Local environment rigidity and the evolution of optical properties in the green-emitting phosphor Ba 1− x Sr x ScO 2 F:Eu 2+

Hariyani, Shruti; Amachraa, Mahdi; Khan, Mariam; Ong, Shyue Ping; Brgoch, Jakoah

doi:10.1039/D1TC05411B

Title: Local environment rigidity and the evolution of optical properties in the green-emitting phosphor Ba _{1− x} Sr _x ScO ₂ F:Eu ²⁺

Journal Article · 24 February 2022 · Journal of Materials Chemistry C

DOI: https://doi.org/10.1039/D1TC05411B · OSTI ID:1844025

^[1];

^[2]; Khan, Mariam ^[3];

^[2];

^[1]

Department of Chemistry, University of Houston, Houston, Texas 77204, USA, Texas Center for Superconductivity, University of Houston, Houston, Texas, 77204, USA
Department of NanoEngineering, University of California San Diego, La Jolla, California 92093, USA
Department of Chemistry, University of Houston, Houston, Texas 77204, USA

(Ba _{1− x} Sr _x ) _0.98 Eu _0.02 ScO ₂ F produces a tunable emission from cyan to green upon Sr ²⁺ substitution. Ab initio molecular dynamics simulations revealed that Sr ²⁺ weakens the local rigidity lowering the efficiency and thermal stability of the phosphors.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1844025

Journal Information:: Journal of Materials Chemistry C, Journal Name: Journal of Materials Chemistry C Journal Issue: 8 Vol. 10; ISSN JMCCCX; ISSN 2050-7526

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Title: Local environment rigidity and the evolution of optical properties in the green-emitting phosphor Ba _{1− x} Sr _x ScO ₂ F:Eu ²⁺