Synthesis of new two-dimensional titanium carbonitride Ti2C0.5N0.5Tx MXene and its performance as an electrode material for sodium-ion battery
Abstract
Two-dimensional (2D) layered transition metal carbides/nitrides, called MXenes, are attractive alternative electrode materials for electrochemical energy storage. Owing to their metallic electrical conductivity and low ion diffusion barrier, MXenes are promising anode materials for sodium-ion batteries (SIBs). Herein, we report on a new 2D carbonitride MXene, viz., Ti2C0.5N0.5Tx (Tx stands for surface terminations), and the only second carbonitride after Ti3CNTx so far. A new type of in situ HF (HCl/KF) etching condition was employed to synthesize multilayer Ti2C0.5N0.5Tx powders from Ti2AlC0.5N0.5. Spontaneous intercalation of tetramethylammonium followed by sonication in water allowed for large-scale delamination of this new titanium carbonitride into 2D sheets. Multilayer Ti2C0.5N0.5Tx powders showed higher specific capacities and larger electroactive surface area than those of Ti2CTx powders. Multilayer Ti2C0.5N0.5Tx powders show a specific capacity of 182 mAh g-1 at 20 mA g-1, the highest among all reported MXene electrodes as SIBs with excellent cycling stability.
- Authors:
-
[1];
[2];
[3];
[1];
[1]
- Tulane Univ., New Orleans, LA (United States)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1842650
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- InfoMat
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 12; Journal ID: ISSN 2567-3165
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; MXene; sodium-ion battery; titanium carbonitride; two-dimensional
Citation Formats
Liang, Kun, Tabassum, Anika, Majed, Ahmad, Dun, Chaochao, Yang, Feipeng, Guo, Jinghua, Prenger, Kaitlyn, Urban, Jeffrey J., and Naguib, Michael. Synthesis of new two-dimensional titanium carbonitride Ti2C0.5N0.5Tx MXene and its performance as an electrode material for sodium-ion battery. United States: N. p., 2021.
Web. doi:10.1002/inf2.12269.
Liang, Kun, Tabassum, Anika, Majed, Ahmad, Dun, Chaochao, Yang, Feipeng, Guo, Jinghua, Prenger, Kaitlyn, Urban, Jeffrey J., & Naguib, Michael. Synthesis of new two-dimensional titanium carbonitride Ti2C0.5N0.5Tx MXene and its performance as an electrode material for sodium-ion battery. United States. https://doi.org/10.1002/inf2.12269
Liang, Kun, Tabassum, Anika, Majed, Ahmad, Dun, Chaochao, Yang, Feipeng, Guo, Jinghua, Prenger, Kaitlyn, Urban, Jeffrey J., and Naguib, Michael. Sun .
"Synthesis of new two-dimensional titanium carbonitride Ti2C0.5N0.5Tx MXene and its performance as an electrode material for sodium-ion battery". United States. https://doi.org/10.1002/inf2.12269. https://www.osti.gov/servlets/purl/1842650.
@article{osti_1842650,
title = {Synthesis of new two-dimensional titanium carbonitride Ti2C0.5N0.5Tx MXene and its performance as an electrode material for sodium-ion battery},
author = {Liang, Kun and Tabassum, Anika and Majed, Ahmad and Dun, Chaochao and Yang, Feipeng and Guo, Jinghua and Prenger, Kaitlyn and Urban, Jeffrey J. and Naguib, Michael},
abstractNote = {Two-dimensional (2D) layered transition metal carbides/nitrides, called MXenes, are attractive alternative electrode materials for electrochemical energy storage. Owing to their metallic electrical conductivity and low ion diffusion barrier, MXenes are promising anode materials for sodium-ion batteries (SIBs). Herein, we report on a new 2D carbonitride MXene, viz., Ti2C0.5N0.5Tx (Tx stands for surface terminations), and the only second carbonitride after Ti3CNTx so far. A new type of in situ HF (HCl/KF) etching condition was employed to synthesize multilayer Ti2C0.5N0.5Tx powders from Ti2AlC0.5N0.5. Spontaneous intercalation of tetramethylammonium followed by sonication in water allowed for large-scale delamination of this new titanium carbonitride into 2D sheets. Multilayer Ti2C0.5N0.5Tx powders showed higher specific capacities and larger electroactive surface area than those of Ti2CTx powders. Multilayer Ti2C0.5N0.5Tx powders show a specific capacity of 182 mAh g-1 at 20 mA g-1, the highest among all reported MXene electrodes as SIBs with excellent cycling stability.},
doi = {10.1002/inf2.12269},
journal = {InfoMat},
number = 12,
volume = 3,
place = {United States},
year = {Sun Dec 12 00:00:00 EST 2021},
month = {Sun Dec 12 00:00:00 EST 2021}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Synthesis and characterization of two-dimensional Nb 4 C 3 (MXene)
journal, January 2014
- Ghidiu, M.; Naguib, M.; Shi, C.
