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Title: An Exception to the Carothers Equation Caused by the Accelerated Chain Extension in a Pd/Ag Cocatalyzed Cross Dehydrogenative Coupling Polymerization

Journal Article · · Journal of the American Chemical Society
 [1];  [2]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4]
  1. Molecular Engineering & Sciences Institute, University of Washington, Seattle, Washington 98195, United States
  2. Center of Chemistry for Frontier Technologies, Department of Chemistry, State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China, Key Laboratory of Precise Synthesis of Functional Molecules of Zhejiang Province, School of Science, Westlake University, 18 Shilongshan Road, Hangzhou 310024, Zhejiang Province, China
  3. Department of Chemical and Biomolecular Engineering and Department of Chemistry and Biochemistry, University of California Los Angeles, Los Angeles, California 90095, United States
  4. Molecular Engineering & Sciences Institute, University of Washington, Seattle, Washington 98195, United States, Material Science & Engineering Department, University of Washington, Seattle, Washington 98195, United States, Department of Chemistry, University of Washington, Seattle, Washington 98195, United States

Not Available

Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC0020046
OSTI ID:
1843080
Journal Information:
Journal of the American Chemical Society, Journal Name: Journal of the American Chemical Society Journal Issue: 5 Vol. 144; ISSN 0002-7863
Publisher:
American Chemical SocietyCopyright Statement
Country of Publication:
United States
Language:
English

References (32)

Principles of Polymerization book January 2004
25th Anniversary Article: Organic Field-Effect Transistors: The Path Beyond Amorphous Silicon journal January 2014
The Palladium-Catalyzed Cross-Coupling Reactions of Organotin Reagents with Organic Electrophiles [New Synthetic Methods(58)] journal June 1986
Reaction Progress Kinetic Analysis: A Powerful Methodology for Mechanistic Studies of Complex Catalytic Reactions journal July 2005
Variable Time Normalization Analysis: General Graphical Elucidation of Reaction Orders from Concentration Profiles journal November 2016
Nonstoichiometric polycondensation I. synthesis of polythioether from dibromomethane and 4,4′-thiobisbenzenethiol journal October 2003
A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides journal January 1979
Conductive polymer-based sensors for biomedical applications journal January 2011
Recent advances in high performance donor-acceptor polymers for organic photovoltaics journal July 2017
Molar Mass versus Polymer Solar Cell Performance: Highlighting the Role of Homocouplings journal May 2015
A Direct C–H Coupling Method for Preparing π-Conjugated Functional Polymers with High Regioregularity journal January 2018
Mechanistic Origin of β-Defect Formation in Thiophene-Based Polymers Prepared by Direct (Hetero)arylation journal October 2018
Role of Silver Salts in Palladium-Catalyzed Arene and Heteroarene C–H Functionalization Reactions journal July 2016
C–H Acidity and Arene Nucleophilicity as Orthogonal Control of Chemoselectivity in Dual C–H Bond Activation journal March 2019
Oligothiophene Synthesis by a General C–H Activation Mechanism: Electrophilic Concerted Metalation–Deprotonation ( e CMD) journal June 2019
Mechanistic Study of Pd/Ag Dual-Catalyzed Cross-Dehydrogenative Coupling of Perfluoroarenes with Thiophenes journal February 2020
Nonstoichiometric Stille Coupling Polycondensation for Synthesizing Naphthalene-Diimide-Based π-Conjugated Polymers journal August 2015
Synthesis of Conjugated Polymers Containing Octafluorobiphenylene Unit via Pd-Catalyzed Cross-Dehydrogenative-Coupling Reaction journal December 2017
Palladium-Catalyzed C−H Homocoupling of Thiophenes:  Facile Construction of Bithiophene Structure journal April 2004
Homocoupling Defects in Diketopyrrolopyrrole-Based Copolymers and Their Effect on Photovoltaic Performance journal July 2014
Au-Catalyzed Cross-Coupling of Arenes via Double C–H Activation journal December 2015
Direct (Hetero)arylation Polymerization: Trends and Perspectives journal July 2016
High Molecular Weight Aromatic Polyformals Free of Macrocyclic Oligomers. A Condensative Chain Polymerization Reaction journal May 2001
Significance of Stoichiometric Imbalance in Step Polymerization via Reactive Intermediate journal July 1999
Synthesis of Thiophene- and Bithiophene-Based Alternating Copolymers via Pd-Catalyzed Direct C–H Arylation journal November 2011
Transition-State Metal Aryl Bond Stability Determines Regioselectivity in Palladium Acetate Mediated C–H Bond Activation of Heteroarenes journal July 2012
Low bandgap semiconducting polymers for polymeric photovoltaics journal January 2016
Exploration and development of gold- and silver-catalyzed cross dehydrogenative coupling toward donor–acceptor π-conjugated polymer synthesis journal January 2019
Advances in applying C–H functionalization and naturally sourced building blocks in organic semiconductor synthesis journal January 2021
Effect of synthetic accessibility on the commercial viability of organic photovoltaics journal January 2013
Polymers and polyfunctionality journal January 1936
The Catalytic Cross-Coupling of Unactivated Arenes journal May 2007