom probe tomography journal July 2021
Cryo-STEM mapping of solid–liquid interfaces and dendrites in lithium-metal batteries journal August 2018
Electric-field-tuned topological phase transition in ultrathin Na3Bi journal December 2018
(S)TEM-EELS as an advanced characterization technique for lithium-ion batteries journal January 2021
Challenges in the development of advanced Li-ion batteries: a review journal January 2011
Modulation of external electric field on surface states of topological insulator Bi 2 Se 3 thin films journal November 2012
Behavior of molecules and molecular ions near a field emitter journal March 2016
Quantification of solute deuterium in titanium deuteride by atom probe tomography with both laser pulsing and high-voltage pulsing: influence of the surface electric field journal May 2019
Crystalline structure and electrical conductivity of nickel substituted spinel lithium manganese oxide journal March 2019
Simulation of field-induced molecular dissociation in atom-probe tomography: Identification of a neutral emission channel journal June 2017
Reactive Chemical Doping of the Bi 2 Se 3 Topological Insulator journal October 2011
Effects of optical dopants and laser wavelength on atom probe tomography analyses of borosilicate glasses journal June 2017
Cryo‐FIB‐lift‐out: practically impossible to practical reality journal September 2020
An atom probe study of the anomalous field evaporation of alloys containing silicon journal May 1981
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries journal February 2006
An environmental transfer hub for multimodal atom probe tomography journal May 2017
The Laplace Project: An integrated suite for preparing and transferring atom probe samples under cryogenic and UHV conditions journal December 2018
Cryo-focused ion beam preparation of perovskite based solar cells for atom probe tomography journal January 2020
Optimization of Pt-C Deposits by Cryo-FIBID: Substantial Growth Rate Increase and Quasi-Metallic Behaviour journal September 2020