- Chem. Commun., Vol. 50, Issue 67
Stamping of Flexible, Coplanar Micro-Supercapacitors Using MXene Inks
journal, January 2018
- Zhang, Chuanfang John; Kremer, Matthias P.; Seral-Ascaso, Andrés
- Advanced Functional Materials, Vol. 28, Issue 9
Metallic Ti 3 C 2 T x MXene Gas Sensors with Ultrahigh Signal-to-Noise Ratio
journal, January 2018
- Kim, Seon Joon; Koh, Hyeong-Jun; Ren, Chang E.
- ACS Nano, Vol. 12, Issue 2
Synthesis and Electromagnetic Absorbing Properties of Titanium Carbonitride with Quantificational Carbon Doping
journal, December 2015
- Hong, Xiangyun; Wang, Qun; Tang, Zhanghong
- The Journal of Physical Chemistry C, Vol. 120, Issue 1
An Outlook on Low-Volume-Change Lithium Metal Anodes for Long-Life Batteries
journal, May 2020
- Ye, Huan; Zhang, Ying; Yin, Ya-Xia
- ACS Central Science, Vol. 6, Issue 5
Tailoring Electronic and Optical Properties of MXenes through Forming Solid Solutions
journal, October 2020
- Han, Meikang; Maleski, Kathleen; Shuck, Christopher Eugene
- Journal of the American Chemical Society, Vol. 142, Issue 45
Efficient and cost-effective method to synthesize highly purified Ti 4 AlN 3 and Ti 2 AlN
journal, February 2019
- Ud Din, Muhammad Faraz; Yang, Chenhui; Tang, Yi
- Journal of Advanced Dielectrics, Vol. 09, Issue 01
PtSn nanoparticles supported on titanium carbonitride for the ethanol oxidation reaction
journal, December 2018
- Roca-Ayats, M.; Guillén-Villafuerte, O.; García, G.
- Applied Catalysis B: Environmental, Vol. 237
MXenes: Two-Dimensional Building Blocks for Future Materials and Devices
journal, April 2021
- Gogotsi, Yury; Huang, Qing
- ACS Nano, Vol. 15, Issue 4
Interwoven MXene Nanosheet/Carbon-Nanotube Composites as Li-S Cathode Hosts
journal, November 2016
- Liang, Xiao; Rangom, Yverick; Kwok, Chun Yuen
- Advanced Materials, Vol. 29, Issue 3
Intercalation and delamination of layered carbides and carbonitrides
journal, April 2013
- Mashtalir, Olha; Naguib, Michael; Mochalin, Vadym N.
- Nature Communications, Vol. 4, Issue 1
Role of Surface Structure on Li-Ion Energy Storage Capacity of Two-Dimensional Transition-Metal Carbides
journal, April 2014
- Xie, Yu; Naguib, Michael; Mochalin, Vadym N.
- Journal of the American Chemical Society, Vol. 136, Issue 17
Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes
journal, July 2020
- Kamysbayev, Vladislav; Filatov, Alexander S.; Hu, Huicheng
- Science, Vol. 369, Issue 6506
Ionic liquid-based synthesis of MXene
journal, January 2020
- Husmann, Samantha; Budak, Öznil; Shim, Hwirim
- Chemical Communications, Vol. 56, Issue 75
Large-scale delamination of multi-layers transition metal carbides and carbonitrides “MXenes”
journal, January 2015
- Naguib, Michael; Unocic, Raymond R.; Armstrong, Beth L.
