Boric acid removal with polyol-functionalized polyether membranes

Landsman, Matthew R.; Rivers, Frederick; Pedretti, Benjamin J.; Freeman, Benny D.; Lawler, Desmond F.; Lynd, Nathaniel A.; Katz, Lynn E.

doi:10.1016/j.memsci.2021.119690

Title: Boric acid removal with polyol-functionalized polyether membranes

Journal Article · 04 August 2021 · Journal of Membrane Science

DOI: https://doi.org/10.1016/j.memsci.2021.119690 · OSTI ID:1841757

^[1];

^[2];

^[2]; Freeman, Benny D. ^[2];

^[2]; Lynd, Nathaniel A. ^[2];

^[2]

Univ. of Texas, Austin, TX (United States); The University of Texas at Austin
Univ. of Texas, Austin, TX (United States)

Poor selectivity of conventional desalination membranes for boron often necessitates multi-stage treatment trains to achieve desired boron removal for end uses such as irrigation. One approach to membrane design for improved single-pass boric acid removal is via incorporation of chelating ligands that selectively sorb boron. In this study, membranes based on epoxy-amine cross-linked poly(glycidyl glycidyl ether) (PGGE) were synthesized and functionalized with N-methyl-d-glucamine (NMDG), a polyol known to interact selectively with boron. PGGE and PGGE-NMDG membranes exhibited boron sorption isotherms that were well-described by dual mode isotherms. PGGE-NMDG sorbed 2.5 mmol B/g dry polymer from a neutral aqueous solution containing 100 mmol B/L, which was almost three times the adsorption density of a commercial boron selective resin, Amberlite IRA743. Further, the membranes were regenerated in acid without a significant loss of boron sorption capacity over four cycles. Interactions between boron and NMDG and PGGE sites (e.g., epoxides) impacted boron diffusion in both membranes. The use of ligand functionalized membranes to capture target solutes such as boron requires high loading of interacting sites to maximize uptake capacity. Establishing fundamental structure/property rules for boron selectivity could lead to new material designs with improved boron separation properties for water purification.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0019272

OSTI ID:: 1841757

Journal Information:: Journal of Membrane Science, Journal Name: Journal of Membrane Science Vol. 638; ISSN 0376-7388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Boron
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Poly(allyl glycidyl ether)
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Title: Boric acid removal with polyol-functionalized polyether membranes

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