Synthesis and Mechanical Properties of sub 5‐μm PolyUiO‐66 Thin Films on Gold Surfaces

Frederick, Esther; Appelhans, Leah N.; Del Rio, Frank W.; Strong, Jr., Kevin T.; Smith, Sean; Dickens, Sara; Vreeland, Erika

doi:10.1002/cphc.202100673

Title: Synthesis and Mechanical Properties of sub 5‐μm PolyUiO‐66 Thin Films on Gold Surfaces

Journal Article · 14 January 2022 · ChemPhysChem

DOI: https://doi.org/10.1002/cphc.202100673 · OSTI ID:1843623

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^[1]; Smith, Sean ^[1];

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Sandia National Laboratories Albuquerque, NM 87185 USA

Abstract Metal‐organic framework (MOF) thin films currently lack the mechanical stability needed for electronic device applications. Polymer‐based metal‐organic frameworks (polyMOFs) have been suggested to provide mechanical advantages over MOFs, however, the mechanical properties of polyMOFs have not yet been characterized. In this work, we developed a method to synthesize continuous sub‐5 μm polyUiO‐66(Zr) films on Au substrates, which allowed us to undertake initial mechanical property investigations. Comparisons between polyUiO‐66 and UiO‐66 thin films determined polyUiO‐66 thin films exhibit a lower modulus but similar hardness to UiO‐66 thin films. The initial mechanical characterization indicates that further development is needed to leverage the mechanical property advantages of polyMOFs over MOFs. Additionally, the demonstration in this work of a continuous surface‐supported polyUiO‐66 thin film enables utilization of this emerging class of polyMOF materials in sensors and devices applications.

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Sponsoring Organization:: USDOE

OSTI ID:: 1843623

Journal Information:: ChemPhysChem, Journal Name: ChemPhysChem Journal Issue: 3 Vol. 23; ISSN 1439-4235

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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