- Dalton Transactions, Vol. 44, Issue 20
Two-Dimensional Transition Metal Carbides
journal, January 2012
- Naguib, Michael; Mashtalir, Olha; Carle, Joshua
- ACS Nano, Vol. 6, Issue 2
MOF-Derived CoSe2@N-Doped Carbon Matrix Confined in Hollow Mesoporous Carbon Nanospheres as High-Performance Anodes for Potassium-Ion Batteries
journal, October 2020
- Yang, Su Hyun; Park, Seung-Keun; Kang, Yun Chan
- Nano-Micro Letters, Vol. 13, Issue 1
Metallic MXene Saturable Absorber for Femtosecond Mode-Locked Lasers
journal, July 2017
- Jhon, Young In; Koo, Joonhoi; Anasori, Babak
- Advanced Materials, Vol. 29, Issue 40
Density functional theory study on the Ti3CN and Ti3CNT2 (T = O, S and F) as high capacity anode material for Na ion batteries
journal, November 2020
- Guo, Weibing; She, Zongyu; Xue, Haitao
- Applied Surface Science, Vol. 529
Exploring the Potentials of Ti 3 C i N 2– i T x ( i = 0, 1, 2)-MXene for Anode Materials of High-Performance Sodium-Ion Batteries
journal, May 2021
- Zhang, Wenshu; Liu, Siyang; Chen, Jian
- ACS Applied Materials & Interfaces, Vol. 13, Issue 19
Young’s Modulus and Tensile Strength of Ti 3 C 2 MXene Nanosheets As Revealed by In Situ TEM Probing, AFM Nanomechanical Mapping, and Theoretical Calculations
journal, July 2020
- Firestein, Konstantin L.; von Treifeldt, Joel E.; Kvashnin, Dmitry G.
- Nano Letters, Vol. 20, Issue 8
Porous Ti 3 C 2 T x MXene for Ultrahigh-Rate Sodium-Ion Storage with Long Cycle Life
journal, January 2018
- Xie, Xiuqiang; Kretschmer, Katja; Anasori, Babak
- ACS Applied Nano Materials, Vol. 1, Issue 2
Two-Dimensional Titanium Carbonitride Mxene for High-Performance Sodium Ion Batteries
journal, November 2018
- Zhu, Jingwen; Wang, Ming; Lyu, Miaoqiang
- ACS Applied Nano Materials, Vol. 1, Issue 12
Conductive two-dimensional titanium carbide ‘clay’ with high volumetric capacitance
journal, November 2014
- Ghidiu, Michael; Lukatskaya, Maria R.; Zhao, Meng-Qiang
- Nature, Vol. 516, Issue 7529
NiS 2 /FeS Holey Film as Freestanding Electrode for High-Performance Lithium Battery
journal, July 2017
- Liang, Kun; Marcus, Kyle; Zhang, Shoufeng
- Advanced Energy Materials, Vol. 7, Issue 22
Effects of Synthesis and Processing on Optoelectronic Properties of Titanium Carbonitride MXene
journal, March 2019
- Hantanasirisakul, Kanit; Alhabeb, Mohamed; Lipatov, Alexey
- Chemistry of Materials, Vol. 31, Issue 8
Periodically Patterned Au-TiO 2 Heterostructures for Photoelectrochemical Sensor
journal, April 2017
- Guo, Limin; Li, Zhao; Marcus, Kyle
- ACS Sensors, Vol. 2, Issue 5
Selective Etching of Silicon from Ti 3 SiC 2 (MAX) To Obtain 2D Titanium Carbide (MXene)
journal, March 2018
- Alhabeb, Mohamed; Maleski, Kathleen; Mathis, Tyler S.
- Angewandte Chemie International Edition, Vol. 57, Issue 19
Improved synthesis of Ti 3 C 2 T x MXenes resulting in exceptional electrical conductivity, high synthesis yield, and enhanced capacitance
journal, January 2021
- Shayesteh Zeraati, Ali; Mirkhani, Seyyed Alireza; Sun, Pengcheng
- Nanoscale, Vol. 13, Issue 6
Understanding Chemistry of Two-Dimensional Transition Metal Carbides and Carbonitrides (MXenes) with Gas Analysis
journal, July 2020
- Huang, Shuohan; Mochalin, Vadym N.
