Elucidating the Effect of Borate Additive in High‐Voltage Electrolyte for Li‐Rich Layered Oxide Materials

Li, Yixuan; Li, Weikang; Shimizu, Ryosuke; Cheng, Diyi; Nguyen, HongNam; Paulsen, Jens; Kumakura, Shinichi; Zhang, Minghao; Meng, Ying Shirley

doi:10.1002/aenm.202103033

Title: Elucidating the Effect of Borate Additive in High‐Voltage Electrolyte for Li‐Rich Layered Oxide Materials

Journal Article · 28 January 2022 · Advanced Energy Materials

DOI: https://doi.org/10.1002/aenm.202103033 · OSTI ID:1842853

^[1]; Li, Weikang ^[1]; Shimizu, Ryosuke ^[1]; Cheng, Diyi ^[2]; Nguyen, HongNam ^[3]; Paulsen, Jens ^[3]; Kumakura, Shinichi ^[4]; Zhang, Minghao ^[1];

^[5]

Department of NanoEngineering University of California San Diego La Jolla CA 92093 USA
Department of Materials Science and Engineering University of California San Diego La Jolla CA 92093 USA
Umicore Korea Chungeonam‐do 31093 Republic of Korea
Umicore Japan Minato Tokyo 107‐0061 Japan
Department of NanoEngineering University of California San Diego La Jolla CA 92093 USA, Department of Materials Science and Engineering University of California San Diego La Jolla CA 92093 USA

Abstract Lithium‐rich layered oxides (LRLO) have attracted great interest for high‐energy Li‐ion batteries due to their high theoretical capacity. However, capacity decay and voltage fade during the cycling impede the practical application of LRLO. Herein, the use of lithium bis‐(oxalate)borate (LiBOB) as an electrolyte additive is reported to improve the cycling stability in high voltage LRLO/graphite full cells. The cell with LiBOB‐containing electrolyte delivers 248 mAh g ⁻¹ initial capacity and shows no capacity decay after 70 cycles as well as 95.5% retention after 150 cycles over 4.5 V cycling. A systematic mechanism study for the LiBOB‐enabled cycling performance improvement is conducted. Analytical electron microscopy under cryo‐condition confirms the formation of a uniform interphase and less phase transformation on the LRLO particle, accompanied by less voltage decay in the cathode. The formation of B‐F species is identified in the cycled electrolyte, elucidating the HF scavenger effect of LiBOB. Due to less HF corrosion on both electrode interphases, a reduced amount of transition metal dissolution and redeposition on the graphite is proved, thereby mitigating the capacity decay in LRLO/graphite full cells. These findings suggest that the borate additive is a promising strategy to optimize high voltage electrolyte for the industrialization of LRLO.

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Sponsoring Organization:: USDOE

OSTI ID:: 1842853

Journal Information:: Advanced Energy Materials, Journal Name: Advanced Energy Materials Journal Issue: 11 Vol. 12; ISSN 1614-6832

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Increased Cycling Performance of Li-Ion Batteries by Phosphoric Acid Modified LiNi _0.5 Mn _1.5 O ₄ Cathodes in the Presence of LiBOB Abeywardana, Maheeka Yapa; Laszczynski, Nina; Kuenzel, Matthias International Journal of Electrochemistry, Vol. 2019 https://doi.org/10.1155/2019/8636540	journal	July 2019

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