Application of Ionic Liquids for the Recycling and Recovery of Technologically Critical and Valuable Metals

Inman, Grace; Nlebedim, Ikenna C.; Prodius, Denis

doi:10.3390/en15020628

Title: Application of Ionic Liquids for the Recycling and Recovery of Technologically Critical and Valuable Metals

Journal Article · 17 January 2022 · Energies

DOI: https://doi.org/10.3390/en15020628 · OSTI ID:1842209

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Ames Lab., Ames, IA (United States)

Population growth has led to an increased demand for raw minerals and energy resources; however, their supply cannot easily be provided in the same proportions. Modern technologies contain materials that are becoming more finely intermixed because of the broadening palette of elements used, and this outcome creates certain limitations for recycling. The recovery and separation of individual elements, critical materials and valuable metals from complex systems requires complex energy-consuming solutions with many hazardous chemicals used. Significant pressure is brought to bear on the improvement of separation and recycling approaches by the need to balance sustainability, efficiency, and environmental impacts. Due to the increase in environmental consciousness in chemical research and industry, the challenge for a sustainable environment calls for clean procedures that avoid the use of harmful organic solvents. Ionic liquids, also known as molten salts and future solvents, are endowed with unique features that have already had a promising impact on cutting-edge science and technologies. This review aims to address the current challenges associated with the energy-efficient design, recovery, recycling, and separation of valuable metals employing ionic liquids.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Energy Efficiency Office. Advanced Manufacturing Office; USDOE Office of Science (SC), Workforce Development for Teachers and Scientists (WDTS)

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1842209

Report Number(s):: IS-J--10,703; Critical Materials Institute (3.3.13)

Journal Information:: Energies, Journal Name: Energies Journal Issue: 2 Vol. 15; ISSN 1996-1073