- ACS Nano, Vol. 14, Issue 8
A Two-Dimensional Lamellar Membrane: MXene Nanosheet Stacks
journal, January 2017
- Ding, Li; Wei, Yanying; Wang, Yanjie
- Angewandte Chemie, Vol. 129, Issue 7
Uniform yolk-shell iron sulfide–carbon nanospheres for superior sodium–iron sulfide batteries
journal, October 2015
- Wang, Yun-Xiao; Yang, Jianping; Chou, Shu-Lei
- Nature Communications, Vol. 6, Issue 1
Multiscale and Multimodal Characterization of 2D Titanium Carbonitride MXene
journal, April 2020
- Sun, Weiwei; Wang, Hsiu‐Wen; Vlcek, Lukas
- Advanced Materials Interfaces, Vol. 7, Issue 11
X-ray photoelectron spectroscopy of select multi-layered transition metal carbides (MXenes)
journal, January 2016
- Halim, Joseph; Cook, Kevin M.; Naguib, Michael
- Applied Surface Science, Vol. 362
Electronic properties and applications of MXenes: a theoretical review
journal, January 2017
- Khazaei, Mohammad; Ranjbar, Ahmad; Arai, Masao
- Journal of Materials Chemistry C, Vol. 5, Issue 10
Graphene-like titanium carbides and nitrides Tin+1Cn, Tin+1Nn (n=1, 2, and 3) from de-intercalated MAX phases: First-principles probing of their structural, electronic properties and relative stability
journal, December 2012
- Shein, I. R.; Ivanovskii, A. L.
- Computational Materials Science, Vol. 65
Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2
journal, August 2011
- Naguib, Michael; Kurtoglu, Murat; Presser, Volker
- Advanced Materials, Vol. 23, Issue 37, p. 4248-4253
Environmental Friendly Scalable Production of Colloidal 2D Titanium Carbonitride MXene with Minimized Nanosheets Restacking for Excellent Cycle Life Lithium-Ion Batteries
journal, May 2017
- Du, Fei; Tang, Huan; Pan, Limei
- Electrochimica Acta, Vol. 235
Two-Dimensional Molybdenum Carbide (MXene) as an Efficient Electrocatalyst for Hydrogen Evolution
journal, August 2016
- Seh, Zhi Wei; Fredrickson, Kurt D.; Anasori, Babak
- ACS Energy Letters, Vol. 1, Issue 3
Synthesis of Mo 4 VAlC 4 MAX Phase and Two-Dimensional Mo 4 VC 4 MXene with Five Atomic Layers of Transition Metals
journal, December 2019
- Deysher, Grayson; Shuck, Christopher Eugene; Hantanasirisakul, Kanit
- ACS Nano, Vol. 14, Issue 1
25th Anniversary Article: MXenes: A New Family of Two-Dimensional Materials
journal, December 2013
- Naguib, Michael; Mochalin, Vadym N.; Barsoum, Michel W.
- Advanced Materials, Vol. 26, Issue 7, p. 992-1005
Two-Dimensional Nb-Based M 4 C 3 Solid Solutions (MXenes)
journal, October 2015
- Yang, Jian; Naguib, Michael; Ghidiu, Michael
- Journal of the American Ceramic Society, Vol. 99, Issue 2
Promotion of oxygen reduction and water oxidation at Pt-based electrocatalysts by titanium carbonitride
journal, April 2016
- Roca-Ayats, M.; Herreros, E.; García, G.
- Applied Catalysis B: Environmental, Vol. 183
Anomalous absorption of electromagnetic
waves by 2D transition metal carbonitride
Ti3CNTx
(MXene)
journal, July 2020
- Iqbal, Aamir; Shahzad, Faisal; Hantanasirisakul, Kanit
- Science, Vol. 369, Issue 6502
Role of acid mixtures etching on the surface chemistry and sodium ion storage in Ti 3 C 2 T x MXene
journal, January 2020
- Anayee, Mark; Kurra, Narendra; Alhabeb, Mohamed
- Chemical Communications, Vol. 56, Issue 45
Synthesis of new M-layer solid-solution 312 MAX phases (Ta 1−x Ti x ) 3 AlC 2 ( x = 0.4, 0.62, 0.75, 0.91 or 0.95), and their corresponding MXenes
journal, January 2021
- Rigby, Maxwell T. P.; Natu, Varun; Sokol, Maxim
- RSC Advances, Vol. 11, Issue 5
Catalytic Activity of Ti‐based MXenes for the Hydrogenation of Furfural
journal, October 2020
- Naguib, Michael; Tang, Wenjie; Browning, Katie L.
- ChemCatChem, Vol. 12, Issue 22
High-throughput theoretical optimization of the hydrogen evolution reaction on MXenes by transition metal modification
journal, January 2018
- Li, Pengkun; Zhu, Jinguo; Handoko, Albertus D.
- Journal of Materials Chemistry A, Vol. 6, Issue 10
Synthesis and electrochemical properties of 2D molybdenum vanadium carbides – solid solution MXenes
journal, January 2020
- Pinto, David; Anasori, Babak; Avireddy, Hemesh
- Journal of Materials Chemistry A, Vol. 8, Issue 18
Ten Years of Progress in the Synthesis and Development of MXenes
journal, August 2021
- Naguib, Michael; Barsoum, Michel W.; Gogotsi, Yury
- Advanced Materials, Vol. 33, Issue 39
Sodium-Ion Intercalation Mechanism in MXene Nanosheets
journal, February 2016
- Kajiyama, Satoshi; Szabova, Lucie; Sodeyama, Keitaro
- ACS Nano, Vol. 10, Issue 3
High-Entropy 2D Carbide MXenes: TiVNbMoC 3 and TiVCrMoC 3
journal, June 2021
- Nemani, Srinivasa Kartik; Zhang, Bowen; Wyatt, Brian C.
- ACS Nano, Vol. 15, Issue 8
Processing and characterization of Ti2AlC, Ti2AlN, and Ti2AlC0.5N0.5
journal, July 2000
- Barsoum, M. W.; El-Raghy, T.; Ali, M.
- Metallurgical and Materials Transactions A, Vol. 31, Issue 7
A general Lewis acidic etching route for preparing MXenes with enhanced electrochemical performance in non-aqueous electrolyte
journal, April 2020
- Li, Youbing; Shao, Hui; Lin, Zifeng
- Nature Materials, Vol. 19, Issue 8
Transparent, conductive solution processed spincast 2D Ti 2 CT x (MXene) films
journal, March 2017
- Ying, Guobing; Dillon, Andrew D.; Fafarman, Aaron T.
- Materials Research Letters, Vol. 5, Issue 6
2D Ti3C2Tz MXene Synthesized by Water-free Etching of Ti3AlC2 in Polar Organic Solvents
journal, March 2020
- Natu, Varun; Pai, Rahul; Sokol, Maxim
- Chem, Vol. 6, Issue 3
Electrochemical performance of MXenes as K-ion battery anodes
journal, January 2017
- Naguib, Michael; Adams, Ryan A.; Zhao, Yunpu
- Chemical Communications, Vol. 53, Issue 51
Atomic-Scale Recognition of Surface Structure and Intercalation Mechanism of Ti 3 C 2 X
journal, February 2015
- Wang, Xuefeng; Shen, Xi; Gao, Yurui
- Journal of the American Chemical Society, Vol. 137, Issue 7
Element Replacement Approach by Reaction with Lewis Acidic Molten Salts to Synthesize Nanolaminated MAX Phases and MXenes
journal, March 2019
- Li, Mian; Lu, Jun; Luo, Kan
- Journal of the American Chemical Society, Vol. 141, Issue 11
Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides
journal, July 2017
- Lukatskaya, Maria R.; Kota, Sankalp; Lin, Zifeng
- Nature Energy, Vol. 2, Issue 8
2D metal carbides and nitrides (MXenes) for energy storage
journal, January 2017
- Anasori, Babak; Lukatskaya, Maria R.; Gogotsi, Yury
- Nature Reviews Materials, Vol. 2, Issue 2
Prediction and Characterization of MXene Nanosheet Anodes for Non-Lithium-Ion Batteries
journal, August 2014
- Xie, Yu; Dall’Agnese, Yohan; Naguib, Michael
- ACS Nano, Vol. 8, Issue 9