Publisher:: MDPICopyright Statement

Country of Publication:: United States

Language:: English

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Recycling of bonded NdFeB permanent magnets using ionic liquids Önal, Mehmet Ali Recai; Dewilde, Sven; Degri, Malik Green Chemistry, Vol. 22, Issue 9 https://doi.org/10.1039/D0GC00647E	journal	January 2020
Solvometallurgical recovery of cobalt from lithium-ion battery cathode materials using deep-eutectic solvents Peeters, Nand; Binnemans, Koen; Riaño, Sofía Green Chemistry, Vol. 22, Issue 13 https://doi.org/10.1039/D0GC00940G	journal	January 2020
Functionalized ionic liquids based on vegetable oils for rare earth elements recovery Li, Fujian; Zeng, Jingyao; Sun, Xiaoqi RSC Advances, Vol. 10, Issue 45 https://doi.org/10.1039/D0RA00448K	journal	January 2020
Effects of thiol substitution in deep-eutectic solvents (DESs) as solvents for metal oxides Damilano, Giacomo; Laitinen, Antero; Willberg-Keyriläinen, Pia RSC Advances, Vol. 10, Issue 39 https://doi.org/10.1039/D0RA03696J	journal	January 2020
Non-aqueous solvent extraction of indium from an ethylene glycol feed solution by the ionic liquid Cyphos IL 101: speciation study and continuous counter-current process in mixer–settlers Deferm, Clio; Onghena, Bieke; Nguyen, Viet Tu RSC Advances, Vol. 10, Issue 41 https://doi.org/10.1039/D0RA04684A	journal	January 2020
Recovery of yttrium and europium from spent fluorescent lamps using pure levulinic acid and the deep eutectic solvent levulinic acid–choline chloride Pateli, Ioanna M.; Abbott, Andrew P.; Binnemans, Koen RSC Advances, Vol. 10, Issue 48 https://doi.org/10.1039/D0RA05508E	journal	January 2020
Nanoscale electrodeposition of germanium on Au(111) from an ionic liquid: an in situ STM study of phase formation Endres, Frank; Zein El Abedin, Sherif Physical Chemistry Chemical Physics, Vol. 4, Issue 9 https://doi.org/10.1039/b110560b	journal	March 2002
Extraction separation of rare-earth ions via competitive ligand complexations between aqueous and ionic-liquid phases Sun, Xiaoqi; Bell, Jason R.; Luo, Huimin Dalton Transactions, Vol. 40, Issue 31 https://doi.org/10.1039/c1dt10873e	journal	January 2011
An environmentally friendlier approach to hydrometallurgy: highly selective separation of cobalt from nickel by solvent extraction with undiluted phosphonium ionic liquids Wellens, Sil; Thijs, Ben; Binnemans, Koen Green Chemistry, Vol. 14, Issue 6 https://doi.org/10.1039/c2gc35246j	journal	January 2012
Separation of cobalt and nickel by solvent extraction with two mutually immiscible ionic liquids Wellens, Sil; Thijs, Ben; Möller, Claudia Physical Chemistry Chemical Physics, Vol. 15, Issue 24 https://doi.org/10.1039/c3cp50819f	journal	January 2013
Liquid–liquid extraction of neodymium(iii) by dialkylphosphate ionic liquids from acidic medium: the importance of the ionic liquid cation Rout, Alok; Kotlarska, Justyna; Dehaen, Wim Physical Chemistry Chemical Physics, Vol. 15, Issue 39 https://doi.org/10.1039/c3cp52218k	journal	January 2013
Mechanistic investigation of solvent extraction based on anion-functionalized ionic liquids for selective separation of rare-earth ions Sun, Xiaoqi; Luo, Huimin; Dai, Sheng Dalton Transactions, Vol. 42, Issue 23 https://doi.org/10.1039/c3dt50148e	journal	January 2013
An americium-fueled gas core nuclear rocket Kammash, Terry; Galbraith, David L.; Jan, Ta-Rong Proceedings of the tenth symposium on space nuclear power and propulsion, AIP Conference Proceedings https://doi.org/10.1063/1.43073	conference	January 1993
Ionic Liquids—An Overview Forsyth, Stewart A.; Pringle, Jennifer M.; MacFarlane, Douglas R. Australian Journal of Chemistry, Vol. 57, Issue 2 https://doi.org/10.1071/CH03231	journal	January 2004
Recent Progress in Ionic Liquids and their Applications in Organic Synthesis Hajipour, Abdol R.; Rafiee, Fatemeh Organic Preparations and Procedures International, Vol. 47, Issue 4 https://doi.org/10.1080/00304948.2015.1052317	journal	June 2015
Extraction of Metal Ions with Task Specific Ionic Liquids: Influence of a Coordinating Anion Zhou, Yingsai; Boudesocque, Stéphanie; Mohamadou, Aminou Separation Science and Technology, Vol. 50, Issue 1 https://doi.org/10.1080/01496395.2014.952747	journal	December 2014
The Race for Critical Minerals in an Era of Geopolitical Realignments Kalantzakos, Sophia The International Spectator, Vol. 55, Issue 3 https://doi.org/10.1080/03932729.2020.1786926	journal	July 2020
Progress towards the Full Recovery of Neptunium in an Advanced PUREX Process Taylor, R. J.; Gregson, C. R.; Carrott, M. J. Solvent Extraction and Ion Exchange, Vol. 31, Issue 4 https://doi.org/10.1080/07366299.2013.800438	journal	July 2013
Selective Extraction of Americium from Curium and the Lanthanides by the Lipophilic Ligand CyMe ₄ BTPhen Dissolved in Aliquat-336 Nitrate Ionic Liquid Zsabka, Peter; Hecke, Karen Van; Wilden, Andreas Solvent Extraction and Ion Exchange, Vol. 38, Issue 2 https://doi.org/10.1080/07366299.2019.1708006	journal	January 2020
Solvent Extraction Studies for the Separation of Trivalent Actinides from Lanthanides with a Triazole-functionalized 1,10-phenanthroline Extractant Zsabka, Peter; Opsomer, Tomas; Van Hecke, Karen Solvent Extraction and Ion Exchange, Vol. 38, Issue 7 https://doi.org/10.1080/07366299.2020.1790105	journal	July 2020
A Review on Germanium Resources and its Extraction by Hydrometallurgical Method Nguyen, Thi Hong; Lee, Man Seung Mineral Processing and Extractive Metallurgy Review, Vol. 42, Issue 6 https://doi.org/10.1080/08827508.2020.1756795	journal	May 2020
CHEMISTRY: Ionic Liquids--Solvents of the Future? Rogers, R. D.; Seddon, Kenneth R. Science, Vol. 302, Issue 5646, p. 792-793 https://doi.org/10.1126/science.1090313	journal	October 2003
Metal-selective Deprotection-mediated Palladium(II) Extraction by Ionic Liquids with Tetrahydropyran-2 H -yl-protected Thiol Moieties Funaki, Kenji; Ma, Su; Kawamura, Shotaro Chemistry Letters, Vol. 46, Issue 4 https://doi.org/10.1246/cl.161153	journal	April 2017
Application of Ionic Liquids to Extraction Separation of Rare Earth Metals with an Effective Diglycol Amic Acid Extractant Kubota, Fukiko; Shimobori, Yousuke; Baba, Yuzo JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, Vol. 44, Issue 5 https://doi.org/10.1252/jcej.11we005	journal	January 2011
Dissolution of uranium oxides and electrochemical behavior of U(VI) in task specific ionic liquid Rao, Ch. Jagadeeswara; Venkatesan, K. A.; Nagarajan, K. Radiochimica Acta, Vol. 96, Issue 7, p. 403-409 https://doi.org/10.1524/ract.2008.1508	journal	July 2008
Reducing the Competition: A Dual-Purpose Ionic Liquid for the Extraction of Gallium from Iron Chloride Solutions M. M. Kinsman, Luke; A. Morrison, Carole; T. Ngwenya, Bryne Molecules, Vol. 25, Issue 18 https://doi.org/10.3390/molecules25184047	journal	September 2020
Removal of palladium(II) from aqueous chloride solutions with Cyphos phosphonium ionic liquids as metal ion carriers for liquid-liquid extraction and transport across polymer inclusion membranes Regel-Rosocka, Magdalena; Rzelewska, Martyna; Baczynska, Monika Faculty of Geoengineering, Mining and Geology, Wrocław University of Technology, Wrocław https://doi.org/10.5277/ppmp150221	text	January 2015

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